Distinguishing electronic contributions of surface and sub-surface transition metal atoms in Ti-based MXenes
- Authors:
-
[1];
[2];
[3];
[6];
[1];
[1]
- Drexel Univ., Philadelphia, PA (United States)
- Univ. of Pennsylvania, Philadelphia, PA (United States)
- Drexel Univ., Philadelphia, PA (United States); Indiana Univ.—Purdue Univ. Indianapolis, IN (United States)
- Univ. of Saskatchewan, Saskatoon, SK (Canada); Univ. of British Columbia, Vancouver, BC (Canada)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Cornell Univ., Ithaca, NY (United States)
- Publication Date:
- Research Org.:
- Drexel Univ., Philadelphia, PA (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Science Foundation (NSF); Department of Defense (DoD)
- OSTI Identifier:
- 1594224
- Alternate Identifier(s):
- OSTI ID: 1635482
- Report Number(s):
- BNL-216104-2020-JAAM
Journal ID: ISSN 2053-1583
- Grant/Contract Number:
- SC0018618; SC0012704; W911NF-16-1-0447; EFMA-542879; CMMI-1727717; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- 2D Materials
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 2; Journal ID: ISSN 2053-1583
- Publisher:
- IOP Publishing
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; MXene; x-ray absorption spectroscopy; electronic structure; titanium
Citation Formats
Yang, Yizhou, Hantanasirisakul, Kanit, Frey, Nathan C., Anasori, Babak, Green, Robert J., Rogge, Paul C., Waluyo, Iradwikanari, Hunt, Adrian, Shafer, Padraic, Arenholz, Elke, Shenoy, Vivek B., Gogotsi, Yury, and May, Steven J. Distinguishing electronic contributions of surface and sub-surface transition metal atoms in Ti-based MXenes. United States: N. p., 2020.
Web. doi:10.1088/2053-1583/ab68e7.
Yang, Yizhou, Hantanasirisakul, Kanit, Frey, Nathan C., Anasori, Babak, Green, Robert J., Rogge, Paul C., Waluyo, Iradwikanari, Hunt, Adrian, Shafer, Padraic, Arenholz, Elke, Shenoy, Vivek B., Gogotsi, Yury, & May, Steven J. Distinguishing electronic contributions of surface and sub-surface transition metal atoms in Ti-based MXenes. United States. doi:10.1088/2053-1583/ab68e7.
Yang, Yizhou, Hantanasirisakul, Kanit, Frey, Nathan C., Anasori, Babak, Green, Robert J., Rogge, Paul C., Waluyo, Iradwikanari, Hunt, Adrian, Shafer, Padraic, Arenholz, Elke, Shenoy, Vivek B., Gogotsi, Yury, and May, Steven J. Wed .
"Distinguishing electronic contributions of surface and sub-surface transition metal atoms in Ti-based MXenes". United States. doi:10.1088/2053-1583/ab68e7. https://www.osti.gov/servlets/purl/1594224.
@article{osti_1594224,
title = {Distinguishing electronic contributions of surface and sub-surface transition metal atoms in Ti-based MXenes},
author = {Yang, Yizhou and Hantanasirisakul, Kanit and Frey, Nathan C. and Anasori, Babak and Green, Robert J. and Rogge, Paul C. and Waluyo, Iradwikanari and Hunt, Adrian and Shafer, Padraic and Arenholz, Elke and Shenoy, Vivek B. and Gogotsi, Yury and May, Steven J.},
abstractNote = {},
doi = {10.1088/2053-1583/ab68e7},
journal = {2D Materials},
number = 2,
volume = 7,
place = {United States},
year = {2020},
month = {2}
}
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Works referenced in this record:
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
journal, August 2011
- Naguib, Michael; Kurtoglu, Murat; Presser, Volker
- Advanced Materials, Vol. 23, Issue 37, p. 4248-4253
25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials
journal, December 2013
- Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W.
- Advanced Materials, Vol. 26, Issue 7, p. 992-1005
Surface and Heterointerface Engineering of 2D MXenes and Their Nanocomposites: Insights into Electro- and Photocatalysis
journal, January 2019
- Peng, Jiahe; Chen, Xingzhu; Ong, Wee-Jun
- Chem, Vol. 5, Issue 1
Recent advances in MXenes: From fundamentals to applications
journal, June 2019
- Khazaei, Mohammad; Mishra, Avanish; Venkataramanan, Natarajan S.
