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Title: Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology

Abstract

A {Ni 8 } cluster with trapezoidal prismatic topology was prepared via the click reaction between MeCN and N 3 ions.

Authors:
 [1];  [1];  [1];  [2]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, 1812 Sir Isaac Brock Way, Brock University, Canada
  2. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, USA
  3. Department de Quimica Inorgànica i Orgànica, Secció Inorgànica and Institut de Nanociència i Nanotecnologia (IN2UB), Universitat de Barcelona, 08028 Barcelona, Spain
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1593493
Alternate Identifier(s):
OSTI ID: 1531184; OSTI ID: 1581603
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 31; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United Kingdom
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Abbasi, Parisa, Athanasopoulou, Angeliki A., Mazarakioti, Eleni C., Gagnon, Kevin J., Teat, Simon J., Escuer, Albert, Pilkington, Melanie, and Stamatatos, Theocharis C. Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT01998G.
Abbasi, Parisa, Athanasopoulou, Angeliki A., Mazarakioti, Eleni C., Gagnon, Kevin J., Teat, Simon J., Escuer, Albert, Pilkington, Melanie, & Stamatatos, Theocharis C. Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology. United Kingdom. doi:10.1039/C9DT01998G.
Abbasi, Parisa, Athanasopoulou, Angeliki A., Mazarakioti, Eleni C., Gagnon, Kevin J., Teat, Simon J., Escuer, Albert, Pilkington, Melanie, and Stamatatos, Theocharis C. Tue . "Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology". United Kingdom. doi:10.1039/C9DT01998G.
@article{osti_1593493,
title = {Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology},
author = {Abbasi, Parisa and Athanasopoulou, Angeliki A. and Mazarakioti, Eleni C. and Gagnon, Kevin J. and Teat, Simon J. and Escuer, Albert and Pilkington, Melanie and Stamatatos, Theocharis C.},
abstractNote = {A {Ni 8 } cluster with trapezoidal prismatic topology was prepared via the click reaction between MeCN and N 3 − ions.},
doi = {10.1039/C9DT01998G},
journal = {Dalton Transactions},
number = 31,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9DT01998G

Citation Metrics:
Cited by: 1 work
Citation information provided by
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Works referenced in this record:

Self-Assembly of Thiacalix[4]arene-Supported Nickel(II)/Cobalt(II) Complexes Sustained by in Situ Generated 5-Methyltetrazolate Ligand
journal, May 2012

  • Xiong, Kecai; Jiang, Feilong; Gai, Yanli
  • Crystal Growth & Design, Vol. 12, Issue 6
  • DOI: 10.1021/cg300483c

Waterproof architectures through subcomponent self-assembly
journal, January 2019

  • Percástegui, Edmundo G.; Mosquera, Jesús; Ronson, Tanya K.
  • Chemical Science, Vol. 10, Issue 7
  • DOI: 10.1039/C8SC05085F

Click Chemistry: Diverse Chemical Function from a Few Good Reactions
journal, June 2001


Effective dehydrogenation of 2-pyridylmethanol derivatives catalyzed by an iron complex
journal, January 2014

  • Kamitani, Masahiro; Ito, Masaki; Itazaki, Masumi
  • Chem. Commun., Vol. 50, Issue 59
  • DOI: 10.1039/C4CC01498G

Diol-type ligands as central ‘players’ in the chemistry of high-spin molecules and single-molecule magnets
journal, January 2008

  • Tasiopoulos, Anastasios J.; Perlepes, Spyros P.
  • Dalton Transactions, Issue 41
  • DOI: 10.1039/b805014g

Bis-tris propane as a flexible ligand for high-nuclearity complexes
journal, August 2018


Preparation of 5-Substituted 1 H -Tetrazoles from Nitriles in Water
journal, November 2001

  • Demko, Zachary P.; Sharpless, K. Barry
  • The Journal of Organic Chemistry, Vol. 66, Issue 24
  • DOI: 10.1021/jo010635w

Cu-Catalyzed Azide−Alkyne Cycloaddition
journal, August 2008

  • Meldal, Morten; Tornøe, Christian Wenzel
  • Chemical Reviews, Vol. 108, Issue 8
  • DOI: 10.1021/cr0783479

Using tripodal alcohols to build high-spin molecules and single-molecule magnets
journal, January 2005


Polyhedral Metal-Imidazolate Cages: Control of Self-Assembly and Cage to Cage Transformation
journal, October 2013

  • Zhou, Xiao-Ping; Wu, Yuan; Li, Dan
  • Journal of the American Chemical Society, Vol. 135, Issue 43
  • DOI: 10.1021/ja4092984

