Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Evidence for the Band‐Edge Exciton of CuInS 2 Nanocrystals Enables Record Efficient Large‐Area Luminescent Solar Concentrators

Authors:
 [1];  [1];  [2];  [3];  [2];  [4];  [5];  [2];  [1];  [6];  [1];  [7]; ORCiD logo [1]
+ Show Author Affiliations
  1. Dipartimento di Scienza dei Materiali Università degli studi di Milano‐Bicocca Via Roberto Cozzi 55 IT‐20125 Milano Italy
  2. Glass to Power SpA Via Fortunato Zeni 8 IT‐38068 Rovereto Italy
  3. Dipartimento di Energia Politecnico di Milano Via Ponzio 34/3 IT‐20133 Milano Italy
  4. Istituto Italiano di Tecnologia Via Morego 30 IT‐16163 Genova Italy
  5. Dipartimento di Scienza dei Materiali Università degli studi di Milano‐Bicocca Via Roberto Cozzi 55 IT‐20125 Milano Italy, Glass to Power SpA Via Fortunato Zeni 8 IT‐38068 Rovereto Italy
  6. Dipartimento di Energia Politecnico di Milano Via Ponzio 34/3 IT‐20133 Milano Italy, IFN‐CNR Piazza Leonardo da Vinci 32 IT‐20133 Milano Italy
  7. National High Magnetic Field Laboratory Los Alamos National Laboratory Los Alamos NM 87545 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1593164
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 30 Journal Issue: 4; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Anand, Abhinav, Zaffalon, Matteo L., Gariano, Graziella, Camellini, Andrea, Gandini, Marina, Brescia, Rosaria, Capitani, Chiara, Bruni, Francesco, Pinchetti, Valerio, Zavelani‐Rossi, Margherita, Meinardi, Francesco, Crooker, Scott A., and Brovelli, Sergio. Evidence for the Band‐Edge Exciton of CuInS 2 Nanocrystals Enables Record Efficient Large‐Area Luminescent Solar Concentrators. Germany: N. p., 2019. Web. doi:10.1002/adfm.201906629.
Copy to clipboard
Anand, Abhinav, Zaffalon, Matteo L., Gariano, Graziella, Camellini, Andrea, Gandini, Marina, Brescia, Rosaria, Capitani, Chiara, Bruni, Francesco, Pinchetti, Valerio, Zavelani‐Rossi, Margherita, Meinardi, Francesco, Crooker, Scott A., & Brovelli, Sergio. Evidence for the Band‐Edge Exciton of CuInS 2 Nanocrystals Enables Record Efficient Large‐Area Luminescent Solar Concentrators. Germany. https://doi.org/10.1002/adfm.201906629
Copy to clipboard
Anand, Abhinav, Zaffalon, Matteo L., Gariano, Graziella, Camellini, Andrea, Gandini, Marina, Brescia, Rosaria, Capitani, Chiara, Bruni, Francesco, Pinchetti, Valerio, Zavelani‐Rossi, Margherita, Meinardi, Francesco, Crooker, Scott A., and Brovelli, Sergio. Fri . "Evidence for the Band‐Edge Exciton of CuInS 2 Nanocrystals Enables Record Efficient Large‐Area Luminescent Solar Concentrators". Germany. https://doi.org/10.1002/adfm.201906629.
Copy to clipboard
@article{osti_1593164,
title = {Evidence for the Band‐Edge Exciton of CuInS 2 Nanocrystals Enables Record Efficient Large‐Area Luminescent Solar Concentrators},
author = {Anand, Abhinav and Zaffalon, Matteo L. and Gariano, Graziella and Camellini, Andrea and Gandini, Marina and Brescia, Rosaria and Capitani, Chiara and Bruni, Francesco and Pinchetti, Valerio and Zavelani‐Rossi, Margherita and Meinardi, Francesco and Crooker, Scott A. and Brovelli, Sergio},
abstractNote = {},
doi = {10.1002/adfm.201906629},
journal = {Advanced Functional Materials},
number = 4,
volume = 30,
place = {Germany},
year = {2019},
month = {11}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Accepted Manuscript (Publisher)
Publisher's Version of Record
https://doi.org/10.1002/adfm.201906629
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 12 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Spectro-electrochemical Probing of Intrinsic and Extrinsic Processes in Exciton Recombination in I–III–VI 2 Nanocrystals
journal, June 2017

