Far-field midinfrared superresolution imaging and spectroscopy of single high aspect ratio gold nanowires
Abstract
Significance Traditional optical microscopy methods are limited by diffraction. This makes it hard to image and study nanostructures in the midinfrared, a relatively unexplored spectral region of chemical significance. Here we use infrared (IR) photothermal heterodyne imaging (IR-PHI), a far-field superresolution optical technique, to study the Fabry–Pérot resonances of single gold nanowires in the 2,800 to 4,000-cm −1 region. Because the spatial resolution of IR-PHI is on the order of a few hundred nanometers, we are able to directly resolve the structure of the Fabry–Pérot resonances and assign the mode order. This cannot be done with traditional optical measurements. IR absorption spectra recorded using IR-PHI show narrow linewidths, in several cases below the limit imposed by Au’s Drude relaxation parameter.
- Authors:
-
[1];
[1];
[2];
[3];
[4];
[3];
[1];
[1];
[6]
- Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556,
- Department of Materials Science and Engineering, University of Tennessee, Knoxville, TN 37996,
- Department of Chemistry, University of Washington, Seattle, WA 98195,
- Department of Materials Science and Engineering, University of Tennessee, Knoxville, TN 37996,, Center for Nanophase Materials Science, Oak Ridge National Laboratory, Oak Ridge, TN 37831,
- Department of Physics, University of Notre Dame, Notre Dame, IN 46556
- Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556,, Department of Physics, University of Notre Dame, Notre Dame, IN 46556
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1592822
- Grant/Contract Number:
- SC0018169; Center for Nanophase Materials Sciences
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 117 Journal Issue: 5; Journal ID: ISSN 0027-8424
- Publisher:
- Proceedings of the National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Aleshire, Kyle, Pavlovetc, Ilia M., Collette, Robyn, Kong, Xiang-Tian, Rack, Philip D., Zhang, Shubin, Masiello, David J., Camden, Jon P., Hartland, Gregory V., and Kuno, Masaru. Far-field midinfrared superresolution imaging and spectroscopy of single high aspect ratio gold nanowires. United States: N. p., 2020.
Web. doi:10.1073/pnas.1916433117.
Aleshire, Kyle, Pavlovetc, Ilia M., Collette, Robyn, Kong, Xiang-Tian, Rack, Philip D., Zhang, Shubin, Masiello, David J., Camden, Jon P., Hartland, Gregory V., & Kuno, Masaru. Far-field midinfrared superresolution imaging and spectroscopy of single high aspect ratio gold nanowires. United States. https://doi.org/10.1073/pnas.1916433117
Aleshire, Kyle, Pavlovetc, Ilia M., Collette, Robyn, Kong, Xiang-Tian, Rack, Philip D., Zhang, Shubin, Masiello, David J., Camden, Jon P., Hartland, Gregory V., and Kuno, Masaru. Tue .
"Far-field midinfrared superresolution imaging and spectroscopy of single high aspect ratio gold nanowires". United States. https://doi.org/10.1073/pnas.1916433117.
@article{osti_1592822,
title = {Far-field midinfrared superresolution imaging and spectroscopy of single high aspect ratio gold nanowires},
author = {Aleshire, Kyle and Pavlovetc, Ilia M. and Collette, Robyn and Kong, Xiang-Tian and Rack, Philip D. and Zhang, Shubin and Masiello, David J. and Camden, Jon P. and Hartland, Gregory V. and Kuno, Masaru},
abstractNote = {Significance Traditional optical microscopy methods are limited by diffraction. This makes it hard to image and study nanostructures in the midinfrared, a relatively unexplored spectral region of chemical significance. Here we use infrared (IR) photothermal heterodyne imaging (IR-PHI), a far-field superresolution optical technique, to study the Fabry–Pérot resonances of single gold nanowires in the 2,800 to 4,000-cm −1 region. Because the spatial resolution of IR-PHI is on the order of a few hundred nanometers, we are able to directly resolve the structure of the Fabry–Pérot resonances and assign the mode order. This cannot be done with traditional optical measurements. IR absorption spectra recorded using IR-PHI show narrow linewidths, in several cases below the limit imposed by Au’s Drude relaxation parameter.},
doi = {10.1073/pnas.1916433117},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 5,
volume = 117,
place = {United States},
year = {2020},
month = {1}
}
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https://doi.org/10.1073/pnas.1916433117
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