Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships

Eren, Bilge; Eren, Erdal; Guney, Murat; Jean, Yan‐Ching; Van Horn, J. David

doi:10.1002/pol.20190031

Title: Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships

Authors:

^[1]; Eren, Erdal ^[1]; Guney, Murat ^[1]; Jean, Yan‐Ching ^[2];

^[2]

Faculty of Science and Arts, Department of Chemistry Bilecik Seyh Edebali University 11210 Bilecik Turkey
Department of Chemistry University of Missouri‐Kansas City Kansas City Missouri 64110

Publication Date:: 2020-01-20

Sponsoring Org.:: USDOE

OSTI Identifier:: 1592521

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Polymer Science

Additional Journal Information:: Journal Name: Journal of Polymer Science Journal Volume: 58 Journal Issue: 4; Journal ID: ISSN 2642-4150

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: United States

Language:: English

Citation Formats


                    Eren, Bilge, Eren, Erdal, Guney, Murat, Jean, Yan‐Ching, and Van Horn, J. David. Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships.  United States: N. p., 2020. 
Web.  doi:10.1002/pol.20190031.

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                    Eren, Bilge, Eren, Erdal, Guney, Murat, Jean, Yan‐Ching, & Van Horn, J. David. Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships.  United States.  https://doi.org/10.1002/pol.20190031

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                    Eren, Bilge, Eren, Erdal, Guney, Murat, Jean, Yan‐Ching, and Van Horn, J. David. Mon .  
"Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships".  United States.  https://doi.org/10.1002/pol.20190031.

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@article{osti_1592521,

  title        = {Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships},

  author       = {Eren, Bilge and Eren, Erdal and Guney, Murat and Jean, Yan‐Ching and Van Horn, J. David},

  abstractNote = {},

  doi          = {10.1002/pol.20190031},

  journal      = {Journal of Polymer Science},

  number       = 4,

  volume       = 58,

  place        = {United States},

  year         = {2020},

  month        = {1}

}

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The states of water within poly(vinyl alcohol) thin films part 1: Investigations by positron annihilation lifetime spectroscopy

Conference Hodge, R M ; Edward, G H ; Simon, G P ; ...

In order to produce poly(vinyl alcohol) (PVA) material suitable for thermoplastic processing, it is necessary to plasticize the polymer with water. In the present study the accommodation of water within the PVA network is examined. Positron annihilation lifetime spectroscopy (PALS) is used to determine the effect of water on the free volume of the polymer. The PALS parameters give information on the average size of the free volume sites and the relative concentration of free volume sites. A model is proposed in which water initially enters the polymer in a molecular form, distributing itself along and becoming bound to themore »« less
Characterization of fatigue-induced free volume changes in a bulk metallic glass using positron annihilation spectroscopy

Journal Article Vallery, R S ; Liu, M ; Gidley, D W ; ... - Applied Physics Letters

Depth-profiled Doppler broadening spectroscopy of positron annihilation on the cyclic fatigue-induced fracture surfaces of three amorphous Zr{sub 44}Ti{sub 11}Ni{sub 10}Cu{sub 10}Be{sub 25} metallic glass specimens reveals the presence of a 30-50 nm layer of increased free volume that is generated by the propagating fatigue crack tip. The presence and character of this fatigue transformation zone is independent of the initial amount of bulk free volume, which was varied by structural relaxation via annealing, and the voids generated in the zone by intense cyclic deformation are distinct from those typical of the bulk.
https://doi.org/10.1063/1.2825427

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Title: Positron annihilation lifetime spectroscopy study of polyvinylpyrrolidone‐added polyvinylidene fluoride membranes: Investigation of free volume and permeation relationships

Citation Formats

Pervaporative seawater desalination using NaA zeolite membrane: Mechanisms of high water flux and high salt rejection journal, April 2011

Slow hydrophobic hydration induced polymer ultrafiltration membranes with high water flux journal, December 2014

The kinetic study for asymmetric membrane formation via phase-inversion process journal, October 1996

Controlled synthesis of high performance polyamide membrane with thin dense layer for water desalination journal, October 2010

Positronium Annihilation in Molecular Substances journal, June 1972

Applications of Positron Annihilation Spectroscopy to Life Science journal, September 2012

Non-isothermal crystallization of PVDF/PMMA blends processed in low and high shear mixers journal, September 2012

Using nanocomposite materials technology to understand and control reverse osmosis membrane compaction journal, October 2010

Rational Design of a Tetrameric Protein to Enhance Interactions between Self-Assembled Fibers Gives Molecular Hydrogels journal, March 2012

