Structural features associated with multiferroic behavior in the RX 3(BO3)4 system

doi:10.1088/1361-648X/ab415f

Title: Structural features associated with multiferroic behavior in the RX ₃(BO₃)₄ system

Abstract

We report the magnetoelectric effect in the RX₃(BO₃)₄ system (R = Ho, Eu, Sm, Nd, Gd; X = Fe, Al) varies significantly with the cation R despite very similar structural arrangements. Our structural studies reveal a symmetry reducing tilting of the BO₃ planes and of the FeO₆ polyhedra in the systems exhibiting low magnetic field induced electric polarization. Neutron scattering measurements reveal a lack of magnetic ordering indicating the primary importance of the atomic structure in the multiferroic behavior of this system.

Authors:

Zhang, H. ^[1]; Liu, S. ^[1]; Nelson, Christie S. ^[2]; Bezmaternykh, L. N. ^[3];

^[4]; Wang, S. G. ^[4];

^[5]; Page, K. ^[6]; Matsuda, M. ^[6]; Pajerowski, D. M. ^[6]; Williams, T. J. ^[6];

^[1]

New Jersey Institute of Technology, Newark, NJ (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
L.V. Kirensky Institute of Physics, Krasnoyarsk (Russia)
Univ. of Chicago, IL (United States)
PSL Univ., CNRS, Paris (France); Sorbonne Univ., Paris (France)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: 2019-09-04

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

OSTI Identifier:: 1593268

Report Number(s):: BNL-213550-2020-JAAM
Journal ID: ISSN 0953-8984

Grant/Contract Number:: SC0012704; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physics. Condensed Matter

Additional Journal Information:: Journal Volume: 31; Journal Issue: 50; Journal ID: ISSN 0953-8984

Publisher:: IOP Publishing

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Zhang, H., Liu, S., Nelson, Christie S., Bezmaternykh, L. N., Chen, Y-S, Wang, S. G., Lobo, R. P. S. M., Page, K., Matsuda, M., Pajerowski, D. M., Williams, T. J., and Tyson, T. A. Structural features associated with multiferroic behavior in the RX 3(BO3)4 system.  United States: N. p., 2019. 
        Web.  doi:10.1088/1361-648X/ab415f.

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                    Zhang, H., Liu, S., Nelson, Christie S., Bezmaternykh, L. N., Chen, Y-S, Wang, S. G., Lobo, R. P. S. M., Page, K., Matsuda, M., Pajerowski, D. M., Williams, T. J., & Tyson, T. A. Structural features associated with multiferroic behavior in the RX 3(BO3)4 system.  United States.  doi:10.1088/1361-648X/ab415f.

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                    Zhang, H., Liu, S., Nelson, Christie S., Bezmaternykh, L. N., Chen, Y-S, Wang, S. G., Lobo, R. P. S. M., Page, K., Matsuda, M., Pajerowski, D. M., Williams, T. J., and Tyson, T. A. Wed .  
        "Structural features associated with multiferroic behavior in the RX 3(BO3)4 system".  United States.  doi:10.1088/1361-648X/ab415f.  https://www.osti.gov/servlets/purl/1593268.

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@article{osti_1593268,

  title        = {Structural features associated with multiferroic behavior in the RX 3(BO3)4 system},

  author       = {Zhang, H. and Liu, S. and Nelson, Christie S. and Bezmaternykh, L. N. and Chen, Y-S and Wang, S. G. and Lobo, R. P. S. M. and Page, K. and Matsuda, M. and Pajerowski, D. M. and Williams, T. J. and Tyson, T. A.},

  abstractNote = {We report the magnetoelectric effect in the RX3(BO3)4 system (R = Ho, Eu, Sm, Nd, Gd; X = Fe, Al) varies significantly with the cation R despite very similar structural arrangements. Our structural studies reveal a symmetry reducing tilting of the BO3 planes and of the FeO6 polyhedra in the systems exhibiting low magnetic field induced electric polarization. Neutron scattering measurements reveal a lack of magnetic ordering indicating the primary importance of the atomic structure in the multiferroic behavior of this system.},

  doi          = {10.1088/1361-648X/ab415f},

  journal      = {Journal of Physics. Condensed Matter},

  number       = 50,

  volume       = 31,

  place        = {United States},

  year         = {2019},

  month        = {9}

}

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DOI: 10.1088/1361-648X/ab415f

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Title: Structural features associated with multiferroic behavior in the RX 3(BO3)4 system

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Title: Structural features associated with multiferroic behavior in the RX ₃(BO₃)₄ system

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