- Current Opinion in Solid State and Materials Science, Vol. 23, Issue 3
Pseudocapacitive Electrodes Produced by Oxidant-Free Polymerization of Pyrrole between the Layers of 2D Titanium Carbide (MXene)
journal, December 2015
- Boota, Muhammad; Anasori, Babak; Voigt, Cooper
- Advanced Materials, Vol. 28, Issue 7
MXene: a promising transition metal carbide anode for lithium-ion batteries
journal, March 2012
- Naguib, Michael; Come, Jérémy; Dyatkin, Boris
- Electrochemistry Communications, Vol. 16, Issue 1, p. 61-64
Nitrogen-doped Ti 3 C 2 T x MXene electrodes for high-performance supercapacitors
journal, August 2017
- Wen, Yangyang; Rufford, Thomas E.; Chen, Xingzhu
- Nano Energy, Vol. 38
A Non-Aqueous Asymmetric Cell with a Ti 2 C-Based Two-Dimensional Negative Electrode
journal, January 2012
- Come, J.; Naguib, M.; Rozier, P.
- Journal of The Electrochemical Society, Vol. 159, Issue 8
2D metal carbides and nitrides (MXenes) for energy storage
journal, January 2017
- Anasori, Babak; Lukatskaya, Maria R.; Gogotsi, Yury
- Nature Reviews Materials, Vol. 2, Issue 2
Electromagnetic interference shielding with 2D transition metal carbides (MXenes)
journal, September 2016
- Shahzad, F.; Alhabeb, M.; Hatter, C. B.
- Science, Vol. 353, Issue 6304
Ti 3 C 2 MXene: a promising microwave absorbing material
journal, January 2018
- Feng, Wanlin; Luo, Heng; Wang, Yu
- RSC Advances, Vol. 8, Issue 5
Ti 3 C 2 MXenes with Modified Surface for High-Performance Electromagnetic Absorption and Shielding in the X-Band
journal, August 2016
- Han, Meikang; Yin, Xiaowei; Wu, Heng
- ACS Applied Materials & Interfaces, Vol. 8, Issue 32
Hydrophobic, Flexible, and Lightweight MXene Foams for High-Performance Electromagnetic-Interference Shielding
journal, August 2017
- Liu, Ji; Zhang, Hao-Bin; Sun, Renhui
- Advanced Materials, Vol. 29, Issue 38
2D MXenes: Electromagnetic property for microwave absorption and electromagnetic interference shielding
journal, March 2019
- Cao, Mao-Sheng; Cai, Yong-Zhu; He, Peng
- Chemical Engineering Journal, Vol. 359
Enhanced Terahertz Shielding of MXenes with Nano-Metamaterials
journal, January 2018
- Choi, Geunchang; Shahzad, Faisal; Bahk, Young-Mi
- Advanced Optical Materials, Vol. 6, Issue 5
2D titanium carbide (MXene) for wireless communication
journal, September 2018
- Sarycheva, Asia; Polemi, Alessia; Liu, Yuqiao
- Science Advances, Vol. 4, Issue 9
Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)
journal, August 2015
- Anasori, Babak; Xie, Yu; Beidaghi, Majid
- ACS Nano, Vol. 9, Issue 10
Double transition metal MXenes with wide band gaps and novel magnetic properties
journal, January 2018
- Sun, Weiwei; Xie, Yu; Kent, Paul R. C.
- Nanoscale, Vol. 10, Issue 25
Two-dimensional Mo1.33C MXene with divacancy ordering prepared from parent 3D laminate with in-plane chemical ordering
journal, April 2017
- Tao, Quanzheng; Dahlqvist, Martin; Lu, Jun
- Nature Communications, Vol. 8, Issue 1
Two-Dimensional Transition Metal Carbides
journal, January 2012
- Naguib, Michael; Mashtalir, Olha; Carle, Joshua
- ACS Nano, Vol. 6, Issue 2
(Cr 2/3 Ti 1/3 ) 3 AlC 2 and (Cr 5/8 Ti 3/8 ) 4 AlC 3 : New MAX-phase Compounds in Ti-Cr-Al-C System
journal, December 2013
- Liu, Zhimou; Zheng, Liya; Sun, Luchao
- Journal of the American Ceramic Society, Vol. 97, Issue 1
Control of electronic properties of 2D carbides (MXenes) by manipulating their transition metal layers
journal, January 2016
- Anasori, Babak; Shi, Chenyang; Moon, Eun Ju
- Nanoscale Horizons, Vol. 1, Issue 3
Electronic properties and applications of MXenes: a theoretical review
journal, January 2017
- Khazaei, Mohammad; Ranjbar, Ahmad; Arai, Masao
- Journal of Materials Chemistry C, Vol. 5, Issue 10
Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes)
journal, November 2018
- Hantanasirisakul, Kanit; Gogotsi, Yury
- Advanced Materials, Vol. 30, Issue 52
Understanding the MXene Pseudocapacitance
journal, February 2018
- Zhan, Cheng; Naguib, Michael; Lukatskaya, Maria
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 6
Control of MXenes’ electronic properties through termination and intercalation
journal, January 2019
- Hart, James L.; Hantanasirisakul, Kanit; Lang, Andrew C.