Nanofiltration membranes synthesized from hyperbranched polyethyleneimine journal, January 2009

Water permeability and water/salt selectivity tradeoff in polymers for desalination journal, March 2011

Extension of the Equation for the Annihilation Lifetime of ortho -Positronium at a Cavity Larger than 1 nm in Radius journal, May 1999

Permeability of N 2 , Ar, He, O 2 and CO 2 through biaxially oriented polyester films — dependence on free volume journal, March 2001

Diffusion of small-molecule penetrants in polyethylene: free volume and morphology journal, July 1996

Morphological study of poly(vinylidene fluoride) asymmetric membranes: Effects of the solvent, additive, and dope temperature journal, January 2004

Hybrid Organic−Inorganic Membrane: Solving the Tradeoff between Permeability and Selectivity journal, December 2005

Effects of molecular weight of polyvinylpyrrolidone on precipitation kinetics during the formation of asymmetric polyacrylonitrile membrane journal, April 2002

Preparation of poly(vinylidene fluoride)(pvdf) ultrafiltration membrane modified by nano-sized alumina (Al2O3) and its antifouling research journal, August 2005

A simple shape-free model for pore-size estimation with positron annihilation lifetime spectroscopy journal, June 2013

Program system for analysing positron lifetime spectra and angular correlation curves journal, July 1981

On the structure and morphology of polyvinylidene fluoride–nanoclay nanocomposites journal, February 2006

Preparation, characterization and performance enhancement of polysulfone ultrafiltration membrane using PBI as hydrophilic modifier journal, February 2015

Improving the flux of PDMS membranes via localized heating through incorporation of gold nanoparticles journal, February 2013

Intrinsically Hierarchical Nanoporous Polymers via Polymerization-Induced Microphase Separation journal, May 2017

Porous PVDF asymmetric hollow fiber membranes prepared with the use of small molecular additives journal, September 2000

Preparation of PVDF hollow-fiber membranes via immersion precipitation journal, January 2001

Preparation and characterization of modified nano-porous PVDF membrane with high antifouling property using UV photo-grafting journal, May 2009

High-flux reverse osmosis membranes incorporated with hydrophilic additives for brackish water desalination journal, January 2013

Characterization of fouled nanofiltration membranes using positron annihilation spectroscopy journal, October 2011

Comparative Study of Different Probing Techniques for the Analysis of the Free Volume Distribution in Amorphous Glassy Perfluoropolymers journal, October 2009

Determinants of Water Permeability through Nanoscopic Hydrophilic Channels journal, February 2009

Rational design of phase inversion membranes by tailoring thermodynamics and kinetics of casting solution using polymer additives journal, August 2013

Unusual trend of increasing selectivity and decreasing flux with decreasing thickness in pervaporation separation of ethanol/water mixtures using sodium alginate blend membranes journal, March 2012

Preparation of ultra-thin poly(vinyl alcohol) membranes supported on polysulfone hollow fiber and their application for production of pure water from seawater journal, July 2015

Effect of high-temperature spinning and PVP additive on the properties of PVDF hollow fiber membranes for microfiltration journal, December 2006

Incorporating Zwitterionic Graphene Oxides into Sodium Alginate Membrane for Efficient Water/Alcohol Separation journal, January 2016

Water Transportation in Epoxy Resin journal, February 2005

Clarification of Orange Press Liquors by PVDF Hollow Fiber Membranes journal, January 2016

Effect of molecular weight of PEG on membrane morphology and transport properties journal, February 2008

Multilayered Poly(vinylidene fluoride) Composite Membranes with Improved Interfacial Compatibility: Correlating Pervaporation Performance with Free Volume Properties journal, September 2011

Correlations between free volume characteristics and pervaporation permeability of novel PVA–GPTMS hybrid membranes journal, April 2006

Modification of PVDF membrane by chitosan solution for reducing protein fouling journal, October 2009

Effects of water chemistry on structure and performance of polyamide composite membranes journal, February 2014

Structure and ionic conductivity of porous polymer electrolytes based on PVDF-HFP copolymer membranes journal, September 2006

Preparation and characterization of polyvinylidene fluoride (PVDF) hollow fiber membranes journal, November 1999

Effect of added NaX nano-zeolite into polyamide as a top thin layer of membrane on water flux and salt rejection in a reverse osmosis process journal, June 2011

Recent advances in the formation of phase inversion membranes made from amorphous or semi-crystalline polymers journal, May 1996

Positron annihilation in amine-cured epoxy polymers—pressure dependence journal, August 1990