Radiative and Nonradiative Recombination in CuInS 2 Nanocrystals and CuInS 2 -Based Core/Shell Nanocrystals
journal, August 2016

  • Berends, Anne C.; Rabouw, Freddy T.; Spoor, Frank C. M.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 17
  • DOI: 10.1021/acs.jpclett.6b01668

Universal Role of Discrete Acoustic Phonons in the Low-Temperature Optical Emission of Colloidal Quantum Dots
journal, April 2009

Noninjection Gram-Scale Synthesis of Monodisperse Pyramidal CuInS 2 Nanocrystals and Their Size-Dependent Properties
journal, August 2010

  • Zhong, Haizheng; Lo, Shun S.; Mirkovic, Tihana
  • ACS Nano, Vol. 4, Issue 9
  • DOI: 10.1021/nn1015538

Highly Luminescent, Size- and Shape-Tunable Copper Indium Selenide Based Colloidal Nanocrystals
journal, August 2013

  • Yarema, Olesya; Bozyigit, Deniz; Rousseau, Ian
  • Chemistry of Materials, Vol. 25, Issue 18
  • DOI: 10.1021/cm402306q

Large Stokes Shift and High Efficiency Luminescent Solar Concentrator Incorporated with CuInS2/ZnS Quantum Dots
journal, December 2015

  • Li, Chen; Chen, Wei; Wu, Dan
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep17777

Highly efficient large-area colourless luminescent solar concentrators using heavy-metal-free colloidal quantum dots
journal, August 2015

  • Meinardi, Francesco; McDaniel, Hunter; Carulli, Francesco
  • Nature Nanotechnology, Vol. 10, Issue 10
  • DOI: 10.1038/nnano.2015.178

Pervasive Cation Vacancies and Antisite Defects in Copper Indium Diselenide (CuInSe 2 ) Nanocrystals
journal, March 2019

  • Houck, Daniel W.; Assaf, Eli I.; Shin, Haein
  • The Journal of Physical Chemistry C, Vol. 123, Issue 14
  • DOI: 10.1021/acs.jpcc.9b00558

Doped Halide Perovskite Nanocrystals for Reabsorption-Free Luminescent Solar Concentrators
journal, September 2017

Excitonic pathway to photoinduced magnetism in colloidal nanocrystals with nonmagnetic dopants
journal, December 2017

Highly efficient luminescent solar concentrators based on earth-abundant indirect-bandgap silicon quantum dots
journal, February 2017

  • Meinardi, Francesco; Ehrenberg, Samantha; Dhamo, Lorena
  • Nature Photonics, Vol. 11, Issue 3
  • DOI: 10.1038/nphoton.2017.5

Highly Luminescent Water-Dispersible NIR-Emitting Wurtzite CuInS 2 /ZnS Core/Shell Colloidal Quantum Dots
journal, May 2017

Observation of the "Dark Exciton" in CdSe Quantum Dots
journal, November 1995

Copper’s Role in the Photoluminescence of Ag 1– x Cu x InS 2 Nanocrystals, from Copper-Doped AgInS 2 ( x ∼ 0) to CuInS 2 ( x = 1)
journal, December 2018

Quantized Electronic Doping towards Atomically Controlled “Charge-Engineered” Semiconductor Nanocrystals
journal, January 2019

Synthesis and Application of Colloidal CuInS 2 Semiconductor Nanocrystals
journal, November 2013

