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Title: Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {Ni II 8} complex with a trapezoidal prismatic topology

Abstract

The synthesis of a new {Ni 8} cluster bearing tetrazolate- and azido-bridging ligands, and supported by chelating α-methyl-2-pyridine-methanol (mpmH) groups, is described herein. The reported compound has a unique trapezoidal prismatic topology, resulting from an unexpected in situ click reaction between the MeCN reaction solvent and the N 3- ions under mild, room-temperature conditions. Such a click chemistry approach to the preparation of 0-D compounds is relatively unexplored and represents a fruitful strategy for the synthesis of new coordination clusters and molecule-based magnetic materials.

Authors:
 [1];  [1];  [1];  [2]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]; ORCiD logo [4]
  1. Brock Univ., St. Catharines ON (Canada)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  3. Univ. de Barcelona (Spain)
  4. Brock Univ., St. Catharines ON (Canada); Univ. of Patras (Greece)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1593493
Alternate Identifier(s):
OSTI ID: 1531184; OSTI ID: 1581603
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 48; Journal Issue: 31; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Abbasi, Parisa, Athanasopoulou, Angeliki A., Mazarakioti, Eleni C., Gagnon, Kevin J., Teat, Simon J., Escuer, Albert, Pilkington, Melanie, and Stamatatos, Theocharis C. Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology. United States: N. p., 2019. Web. doi:10.1039/c9dt01998g.
Abbasi, Parisa, Athanasopoulou, Angeliki A., Mazarakioti, Eleni C., Gagnon, Kevin J., Teat, Simon J., Escuer, Albert, Pilkington, Melanie, & Stamatatos, Theocharis C. Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology. United States. doi:10.1039/c9dt01998g.
Abbasi, Parisa, Athanasopoulou, Angeliki A., Mazarakioti, Eleni C., Gagnon, Kevin J., Teat, Simon J., Escuer, Albert, Pilkington, Melanie, and Stamatatos, Theocharis C. Thu . "Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology". United States. doi:10.1039/c9dt01998g.
@article{osti_1593493,
title = {Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology},
author = {Abbasi, Parisa and Athanasopoulou, Angeliki A. and Mazarakioti, Eleni C. and Gagnon, Kevin J. and Teat, Simon J. and Escuer, Albert and Pilkington, Melanie and Stamatatos, Theocharis C.},
abstractNote = {The synthesis of a new {Ni8} cluster bearing tetrazolate- and azido-bridging ligands, and supported by chelating α-methyl-2-pyridine-methanol (mpmH) groups, is described herein. The reported compound has a unique trapezoidal prismatic topology, resulting from an unexpected in situ click reaction between the MeCN reaction solvent and the N3- ions under mild, room-temperature conditions. Such a click chemistry approach to the preparation of 0-D compounds is relatively unexplored and represents a fruitful strategy for the synthesis of new coordination clusters and molecule-based magnetic materials.},
doi = {10.1039/c9dt01998g},
journal = {Dalton Transactions},
number = 31,
volume = 48,
place = {United States},
year = {2019},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/c9dt01998g

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