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Title: In-depth understanding of the CO 2 limitation of air fed anion exchange membrane fuel cells

Abstract

Ex situ physico-chemical, electrochemical, and morphological analysis sheds light on the CO 2 limitation of ambient air anion exchange membrane fuel cells.

Authors:
 [1];  [2];  [2];  [2];  [1];  [3];  [3];  [2]; ORCiD logo [1]
  1. Department of Chemical and Biological Engineering, Colorado School of Mines, Golden, USA
  2. National Renewable Energy Laboratory, Golden, USA
  3. Advanced Photon Source, Argonne National Laboratory, Lemont, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1593485
Grant/Contract Number:  
AC02-06CH11357; AC36-08GO28308
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Sustainable Energy & Fuels
Additional Journal Information:
Journal Name: Sustainable Energy & Fuels; Journal ID: ISSN 2398-4902
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Divekar, Ashutosh G., Yang-Neyerlin, Ami C., Antunes, Christopher M., Strasser, Derek J., Motz, Andrew R., Seifert, Soenke S., Zuo, Xiaobing, Pivovar, Bryan S., and Herring, Andrew M. In-depth understanding of the CO 2 limitation of air fed anion exchange membrane fuel cells. United Kingdom: N. p., 2020. Web. doi:10.1039/C9SE01212E.
Divekar, Ashutosh G., Yang-Neyerlin, Ami C., Antunes, Christopher M., Strasser, Derek J., Motz, Andrew R., Seifert, Soenke S., Zuo, Xiaobing, Pivovar, Bryan S., & Herring, Andrew M. In-depth understanding of the CO 2 limitation of air fed anion exchange membrane fuel cells. United Kingdom. doi:10.1039/C9SE01212E.
Divekar, Ashutosh G., Yang-Neyerlin, Ami C., Antunes, Christopher M., Strasser, Derek J., Motz, Andrew R., Seifert, Soenke S., Zuo, Xiaobing, Pivovar, Bryan S., and Herring, Andrew M. Wed . "In-depth understanding of the CO 2 limitation of air fed anion exchange membrane fuel cells". United Kingdom. doi:10.1039/C9SE01212E.
@article{osti_1593485,
title = {In-depth understanding of the CO 2 limitation of air fed anion exchange membrane fuel cells},
author = {Divekar, Ashutosh G. and Yang-Neyerlin, Ami C. and Antunes, Christopher M. and Strasser, Derek J. and Motz, Andrew R. and Seifert, Soenke S. and Zuo, Xiaobing and Pivovar, Bryan S. and Herring, Andrew M.},
abstractNote = {Ex situ physico-chemical, electrochemical, and morphological analysis sheds light on the CO 2 limitation of ambient air anion exchange membrane fuel cells.},
doi = {10.1039/C9SE01212E},
journal = {Sustainable Energy & Fuels},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on January 3, 2021
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Works referenced in this record:

Mathematical Modeling of the Concentration Profile of Carbonate Ions in an Anion Exchange Membrane Fuel Cell
journal, January 2011

  • Siroma, Z.; Watanabe, S.; Yasuda, K.
  • Journal of The Electrochemical Society, Vol. 158, Issue 6
  • DOI: 10.1149/1.3576120

The impact of alkyl tri‐methyl ammonium side chains on perfluorinated ionic membranes for electrochemical applications
journal, March 2019

  • Divekar, Ashutosh G.; Kuo, Mei‐Chen; Park, Andrew M.
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 57, Issue 11
  • DOI: 10.1002/polb.24825

Review of cell performance in anion exchange membrane fuel cells
journal, January 2018


Quantifying and elucidating the effect of CO 2 on the thermodynamics, kinetics and charge transport of AEMFCs
journal, January 2019

  • Zheng, Yiwei; Omasta, Travis J.; Peng, Xiong
  • Energy & Environmental Science, Vol. 12, Issue 9
  • DOI: 10.1039/C9EE01334B

Impact of carbonation processes in anion exchange membrane fuel cells
journal, February 2018


Bicarbonate and chloride anion transport in anion exchange membranes
journal, September 2016


Insight into the multiscale structure of pre-stretched recast Nafion® membranes: Focus on the crystallinity features
journal, April 2015


Along-the-Channel Impacts of Water Management and Carbon-Dioxide Contamination in Hydroxide-Exchange-Membrane Fuel Cells: A Modeling Study
journal, January 2019

  • Gerhardt, Michael R.; Pant, Lalit M.; Weber, Adam Z.
  • Journal of The Electrochemical Society, Vol. 166, Issue 7
  • DOI: 10.1149/2.0171907jes

