Pyrene‐Based Noncovalent Immobilization of Nitrogenase on Carbon Surfaces

Patel, Janki; Cai, Rong; Milton, Ross; Chen, Hui; Minteer, Shelley D.

doi:10.1002/cbic.201900697

Title: Pyrene‐Based Noncovalent Immobilization of Nitrogenase on Carbon Surfaces

Journal Article · 20 January 2020 · ChemBioChem: a European journal of chemical biology

DOI: https://doi.org/10.1002/cbic.201900697 · OSTI ID:1592522

Patel, Janki ^[1]; Cai, Rong ^[1]; Milton, Ross ^[2]; Chen, Hui ^[1];

^[1]

Department of Chemistry University of Utah 315 S 1400 E Salt Lake City UT 84112 USA
Department of Inorganic and Analytical Chemistry University of Geneva, Sciences II Quai Ernest-Ansermet 30 1211 Geneva 4 Switzerland

Abstract Early work with viologen‐mediated nitrogenase bio‐electrochemistry focused on bio‐electrocatalysis with the enzyme in solution, but biocatalyst immobilization at electrode surfaces is favorable as it provides a high effective concentration of biocatalyst at the electrode surface. We have used a pyrene–peptide linker as a method for immobilizing nitrogenase on carbon electrode surfaces for nitrogenase bio‐electrocatalysis.

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Sponsoring Organization:: USDOE

OSTI ID:: 1592522

Journal Information:: ChemBioChem: a European journal of chemical biology, Journal Name: ChemBioChem: a European journal of chemical biology Journal Issue: 12 Vol. 21; ISSN 1439-4227

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: France

Language:: English

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