Tripodal Tetraamine Ligands Containing Three Pyridine Units: Theother Polypyridyl Ligands
journal, June 2008


An Improved Synthesis of 5-Substituted Tetrazoles
journal, August 1958

  • Finnegan, William G.; Henry, Ronald A.; Lofquist, Robert
  • Journal of the American Chemical Society, Vol. 80, Issue 15
  • DOI: 10.1021/ja01548a028

Unprecedented chemical transformation: crystallographic evidence for 1,1,2,2-tetrahydroxyethane captured within an Fe6Dy3 single molecule magnet
journal, January 2013

  • Schmidt, Sebastian; Prodius, Denis; Mereacre, Valeriu
  • Chemical Communications, Vol. 49, Issue 17
  • DOI: 10.1039/c2cc38006d

A Polyoxometalate Containing the{Ni2N3} Fragment: Ferromagnetic Coupling in a NiIIμ-1,1 Azido Complex with a Large Bridging Angle
journal, April 2004

  • Mialane, Pierre; Dolbecq, Anne; Rivière, Eric
  • Angewandte Chemie International Edition, Vol. 43, Issue 17
  • DOI: 10.1002/anie.200353433

A novel high-spin tridecanuclear Ni II cluster with an azido-bridged core exhibiting disk-like topology
journal, January 2012

  • Brunet, Gabriel; Habib, Fatemah; Cook, Cyril
  • Chem. Commun., Vol. 48, Issue 9
  • DOI: 10.1039/C2CC16221K

Rational linkage of magnetic molecules using click chemistry
journal, January 2015

  • Plenk, Christian; Krause, Jasmin; Beck, Martin
  • Chemical Communications, Vol. 51, Issue 30
  • DOI: 10.1039/C5CC00595G

Directed assembly of metal–organic cubes from deliberately predesigned molecular building blocks
journal, January 2004

  • Liu, Yunling; Kravtsov, Victor; Walsh, Rosa D.
  • Chem. Commun., Issue 24
  • DOI: 10.1039/B409459J

Targeted construction of azido-bridged Ni 4 complexes with decisive effect of µ-1,3-azide torsion on the spin ground state
journal, January 2006

  • Demeshko, Serhiy; Leibeling, Guido; Dechert, Sebastian
  • Dalton Trans., Issue 28
  • DOI: 10.1039/B517254C

Nucleophilic Addition of Water and Alcohols to Dicyanonitrosomethanide: Ligands with Diverse Bonding Modes in Magnetically Coupled d-Block Complexes
journal, November 2009

  • Chesman, Anthony S. R.; Turner, David R.; Moubaraki, Boujemaa
  • European Journal of Inorganic Chemistry, Vol. 2010, Issue 1
  • DOI: 10.1002/ejic.200900779

A Mn 6 Cluster inside a Mn 10 Wheel: Characterization of a Mn 16 -Oximate Complex Resulting from a Tetrazole-2-pyridylketoneoximate Ligand : A Mn
journal, January 2015

  • Alcazar, Laura; Font-Bardia, Mercè; Escuer, Albert
  • European Journal of Inorganic Chemistry, Vol. 2015, Issue 8
  • DOI: 10.1002/ejic.201403128

Ground state spin-switching via targeted structural distortion: twisted single-molecule magnets from derivatised salicylaldoximes
journal, January 2008

  • Milios, Constantinos J.; Piligkos, Stergios; Brechin, Euan K.
  • Dalton Trans., Issue 14
  • DOI: 10.1039/B716355J

Mechanisms of Tetrazole Formation by Addition of Azide to Nitriles
journal, October 2002

  • Himo, Fahmi; Demko, Zachary P.; Noodleman, Louis
  • Journal of the American Chemical Society, Vol. 124, Issue 41
  • DOI: 10.1021/ja0206644

Versatility of Azide in Serendipitous Assembly of Copper(II) Magnetic Polyclusters
journal, June 2013

  • Mukherjee, Sandip; Mukherjee, Partha Sarathi
  • Accounts of Chemical Research, Vol. 46, Issue 11
  • DOI: 10.1021/ar400059q

Magnetic Coupling in End-On Azido-Bridged Transition Metal Complexes:  A Density Functional Study
journal, November 1998

  • Ruiz, Eliseo; Cano, Joan; Alvarez, Santiago
  • Journal of the American Chemical Society, Vol. 120, Issue 43
  • DOI: 10.1021/ja981661n

The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry
journal, September 2014

