Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Cao, Yuhe; Zhang, Kuang; Sanyal, Oishi; Koros, William J.

doi:10.1002/anie.201906653

Title: Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Journal Article · 24 June 2019 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201906653 · OSTI ID:1594576

Cao, Yuhe ^[1]; Zhang, Kuang ^[2]; Sanyal, Oishi ^[2];

^[2]

Georgia Inst. of Technology, Atlanta, GA (United States); Georgia Tech
Georgia Inst. of Technology, Atlanta, GA (United States)

Dip coating and pyrolysis processes are needed to create multi-layer asymmetric carbon molecular sieve (CMS) hollow fiber membranes with excellent gas separation properties. Coating of an economical engineered support with a high-performance polyimide to create precursor fibers with a dense skin layer reduces material cost by 25-fold compared to monolithic precursors or ceramic supports. CMS permeation results with CO₂/CH₄ (50:50) mixed gas feed reflect attractive CO₂/CH₄ selectivity of 58.8 and CO₂ permeance of 310 GPU at 35 °C.

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Research Organization:: Georgia Inst. of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: FG02-04ER15510

OSTI ID:: 1594576

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 35 Vol. 58; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (28)

Ultrathin carbon molecular sieve membrane for propylene/propane separation Ma, Xiaoli; Lin, Y. S.; Wei, Xiaotong AIChE Journal, Vol. 62, Issue 2 https://doi.org/10.1002/aic.15005	journal	August 2015
High-Flux Carbon Molecular Sieve Membranes for Gas Separation Richter, Hannes; Voss, Hartwig; Kaltenborn, Nadine Angewandte Chemie, Vol. 129, Issue 27 https://doi.org/10.1002/ange.201701851	journal	June 2017
High-Flux Carbon Molecular Sieve Membranes for Gas Separation Richter, Hannes; Voss, Hartwig; Kaltenborn, Nadine Angewandte Chemie International Edition, Vol. 56, Issue 27 https://doi.org/10.1002/anie.201701851	journal	June 2017
Investigation of porosity of carbon materials and related effects on gas separation properties Steel, Keisha M.; Koros, William J. Carbon, Vol. 41, Issue 2 https://doi.org/10.1016/S0008-6223(02)00309-3	journal	February 2003
Preparation and gas permeation properties of carbon molecular sieve membranes based on sulfonated phenolic resin Zhou, Weiliang; Yoshino, Makoto; Kita, Hidetoshi Journal of Membrane Science, Vol. 217, Issue 1-2 https://doi.org/10.1016/S0376-7388(03)00074-7	journal	June 2003
Preparation of supported asymmetric carbon molecular sieve membranes Fuertes, A. B.; Centeno, T. A. Journal of Membrane Science, Vol. 144, Issue 1-2 https://doi.org/10.1016/S0376-7388(98)00037-4	journal	June 1998
Improvement of CO2/CH4 separation characteristics of polyimides by chemical crosslinking Staudt-Bickel, Claudia; J. Koros, William Journal of Membrane Science, Vol. 155, Issue 1 https://doi.org/10.1016/S0376-7388(98)00306-8	journal	March 1999
Supported carbon molecular sieve membranes based on a phenolic resin Centeno, Teresa A.; Fuertes, Antonio B. Journal of Membrane Science, Vol. 160, Issue 2 https://doi.org/10.1016/S0376-7388(99)00083-6	journal	July 1999
Carbon molecular sieve membranes from polyetherimide Fuertes, A. B.; Centeno, T. A. Microporous and Mesoporous Materials, Vol. 26, Issue 1-3 https://doi.org/10.1016/S1387-1811(98)00204-2	journal	December 1998
Fabrication of carbon membranes for gas separation––a review Saufi, S. M.; Ismail, A. F. Carbon, Vol. 42, Issue 2 https://doi.org/10.1016/j.carbon.2003.10.022	journal	January 2004
Separation of CO2/CH4 through carbon molecular sieve membranes derived from P84 polyimide Tin, Pei Shi; Chung, Tai-Shung; Liu, Ye Carbon, Vol. 42, Issue 15 https://doi.org/10.1016/j.carbon.2004.07.026	journal	January 2004
An investigation of the effects of pyrolysis parameters on gas separation properties of carbon materials Steel, Keisha M.; Koros, William J. Carbon, Vol. 43, Issue 9 https://doi.org/10.1016/j.carbon.2005.02.028	journal	August 2005
