Three Electron Reversible Redox Reaction in Sodium Vanadium Chromium Phosphate as a High‐Energy‐Density Cathode for Sodium‐Ion Batteries

doi:10.1002/adfm.201908680

This content will become publicly available on January 16, 2021

Title: Three Electron Reversible Redox Reaction in Sodium Vanadium Chromium Phosphate as a High‐Energy‐Density Cathode for Sodium‐Ion Batteries

Authors:

Zhao, Yongjie ^[1];

^[2];

^[2]; Jin, Haibo ^[3];

^[2]

Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green ApplicationsSchool of Materials Science and EngineeringBeijing Institute of Technology Beijing 100081 China, Materials Science and Engineering Program and Texas Materials InstituteUniversity of Texas at Austin Austin TX 78712 USA
Materials Science and Engineering Program and Texas Materials InstituteUniversity of Texas at Austin Austin TX 78712 USA
Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green ApplicationsSchool of Materials Science and EngineeringBeijing Institute of Technology Beijing 100081 China

Publication Date:: 2020-01-17

Sponsoring Org.:: USDOE

OSTI Identifier:: 1592182

Grant/Contract Number:: DE‐EE0007762

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Advanced Functional Materials

Additional Journal Information:: Journal Name: Advanced Functional Materials; Journal ID: ISSN 1616-301X

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Zhao, Yongjie, Gao, Xiangwen, Gao, Hongcai, Jin, Haibo, and Goodenough, John B. Three Electron Reversible Redox Reaction in Sodium Vanadium Chromium Phosphate as a High‐Energy‐Density Cathode for Sodium‐Ion Batteries.  Germany: N. p., 2020. 
        Web.  doi:10.1002/adfm.201908680.

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                    Zhao, Yongjie, Gao, Xiangwen, Gao, Hongcai, Jin, Haibo, & Goodenough, John B. Three Electron Reversible Redox Reaction in Sodium Vanadium Chromium Phosphate as a High‐Energy‐Density Cathode for Sodium‐Ion Batteries.  Germany.  doi:10.1002/adfm.201908680.

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                    Zhao, Yongjie, Gao, Xiangwen, Gao, Hongcai, Jin, Haibo, and Goodenough, John B. Fri .  
        "Three Electron Reversible Redox Reaction in Sodium Vanadium Chromium Phosphate as a High‐Energy‐Density Cathode for Sodium‐Ion Batteries".  Germany.  doi:10.1002/adfm.201908680.

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@article{osti_1592182,

  title        = {Three Electron Reversible Redox Reaction in Sodium Vanadium Chromium Phosphate as a High‐Energy‐Density Cathode for Sodium‐Ion Batteries},

  author       = {Zhao, Yongjie and Gao, Xiangwen and Gao, Hongcai and Jin, Haibo and Goodenough, John B.},

  abstractNote = {},

  doi          = {10.1002/adfm.201908680},

  journal      = {Advanced Functional Materials},

  number       = ,

  volume       = ,

  place        = {Germany},

  year         = {2020},

  month        = {1}

}

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DOI: 10.1002/adfm.201908680

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This content will become publicly available on January 16, 2021

Title: Three Electron Reversible Redox Reaction in Sodium Vanadium Chromium Phosphate as a High‐Energy‐Density Cathode for Sodium‐Ion Batteries

Citation Formats

Fast Na+-ion transport in skeleton structures journal, February 1976

Na3V2O2(PO4)2F/graphene sandwich structure for high-performance cathode of a sodium-ion battery journal, January 2013

Neat Design for the Structure of Electrode To Optimize the Lithium-Ion Battery Performance journal, July 2018

Carbon-Coated Na 3 V 2 (PO 4 ) 3 Embedded in Porous Carbon Matrix: An Ultrafast Na-Storage Cathode with the Potential of Outperforming Li Cathodes journal, March 2014

Graphene boosted pseudocapacitive lithium storage: A case of G-Fe2O3 journal, August 2018

Sodium Extraction from NASICON-Structured Na 3 MnTi(PO 4 ) 3 through Mn(III)/Mn(II) and Mn(IV)/Mn(III) Redox Couples journal, September 2016

Exploring the high-voltage Mg 2+ /Na + co-intercalation reaction of Na 3 VCr(PO 4 ) 3 in Mg-ion batteries journal, January 2019

3D Graphene Decorated NaTi 2 (PO 4 ) 3 Microspheres as a Superior High-Rate and Ultracycle-Stable Anode Material for Sodium Ion Batteries journal, June 2016

An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na 3 MnTi(PO 4 ) 3 journal, September 2016

Sodium vanadium titanium phosphate electrode for symmetric sodium-ion batteries with high power and long lifespan journal, June 2017

Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights journal, October 2015

Effect of Carbon Matrix Dimensions on the Electrochemical Properties of Na 3 V 2 (PO 4 ) 3 Nanograins for High-Performance Symmetric Sodium-Ion Batteries journal, March 2014

Na 3 MnZr(PO 4 ) 3 : A High-Voltage Cathode for Sodium Batteries journal, December 2018

Novel K 3 V 2 (PO 4 ) 3 /C Bundled Nanowires as Superior Sodium-Ion Battery Electrode with Ultrahigh Cycling Stability journal, June 2015