  • Escuer, Albert; Esteban, Jordi; Perlepes, Spyros P.
  • Coordination Chemistry Reviews, Vol. 275
  • DOI: 10.1016/j.ccr.2014.04.001

Octanuclear Ni( ii ) cubes based on halogen-substituted pyrazolates: synthesis, structure, electrochemistry and magnetism
journal, January 2016

  • Wang, Zhi; Jagličić, Zvonko; Han, Lu-Lu
  • CrystEngComm, Vol. 18, Issue 19
  • DOI: 10.1039/C6CE00528D

Synthesis, crystal and molecular structure and magnetic properties of [Ni3(L1)4(NCS)4(OH)2(OH2)2](L1= 2,5-diamino-1,3,4-thiadiazole)
journal, January 1991

  • Fabretti, Antonio C.; Malavasi, Wanda; Gatteschi, Dante
  • Journal of the Chemical Society, Dalton Transactions, Issue 9
  • DOI: 10.1039/dt9910002331

Reversible shrinkage and expansion of a blue photofluorescent cadmium coordination polymer and in situ tetrazole ligand synthesis
journal, January 2008

  • Deng, Hong; Qiu, Yong-Cai; Li, Ying-Hua
  • Chemical Communications, Issue 19
  • DOI: 10.1039/b800938d

In situ tetrazole templated chair-like decanuclear azido-cobalt( ii ) SMM containing both tetra- and octa-hedral Co( ii ) ions
journal, January 2015

  • Zhang, Yuan-Zhu; Gao, Song; Sato, Osamu
  • Dalton Transactions, Vol. 44, Issue 2
  • DOI: 10.1039/C4DT03211J

Transition Metal Single-Molecule Magnets: A {Mn 31 } Nanosized Cluster with a Large Energy Barrier of ∼60 K and Magnetic Hysteresis at ∼5 K
journal, October 2017

  • Abbasi, Parisa; Quinn, Kevan; Alexandropoulos, Dimitris I.
  • Journal of the American Chemical Society, Vol. 139, Issue 44
  • DOI: 10.1021/jacs.7b10130

The growing applications of click chemistry
journal, January 2007

  • Moses, John E.; Moorhouse, Adam D.
  • Chem. Soc. Rev., Vol. 36, Issue 8
  • DOI: 10.1039/B613014N

Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions
journal, January 2016

  • Papatriantafyllopoulou, Constantina; Moushi, Eleni E.; Christou, George
  • Chemical Society Reviews, Vol. 45, Issue 6
  • DOI: 10.1039/C5CS00590F

Decorating Diruthenium Compounds with Fréchet Dendrons via the Click Reaction
journal, October 2011

  • Forrest, William P.; Cao, Zhi; Chen, Wei-Zhong
  • Inorganic Chemistry, Vol. 50, Issue 19
  • DOI: 10.1021/ic200929r

In situhydrothermal synthesis of tetrazole coordination polymers with interesting physical properties
journal, January 2008

  • Zhao, Hong; Qu, Zhi-Rong; Ye, Heng-Yun
  • Chem. Soc. Rev., Vol. 37, Issue 1
  • DOI: 10.1039/B616738C

A Polyoxometalate Containing the{Ni2N3} Fragment: Ferromagnetic Coupling in a NiIIμ-1,1 Azido Complex with a Large Bridging Angle
journal, April 2004

  • Mialane, Pierre; Dolbecq, Anne; Rivière, Eric
  • Angewandte Chemie, Vol. 116, Issue 17
  • DOI: 10.1002/ange.200353433

    Works referencing / citing this record:

    Click Chemistry: Diverse Chemical Function from a Few Good Reactions
    journal, June 2001


    A Polyoxometalate Containing the{Ni2N3} Fragment: Ferromagnetic Coupling in a NiIIμ-1,1 Azido Complex with a Large Bridging Angle
    journal, April 2004

    • Mialane, Pierre; Dolbecq, Anne; Rivière, Eric
    • Angewandte Chemie International Edition, Vol. 43, Issue 17
    • DOI: 10.1002/anie.200353433

    Tripodal Tetraamine Ligands Containing Three Pyridine Units: Theother Polypyridyl Ligands
    journal, June 2008


    Nucleophilic Addition of Water and Alcohols to Dicyanonitrosomethanide: Ligands with Diverse Bonding Modes in Magnetically Coupled d-Block Complexes
    journal, November 2009

    • Chesman, Anthony S. R.; Turner, David R.; Moubaraki, Boujemaa
    • European Journal of Inorganic Chemistry, Vol. 2010, Issue 1
    • DOI: 10.1002/ejic.200900779