A Study of Carbonate Formation Kinetics and Morphological Effects Observed on OH - Form of Pfaem When Exposed to Air Containing CO 2
journal, August 2017

  • Divekar, Ashutosh G.; Park, Andrew Michael; Owczarczyk, Zbyslaw R.
  • ECS Transactions, Vol. 80, Issue 8
  • DOI: 10.1149/08008.1005ecst

Anionic polysulfone ionomers and membranes containing fluorenyl groups for anionic fuel cells
journal, May 2009


Synthesis and characterization of perfluoro quaternary ammonium anion exchange membranes
journal, September 2012

  • Vandiver, Melissa A.; Horan, James L.; Yang, Yuan
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 24
  • DOI: 10.1002/polb.23171

Beyond catalysis and membranes: visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs
journal, January 2018

  • Omasta, Travis J.; Park, Andrew M.; LaManna, Jacob M.
  • Energy & Environmental Science, Vol. 11, Issue 3
  • DOI: 10.1039/C8EE00122G

Interplay between water uptake, ion interactions, and conductivity in an e-beam grafted poly(ethylene-co-tetrafluoroethylene) anion exchange membrane
journal, January 2015

  • Pandey, Tara P.; Maes, Ashley M.; Sarode, Himanshu N.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 6
  • DOI: 10.1039/C4CP05755D

H2/air alkaline membrane fuel cell performance and durability, using novel ionomer and non-platinum group metal cathode catalyst
journal, September 2010


Anion-exchange membranes in electrochemical energy systems
journal, January 2014

  • Varcoe, John R.; Atanassov, Plamen; Dekel, Dario R.
  • Energy & Environmental Science, Vol. 7, Issue 10, p. 3135-3191
  • DOI: 10.1039/C4EE01303D

Carbonation effects on the performance of alkaline polymer electrolyte fuel cells
journal, June 2015


Effects of Carbon Dioxide on the Performance of Anion-Exchange Membrane Fuel Cells
journal, January 2011


Determination of Carbonate Ion in MEA during the Alkaline Membrane Fuel Cell (AMFC) Operation
conference, January 2010

  • Watanabe, Shin; Fukuta, Kenji; Yanagi, Hiroyuki
  • 218th ECS Meeting, ECS Transactions
  • DOI: 10.1149/1.3484674

A practical method for measuring the true hydroxide conductivity of anion exchange membranes
journal, March 2018


Interplay between Structure and Relaxations in Perfluorosulfonic Acid Proton Conducting Membranes
journal, December 2012

  • Giffin, Guinevere A.; Haugen, Gregory M.; Hamrock, Steven J.
  • Journal of the American Chemical Society, Vol. 135, Issue 2
  • DOI: 10.1021/ja3099799

The nature and transport mechanism of hydrated hydroxide ions in aqueous solution
journal, June 2002

  • Tuckerman, Mark E.; Marx, Dominik; Parrinello, Michele
  • Nature, Vol. 417, Issue 6892
  • DOI: 10.1038/nature00797

Corrigendum to “Characterization and use of anionic membranes for alkaline fuel cells”
journal, March 2002


Anion Exchange Membrane Ionic Conductivity in the Presence of Carbon Dioxide under Fuel Cell Operating Conditions
journal, January 2017

  • Wrubel, Jacob A.; Peracchio, Aldo A.; Cassenti, Brice N.
  • Journal of The Electrochemical Society, Vol. 164, Issue 12
  • DOI: 10.1149/2.0331712jes

Effect of humidity on the interaction of CO2 with alkaline anion exchange membranes probed using the quartz crystal microbalance
journal, September 2017


New Insights into Perfluorinated Sulfonic-Acid Ionomers
journal, January 2017


Separation of CO2 from flue gas using electrochemical cells
journal, June 2010


Hydroxide, halide and water transport in a model anion exchange membrane
journal, August 2014


In-situ Observation of CO
conference, January 2009

  • Fukuta, Kenji; Inoue, Hiroshi; Watanabe, Shin
  • 215th ECS Meeting, ECS Transactions
  • DOI: 10.1149/1.3271358

Anion exchange membranes for alkaline fuel cells: A review
journal, July 2011

  • Merle, Géraldine; Wessling, Matthias; Nijmeijer, Kitty
  • Journal of Membrane Science, Vol. 377, Issue 1-2, p. 1-35
  • DOI: 10.1016/j.memsci.2011.04.043

Effect of CO2 on the properties of anion exchange membranes for fuel cell applications
journal, September 2019


Effects of CO2 Concentration and Electric Current on the Ionic Conductivity of Anion Exchange Membranes for Fuel Cells
journal, January 2011


