Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Cao, Yuhe; Zhang, Kuang; Sanyal, Oishi; Koros, William J.

doi:10.1002/anie.201906653

Title: Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

Journal Article · 25 June 2019 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201906653 · OSTI ID:1594576

Cao, Yuhe ^[1]; Zhang, Kuang ^[1]; Sanyal, Oishi ^[1];

^[1]

Georgia Inst. of Technology, Atlanta, GA (United States)

Abstract Dip coating and pyrolysis processes are used to create multi‐layer asymmetric carbon molecular sieve (CMS) hollow fiber membranes with excellent gas separation properties. Coating of an economical engineered support with a high‐performance polyimide to create precursor fibers with a dense skin layer reduces material cost by 25‐fold compared to monolithic precursors or ceramic supports. CMS permeation results with CO ₂ /CH ₄ (50:50) mixed gas feed show attractive CO ₂ /CH ₄ selectivity of 58.8 and CO ₂ permeance of 310 GPU at 35 °C.

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Research Organization:: Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE

Grant/Contract Number:: FG02-04ER15510

OSTI ID:: 1594576

Alternate ID(s):: OSTI ID: 1544900

Journal Information:: Angewandte Chemie (International Edition), Vol. 58, Issue 35; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 32 works

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Title: Carbon Molecular Sieve Membrane Preparation by Economical Coating and Pyrolysis of Porous Polymer Hollow Fibers

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