Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {Ni II 8} complex with a trapezoidal prismatic topology
Abstract
The synthesis of a new {Ni 8} cluster bearing tetrazolate- and azido-bridging ligands, and supported by chelating α-methyl-2-pyridine-methanol (mpmH) groups, is described herein. The reported compound has a unique trapezoidal prismatic topology, resulting from an unexpected in situ click reaction between the MeCN reaction solvent and the N 3- ions under mild, room-temperature conditions. Such a click chemistry approach to the preparation of 0-D compounds is relatively unexplored and represents a fruitful strategy for the synthesis of new coordination clusters and molecule-based magnetic materials.
- Authors:
-
[2];
[3];
[1];
[4]
- Brock Univ., St. Catharines ON (Canada)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Univ. de Barcelona (Spain)
- Brock Univ., St. Catharines ON (Canada); Univ. of Patras (Greece)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- OSTI Identifier:
- 1593493
- Alternate Identifier(s):
- OSTI ID: 1531184; OSTI ID: 1581603
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Published Article
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Volume: 48; Journal Issue: 31; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Abbasi, Parisa, Athanasopoulou, Angeliki A., Mazarakioti, Eleni C., Gagnon, Kevin J., Teat, Simon J., Escuer, Albert, Pilkington, Melanie, and Stamatatos, Theocharis C. Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology. United States: N. p., 2019.
Web. doi:10.1039/c9dt01998g.
Abbasi, Parisa, Athanasopoulou, Angeliki A., Mazarakioti, Eleni C., Gagnon, Kevin J., Teat, Simon J., Escuer, Albert, Pilkington, Melanie, & Stamatatos, Theocharis C. Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology. United States. doi:10.1039/c9dt01998g.
Abbasi, Parisa, Athanasopoulou, Angeliki A., Mazarakioti, Eleni C., Gagnon, Kevin J., Teat, Simon J., Escuer, Albert, Pilkington, Melanie, and Stamatatos, Theocharis C. Thu .
"Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology". United States. doi:10.1039/c9dt01998g.
@article{osti_1593493,
title = {Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology},
author = {Abbasi, Parisa and Athanasopoulou, Angeliki A. and Mazarakioti, Eleni C. and Gagnon, Kevin J. and Teat, Simon J. and Escuer, Albert and Pilkington, Melanie and Stamatatos, Theocharis C.},
abstractNote = {The synthesis of a new {Ni8} cluster bearing tetrazolate- and azido-bridging ligands, and supported by chelating α-methyl-2-pyridine-methanol (mpmH) groups, is described herein. The reported compound has a unique trapezoidal prismatic topology, resulting from an unexpected in situ click reaction between the MeCN reaction solvent and the N3- ions under mild, room-temperature conditions. Such a click chemistry approach to the preparation of 0-D compounds is relatively unexplored and represents a fruitful strategy for the synthesis of new coordination clusters and molecule-based magnetic materials.},
doi = {10.1039/c9dt01998g},
journal = {Dalton Transactions},
number = 31,
volume = 48,
place = {United States},
year = {2019},
month = {6}
}
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DOI: 10.1039/c9dt01998g
DOI: 10.1039/c9dt01998g
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