    A Mn 6 Cluster inside a Mn 10 Wheel: Characterization of a Mn 16 -Oximate Complex Resulting from a Tetrazole-2-pyridylketoneoximate Ligand : A Mn
    journal, January 2015

    • Alcazar, Laura; Font-Bardia, Mercè; Escuer, Albert
    • European Journal of Inorganic Chemistry, Vol. 2015, Issue 8
    • DOI: 10.1002/ejic.201403128

    The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry
    journal, September 2014

    • Escuer, Albert; Esteban, Jordi; Perlepes, Spyros P.
    • Coordination Chemistry Reviews, Vol. 275
    • DOI: 10.1016/j.ccr.2014.04.001

    Bis-tris propane as a flexible ligand for high-nuclearity complexes
    journal, August 2018


    Versatility of Azide in Serendipitous Assembly of Copper(II) Magnetic Polyclusters
    journal, June 2013

    • Mukherjee, Sandip; Mukherjee, Partha Sarathi
    • Accounts of Chemical Research, Vol. 46, Issue 11
    • DOI: 10.1021/ar400059q

    Self-Assembly of Thiacalix[4]arene-Supported Nickel(II)/Cobalt(II) Complexes Sustained by in Situ Generated 5-Methyltetrazolate Ligand
    journal, May 2012

    • Xiong, Kecai; Jiang, Feilong; Gai, Yanli
    • Crystal Growth & Design, Vol. 12, Issue 6
    • DOI: 10.1021/cg300483c

    Cu-Catalyzed Azide−Alkyne Cycloaddition
    journal, August 2008

    • Meldal, Morten; Tornøe, Christian Wenzel
    • Chemical Reviews, Vol. 108, Issue 8
    • DOI: 10.1021/cr0783479

    Decorating Diruthenium Compounds with Fréchet Dendrons via the Click Reaction
    journal, October 2011

    • Forrest, William P.; Cao, Zhi; Chen, Wei-Zhong
    • Inorganic Chemistry, Vol. 50, Issue 19
    • DOI: 10.1021/ic200929r

    An Improved Synthesis of 5-Substituted Tetrazoles
    journal, August 1958

    • Finnegan, William G.; Henry, Ronald A.; Lofquist, Robert
    • Journal of the American Chemical Society, Vol. 80, Issue 15
    • DOI: 10.1021/ja01548a028

    Mechanisms of Tetrazole Formation by Addition of Azide to Nitriles
    journal, October 2002

    • Himo, Fahmi; Demko, Zachary P.; Noodleman, Louis
    • Journal of the American Chemical Society, Vol. 124, Issue 41
    • DOI: 10.1021/ja0206644

    Polyhedral Metal-Imidazolate Cages: Control of Self-Assembly and Cage to Cage Transformation
    journal, October 2013

    • Zhou, Xiao-Ping; Wu, Yuan; Li, Dan
    • Journal of the American Chemical Society, Vol. 135, Issue 43
    • DOI: 10.1021/ja4092984

    Magnetic Coupling in End-On Azido-Bridged Transition Metal Complexes:  A Density Functional Study
    journal, November 1998

    • Ruiz, Eliseo; Cano, Joan; Alvarez, Santiago
    • Journal of the American Chemical Society, Vol. 120, Issue 43
    • DOI: 10.1021/ja981661n

    Transition Metal Single-Molecule Magnets: A {Mn 31 } Nanosized Cluster with a Large Energy Barrier of ∼60 K and Magnetic Hysteresis at ∼5 K
    journal, October 2017

    • Abbasi, Parisa; Quinn, Kevan; Alexandropoulos, Dimitris I.
    • Journal of the American Chemical Society, Vol. 139, Issue 44
    • DOI: 10.1021/jacs.7b10130

    Preparation of 5-Substituted 1 H -Tetrazoles from Nitriles in Water
    journal, November 2001

    • Demko, Zachary P.; Sharpless, K. Barry
    • The Journal of Organic Chemistry, Vol. 66, Issue 24
    • DOI: 10.1021/jo010635w

    Directed assembly of metal–organic cubes from deliberately predesigned molecular building blocks
    journal, January 2004

    • Liu, Yunling; Kravtsov, Victor; Walsh, Rosa D.
    • Chem. Commun., Issue 24
    • DOI: 10.1039/b409459j

    Using tripodal alcohols to build high-spin molecules and single-molecule magnets
    journal, January 2005


    Targeted construction of azido-bridged Ni 4 complexes with decisive effect of µ-1,3-azide torsion on the spin ground state
    journal, January 2006