Progress in the production and modification of PVDF membranes journal, June 2011

High flux composite PTMSP-silica nanohybrid membranes for the pervaporation of ethanol/water mixtures journal, April 2010

Performances of poly(vinylidene fluoride- co -hexafluoropropylene) ultrafiltration membranes modified with poly(vinyl pyrrolidone) journal, June 2015

High flux low pressure thin film nanocomposite ultrafiltration membranes based on nanofibrous substrates journal, April 2013

Effect of additives on the morphology and properties of poly(vinylidene fluoride) blend hollow fiber membrane prepared by the thermally induced phase separation method journal, December 2012

Effect of Free Volume on Water and Salt Transport Properties in Directly Copolymerized Disulfonated Poly(arylene ether sulfone) Random Copolymers journal, June 2011

Preparation of hollow fibre membranes from PVDF/PVP blends and their application in VMD journal, November 2010

High flux positively charged nanofiltration membranes prepared by UV-initiated graft polymerization of methacrylatoethyl trimethyl ammonium chloride (DMC) onto polysulfone membranes journal, January 2011

The upper bound of thin-film composite (TFC) polyamide membranes for desalination journal, November 2019

Surface grafting control of PEGylated poly(vinylidene fluoride) antifouling membrane via surface-initiated radical graft copolymerization journal, December 2009

Free-volume hole relaxation in molecularly oriented glassy polymers journal, February 2014

Influence of the addition of PVP on the morphology of asymmetric polyimide phase inversion membranes: effect of PVP molecular weight journal, June 2004

Maximizing the right stuff: The trade-off between membrane permeability and selectivity journal, June 2017

Isothermal phase diagrams and phase-inversion behavior of poly(vinylidene fluoride)/solvents/additives/water systems journal, January 2003

Enhanced water permeation through sodium alginate membranes by incorporating graphene oxides journal, November 2014

Pervaporation separation of a ternary azeotrope containing ethyl acetate, ethanol and water using a buckypaper supported ionic liquid membrane journal, May 2016

Effect of PEG additives on properties and morphologies of polyetherimide membranes prepared by phase inversion journal, January 2010

Design and performance of foul-resistant poly(vinylidene fluoride) membranes prepared in a single-step by surface segregation journal, June 2002

Perspective of Positron Annihilation Spectroscopy in Polymers journal, August 2013

Thermodynamic and rheological variation in polysulfone solution by PVP and its effect in the preparation of phase inversion membrane journal, June 2002

Preparation and Characterization of Membranes Formed by Nonsolvent Induced Phase Separation: A Review journal, April 2011

Hydrophilic modification of poly (vinylidene fluoride) microporous membrane journal, February 2009

Porous PVDF/TPU blends asymmetric hollow fiber membranes prepared with the use of hydrophilic additive PVP (K30) journal, March 2008

Effects of mixed solvents and PVDF types on performances of PVDF microporous membranes journal, February 2010

Role of free volume characteristics of polymer matrix in bulk physical properties of polymer nanocomposites: A review of positron annihilation lifetime studies journal, December 2017

Positron annihilation spectroscopy for chemical analysis: A novel probe for microstructural analysis of polymers journal, August 1990

Synthesis of PVDF ultrafiltration membranes supported on polyester fabrics for separation of organic matter from water journal, August 2014

Relationship between performance deterioration of a polyamide reverse osmosis membrane used in a seawater desalination plant and changes in its physicochemical properties journal, September 2016

Surface immobilization of polymer brushes onto porous poly(vinylidene fluoride) membrane by electron beam to improve the hydrophilicity and fouling resistance journal, May 2007

Evolution of the precipitation kinetics, morphologies, permeation performances, and crystallization behaviors of polyvinylidenefluoride (PVDF) hollow fiber membrane by adding different molecular weight polyvinylpyrrolidone (PVP) journal, January 2010

Pervaporative seawater desalination using NaA zeolite membrane: Mechanisms of high water flux and high salt rejection
journal, April 2011

Slow hydrophobic hydration induced polymer ultrafiltration membranes with high water flux
journal, December 2014

The kinetic study for asymmetric membrane formation via phase-inversion process
journal, October 1996

Controlled synthesis of high performance polyamide membrane with thin dense layer for water desalination
journal, October 2010

Positronium Annihilation in Molecular Substances
journal, June 1972

Applications of Positron Annihilation Spectroscopy to Life Science
journal, September 2012

Non-isothermal crystallization of PVDF/PMMA blends processed in low and high shear mixers
journal, September 2012