- Nature Communications, Vol. 10, Issue 1
Large-Area Highly Conductive Transparent Two-Dimensional Ti 2 CT x Film
journal, January 2017
- Yang, Yajie; Umrao, Sima; Lai, Shen
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 4
Surface group modification and carrier transport properties of layered transition metal carbides (Ti 2 CT x , T: –OH, –F and –O)
journal, January 2015
- Lai, Shen; Jeon, Jaeho; Jang, Sung Kyu
- Nanoscale, Vol. 7, Issue 46
Oxide Thin-Film Electronics using All-MXene Electrical Contacts
journal, February 2018
- Wang, Zhenwei; Kim, Hyunho; Alshareef, Husam N.
- Advanced Materials, Vol. 30, Issue 15
Effects of Synthesis and Processing on Optoelectronic Properties of Titanium Carbonitride MXene
journal, March 2019
- Hantanasirisakul, Kanit; Alhabeb, Mohamed; Lipatov, Alexey
- Chemistry of Materials, Vol. 31, Issue 8
Variable range hopping and thermally activated transport in molybdenum-based MXenes
journal, September 2018
- Halim, Joseph; Moon, Eun Ju; Eklund, Per
- Physical Review B, Vol. 98, Issue 10
Topological insulators in the ordered double transition metals MXenes ( , W; , Zr, Hf)
journal, September 2016
- Khazaei, Mohammad; Ranjbar, Ahmad; Arai, Masao
- Physical Review B, Vol. 94, Issue 12
Theoretical prediction of two-dimensional functionalized MXene nitrides as topological insulators
journal, November 2017
- Liang, Yunye; Khazaei, Mohammad; Ranjbar, Ahmad
- Physical Review B, Vol. 96, Issue 19
Large-gap two-dimensional topological insulator in oxygen functionalized MXene
journal, August 2015
- Weng, Hongming; Ranjbar, Ahmad; Liang, Yunye
- Physical Review B, Vol. 92, Issue 7
Large-Gap Quantum Spin Hall State in MXenes: d -Band Topological Order in a Triangular Lattice
journal, September 2016
- Si, Chen; Jin, Kyung-Hwan; Zhou, Jian
- Nano Letters, Vol. 16, Issue 10
Controlling topological electronic structure of multifunctional MXene layer
journal, August 2018
- Balcı, Erdem; Akkuş, Ünal Özden; Berber, Savas
- Applied Physics Letters, Vol. 113, Issue 8
Doped Sc 2 C(OH) 2 MXene: new type s-pd band inversion topological insulator
journal, March 2018
- Balcı, Erdem; Akkuş, Ünal Özden; Berber, Savas
- Journal of Physics: Condensed Matter, Vol. 30, Issue 15
High and anisotropic carrier mobility in experimentally possible Ti 2 CO 2 (MXene) monolayers and nanoribbons
journal, January 2015
- Zhang, Xu; Zhao, Xudong; Wu, Dihua
- Nanoscale, Vol. 7, Issue 38
Rational Design of Two-Dimensional Metallic and Semiconducting Spintronic Materials Based on Ordered Double-Transition-Metal MXenes
journal, January 2017
- Dong, Liang; Kumar, Hemant; Anasori, Babak
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 2
High-Throughput Survey of Ordering Configurations in MXene Alloys Across Compositions and Temperatures
journal, March 2017
- Tan, Teck Leong; Jin, Hong Mei; Sullivan, Michael B.
- ACS Nano, Vol. 11, Issue 5
Tuning Noncollinear Spin Structure and Anisotropy in Ferromagnetic Nitride MXenes
journal, May 2018
- Frey, Nathan C.; Kumar, Hemant; Anasori, Babak
- ACS Nano, Vol. 12, Issue 6
Fe 2 C monolayer: An intrinsic ferromagnetic MXene
journal, July 2017
- Yue, Yunliang
- Journal of Magnetism and Magnetic Materials, Vol. 434
Cold Sintered Ceramic Nanocomposites of 2D MXene and Zinc Oxide
journal, June 2018
- Guo, Jing; Legum, Benjamin; Anasori, Babak
- Advanced Materials, Vol. 30, Issue 32
Probing the impact of magnetic interactions on the lattice dynamics of two-dimensional Ti 2 X (X = C, N) MXenes
journal, January 2018
- Sternik, Małgorzata; Wdowik, Urszula D.