    • Demeshko, Serhiy; Leibeling, Guido; Dechert, Sebastian
    • Dalton Trans., Issue 28
    • DOI: 10.1039/b517254c

    The growing applications of click chemistry
    journal, January 2007

    • Moses, John E.; Moorhouse, Adam D.
    • Chem. Soc. Rev., Vol. 36, Issue 8
    • DOI: 10.1039/b613014n

    In situhydrothermal synthesis of tetrazole coordination polymers with interesting physical properties
    journal, January 2008

    • Zhao, Hong; Qu, Zhi-Rong; Ye, Heng-Yun
    • Chem. Soc. Rev., Vol. 37, Issue 1
    • DOI: 10.1039/b616738c

    Ground state spin-switching via targeted structural distortion: twisted single-molecule magnets from derivatised salicylaldoximes
    journal, January 2008

    • Milios, Constantinos J.; Piligkos, Stergios; Brechin, Euan K.
    • Dalton Trans., Issue 14
    • DOI: 10.1039/b716355j

    Reversible shrinkage and expansion of a blue photofluorescent cadmium coordination polymer and in situ tetrazole ligand synthesis
    journal, January 2008

    • Deng, Hong; Qiu, Yong-Cai; Li, Ying-Hua
    • Chemical Communications, Issue 19
    • DOI: 10.1039/b800938d

    Diol-type ligands as central ‘players’ in the chemistry of high-spin molecules and single-molecule magnets
    journal, January 2008

    • Tasiopoulos, Anastasios J.; Perlepes, Spyros P.
    • Dalton Transactions, Issue 41
    • DOI: 10.1039/b805014g

    A novel high-spin tridecanuclear Ni II cluster with an azido-bridged core exhibiting disk-like topology
    journal, January 2012

    • Brunet, Gabriel; Habib, Fatemah; Cook, Cyril
    • Chem. Commun., Vol. 48, Issue 9
    • DOI: 10.1039/c2cc16221k

    Unprecedented chemical transformation: crystallographic evidence for 1,1,2,2-tetrahydroxyethane captured within an Fe6Dy3 single molecule magnet
    journal, January 2013

    • Schmidt, Sebastian; Prodius, Denis; Mereacre, Valeriu
    • Chemical Communications, Vol. 49, Issue 17
    • DOI: 10.1039/c2cc38006d

    Effective dehydrogenation of 2-pyridylmethanol derivatives catalyzed by an iron complex
    journal, January 2014

    • Kamitani, Masahiro; Ito, Masaki; Itazaki, Masumi
    • Chem. Commun., Vol. 50, Issue 59
    • DOI: 10.1039/c4cc01498g

    In situ tetrazole templated chair-like decanuclear azido-cobalt( ii ) SMM containing both tetra- and octa-hedral Co( ii ) ions
    journal, January 2015

    • Zhang, Yuan-Zhu; Gao, Song; Sato, Osamu
    • Dalton Transactions, Vol. 44, Issue 2
    • DOI: 10.1039/c4dt03211j

    Rational linkage of magnetic molecules using click chemistry
    journal, January 2015

    • Plenk, Christian; Krause, Jasmin; Beck, Martin
    • Chemical Communications, Vol. 51, Issue 30
    • DOI: 10.1039/c5cc00595g

    Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions
    journal, January 2016

    • Papatriantafyllopoulou, Constantina; Moushi, Eleni E.; Christou, George
    • Chemical Society Reviews, Vol. 45, Issue 6
    • DOI: 10.1039/c5cs00590f

    Octanuclear Ni( ii ) cubes based on halogen-substituted pyrazolates: synthesis, structure, electrochemistry and magnetism
    journal, January 2016

    • Wang, Zhi; Jagličić, Zvonko; Han, Lu-Lu
    • CrystEngComm, Vol. 18, Issue 19
    • DOI: 10.1039/c6ce00528d

    Waterproof architectures through subcomponent self-assembly
    journal, January 2019

    • Percástegui, Edmundo G.; Mosquera, Jesús; Ronson, Tanya K.
    • Chemical Science, Vol. 10, Issue 7
    • DOI: 10.1039/c8sc05085f

    Synthesis, crystal and molecular structure and magnetic properties of [Ni3(L1)4(NCS)4(OH)2(OH2)2](L1= 2,5-diamino-1,3,4-thiadiazole)
    journal, January 1991

    • Fabretti, Antonio C.; Malavasi, Wanda; Gatteschi, Dante
    • Journal of the Chemical Society, Dalton Transactions, Issue 9
    • DOI: 10.1039/dt9910002331