Superior Electrochemical Performance and Storage Mechanism of Na 3 V 2 (PO 4 ) 3 Cathode for Room-Temperature Sodium-Ion Batteries journal, October 2012

Effect of aluminum doping on carbon loaded Na3V2(PO4)3 as cathode material for sodium-ion batteries journal, October 2015

Improved Reversibility of Fe 3+ /Fe 4+ Redox Couple in Sodium Super Ion Conductor Type Na 3 Fe 2 (PO 4 ) 3 for Sodium-Ion Batteries journal, January 2017

A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO 2 with Excellent Long‐Term Cyclability and High‐Rate Capability journal, April 2019

High-Voltage Cr 4+ /Cr 3+ Redox Couple in Polyanion Compounds journal, February 2018

Direct atomic-scale confirmation of three-phase storage mechanism in Li4Ti5O12 anodes for room-temperature sodium-ion batteries journal, May 2013

Realizing Three-Electron Redox Reactions in NASICON-Structured Na 3 MnTi(PO 4 ) 3 for Sodium-Ion Batteries journal, January 2019

Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material journal, February 2019

Additional Sodium Insertion into Polyanionic Cathodes for Higher-Energy Na-Ion Batteries journal, May 2017

Carbon-coated hierarchical NaTi2(PO4)3 mesoporous microflowers with superior sodium storage performance journal, October 2016

Exploring Highly Reversible 1.5-Electron Reactions (V 3+ /V 4+ /V 5+ ) in Na 3 VCr(PO 4 ) 3 Cathode for Sodium-Ion Batteries journal, December 2017

Atomic Structure and Kinetics of NASICON Na x V 2 (PO 4 ) 3 Cathode for Sodium-Ion Batteries journal, April 2014

Na x MV(PO 4 ) 3 (M = Mn, Fe, Ni) Structure and Properties for Sodium Extraction journal, November 2016

Fast Na+-ion transport in skeleton structures
journal, February 1976

Na3V2O2(PO4)2F/graphene sandwich structure for high-performance cathode of a sodium-ion battery
journal, January 2013

Neat Design for the Structure of Electrode To Optimize the Lithium-Ion Battery Performance
journal, July 2018

Carbon-Coated Na ₃ V ₂ (PO ₄ ) ₃ Embedded in Porous Carbon Matrix: An Ultrafast Na-Storage Cathode with the Potential of Outperforming Li Cathodes
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journal, September 2016

Exploring the high-voltage Mg 2+ /Na + co-intercalation reaction of Na 3 VCr(PO 4 ) 3 in Mg-ion batteries
journal, January 2019

3D Graphene Decorated NaTi ₂ (PO ₄ ) ₃ Microspheres as a Superior High-Rate and Ultracycle-Stable Anode Material for Sodium Ion Batteries
journal, June 2016

An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na 3 MnTi(PO 4 ) 3
journal, September 2016

Sodium vanadium titanium phosphate electrode for symmetric sodium-ion batteries with high power and long lifespan
journal, June 2017

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journal, October 2015

Effect of Carbon Matrix Dimensions on the Electrochemical Properties of Na ₃ V ₂ (PO ₄ ) ₃ Nanograins for High-Performance Symmetric Sodium-Ion Batteries
journal, March 2014

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journal, December 2018

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Superior Electrochemical Performance and Storage Mechanism of Na ₃ V ₂ (PO ₄ ) ₃ Cathode for Room-Temperature Sodium-Ion Batteries
journal, October 2012

Effect of aluminum doping on carbon loaded Na3V2(PO4)3 as cathode material for sodium-ion batteries
journal, October 2015

Improved Reversibility of Fe 3+ /Fe 4+ Redox Couple in Sodium Super Ion Conductor Type Na 3 Fe 2 (PO 4 ) 3 for Sodium-Ion Batteries
journal, January 2017

A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO 2 with Excellent Long‐Term Cyclability and High‐Rate Capability
journal, April 2019

High-Voltage Cr 4+ /Cr 3+ Redox Couple in Polyanion Compounds
journal, February 2018

Direct atomic-scale confirmation of three-phase storage mechanism in Li4Ti5O12 anodes for room-temperature sodium-ion batteries
journal, May 2013

Realizing Three-Electron Redox Reactions in NASICON-Structured Na 3 MnTi(PO 4 ) 3 for Sodium-Ion Batteries
journal, January 2019

Higher energy and safer sodium ion batteries via an electrochemically made disordered Na3V2(PO4)2F3 material
journal, February 2019

Additional Sodium Insertion into Polyanionic Cathodes for Higher-Energy Na-Ion Batteries
journal, May 2017

Carbon-coated hierarchical NaTi2(PO4)3 mesoporous microflowers with superior sodium storage performance
journal, October 2016

Exploring Highly Reversible 1.5-Electron Reactions (V 3+ /V 4+ /V 5+ ) in Na 3 VCr(PO 4 ) 3 Cathode for Sodium-Ion Batteries
journal, December 2017

Atomic Structure and Kinetics of NASICON Na _x V ₂ (PO ₄ ) ₃ Cathode for Sodium-Ion Batteries
journal, April 2014

Na _x MV(PO ₄ ) ₃ (M = Mn, Fe, Ni) Structure and Properties for Sodium Extraction
journal, November 2016