- Physical Chemistry Chemical Physics, Vol. 20, Issue 11
Tuning magnetic properties of Cr2M2C3T2 (M = Ti and V) using extensile strain
journal, November 2017
- Yang, Jianhui; Luo, Xuepiao; Zhou, Xumeng
- Computational Materials Science, Vol. 139
Prediction of MXene based 2D tunable band gap semiconductors: GW quasiparticle calculations
journal, January 2019
- Zhang, Yujuan; Xia, Weiyi; Wu, Yabei
- Nanoscale, Vol. 11, Issue 9
MXene: a promising photocatalyst for water splitting
journal, January 2016
- Guo, Zhonglu; Zhou, Jian; Zhu, Linggang
- Journal of Materials Chemistry A, Vol. 4, Issue 29
Half-Metallic Ferromagnetism and Surface Functionalization-Induced Metal–Insulator Transition in Graphene-like Two-Dimensional Cr 2 C Crystals
journal, August 2015
- Si, Chen; Zhou, Jian; Sun, Zhimei
- ACS Applied Materials & Interfaces, Vol. 7, Issue 31
X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes)
journal, January 2016
- Halim, Joseph; Cook, Kevin M.; Naguib, Michael
- Applied Surface Science, Vol. 362
Resolving the Structure of Ti 3 C 2 T x MXenes through Multilevel Structural Modeling of the Atomic Pair Distribution Function
journal, December 2015
- Wang, Hsiu-Wen; Naguib, Michael; Page, Katharine
- Chemistry of Materials, Vol. 28, Issue 1
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Tunable electronic and magnetic properties of Cr 2 M′C 2 T 2 (M′ = Ti or V; T = O, OH or F)
journal, November 2016
- Yang, Jianhui; Zhou, Xumeng; Luo, Xuepiao
- Applied Physics Letters, Vol. 109, Issue 20
On the Chemical Diversity of the MAX Phases
journal, May 2019
- Sokol, Maxim; Natu, Varun; Kota, Sankalp
- Trends in Chemistry, Vol. 1, Issue 2
Crystal structure and formation mechanism of (Cr2/3Ti1/3)3AlC2 MAX phase
journal, July 2014
- Liu, Zhimou; Wu, Erdong; Wang, Jiemin
- Acta Materialia, Vol. 73
Ti 2p X-ray absorption in titanium dioxides (TiO 2 ): the influence of the cation site environment
journal, December 1994
- Crocombette, J. P.; Jollet, F.
- Journal of Physics: Condensed Matter, Vol. 6, Issue 49
In-Situ Analysis of Valence Conversion in Transition Metal Oxides Using Electron Energy-Loss Spectroscopy
journal, August 1997
- Wang, Zhong L.; Yin, Jin S.; Mo, Wei Dong
- The Journal of Physical Chemistry B, Vol. 101, Issue 35
Atomic-resolution imaging of oxidation states in manganites
journal, February 2009
- Varela, M.; Oxley, M. P.; Luo, W.
- Physical Review B, Vol. 79, Issue 8
Oxide Wizard: An EELS Application to Characterize the White Lines of Transition Metal Edges
journal, April 2014
- Yedra, Lluís; Xuriguera, Elena; Estrader, Marta
- Microscopy and Microanalysis, Vol. 20, Issue 3
White lines and d -electron occupancies for the 3 d and 4 d transition metals
journal, April 1993
- Pearson, D. H.; Ahn, C. C.; Fultz, B.
- Physical Review B, Vol. 47, Issue 14
Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films
journal, March 2014
- Halim, Joseph; Lukatskaya, Maria R.; Cook, Kevin M.
- Chemistry of Materials, Vol. 26, Issue 7
Surface Termination Dependent Work Function and Electronic Properties of Ti 3 C 2 T x MXene
journal, December 2018
- Schultz, Thorsten; Frey, Nathan C.; Hantanasirisakul, Kanit
- Chemistry of Materials, Vol. 31, Issue 17
Hybrid density functional study of structural and electronic properties of functionalized Ti ( , N) monolayers
journal, June 2013
- Xie, Yu; Kent, P. R. C.
- Physical Review B, Vol. 87, Issue 23
Optical properties of functionalized Ti 3 C 2 T 2 (T = F, O, OH) MXene: First-principles calculations
journal, May 2016
- Berdiyorov, G. R.
- AIP Advances, Vol. 6, Issue 5
Dependence of elastic and optical properties on surface terminated groups in two-dimensional MXene monolayers: a first-principles study
journal, January 2016
- Bai, Yuelei; Zhou, Kun; Srikanth, Narasimalu
- RSC Advances, Vol. 6, Issue 42