skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on January 19, 2021

Title: Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships

Authors:
ORCiD logo [1];  [1];  [1];  [2]; ORCiD logo [2]
  1. Faculty of Science and Arts, Department of ChemistryBilecik Seyh Edebali University 11210 Bilecik Turkey
  2. Department of ChemistryUniversity of Missouri‐Kansas City Kansas City Missouri 64110
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Nuclear Physics (NP) (SC-26)
OSTI Identifier:
1592521
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Polymer Science
Additional Journal Information:
Journal Name: Journal of Polymer Science Journal Volume: 58 Journal Issue: 4; Journal ID: ISSN 2642-4150
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Country unknown/Code not available
Language:
English

Citation Formats

Eren, Bilge, Eren, Erdal, Guney, Murat, Jean, Yan‐Ching, and Van Horn, J. David. Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships. Country unknown/Code not available: N. p., 2020. Web. doi:10.1002/pol.20190031.
Eren, Bilge, Eren, Erdal, Guney, Murat, Jean, Yan‐Ching, & Van Horn, J. David. Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships. Country unknown/Code not available. doi:10.1002/pol.20190031.
Eren, Bilge, Eren, Erdal, Guney, Murat, Jean, Yan‐Ching, and Van Horn, J. David. Tue . "Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships". Country unknown/Code not available. doi:10.1002/pol.20190031.
@article{osti_1592521,
title = {Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships},
author = {Eren, Bilge and Eren, Erdal and Guney, Murat and Jean, Yan‐Ching and Van Horn, J. David},
abstractNote = {},
doi = {10.1002/pol.20190031},
journal = {Journal of Polymer Science},
number = 4,
volume = 58,
place = {Country unknown/Code not available},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on January 19, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Pervaporative seawater desalination using NaA zeolite membrane: Mechanisms of high water flux and high salt rejection
journal, April 2011


Slow hydrophobic hydration induced polymer ultrafiltration membranes with high water flux
journal, December 2014


The kinetic study for asymmetric membrane formation via phase-inversion process
journal, October 1996


Controlled synthesis of high performance polyamide membrane with thin dense layer for water desalination
journal, October 2010


Positronium Annihilation in Molecular Substances
journal, June 1972

  • Tao, S. J.
  • The Journal of Chemical Physics, Vol. 56, Issue 11
  • DOI: 10.1063/1.1677067

Applications of Positron Annihilation Spectroscopy to Life Science
journal, September 2012


Non-isothermal crystallization of PVDF/PMMA blends processed in low and high shear mixers
journal, September 2012


Using nanocomposite materials technology to understand and control reverse osmosis membrane compaction
journal, October 2010


Rational Design of a Tetrameric Protein to Enhance Interactions between Self-Assembled Fibers Gives Molecular Hydrogels
journal, March 2012

  • Zhang, Xiaoli; Chu, Xinlei; Wang, Ling
  • Angewandte Chemie International Edition, Vol. 51, Issue 18
  • DOI: 10.1002/anie.201108612

Nanofiltration membranes synthesized from hyperbranched polyethyleneimine
journal, January 2009


Water permeability and water/salt selectivity tradeoff in polymers for desalination
journal, March 2011


Extension of the Equation for the Annihilation Lifetime of ortho -Positronium at a Cavity Larger than 1 nm in Radius
journal, May 1999

  • Ito, Kenji; Nakanishi, Hiroshi; Ujihira, Yusuke
  • The Journal of Physical Chemistry B, Vol. 103, Issue 21
  • DOI: 10.1021/jp9831841

Permeability of N 2 , Ar, He, O 2 and CO 2 through biaxially oriented polyester films — dependence on free volume
journal, March 2001


Diffusion of small-molecule penetrants in polyethylene: free volume and morphology
journal, July 1996


Morphological study of poly(vinylidene fluoride) asymmetric membranes: Effects of the solvent, additive, and dope temperature
journal, January 2004

  • Yeow, M. L.; Liu, Y. T.; Li, K.
  • Journal of Applied Polymer Science, Vol. 92, Issue 3
  • DOI: 10.1002/app.20141

Hybrid Organic−Inorganic Membrane:  Solving the Tradeoff between Permeability and Selectivity
journal, December 2005

  • Peng, Fubing; Lu, Lianyu; Sun, Honglei
  • Chemistry of Materials, Vol. 17, Issue 26
  • DOI: 10.1021/cm051890q

Effects of molecular weight of polyvinylpyrrolidone on precipitation kinetics during the formation of asymmetric polyacrylonitrile membrane
journal, April 2002

