Structural features associated with multiferroic behavior in the RX 3(BO3)4 system

Zhang, H.; Liu, S.; Nelson, Christie S.; Bezmaternykh, L. N.; Chen, Y-S; Wang, S. G.; Lobo, R. P. S. M.; Page, K.; Matsuda, M.; Pajerowski, D. M.; Williams, T. J.; Tyson, T. A.

doi:10.1088/1361-648X/ab415f

Title: Structural features associated with multiferroic behavior in the RX ₃(BO₃)₄ system

Abstract

We report the magnetoelectric effect in the RX₃(BO₃)₄ system (R = Ho, Eu, Sm, Nd, Gd; X = Fe, Al) varies significantly with the cation R despite very similar structural arrangements. Our structural studies reveal a symmetry reducing tilting of the BO₃ planes and of the FeO₆ polyhedra in the systems exhibiting low magnetic field induced electric polarization. Neutron scattering measurements reveal a lack of magnetic ordering indicating the primary importance of the atomic structure in the multiferroic behavior of this system.

Authors:

Zhang, H. ^[1]; Liu, S. ^[1]; Nelson, Christie S. ^[2]; Bezmaternykh, L. N. ^[3];

^[4]; Wang, S. G. ^[4];

^[5]; Page, K. ^[6]; Matsuda, M. ^[6]; Pajerowski, D. M. ^[6]; Williams, T. J. ^[6];

^[1]

New Jersey Institute of Technology, Newark, NJ (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
L.V. Kirensky Institute of Physics, Krasnoyarsk (Russia)
Univ. of Chicago, IL (United States)
PSL Univ., CNRS, Paris (France); Sorbonne Univ., Paris (France)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: 2019-09-04

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

OSTI Identifier:: 1593268

Report Number(s):: BNL-213550-2020-JAAM
Journal ID: ISSN 0953-8984; TRN: US2100920

Grant/Contract Number:: SC0012704; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physics. Condensed Matter

Additional Journal Information:: Journal Volume: 31; Journal Issue: 50; Journal ID: ISSN 0953-8984

Publisher:: IOP Publishing

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Zhang, H., Liu, S., Nelson, Christie S., Bezmaternykh, L. N., Chen, Y-S, Wang, S. G., Lobo, R. P. S. M., Page, K., Matsuda, M., Pajerowski, D. M., Williams, T. J., and Tyson, T. A. Structural features associated with multiferroic behavior in the RX 3(BO3)4 system.  United States: N. p., 2019. 
Web.  doi:10.1088/1361-648X/ab415f.

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                    Zhang, H., Liu, S., Nelson, Christie S., Bezmaternykh, L. N., Chen, Y-S, Wang, S. G., Lobo, R. P. S. M., Page, K., Matsuda, M., Pajerowski, D. M., Williams, T. J., & Tyson, T. A. Structural features associated with multiferroic behavior in the RX 3(BO3)4 system.  United States.  https://doi.org/10.1088/1361-648X/ab415f

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                    Zhang, H., Liu, S., Nelson, Christie S., Bezmaternykh, L. N., Chen, Y-S, Wang, S. G., Lobo, R. P. S. M., Page, K., Matsuda, M., Pajerowski, D. M., Williams, T. J., and Tyson, T. A. Wed .  
"Structural features associated with multiferroic behavior in the RX 3(BO3)4 system".  United States.  https://doi.org/10.1088/1361-648X/ab415f.  https://www.osti.gov/servlets/purl/1593268.

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@article{osti_1593268,

  title        = {Structural features associated with multiferroic behavior in the RX 3(BO3)4 system},

  author       = {Zhang, H. and Liu, S. and Nelson, Christie S. and Bezmaternykh, L. N. and Chen, Y-S and Wang, S. G. and Lobo, R. P. S. M. and Page, K. and Matsuda, M. and Pajerowski, D. M. and Williams, T. J. and Tyson, T. A.},

  abstractNote = {We report the magnetoelectric effect in the RX3(BO3)4 system (R = Ho, Eu, Sm, Nd, Gd; X = Fe, Al) varies significantly with the cation R despite very similar structural arrangements. Our structural studies reveal a symmetry reducing tilting of the BO3 planes and of the FeO6 polyhedra in the systems exhibiting low magnetic field induced electric polarization. Neutron scattering measurements reveal a lack of magnetic ordering indicating the primary importance of the atomic structure in the multiferroic behavior of this system.},

  doi          = {10.1088/1361-648X/ab415f},

  journal      = {Journal of Physics. Condensed Matter},

  number       = 50,

  volume       = 31,

  place        = {United States},

  year         = {2019},

  month        = {9}

}

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Title: Structural features associated with multiferroic behavior in the RX 3(BO3)4 system

Abstract

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Title: Structural features associated with multiferroic behavior in the RX ₃(BO₃)₄ system

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Magnetoelectric and magnetoelastic interactions in NdFe3(BO3)4 multiferroics
journal, August 2006

Recent progress on the structural characterizations of domain structures in ferroic and multiferroic perovskite oxides: A review
journal, February 2015

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

Single magnetic chirality in the magnetoelectric ${NdFe}_{3} {({{}^{11}B O}_{3})}_{4}$
journal, March 2010

First principles results on TbAl ₃ (BO ₃ ) ₄ : A promising magneto-optical material
journal, November 2011

Diffraction Studies of Multiferroics
journal, July 2014

Structural and electronic transitions in gadolinium iron borate GdFe3(BO3)4 at high pressures
journal, September 2004

Magnetoelectricity and magnetostriction due to the rare-earth moment in ${TmAl}_{3} {({BO}_{3})}_{4}$
journal, June 2010