  • Kolny-Olesiak, Joanna; Weller, Horst
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 23
  • DOI: 10.1021/am404084d

In Vivo Whole Animal Fluorescence Imaging of a Microparticle-Based Oral Vaccine Containing (CuInSe x S 2– x )/ZnS Core/Shell Quantum Dots
journal, August 2013

  • Panthani, Matthew G.; Khan, Tarik A.; Reid, Dariya K.
  • Nano Letters, Vol. 13, Issue 9
  • DOI: 10.1021/nl402054w

Effect of Electron–Hole Overlap and Exchange Interaction on Exciton Radiative Lifetimes of CdTe/CdSe Heteronanocrystals
journal, March 2016

  • Granados del Águila, Andrés; Groeneveld, Esther; Maan, Jan C.
  • ACS Nano, Vol. 10, Issue 4
  • DOI: 10.1021/acsnano.5b07158

Controlled Synthesis and Optical Properties of Colloidal Ternary Chalcogenide CuInS 2 Nanocrystals
journal, October 2008

  • Zhong, Haizheng; Zhou, Yi; Ye, Mingfu
  • Chemistry of Materials, Vol. 20, Issue 20
  • DOI: 10.1021/cm8006827

Long-lived photoinduced magnetization in copper-doped ZnSe–CdSe core–shell nanocrystals
journal, December 2012

  • Pandey, A.; Brovelli, S.; Viswanatha, R.
  • Nature Nanotechnology, Vol. 7, Issue 12
  • DOI: 10.1038/nnano.2012.210

Determining the Concentration of CuInS 2 Quantum Dots from the Size-Dependent Molar Extinction Coefficient
journal, May 2012

  • Booth, Matthew; Brown, Andrew P.; Evans, Stephen D.
  • Chemistry of Materials, Vol. 24, Issue 11
  • DOI: 10.1021/cm300227b

Solar Energy Collectors with Tunable Transmission
journal, April 2010

Efficient Synthesis of Highly Luminescent Copper Indium Sulfide-Based Core/Shell Nanocrystals with Surprisingly Long-Lived Emission
journal, February 2011

  • Li, Liang; Pandey, Anshu; Werder, Donald J.
  • Journal of the American Chemical Society, Vol. 133, Issue 5, p. 1176-1179
  • DOI: 10.1021/ja108261h

Ray-trace simulation of CuInS(Se)_2 quantum dot based luminescent solar concentrators
journal, January 2015

  • Hu, Xiangmin; Kang, Ruidan; Zhang, Yongyou
  • Optics Express, Vol. 23, Issue 15
  • DOI: 10.1364/OE.23.00A858

Light Emission Mechanisms in CuInS 2 Quantum Dots Evaluated by Spectral Electrochemistry
journal, September 2017

Formation of High-Quality I−III−VI Semiconductor Nanocrystals by Tuning Relative Reactivity of Cationic Precursors
journal, April 2009

  • Xie, Renguo; Rutherford, Michael; Peng, Xiaogang
  • Journal of the American Chemical Society, Vol. 131, Issue 15
  • DOI: 10.1021/ja9005767

Energy band structure of CuInS 2 and optical spectra of CuInS 2 nanocrystals
journal, July 2015

Flexible CuInSe 2 Nanocrystal Solar Cells on Paper
journal, February 2017

Tuning the Luminescence Properties of Colloidal I–III–VI Semiconductor Nanocrystals for Optoelectronics and Biotechnology Applications
journal, October 2012

  • Zhong, Haizheng; Bai, Zelong; Zou, Bingsuo
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 21, p. 3167-3175
  • DOI: 10.1021/jz301345x

Ternary and quaternary metal chalcogenide nanocrystals: synthesis, properties and applications
journal, January 2013

  • Aldakov, Dmitry; Lefrançois, Aurélie; Reiss, Peter
  • Journal of Materials Chemistry C, Vol. 1, Issue 24
  • DOI: 10.1039/c3tc30273c

