A collective elastic fluctuation mechanism for decoupling and stretched relaxation in glassy colloidal and molecular liquids

doi:10.1063/1.5129550

Title: A collective elastic fluctuation mechanism for decoupling and stretched relaxation in glassy colloidal and molecular liquids

Authors:

^[1];

^[2]

Department of Materials Science, University of Illinois, Urbana, Illinois 61801, USA, Material Research Laboratory, University of Illinois, Urbana, Illinois 61801, USA, Center for Membrane Separation and Water Science and Technology, Ocean College, Zhejiang University of Technology, Hangzhou 310014, People’s Republic of China
Department of Materials Science, University of Illinois, Urbana, Illinois 61801, USA, Material Research Laboratory, University of Illinois, Urbana, Illinois 61801, USA, Department of Chemistry, University of Illinois, Urbana, Illinois 61801, USA

Publication Date:: 2020-01-21

Sponsoring Org.:: USDOE

OSTI Identifier:: 1592191

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Chemical Physics

Additional Journal Information:: Journal Name: Journal of Chemical Physics Journal Volume: 152 Journal Issue: 3; Journal ID: ISSN 0021-9606

Publisher:: American Institute of Physics

Country of Publication:: United States

Language:: English

Citation Formats


                    Xie, Shi-Jie, and Schweizer, Kenneth S. A collective elastic fluctuation mechanism for decoupling and stretched relaxation in glassy colloidal and molecular liquids.  United States: N. p., 2020. 
        Web.  doi:10.1063/1.5129550.

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                    Xie, Shi-Jie, & Schweizer, Kenneth S. A collective elastic fluctuation mechanism for decoupling and stretched relaxation in glassy colloidal and molecular liquids.  United States.  doi:10.1063/1.5129550.

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                    Xie, Shi-Jie, and Schweizer, Kenneth S. Tue .  
        "A collective elastic fluctuation mechanism for decoupling and stretched relaxation in glassy colloidal and molecular liquids".  United States.  doi:10.1063/1.5129550.

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@article{osti_1592191,

  title        = {A collective elastic fluctuation mechanism for decoupling and stretched relaxation in glassy colloidal and molecular liquids},

  author       = {Xie, Shi-Jie and Schweizer, Kenneth S.},

  abstractNote = {},

  doi          = {10.1063/1.5129550},

  journal      = {Journal of Chemical Physics},

  number       = 3,

  volume       = 152,

  place        = {United States},

  year         = {2020},

  month        = {1}

}

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DOI: 10.1063/1.5129550

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Nonuniversal Coupling of Cage Scale Hopping and Collective Elastic Distortion as the Origin of Dynamic Fragility Diversity in Glass-Forming Polymer Liquids
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Title: A collective elastic fluctuation mechanism for decoupling and stretched relaxation in glassy colloidal and molecular liquids

Citation Formats

Energy barriers and activated dynamics in a supercooled Lennard-Jones liquid journal, March 2003

Heterogeneous Rouse Model Predicts Polymer Chain Translational Normal Mode Decoupling journal, April 2018

Enhanced translation of probe molecules in supercooled o ‐terphenyl: Signature of spatially heterogeneous dynamics? journal, May 1996

Perspective: Supercooled liquids and glasses journal, August 2012

Analytic treatment of cooperativity effects in supercooled liquids within the framework of the random-walk model journal, July 1995

Rotational Relaxation in ortho -Terphenyl: Using Atomistic Simulations to Bridge Theory and Experiment journal, July 2013

Biphasic rate exchange in supercooled o -terphenyl from an ensemble analysis of single-molecule data journal, October 2018

Activated hopping and dynamical fluctuation effects in hard sphere suspensions and fluids journal, July 2006

Colloquium : The glass transition and elastic models of glass-forming liquids journal, September 2006

Theory of Structural Glasses and Supercooled Liquids journal, May 2007

Lifetime of dynamical heterogeneity in a highly supercooled liquid journal, September 2010

Static lengths in glass-forming monodisperse hard-sphere fluids from periodic array pinning journal, January 2016

Local elastic expansion model for viscous-flow activation energies of glass-forming molecular liquids journal, February 1996

Heterogeneous Viscoelasticity: A Combined Theory of Dynamic and Elastic Heterogeneity journal, July 2015

Nature of the breakdown in the Stokes-Einstein relationship in a hard sphere fluid journal, June 2006

Recent tests of the mode-coupling theory for glassy dynamics journal, January 1999

Heterogeneous relaxation patterns in supercooled liquids studied by solvation dynamics journal, February 2000

Glass transition in colloidal hard spheres: Measurement and mode-coupling-theory analysis of the coherent intermediate scattering function journal, May 1994

Heterogeneous Dynamics and Domains in Supercooled o -Terphenyl: A Single Molecule Study journal, November 2002

Prevalence of approximate t relaxation for the dielectric α process in viscous organic liquids journal, April 2009

Single molecule studies reveal temperature independence of lifetime of dynamic heterogeneity in polystyrene journal, May 2018

From boiling point to glass transition temperature: Transport coefficients in molecular liquids follow three-parameter scaling journal, October 2012

Activated Hopping, Barrier Fluctuations, and Heterogeneity in Glassy Suspensions and Liquids † journal, December 2004

The temperature dependence of the viscoelastic softening and terminal dispersions of linear amorphous polymers journal, April 1982

Evolution of the dynamic susceptibility in molecular glass formers: Results from light scattering, dielectric spectroscopy, and NMR journal, March 2013

Bulk and shear relaxation in glasses and highly viscous liquids journal, June 2012

On the dielectric susceptibility spectra of supercooled o-terphenyl journal, October 2005

Reorientational dynamics in molecular liquids as revealed by dynamic light scattering: From boiling point to glass transition temperature journal, August 2013

How Long Do Regions of Different Dynamics Persist in Supercooled o -Terphenyl? journal, May 1999

Nonuniversal Coupling of Cage Scale Hopping and Collective Elastic Distortion as the Origin of Dynamic Fragility Diversity in Glass-Forming Polymer Liquids journal, December 2016

Breakdown of Time−Temperature Superposition Principle and Universality of Chain Dynamics in Polymers journal, May 2006

Single Molecule Experiments Reveal the Dynamic Heterogeneity and Exchange Time Scales of Polystyrene near the Glass Transition journal, March 2016

Unified Theory of Activated Relaxation in Liquids over 14 Decades in Time journal, October 2013

Mode-coupling approximations, glass theory and disordered systems journal, May 1996

Dynamics on the Way to Forming Glass: Bubbles in Space-Time journal, March 2010

Ideal probe single-molecule experiments reveal the intrinsic dynamic heterogeneity of a supercooled liquid journal, March 2015

Resolving the Mystery of the Chain Friction Mechanism in Polymer Liquids journal, June 2009

Direct observation of molecular cooperativity near the glass transition journal, December 2000

Models of traps and glass phenomenology journal, July 1996

Glassy dynamics journal, January 2000

Collisions, caging, thermodynamics, and jamming in the barrier hopping theory of glassy hard sphere fluids journal, October 2007

Reaction-rate theory: fifty years after Kramers journal, April 1990

Master-equation appoach to the glass transition journal, February 1987

Energy master equation: A low-temperature approximation to Bässler’s random-walk model journal, May 1995

Translational and rotational diffusion in supercooled orthoterphenyl close to the glass transition journal, June 1992

Measurement of the self-intermediate scattering function of suspensions of hard spherical particles near the glass transition journal, November 1998

Microscopic Theory of Heterogeneity and Nonexponential Relaxations in Supercooled Liquids journal, June 2001

Supercooled liquids and the glass transition journal, March 2001

Entropic barriers, activated hopping, and the glass transition in colloidal suspensions journal, July 2003

Theoretical perspective on the glass transition and amorphous materials journal, June 2011

Source of non-Arrhenius average relaxation time in glass-forming liquids journal, August 1998

Heterogeneous dynamics at the glass transition in van der Waals liquids, in the bulk and in thin films journal, March 2001

Dynamical heterogeneity in a highly supercooled liquid: Consistent calculations of correlation length, intensity, and lifetime journal, July 2011

Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. I. General formulation and application to hard sphere fluids journal, May 2014

A structural approach to relaxation in glassy liquids journal, February 2016

Self-Diffusion of Supercooled Tris-naphthylbenzene journal, April 2009

Derivation of a microscopic theory of barriers and activated hopping transport in glassy liquids and suspensions journal, December 2005

Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. II. Thermal liquids journal, May 2014

Hopping in a supercooled Lennard-Jones liquid: Metabasins, waiting time distribution, and diffusion journal, March 2003

S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS journal, October 2000

Energy barriers and activated dynamics in a supercooled Lennard-Jones liquid
journal, March 2003

Heterogeneous Rouse Model Predicts Polymer Chain Translational Normal Mode Decoupling
journal, April 2018

Enhanced translation of probe molecules in supercooled o ‐terphenyl: Signature of spatially heterogeneous dynamics?
journal, May 1996

Perspective: Supercooled liquids and glasses
journal, August 2012

Analytic treatment of cooperativity effects in supercooled liquids within the framework of the random-walk model
journal, July 1995

Rotational Relaxation in ortho -Terphenyl: Using Atomistic Simulations to Bridge Theory and Experiment
journal, July 2013

Biphasic rate exchange in supercooled o -terphenyl from an ensemble analysis of single-molecule data
journal, October 2018

Activated hopping and dynamical fluctuation effects in hard sphere suspensions and fluids
journal, July 2006

Colloquium : The glass transition and elastic models of glass-forming liquids
journal, September 2006

Theory of Structural Glasses and Supercooled Liquids
journal, May 2007

Lifetime of dynamical heterogeneity in a highly supercooled liquid
journal, September 2010

Static lengths in glass-forming monodisperse hard-sphere fluids from periodic array pinning
journal, January 2016

Local elastic expansion model for viscous-flow activation energies of glass-forming molecular liquids
journal, February 1996

Heterogeneous Viscoelasticity: A Combined Theory of Dynamic and Elastic Heterogeneity
journal, July 2015

Nature of the breakdown in the Stokes-Einstein relationship in a hard sphere fluid
journal, June 2006

Recent tests of the mode-coupling theory for glassy dynamics
journal, January 1999

Heterogeneous relaxation patterns in supercooled liquids studied by solvation dynamics
journal, February 2000

Glass transition in colloidal hard spheres: Measurement and mode-coupling-theory analysis of the coherent intermediate scattering function
journal, May 1994

Heterogeneous Dynamics and Domains in Supercooled o -Terphenyl: A Single Molecule Study
journal, November 2002

Prevalence of approximate t relaxation for the dielectric α process in viscous organic liquids
journal, April 2009

Single molecule studies reveal temperature independence of lifetime of dynamic heterogeneity in polystyrene
journal, May 2018

From boiling point to glass transition temperature: Transport coefficients in molecular liquids follow three-parameter scaling
journal, October 2012

Activated Hopping, Barrier Fluctuations, and Heterogeneity in Glassy Suspensions and Liquids ^†
journal, December 2004

The temperature dependence of the viscoelastic softening and terminal dispersions of linear amorphous polymers
journal, April 1982

Evolution of the dynamic susceptibility in molecular glass formers: Results from light scattering, dielectric spectroscopy, and NMR
journal, March 2013

Bulk and shear relaxation in glasses and highly viscous liquids
journal, June 2012

On the dielectric susceptibility spectra of supercooled o-terphenyl
journal, October 2005

Reorientational dynamics in molecular liquids as revealed by dynamic light scattering: From boiling point to glass transition temperature
journal, August 2013

How Long Do Regions of Different Dynamics Persist in Supercooled o -Terphenyl?
journal, May 1999

Nonuniversal Coupling of Cage Scale Hopping and Collective Elastic Distortion as the Origin of Dynamic Fragility Diversity in Glass-Forming Polymer Liquids
journal, December 2016

Breakdown of Time−Temperature Superposition Principle and Universality of Chain Dynamics in Polymers
journal, May 2006

Single Molecule Experiments Reveal the Dynamic Heterogeneity and Exchange Time Scales of Polystyrene near the Glass Transition
journal, March 2016

Unified Theory of Activated Relaxation in Liquids over 14 Decades in Time
journal, October 2013

Mode-coupling approximations, glass theory and disordered systems
journal, May 1996

Dynamics on the Way to Forming Glass: Bubbles in Space-Time
journal, March 2010

Ideal probe single-molecule experiments reveal the intrinsic dynamic heterogeneity of a supercooled liquid
journal, March 2015

Resolving the Mystery of the Chain Friction Mechanism in Polymer Liquids
journal, June 2009

Direct observation of molecular cooperativity near the glass transition
journal, December 2000

Models of traps and glass phenomenology
journal, July 1996

Glassy dynamics
journal, January 2000

Collisions, caging, thermodynamics, and jamming in the barrier hopping theory of glassy hard sphere fluids
journal, October 2007

Reaction-rate theory: fifty years after Kramers
journal, April 1990

Master-equation appoach to the glass transition
journal, February 1987

Energy master equation: A low-temperature approximation to Bässler’s random-walk model
journal, May 1995

Translational and rotational diffusion in supercooled orthoterphenyl close to the glass transition
journal, June 1992

Measurement of the self-intermediate scattering function of suspensions of hard spherical particles near the glass transition
journal, November 1998

Microscopic Theory of Heterogeneity and Nonexponential Relaxations in Supercooled Liquids
journal, June 2001

Supercooled liquids and the glass transition
journal, March 2001

Entropic barriers, activated hopping, and the glass transition in colloidal suspensions
journal, July 2003

Theoretical perspective on the glass transition and amorphous materials
journal, June 2011

Source of non-Arrhenius average relaxation time in glass-forming liquids
journal, August 1998

Heterogeneous dynamics at the glass transition in van der Waals liquids, in the bulk and in thin films
journal, March 2001

Dynamical heterogeneity in a highly supercooled liquid: Consistent calculations of correlation length, intensity, and lifetime
journal, July 2011

Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. I. General formulation and application to hard sphere fluids
journal, May 2014

A structural approach to relaxation in glassy liquids
journal, February 2016

Self-Diffusion of Supercooled Tris-naphthylbenzene
journal, April 2009

Derivation of a microscopic theory of barriers and activated hopping transport in glassy liquids and suspensions
journal, December 2005

Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. II. Thermal liquids
journal, May 2014

Hopping in a supercooled Lennard-Jones liquid: Metabasins, waiting time distribution, and diffusion
journal, March 2003

S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS
journal, October 2000