Using nanocomposite materials technology to understand and control reverse osmosis membrane compaction
journal, October 2010

Rational Design of a Tetrameric Protein to Enhance Interactions between Self-Assembled Fibers Gives Molecular Hydrogels
journal, March 2012

Nanofiltration membranes synthesized from hyperbranched polyethyleneimine
journal, January 2009

Water permeability and water/salt selectivity tradeoff in polymers for desalination
journal, March 2011

Extension of the Equation for the Annihilation Lifetime of ortho -Positronium at a Cavity Larger than 1 nm in Radius
journal, May 1999

Permeability of N 2 , Ar, He, O 2 and CO 2 through biaxially oriented polyester films — dependence on free volume
journal, March 2001

Diffusion of small-molecule penetrants in polyethylene: free volume and morphology
journal, July 1996

Morphological study of poly(vinylidene fluoride) asymmetric membranes: Effects of the solvent, additive, and dope temperature
journal, January 2004

Hybrid Organic−Inorganic Membrane: Solving the Tradeoff between Permeability and Selectivity
journal, December 2005

Effects of molecular weight of polyvinylpyrrolidone on precipitation kinetics during the formation of asymmetric polyacrylonitrile membrane
journal, April 2002

Preparation of poly(vinylidene fluoride)(pvdf) ultrafiltration membrane modified by nano-sized alumina (Al2O3) and its antifouling research
journal, August 2005

A simple shape-free model for pore-size estimation with positron annihilation lifetime spectroscopy
journal, June 2013

Program system for analysing positron lifetime spectra and angular correlation curves
journal, July 1981

On the structure and morphology of polyvinylidene fluoride–nanoclay nanocomposites
journal, February 2006

Preparation, characterization and performance enhancement of polysulfone ultrafiltration membrane using PBI as hydrophilic modifier
journal, February 2015

Improving the flux of PDMS membranes via localized heating through incorporation of gold nanoparticles
journal, February 2013

Intrinsically Hierarchical Nanoporous Polymers via Polymerization-Induced Microphase Separation
journal, May 2017

Porous PVDF asymmetric hollow fiber membranes prepared with the use of small molecular additives
journal, September 2000

Preparation of PVDF hollow-fiber membranes via immersion precipitation
journal, January 2001

Preparation and characterization of modified nano-porous PVDF membrane with high antifouling property using UV photo-grafting
journal, May 2009

High-flux reverse osmosis membranes incorporated with hydrophilic additives for brackish water desalination
journal, January 2013

Characterization of fouled nanofiltration membranes using positron annihilation spectroscopy
journal, October 2011

Comparative Study of Different Probing Techniques for the Analysis of the Free Volume Distribution in Amorphous Glassy Perfluoropolymers
journal, October 2009

Determinants of Water Permeability through Nanoscopic Hydrophilic Channels
journal, February 2009

Rational design of phase inversion membranes by tailoring thermodynamics and kinetics of casting solution using polymer additives
journal, August 2013

Unusual trend of increasing selectivity and decreasing flux with decreasing thickness in pervaporation separation of ethanol/water mixtures using sodium alginate blend membranes
journal, March 2012

Preparation of ultra-thin poly(vinyl alcohol) membranes supported on polysulfone hollow fiber and their application for production of pure water from seawater
journal, July 2015

Effect of high-temperature spinning and PVP additive on the properties of PVDF hollow fiber membranes for microfiltration
journal, December 2006

Incorporating Zwitterionic Graphene Oxides into Sodium Alginate Membrane for Efficient Water/Alcohol Separation
journal, January 2016

Water Transportation in Epoxy Resin
journal, February 2005

Clarification of Orange Press Liquors by PVDF Hollow Fiber Membranes
journal, January 2016

Effect of molecular weight of PEG on membrane morphology and transport properties
journal, February 2008

Multilayered Poly(vinylidene fluoride) Composite Membranes with Improved Interfacial Compatibility: Correlating Pervaporation Performance with Free Volume Properties
journal, September 2011

Correlations between free volume characteristics and pervaporation permeability of novel PVA–GPTMS hybrid membranes
journal, April 2006

Modification of PVDF membrane by chitosan solution for reducing protein fouling
journal, October 2009

Effects of water chemistry on structure and performance of polyamide composite membranes
journal, February 2014

Structure and ionic conductivity of porous polymer electrolytes based on PVDF-HFP copolymer membranes
journal, September 2006

Preparation and characterization of polyvinylidene fluoride (PVDF) hollow fiber membranes
journal, November 1999