Tandem luminescent solar concentrators based on engineered quantum dots
journal, January 2018

Tuning and Probing the Distribution of Cu + and Cu 2+ Trap States Responsible for Broad-Band Photoluminescence in CuInS 2 Nanocrystals
journal, October 2018

  • van der Stam, Ward; de Graaf, Max; Gudjonsdottir, Solrun
  • ACS Nano, Vol. 12, Issue 11
  • DOI: 10.1021/acsnano.8b05843

Near-Band-Edge Electroluminescence from Heavy-Metal-Free Colloidal Quantum Dots
journal, July 2011

  • Tan, Zhanao; Zhang, Yu; Xie, Chuang
  • Advanced Materials, Vol. 23, Issue 31, p. 3553-3558
  • DOI: 10.1002/adma.201100719

The solar noise barrier project: 2. The effect of street art on performance of a large scale luminescent solar concentrator prototype
journal, December 2017

Charge Dynamics in Solution-Processed Nanocrystalline CuInS 2 Solar Cells
journal, May 2015

  • Halpert, Jonathan E.; Morgenstern, Frederik S. F.; Ehrler, Bruno
  • ACS Nano, Vol. 9, Issue 6
  • DOI: 10.1021/acsnano.5b00432

Reduced Carrier Recombination in PbS - CuInS2 Quantum Dot Solar Cells
journal, May 2015

  • Sun, Zhenhua; Sitbon, Gary; Pons, Thomas
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep10626

Nano-engineered electron–hole exchange interaction controls exciton dynamics in core–shell semiconductor nanocrystals
journal, April 2011

  • Brovelli, S.; Schaller, R. D.; Crooker, S. A.
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1281

Charge-Transport Mechanisms in CuInSe x S 2– x Quantum-Dot Films
journal, November 2018

Tunable magnetic exchange interactions in manganese-doped inverted core–shell ZnSe–CdSe nanocrystals
journal, December 2008

  • Bussian, David A.; Crooker, Scott A.; Yin, Ming
  • Nature Materials, Vol. 8, Issue 1
  • DOI: 10.1038/nmat2342

Noninjection, one-pot synthesis of Cu-deficient CuInS2/ZnS core/shell quantum dots and their fluorescent properties
journal, September 2011

  • Nam, Da-Eun; Song, Woo-Seuk; Yang, Heesun
  • Journal of Colloid and Interface Science, Vol. 361, Issue 2
  • DOI: 10.1016/j.jcis.2011.05.058

Excitonic wave function, correlation energy, exchange energy, and oscillator strength in a cubic quantum dot
journal, January 1994

Synthesis of Colloidal CuGaSe 2 , CuInSe 2 , and Cu(InGa)Se 2 Nanoparticles
journal, November 2008

  • Tang, Jiang; Hinds, Sean; Kelley, Shana O.
  • Chemistry of Materials, Vol. 20, Issue 22
  • DOI: 10.1021/cm801655w

Unravelling the Correlation of Electronic Structure and Carrier Dynamics in CuInS 2 Nanoparticles
journal, December 2017

  • Hu, Wenhui; Ludwig, John; Pattengale, Brian
  • The Journal of Physical Chemistry C, Vol. 122, Issue 1
  • DOI: 10.1021/acs.jpcc.7b11369

Hydroxyl-Terminated CuInS 2 Based Quantum Dots: Toward Efficient and Bright Light Emitting Diodes
journal, February 2016

High-Performance CuInS 2 Quantum Dot Laminated Glass Luminescent Solar Concentrators for Windows
journal, January 2018

Multiple temperature regimes of radiative decay in CdSe nanocrystal quantum dots: Intrinsic limits to the dark-exciton lifetime
journal, April 2003

  • Crooker, S. A.; Barrick, T.; Hollingsworth, J. A.
  • Applied Physics Letters, Vol. 82, Issue 17
  • DOI: 10.1063/1.1570923

