Spin-dependent charge transport through 2D chiral hybrid lead-iodide perovskites
Abstract
Chiral-induced spin selectivity (CISS) occurs when the chirality of the transporting medium selects one of the two spin ½ states to transport through the media while blocking the other. Monolayers of chiral organic molecules demonstrate CISS but are limited in their efficiency and utility by the requirement of a monolayer to preserve the spin selectivity. We demonstrate CISS in a system that integrates an inorganic framework with a chiral organic sublattice inducing chirality to the hybrid system. Using magnetic conductive-probe atomic force microscopy, we find that oriented chiral 2D-layered Pb-iodide organic/inorganic hybrid perovskite systems exhibit CISS. Electron transport through the perovskite films depends on the magnetization of the probe tip and the handedness of the chiral molecule. The films achieve a highest spin-polarization transport of up to 86%. Magnetoresistance studies in modified spin-valve devices having only one ferromagnet electrode confirm the occurrence of spin-dependent charge transport through the organic/inorganic layers.
- Authors:
-
[1];
[2];
[1];
[1];
[1];
[1];
[2]
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Univ. of Utah, Salt Lake City, UT (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Hybrid Organic-Inorganic Semiconductors for Energy (CHOISE); National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1593083
- Report Number(s):
- NREL/JA-5900-73594
Journal ID: ISSN 2375-2548
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 12; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 36 MATERIALS SCIENCE; spin dependent transport; spintronics; perovskite; chirality
Citation Formats
Lu, Haipeng, Wang, Jingying, Xiao, Chuanxiao, Pan, Xin, Chen, Xihan, Brunecky, Roman, Berry, Joseph J., Zhu, Kai, Beard, Matthew C., and Vardeny, Zeev Valy. Spin-dependent charge transport through 2D chiral hybrid lead-iodide perovskites. United States: N. p., 2019.
Web. doi:10.1126/sciadv.aay0571.
Lu, Haipeng, Wang, Jingying, Xiao, Chuanxiao, Pan, Xin, Chen, Xihan, Brunecky, Roman, Berry, Joseph J., Zhu, Kai, Beard, Matthew C., & Vardeny, Zeev Valy. Spin-dependent charge transport through 2D chiral hybrid lead-iodide perovskites. United States. https://doi.org/10.1126/sciadv.aay0571
Lu, Haipeng, Wang, Jingying, Xiao, Chuanxiao, Pan, Xin, Chen, Xihan, Brunecky, Roman, Berry, Joseph J., Zhu, Kai, Beard, Matthew C., and Vardeny, Zeev Valy. Fri .
"Spin-dependent charge transport through 2D chiral hybrid lead-iodide perovskites". United States. https://doi.org/10.1126/sciadv.aay0571. https://www.osti.gov/servlets/purl/1593083.
@article{osti_1593083,
title = {Spin-dependent charge transport through 2D chiral hybrid lead-iodide perovskites},
author = {Lu, Haipeng and Wang, Jingying and Xiao, Chuanxiao and Pan, Xin and Chen, Xihan and Brunecky, Roman and Berry, Joseph J. and Zhu, Kai and Beard, Matthew C. and Vardeny, Zeev Valy},
abstractNote = {Chiral-induced spin selectivity (CISS) occurs when the chirality of the transporting medium selects one of the two spin ½ states to transport through the media while blocking the other. Monolayers of chiral organic molecules demonstrate CISS but are limited in their efficiency and utility by the requirement of a monolayer to preserve the spin selectivity. We demonstrate CISS in a system that integrates an inorganic framework with a chiral organic sublattice inducing chirality to the hybrid system. Using magnetic conductive-probe atomic force microscopy, we find that oriented chiral 2D-layered Pb-iodide organic/inorganic hybrid perovskite systems exhibit CISS. Electron transport through the perovskite films depends on the magnetization of the probe tip and the handedness of the chiral molecule. The films achieve a highest spin-polarization transport of up to 86%. Magnetoresistance studies in modified spin-valve devices having only one ferromagnet electrode confirm the occurrence of spin-dependent charge transport through the organic/inorganic layers.},
doi = {10.1126/sciadv.aay0571},
journal = {Science Advances},
number = 12,
volume = 5,
place = {United States},
year = {Fri Dec 06 00:00:00 EST 2019},
month = {Fri Dec 06 00:00:00 EST 2019}
}
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