Oxygen Reduction on Pt in Aqueous K[sub 2]CO[sub 3] and KOH
journal, January 1990

  • Striebel, Kathryn A.
  • Journal of The Electrochemical Society, Vol. 137, Issue 11
  • DOI: 10.1149/1.2086221

Fuel Cell Cathode Studies in Aqueous K[sub 2]CO[sub 3] and KOH
journal, January 1990

  • Striebel, Kathryn A.
  • Journal of The Electrochemical Society, Vol. 137, Issue 11
  • DOI: 10.1149/1.2086222

Influence of CO2 dissolution into anion exchange membrane on fuel cell performance
journal, January 2013


Transient ion exchange of anion exchange membranes exposed to carbon dioxide
journal, November 2015


Effect of CO 2 absorption on ion and water mobility in an anion exchange membrane
journal, March 2018


Orientation of Drawn Nafion at Molecular and Mesoscopic Scales
journal, July 2004

  • van der Heijden, P. C.; Rubatat, L.; Diat, O.
  • Macromolecules, Vol. 37, Issue 14
  • DOI: 10.1021/ma035642w

Synthesis and Characterization of Perfluorinated Anion Exchange Membranes
journal, August 2017

  • Park, Andrew Michael; Owczarczyk, Zbyslaw R.; Garner, L. E.
  • ECS Transactions, Vol. 80, Issue 8
  • DOI: 10.1149/08008.0957ecst

A Small-Angle X-ray Scattering Study of the Development of Morphology in Films Formed from the 3M Perfluorinated Sulfonic Acid Ionomer
journal, September 2012

  • Liu, Yuan; Horan, James L.; Schlichting, Gregory J.
  • Macromolecules, Vol. 45, Issue 18
  • DOI: 10.1021/ma300926e

High-Energy Density, Room-Temperature Carbonate Fuel Cell
journal, January 2006

  • Lang, Christopher M.; Kim, Ketack; Kohl, Paul A.
  • Electrochemical and Solid-State Letters, Vol. 9, Issue 12
  • DOI: 10.1149/1.2353904

Kinetic Equilibrium Study of CO 2 Poisoning Observed in Anion Exchange Membranes When Exposed to Ambient Air and Varying Levels of CO 2 ppm
journal, July 2018

  • Divekar, Ashutosh G.; Pivovar, Bryan S.; Herring, Andrew M.
  • ECS Transactions, Vol. 86, Issue 13
  • DOI: 10.1149/08613.0643ecst

Steady-State dc and Impedance Investigations of H 2 /O 2 Alkaline Membrane Fuel Cells with Commercial Pt/C, Ag/C, and Au/C Cathodes
journal, October 2006

  • Varcoe, John R.; Slade, Robert C. T.; Wright, Graham L.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 42
  • DOI: 10.1021/jp064898b

Anion Exchange Membranes’ Evolution toward High Hydroxide Ion Conductivity and Alkaline Resiliency
journal, June 2018


Anion Exchange Membrane and Ionomer for Alkaline Membrane Fuel Cells (AMFCs)
conference, January 2008

  • Yanagi, Hiroyuki; Fukuta, Kenji
  • 214th ECS Meeting, ECS Transactions
  • DOI: 10.1149/1.2981860

Understanding Anion, Water, and Methanol Transport in a Polyethylene- b -poly(vinylbenzyl trimethylammonium) Copolymer Anion-Exchange Membrane for Electrochemical Applications
journal, January 2017

  • Sarode, Himanshu N.; Yang, Yuan; Motz, Andrew R.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 4
  • DOI: 10.1021/acs.jpcc.6b09205

Humidity fixed points of binary saturated aqueous solutions
journal, January 1977

  • Greenspan, Lewis
  • Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry, Vol. 81A, Issue 1
  • DOI: 10.6028/jres.081A.011

Anion exchange membrane fuel cells: Current status and remaining challenges
journal, January 2018


Alkaline Electrolytes and Reference Electrodes for Alkaline Polymer Electrolyte Membrane Fuel Cells
conference, January 2010

  • Kizewski, Jamie; Mudri, Nurul; Zeng, Rong
  • 218th ECS Meeting, ECS Transactions
  • DOI: 10.1149/1.3484498

Effects of Temperature and Carbon Dioxide on Anion Exchange Membrane Conductivity
journal, January 2011

  • Grew, Kyle N.; Ren, Xiaoming; Chu, Deryn
  • Electrochemical and Solid-State Letters, Vol. 14, Issue 12
  • DOI: 10.1149/2.011112esl