Solution Synthesis and Assembly of Wurtzite-Derived Cu–In–Zn–S Nanorods with Tunable Composition and Band Gap
journal, February 2015

  • Singh, Ajay; Coughlan, Claudia; Milliron, Delia J.
  • Chemistry of Materials, Vol. 27, Issue 5
  • DOI: 10.1021/cm5035613

Unravelling the Size and Temperature Dependence of Exciton Lifetimes in Colloidal ZnSe Quantum Dots
journal, September 2014

  • Eilers, Joren; van Hest, Jacobine; Meijerink, Andries
  • The Journal of Physical Chemistry C, Vol. 118, Issue 40
  • DOI: 10.1021/jp5038238

Bright CuInS 2 /CdS nanocrystal phosphors for high-gain full-spectrum luminescent solar concentrators
journal, January 2015

  • Knowles, Kathryn E.; Kilburn, Troy B.; Alzate, Dane G.
  • Chemical Communications, Vol. 51, Issue 44
  • DOI: 10.1039/C5CC02007G

Large-area luminescent solar concentrators based on ‘Stokes-shift-engineered’ nanocrystals in a mass-polymerized PMMA matrix
journal, April 2014

  • Meinardi, Francesco; Colombo, Annalisa; Velizhanin, Kirill A.
  • Nature Photonics, Vol. 8, Issue 5, p. 392-399
  • DOI: 10.1038/nphoton.2014.54

Size-Dependent Photovoltaic Performance of CuInS 2 Quantum Dot-Sensitized Solar Cells
journal, November 2014

  • Jara, Danilo H.; Yoon, Seog Joon; Stamplecoskie, Kevin G.
  • Chemistry of Materials, Vol. 26, Issue 24
  • DOI: 10.1021/cm5040886

Evidence of Band-Edge Hole Levels Inversion in Spherical CuInS 2 Quantum Dots
journal, September 2018

Copper-Doped Inverted Core/Shell Nanocrystals with “Permanent” Optically Active Holes
journal, November 2011

  • Viswanatha, Ranjani; Brovelli, Sergio; Pandey, Anshu
  • Nano Letters, Vol. 11, Issue 11
  • DOI: 10.1021/nl202572c

Sub-Bandgap Emission and Intraband Defect-Related Excited-State Dynamics in Colloidal CuInS 2 /ZnS Quantum Dots Revealed by Femtosecond Pump–Dump–Probe Spectroscopy
journal, October 2014

  • Kraatz, Ingvar T.; Booth, Matthew; Whitaker, Benjamin J.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 41
  • DOI: 10.1021/jp5065374

Synthesis of CuInS2 fluorescent nanocrystals and enhancement of fluorescence by controlling crystal defect
journal, October 2008

  • Uehara, Masato; Watanabe, Kosuke; Tajiri, Yasuyuki
  • The Journal of Chemical Physics, Vol. 129, Issue 13
  • DOI: 10.1063/1.2987707

Color-Tunable Highly Bright Photoluminescence of Cadmium-Free Cu-Doped Zn–In–S Nanocrystals and Electroluminescence
journal, December 2013

  • Zhang, Wenjin; Lou, Qing; Ji, Wenyu
  • Chemistry of Materials, Vol. 26, Issue 2
  • DOI: 10.1021/cm403584a

Optoelectronic Properties of CuInS 2 Nanocrystals and Their Origin
journal, January 2016

Luminescent solar concentrators for building-integrated photovoltaics
journal, November 2017

  • Meinardi, Francesco; Bruni, Francesco; Brovelli, Sergio
  • Nature Reviews Materials, Vol. 2, Issue 12
  • DOI: 10.1038/natrevmats.2017.72

Magneto-Optical Properties of CuInS 2 Nanocrystals
journal, November 2014

  • Rice, William D.; McDaniel, Hunter; Klimov, Victor I.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 23
  • DOI: 10.1021/jz502154m