  • Kang, Jong Seok; Lee, Young Moo
  • Journal of Applied Polymer Science, Vol. 85, Issue 1
  • DOI: 10.1002/app.10569

A simple shape-free model for pore-size estimation with positron annihilation lifetime spectroscopy
journal, June 2013


Program system for analysing positron lifetime spectra and angular correlation curves
journal, July 1981


On the structure and morphology of polyvinylidene fluoride–nanoclay nanocomposites
journal, February 2006


Preparation, characterization and performance enhancement of polysulfone ultrafiltration membrane using PBI as hydrophilic modifier
journal, February 2015


Improving the flux of PDMS membranes via localized heating through incorporation of gold nanoparticles
journal, February 2013


Intrinsically Hierarchical Nanoporous Polymers via Polymerization-Induced Microphase Separation
journal, May 2017


Porous PVDF asymmetric hollow fiber membranes prepared with the use of small molecular additives
journal, September 2000


Preparation of PVDF hollow-fiber membranes via immersion precipitation
journal, January 2001

  • Kong, Jianfeng; Li, K.
  • Journal of Applied Polymer Science, Vol. 81, Issue 7
  • DOI: 10.1002/app.1595

Preparation and characterization of modified nano-porous PVDF membrane with high antifouling property using UV photo-grafting
journal, May 2009


High-flux reverse osmosis membranes incorporated with hydrophilic additives for brackish water desalination
journal, January 2013


Characterization of fouled nanofiltration membranes using positron annihilation spectroscopy
journal, October 2011


Comparative Study of Different Probing Techniques for the Analysis of the Free Volume Distribution in Amorphous Glassy Perfluoropolymers
journal, October 2009

  • Jansen, Johannes C.; Macchione, Marialuigia; Tocci, Elena
  • Macromolecules, Vol. 42, Issue 19
  • DOI: 10.1021/ma901244d

Determinants of Water Permeability through Nanoscopic Hydrophilic Channels
journal, February 2009


Rational design of phase inversion membranes by tailoring thermodynamics and kinetics of casting solution using polymer additives
journal, August 2013


Unusual trend of increasing selectivity and decreasing flux with decreasing thickness in pervaporation separation of ethanol/water mixtures using sodium alginate blend membranes
journal, March 2012

  • Flynn, Eoin J.; Keane, Donal; Holmes, Justin D.
  • Journal of Colloid and Interface Science, Vol. 370, Issue 1
  • DOI: 10.1016/j.jcis.2011.12.022

Effect of high-temperature spinning and PVP additive on the properties of PVDF hollow fiber membranes for microfiltration
journal, December 2006

  • Cha, Bong Jun; Yang, Jung Mok
  • Macromolecular Research, Vol. 14, Issue 6
  • DOI: 10.1007/BF03218730

Incorporating Zwitterionic Graphene Oxides into Sodium Alginate Membrane for Efficient Water/Alcohol Separation
journal, January 2016

  • Zhao, Jing; Zhu, Yiwei; He, Guangwei
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 3
  • DOI: 10.1021/acsami.5b10551

Water Transportation in Epoxy Resin
journal, February 2005

  • Li, Liang; Zhang, ShuYong; Chen, YueHui
  • Chemistry of Materials, Vol. 17, Issue 4
  • DOI: 10.1021/cm048884z

Clarification of Orange Press Liquors by PVDF Hollow Fiber Membranes
journal, January 2016


Effect of molecular weight of PEG on membrane morphology and transport properties
journal, February 2008


Correlations between free volume characteristics and pervaporation permeability of novel PVA–GPTMS hybrid membranes
journal, April 2006


Modification of PVDF membrane by chitosan solution for reducing protein fouling
journal, October 2009

  • Boributh, Somnuk; Chanachai, Ampai; Jiraratananon, Ratana
  • Journal of Membrane Science, Vol. 342, Issue 1-2
  • DOI: 10.1016/j.memsci.2009.06.022

Effects of water chemistry on structure and performance of polyamide composite membranes
journal, February 2014


Structure and ionic conductivity of porous polymer electrolytes based on PVDF-HFP copolymer membranes
journal, September 2006


Preparation and characterization of polyvinylidene fluoride (PVDF) hollow fiber membranes
journal, November 1999


Effect of added NaX nano-zeolite into polyamide as a top thin layer of membrane on water flux and salt rejection in a reverse osmosis process
journal, June 2011