Effect of polymer precursors on carbon molecular sieve structure and separation performance properties Kiyono, Mayumi; Williams, Paul J.; Koros, William J. Carbon, Vol. 48, Issue 15 https://doi.org/10.1016/j.carbon.2010.08.002	journal	December 2010
Carbon molecular sieve gas separation membranes based on an intrinsically microporous polyimide precursor Ma, Xiaohua; Swaidan, Raja; Teng, Baiyang Carbon, Vol. 62 https://doi.org/10.1016/j.carbon.2013.05.057	journal	October 2013
Carbon molecular sieve membranes derived from Matrimid® polyimide for nitrogen/methane separation Ning, Xue; Koros, William J. Carbon, Vol. 66, p. 511-522 https://doi.org/10.1016/j.carbon.2013.09.028	journal	January 2014
New insights into structural evolution in carbon molecular sieve membranes during pyrolysis Adams, Jason S.; Itta, Arun K.; Zhang, Chen Carbon, Vol. 141 https://doi.org/10.1016/j.carbon.2018.09.039	journal	January 2019
Carbon molecular sieve membranes supported on non-modified ceramic tubes for hydrogen separation in membrane reactors Briceño, Kelly; Iulianelli, Adolfo; Montané, Daniel International Journal of Hydrogen Energy, Vol. 37, Issue 18 https://doi.org/10.1016/j.ijhydene.2012.06.069	journal	September 2012
Carbon molecular sieve membranes derived from thermally labile polymer containing blend polymers and their gas separation properties Kim, Youn Kook; Park, Ho Bum; Lee, Young Moo Journal of Membrane Science, Vol. 243, Issue 1-2 https://doi.org/10.1016/j.memsci.2004.05.001	journal	November 2004
Gas separation of 6FDA–6FpDA membranesEffect of the solvent on polymer surfaces and permselectivity Recio, R.; Palacio, L.; Pradanos, P. Journal of Membrane Science, Vol. 293, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.01.022	journal	April 2007
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Effect of pyrolysis temperature and operating temperature on the performance of nanoporous carbon membranes Anderson, Clare J.; Pas, Steven J.; Arora, Gaurav Journal of Membrane Science, Vol. 322, Issue 1 https://doi.org/10.1016/j.memsci.2008.04.064	journal	September 2008
Carbon membranes from blends of PBI and polyimides for N2/CH4 and CO2/CH4 separation and hydrogen purification Hosseini, Seyed Saeid; Chung, Tai Shung Journal of Membrane Science, Vol. 328, Issue 1-2 https://doi.org/10.1016/j.memsci.2008.12.005	journal	February 2009
High pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosity Swaidan, Raja; Ma, Xiaohua; Litwiller, Eric Journal of Membrane Science, Vol. 447 https://doi.org/10.1016/j.memsci.2013.07.057	journal	November 2013
Enhanced H2/CH4 and H2/CO2 separation by carbon molecular sieve membrane coated on titania modified alumina support: Effects of TiO2 intermediate layer preparation variables on interfacial adhesion Tseng, Hui-Hsin; Wang, Ching-Ting; Zhuang, Guo-Liang Journal of Membrane Science, Vol. 510 https://doi.org/10.1016/j.memsci.2016.02.036	journal	July 2016
Effect of block versus random copolyimide structure on hollow fiber membrane spinnability Qiu, Wulin; Liu, Lu; Koros, William J. Journal of Membrane Science, Vol. 529 https://doi.org/10.1016/j.memsci.2017.01.050	journal	May 2017
Cause and effects of hyperskin features on carbon molecular sieve (CMS) membranes Sanyal, Oishi; Hicks, Stephanie T.; Bhuwania, Nitesh Journal of Membrane Science, Vol. 551 https://doi.org/10.1016/j.memsci.2018.01.021	journal	April 2018
Preparation of Carbon Molecular Sieve Membrane and Diffusion of Binary Mixtures in the Membrane Chen, Y. D.; Yang, R. T. Industrial & Engineering Chemistry Research, Vol. 33, Issue 12 https://doi.org/10.1021/ie00036a033	journal	December 1994
Precursor Selection and Process Conditions in the Preparation of Carbon Membrane for Gas Separation: A Review Salleh, W. N. W.; Ismail, A. F.; Matsuura, T. Separation & Purification Reviews, Vol. 40, Issue 4 https://doi.org/10.1080/15422119.2011.555648	journal	April 2011

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