Strongly Fluorescent Quaternary Cu–In–Zn–S Nanocrystals Prepared from Cu 1- x InS 2 Nanocrystals by Partial Cation Exchange
journal, June 2012

  • De Trizio, Luca; Prato, Mirko; Genovese, Alessandro
  • Chemistry of Materials, Vol. 24, Issue 12
  • DOI: 10.1021/cm301211e

Size-Dependent Band-Gap and Molar Absorption Coefficients of Colloidal CuInS 2 Quantum Dots
journal, July 2018

Band-edge exciton in quantum dots of semiconductors with a degenerate valence band: Dark and bright exciton states
journal, August 1996

Optoelectronic Properties of Ternary I–III–VI 2 Semiconductor Nanocrystals: Bright Prospects with Elusive Origins
journal, March 2019

  • Berends, Anne C.; Mangnus, Mark J. J.; Xia, Chenghui
  • The Journal of Physical Chemistry Letters, Vol. 10, Issue 7
  • DOI: 10.1021/acs.jpclett.8b03653

Defect Luminescence from Wurtzite CuInS 2 Nanocrystals: Combined Experimental and Theoretical Analysis
journal, February 2016

  • Leach, Alice D. P.; Shen, Xiao; Faust, Adam
  • The Journal of Physical Chemistry C, Vol. 120, Issue 9
  • DOI: 10.1021/acs.jpcc.6b00156

Thick-Shell CuInS 2 /ZnS Quantum Dots with Suppressed “Blinking” and Narrow Single-Particle Emission Line Widths
journal, February 2017

Simulation study of environmentally friendly quantum-dot-based photovoltaic windows
journal, January 2017

  • Lesyuk, Rostyslav; Lesnyak, Vladimir; Herguth, Axel
  • Journal of Materials Chemistry C, Vol. 5, Issue 45
  • DOI: 10.1039/C7TC02945D

Exciton lifetimes of CdTe nanocrystal quantum dots in high magnetic fields
journal, January 2011

Performance analysis of a large-area luminescent solar concentrator module
journal, April 2015

Near-Infrared Cu–In–Se-Based Colloidal Nanocrystals via Cation Exchange
journal, March 2018

Highly Emissive and Color-Tunable CuInS2-Based Colloidal Semiconductor Nanocrystals: Off-Stoichiometry Effects and Improved Electroluminescence Performance
journal, March 2012

  • Chen, Bingkun; Zhong, Haizheng; Zhang, Wenqing
  • Advanced Functional Materials, Vol. 22, Issue 10
  • DOI: 10.1002/adfm.201102496

Fine structure and lifetime of dark excitons in transition metal dichalcogenide monolayers
journal, October 2017

Singlet–Triplet Splittings in the Luminescent Excited States of Colloidal Cu + :CdSe, Cu + :InP, and CuInS 2 Nanocrystals: Charge-Transfer Configurations and Self-Trapped Excitons
journal, September 2015

  • Knowles, Kathryn E.; Nelson, Heidi D.; Kilburn, Troy B.
  • Journal of the American Chemical Society, Vol. 137, Issue 40
  • DOI: 10.1021/jacs.5b08547

Tunable Infrared Phosphors Using Cu Doping in Semiconductor Nanocrystals: Surface Electronic Structure Evaluation
journal, January 2013

  • Grandhi, G. Krishnamurthy; Viswanatha, Ranjani
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 3
  • DOI: 10.1021/jz3021588

Indium-Rich AgInS 2 –ZnS Quantum Dots—Ag-/Zn-Dependent Photophysics and Photovoltaics
journal, May 2018

  • Kobosko, Steven M.; Kamat, Prashant V.
  • The Journal of Physical Chemistry C, Vol. 122, Issue 26
  • DOI: 10.1021/acs.jpcc.8b03001
    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: