Pressure-driven valence increase and metallization in the Kondo insulator
Abstract
We report the results of high pressure x-ray diffraction, x-ray absorption, and electrical transport measurements of Kondo insulator Ce3Bi4Pt3 up to 42 GPa, the highest pressure reached in the study of any Ce-based Kl. We observe a smooth decrease in volume and movement toward intermediate Ce valence with pressure, both of which point to increased electron correlations. Despite this, temperature-dependent resistance data show the suppression of the interaction-driven ambient pressure energy gap and development of a semimetallic ground state. We also discuss potential ramifications of these results for the predicted topological KI state.
- Authors:
-
- Univ. of Maryland, College Park, MD (United States)
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Univ. of California, Davis, CA (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Univ. of California, Davis, CA (United States)
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1592040
- Alternate Identifier(s):
- OSTI ID: 1606360
- Report Number(s):
- LLNL-JRNL-771815
Journal ID: ISSN 2469-9950; PRBMDO; 963184
- Grant/Contract Number:
- AC52-07NA27344; SC0014664; FA9550-14-1-0332; DMR-1905891; DMR-1609855; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 100; Journal Issue: 23; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Campbell, Daniel J., Brubaker, Zachary E., Roncaioli, Connor, Saraf, Prathum, Xiao, Yuming, Chow, Paul, Kenney-Benson, Curtis, Popov, Dmitry, Zieve, Rena J., Jeffries, Jason R., and Paglione, Johnpierre. Pressure-driven valence increase and metallization in the Kondo insulator Ce3Bi4Pt3. United States: N. p., 2019.
Web. doi:10.1103/PhysRevB.100.235133.
Campbell, Daniel J., Brubaker, Zachary E., Roncaioli, Connor, Saraf, Prathum, Xiao, Yuming, Chow, Paul, Kenney-Benson, Curtis, Popov, Dmitry, Zieve, Rena J., Jeffries, Jason R., & Paglione, Johnpierre. Pressure-driven valence increase and metallization in the Kondo insulator Ce3Bi4Pt3. United States. doi:10.1103/PhysRevB.100.235133.
Campbell, Daniel J., Brubaker, Zachary E., Roncaioli, Connor, Saraf, Prathum, Xiao, Yuming, Chow, Paul, Kenney-Benson, Curtis, Popov, Dmitry, Zieve, Rena J., Jeffries, Jason R., and Paglione, Johnpierre. Mon .
"Pressure-driven valence increase and metallization in the Kondo insulator Ce3Bi4Pt3". United States. doi:10.1103/PhysRevB.100.235133. https://www.osti.gov/servlets/purl/1592040.
@article{osti_1592040,
title = {Pressure-driven valence increase and metallization in the Kondo insulator Ce3Bi4Pt3},
author = {Campbell, Daniel J. and Brubaker, Zachary E. and Roncaioli, Connor and Saraf, Prathum and Xiao, Yuming and Chow, Paul and Kenney-Benson, Curtis and Popov, Dmitry and Zieve, Rena J. and Jeffries, Jason R. and Paglione, Johnpierre},
abstractNote = {We report the results of high pressure x-ray diffraction, x-ray absorption, and electrical transport measurements of Kondo insulator Ce3Bi4Pt3 up to 42 GPa, the highest pressure reached in the study of any Ce-based Kl. We observe a smooth decrease in volume and movement toward intermediate Ce valence with pressure, both of which point to increased electron correlations. Despite this, temperature-dependent resistance data show the suppression of the interaction-driven ambient pressure energy gap and development of a semimetallic ground state. We also discuss potential ramifications of these results for the predicted topological KI state.},
doi = {10.1103/PhysRevB.100.235133},
journal = {Physical Review B},
number = 23,
volume = 100,
place = {United States},
year = {2019},
month = {12}
}
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