Effect of added NaX nano-zeolite into polyamide as a top thin layer of membrane on water flux and salt rejection in a reverse osmosis process
journal, June 2011

Recent advances in the formation of phase inversion membranes made from amorphous or semi-crystalline polymers
journal, May 1996

Positron annihilation in amine-cured epoxy polymers—pressure dependence
journal, August 1990

Progress in the production and modification of PVDF membranes
journal, June 2011

High flux composite PTMSP-silica nanohybrid membranes for the pervaporation of ethanol/water mixtures
journal, April 2010

Performances of poly(vinylidene fluoride- co -hexafluoropropylene) ultrafiltration membranes modified with poly(vinyl pyrrolidone)
journal, June 2015

High flux low pressure thin film nanocomposite ultrafiltration membranes based on nanofibrous substrates
journal, April 2013

Effect of additives on the morphology and properties of poly(vinylidene fluoride) blend hollow fiber membrane prepared by the thermally induced phase separation method
journal, December 2012

Effect of Free Volume on Water and Salt Transport Properties in Directly Copolymerized Disulfonated Poly(arylene ether sulfone) Random Copolymers
journal, June 2011

Preparation of hollow fibre membranes from PVDF/PVP blends and their application in VMD
journal, November 2010

High flux positively charged nanofiltration membranes prepared by UV-initiated graft polymerization of methacrylatoethyl trimethyl ammonium chloride (DMC) onto polysulfone membranes
journal, January 2011

The upper bound of thin-film composite (TFC) polyamide membranes for desalination
journal, November 2019

Surface grafting control of PEGylated poly(vinylidene fluoride) antifouling membrane via surface-initiated radical graft copolymerization
journal, December 2009

Free-volume hole relaxation in molecularly oriented glassy polymers
journal, February 2014

Influence of the addition of PVP on the morphology of asymmetric polyimide phase inversion membranes: effect of PVP molecular weight
journal, June 2004

Maximizing the right stuff: The trade-off between membrane permeability and selectivity
journal, June 2017

Isothermal phase diagrams and phase-inversion behavior of poly(vinylidene fluoride)/solvents/additives/water systems
journal, January 2003

Enhanced water permeation through sodium alginate membranes by incorporating graphene oxides
journal, November 2014

Pervaporation separation of a ternary azeotrope containing ethyl acetate, ethanol and water using a buckypaper supported ionic liquid membrane
journal, May 2016

Effect of PEG additives on properties and morphologies of polyetherimide membranes prepared by phase inversion
journal, January 2010

Design and performance of foul-resistant poly(vinylidene fluoride) membranes prepared in a single-step by surface segregation
journal, June 2002

Perspective of Positron Annihilation Spectroscopy in Polymers
journal, August 2013

Thermodynamic and rheological variation in polysulfone solution by PVP and its effect in the preparation of phase inversion membrane
journal, June 2002

Preparation and Characterization of Membranes Formed by Nonsolvent Induced Phase Separation: A Review
journal, April 2011

Hydrophilic modification of poly (vinylidene fluoride) microporous membrane
journal, February 2009

Porous PVDF/TPU blends asymmetric hollow fiber membranes prepared with the use of hydrophilic additive PVP (K30)
journal, March 2008

Effects of mixed solvents and PVDF types on performances of PVDF microporous membranes
journal, February 2010

Role of free volume characteristics of polymer matrix in bulk physical properties of polymer nanocomposites: A review of positron annihilation lifetime studies
journal, December 2017

Positron annihilation spectroscopy for chemical analysis: A novel probe for microstructural analysis of polymers
journal, August 1990

Synthesis of PVDF ultrafiltration membranes supported on polyester fabrics for separation of organic matter from water
journal, August 2014

Relationship between performance deterioration of a polyamide reverse osmosis membrane used in a seawater desalination plant and changes in its physicochemical properties
journal, September 2016

Surface immobilization of polymer brushes onto porous poly(vinylidene fluoride) membrane by electron beam to improve the hydrophilicity and fouling resistance
journal, May 2007

Evolution of the precipitation kinetics, morphologies, permeation performances, and crystallization behaviors of polyvinylidenefluoride (PVDF) hollow fiber membrane by adding different molecular weight polyvinylpyrrolidone (PVP)
journal, January 2010

Trade-off between thermodynamic enhancement and kinetic hindrance during phase inversion in the preparation of polysulfone membranes
journal, November 2003

Analysis of annealing effect on pervaporation properties of PVA-GPTMS hybrid membranes through PALS
journal, September 2006