  • Fathizadeh, Mahdi; Aroujalian, Abdolreza; Raisi, Ahmadreza
  • Journal of Membrane Science, Vol. 375, Issue 1-2
  • DOI: 10.1016/j.memsci.2011.03.017

Recent advances in the formation of phase inversion membranes made from amorphous or semi-crystalline polymers
journal, May 1996


Positron annihilation in amine-cured epoxy polymers—pressure dependence
journal, August 1990

  • Wang, Y. Y.; Nakanishi, H.; Jean, Y. C.
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 28, Issue 9
  • DOI: 10.1002/polb.1990.090280902

Progress in the production and modification of PVDF membranes
journal, June 2011


High flux composite PTMSP-silica nanohybrid membranes for the pervaporation of ethanol/water mixtures
journal, April 2010


Performances of poly(vinylidene fluoride- co -hexafluoropropylene) ultrafiltration membranes modified with poly(vinyl pyrrolidone)
journal, June 2015

  • Kanagaraj, Palsamy; Nagendran, Alagumalai; Rana, Dipak
  • Polymer Engineering & Science, Vol. 55, Issue 11
  • DOI: 10.1002/pen.24138

High flux low pressure thin film nanocomposite ultrafiltration membranes based on nanofibrous substrates
journal, April 2013


Preparation of hollow fibre membranes from PVDF/PVP blends and their application in VMD
journal, November 2010


The upper bound of thin-film composite (TFC) polyamide membranes for desalination
journal, November 2019


Surface grafting control of PEGylated poly(vinylidene fluoride) antifouling membrane via surface-initiated radical graft copolymerization
journal, December 2009


Free-volume hole relaxation in molecularly oriented glassy polymers
journal, February 2014


Influence of the addition of PVP on the morphology of asymmetric polyimide phase inversion membranes: effect of PVP molecular weight
journal, June 2004


Maximizing the right stuff: The trade-off between membrane permeability and selectivity
journal, June 2017


Isothermal phase diagrams and phase-inversion behavior of poly(vinylidene fluoride)/solvents/additives/water systems
journal, January 2003

  • Yeow, M. L.; Liu, Y. T.; Li, K.
  • Journal of Applied Polymer Science, Vol. 90, Issue 8
  • DOI: 10.1002/app.12846

Enhanced water permeation through sodium alginate membranes by incorporating graphene oxides
journal, November 2014


Effect of PEG additives on properties and morphologies of polyetherimide membranes prepared by phase inversion
journal, January 2010

  • Chen, Jian; Li, Jiding; Zhan, Xia
  • Frontiers of Chemical Engineering in China, Vol. 4, Issue 3
  • DOI: 10.1007/s11705-009-0280-8

Perspective of Positron Annihilation Spectroscopy in Polymers
journal, August 2013

  • Jean, Y. C.; Van Horn, J. David; Hung, Wei-Song
  • Macromolecules, Vol. 46, Issue 18
  • DOI: 10.1021/ma401309x

Preparation and Characterization of Membranes Formed by Nonsolvent Induced Phase Separation: A Review
journal, April 2011

  • Guillen, Gregory R.; Pan, Yinjin; Li, Minghua
  • Industrial & Engineering Chemistry Research, Vol. 50, Issue 7
  • DOI: 10.1021/ie101928r

Hydrophilic modification of poly (vinylidene fluoride) microporous membrane
journal, February 2009


Effects of mixed solvents and PVDF types on performances of PVDF microporous membranes
journal, February 2010

  • Li, Qian; Xu, Zhen-Liang; Yu, Li-Yun
  • Journal of Applied Polymer Science, Vol. 115, Issue 4
  • DOI: 10.1002/app.31324

Synthesis of PVDF ultrafiltration membranes supported on polyester fabrics for separation of organic matter from water
journal, August 2014

  • Mhlanga, Sabelo D.; Tshabalala, Tumelo G.; Nxumalo, Edward N.
  • IOP Conference Series: Materials Science and Engineering, Vol. 64
  • DOI: 10.1088/1757-899X/64/1/012036

Trade-off between thermodynamic enhancement and kinetic hindrance during phase inversion in the preparation of polysulfone membranes
journal, November 2003


Analysis of annealing effect on pervaporation properties of PVA-GPTMS hybrid membranes through PALS
journal, September 2006


Fabrication and characterization of multi-walled carbon nanotubes/polymer blend membranes
journal, November 2006


High flux nanofiltration membranes based on interfacially polymerized polyamide barrier layer on polyacrylonitrile nanofibrous scaffolds
journal, January 2009