Precise Control of Molecular Self‐Diffusion in Isoreticular and Multivariate Metal‐Organic Frameworks

doi:10.1002/cphc.201901043

Title: Precise Control of Molecular Self‐Diffusion in Isoreticular and Multivariate Metal‐Organic Frameworks

Authors:

Osborn Popp, Thomas M. ^[1]; Plantz, Ariel Z. ^[2]; Yaghi, Omar M. ^[3]; Reimer, Jeffrey A. ^[4]

Department of Chemistry, Kavli Energy NanoSciences Institute at Berkeley, and Berkeley Global Science InstituteUniversity of California-Berkeley Berkeley, California 94720 USA, Department of Chemical and Biomolecular EngineeringUniversity of California-Berkeley Berkeley, California 94720 USA, Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley Berkeley CA 94720 USA
Department of Chemical and Biomolecular EngineeringUniversity of California-Berkeley Berkeley, California 94720 USA
Department of Chemistry, Kavli Energy NanoSciences Institute at Berkeley, and Berkeley Global Science InstituteUniversity of California-Berkeley Berkeley, California 94720 USA, Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley Berkeley CA 94720 USA
Department of Chemical and Biomolecular EngineeringUniversity of California-Berkeley Berkeley, California 94720 USA, Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley Berkeley CA 94720 USA

Publication Date:: 2019-12-12

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1591981

Alternate Identifier(s):: OSTI ID: 1591982

Grant/Contract Number:: SC0001015

Resource Type:: Published Article

Journal Name:: ChemPhysChem

Additional Journal Information:: Journal Name: ChemPhysChem Journal Volume: 21 Journal Issue: 1; Journal ID: ISSN 1439-4235

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Osborn Popp, Thomas M., Plantz, Ariel Z., Yaghi, Omar M., and Reimer, Jeffrey A. Precise Control of Molecular Self‐Diffusion in Isoreticular and Multivariate Metal‐Organic Frameworks.  Germany: N. p., 2019. 
        Web.  doi:10.1002/cphc.201901043.

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                    Osborn Popp, Thomas M., Plantz, Ariel Z., Yaghi, Omar M., & Reimer, Jeffrey A. Precise Control of Molecular Self‐Diffusion in Isoreticular and Multivariate Metal‐Organic Frameworks.  Germany.  doi:10.1002/cphc.201901043.

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                    Osborn Popp, Thomas M., Plantz, Ariel Z., Yaghi, Omar M., and Reimer, Jeffrey A. Thu .  
        "Precise Control of Molecular Self‐Diffusion in Isoreticular and Multivariate Metal‐Organic Frameworks".  Germany.  doi:10.1002/cphc.201901043.

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@article{osti_1591981,

  title        = {Precise Control of Molecular Self‐Diffusion in Isoreticular and Multivariate Metal‐Organic Frameworks},

  author       = {Osborn Popp, Thomas M. and Plantz, Ariel Z. and Yaghi, Omar M. and Reimer, Jeffrey A.},

  abstractNote = {},

  doi          = {10.1002/cphc.201901043},

  journal      = {ChemPhysChem},

  number       = 1,

  volume       = 21,

  place        = {Germany},

  year         = {2019},

  month        = {12}

}

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Works referenced in this record:

A Simple NMR-Based Method for Studying the Spatial Distribution of Linkers within Mixed-Linker Metal-Organic Frameworks
journal, July 2015

Krajnc, Andraž; Kos, Tomaž; Zabukovec Logar, Nataša
Angewandte Chemie, Vol. 127, Issue 36
DOI: 10.1002/ange.201504426

Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
journal, July 2015

Brozek, Carl K.; Michaelis, Vladimir K.; Ong, Ta-Chung
ACS Central Science, Vol. 1, Issue 5
DOI: 10.1021/acscentsci.5b00247

Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010

Deng, H.; Doonan, C. J.; Furukawa, H.
Science, Vol. 327, Issue 5967, p. 846-850
DOI: 10.1126/science.1181761

Revisiting Anisotropic Diffusion of Carbon Dioxide in the Metal–Organic Framework Zn ₂ (dobpdc)
journal, June 2018

Forse, Alexander C.; Altobelli, Stephen A.; Benders, Stefan
The Journal of Physical Chemistry C, Vol. 122, Issue 27
DOI: 10.1021/acs.jpcc.8b02843

Heterogeneous heck coupling in multivariate metal–organic frameworks for enhanced selectivity
journal, May 2015

Brown, Jonathan W.; Jarenwattananon, Nanette N.; Otto, Trenton
Catalysis Communications, Vol. 65
DOI: 10.1016/j.catcom.2015.03.005

“Heterogeneity within Order” in Metal-Organic Frameworks
journal, January 2015

Furukawa, Hiroyasu; Müller, Ulrich; Yaghi, Omar M.
Angewandte Chemie International Edition, Vol. 54, Issue 11
DOI: 10.1002/anie.201410252

NMR-Untersuchungen zur Diffusion von Kohlenwasserstoffen im metall-organischen Netzwerk MOF-5
journal, March 2006

Stallmach, Frank; Gröger, Stefan; Künzel, Volker
Angewandte Chemie, Vol. 118, Issue 13
DOI: 10.1002/ange.200502553

Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008

Britt, D.; Tranchemontagne, D.; Yaghi, O. M.
Proceedings of the National Academy of Sciences, Vol. 105, Issue 33, p. 11623-11627
DOI: 10.1073/pnas.0804900105

Homogeneity of flexible metal–organic frameworks containing mixed linkers
journal, January 2012

Lescouet, Tristan; Kockrick, Emanuel; Bergeret, Gérard
Journal of Materials Chemistry, Vol. 22, Issue 20
DOI: 10.1039/c2jm15966j

Translational and Rotational Motion of C8 Aromatics Adsorbed in Isotropic Porous Media (MOF-5): NMR Studies and MD Simulations
journal, July 2017

Witherspoon, Velencia J.; Yu, Lucy M.; Jawahery, Sudi
The Journal of Physical Chemistry C, Vol. 121, Issue 28
DOI: 10.1021/acs.jpcc.7b03181

Spin Diffusion Measurements: Spin Echoes in the Presence of a Time‐Dependent Field Gradient
journal, January 1965

Stejskal, E. O.; Tanner, J. E.
The Journal of Chemical Physics, Vol. 42, Issue 1
DOI: 10.1063/1.1695690

High Magnetic Field Gradient PGSE NMR in the Presence of a Large Polarizing Field
journal, July 1998

Callaghan, Paul T.; Komlosh, Michal E.; Nyden, Magnus
Journal of Magnetic Resonance, Vol. 133, Issue 1
DOI: 10.1006/jmre.1998.1424

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
Science, Vol. 295, Issue 5554, p. 469-472
DOI: 10.1126/science.1067208

Chromatography in a Single Metal−Organic Framework (MOF) Crystal
journal, November 2010

Han, Shuangbing; Wei, Yanhu; Valente, Cory
Journal of the American Chemical Society, Vol. 132, Issue 46
DOI: 10.1021/ja1074322

Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013

Kong, X.; Deng, H.; Yan, F.
Science, Vol. 341, Issue 6148, p. 882-885
DOI: 10.1126/science.1238339

Pulsed-field gradient nuclear magnetic resonance as a tool for studying translational diffusion: Part II. Experimental aspects
journal, January 1998

Price, William S.
Concepts in Magnetic Resonance, Vol. 10, Issue 4
DOI: 10.1002/(SICI)1099-0534(1998)10:4<197::AID-CMR1>3.0.CO;2-S

Introduction of Functionality, Selection of Topology, and Enhancement of Gas Adsorption in Multivariate Metal–Organic Framework-177
journal, February 2015

Zhang, Yue-Biao; Furukawa, Hiroyasu; Ko, Nakeun
Journal of the American Chemical Society, Vol. 137, Issue 7
DOI: 10.1021/ja512311a

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks
journal, February 2006

Rowsell, Jesse L. C.; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 128, Issue 4, p. 1304-1315
DOI: 10.1021/ja056639q

Construction and calibration of a 50 T/m z-gradient coil for quantitative diffusion microimaging
journal, May 2007

Wright, A. C.; Bataille, H.; Ong, H. H.
Journal of Magnetic Resonance, Vol. 186, Issue 1
DOI: 10.1016/j.jmr.2007.01.011

Characterization of interfacial water in MOF-5 (Zn4(O)(BDC)3)—a combined spectroscopic and theoretical study
journal, January 2008

Schröck, K.; Schröder, F.; Heyden, M.
Physical Chemistry Chemical Physics, Vol. 10, Issue 32
DOI: 10.1039/b807458p

Ethene/ethane mixture diffusion in the MOF sieve ZIF-8 studied by MAS PFG NMR diffusometry
journal, January 2012

Chmelik, Christian; Freude, Dieter; Bux, Helge
Microporous and Mesoporous Materials, Vol. 147, Issue 1
DOI: 10.1016/j.micromeso.2011.06.009

A Simple NMR-Based Method for Studying the Spatial Distribution of Linkers within Mixed-Linker Metal-Organic Frameworks
journal, July 2015

Krajnc, Andraž; Kos, Tomaž; Zabukovec Logar, Nataša
Angewandte Chemie International Edition, Vol. 54, Issue 36
DOI: 10.1002/anie.201504426

Applications of metal-organic frameworks in adsorption/separation processes via hydrogen bonding interactions
journal, February 2017

Ahmed, Imteaz; Jhung, Sung Hwa
Chemical Engineering Journal, Vol. 310
DOI: 10.1016/j.cej.2016.10.115

“Heterogenität innerhalb von Ordnung” in Metall-organischen Gerüsten
journal, January 2015

Furukawa, Hiroyasu; Müller, Ulrich; Yaghi, Omar M.
Angewandte Chemie, Vol. 127, Issue 11
DOI: 10.1002/ange.201410252

NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5
journal, March 2006

Stallmach, Frank; Gröger, Stefan; Künzel, Volker
Angewandte Chemie International Edition, Vol. 45, Issue 13, p. 2123-2126
DOI: 10.1002/anie.200502553

How Can a Hydrophobic MOF be Water-Unstable? Insight into the Hydration Mechanism of IRMOFs
journal, July 2012

De Toni, Marta; Jonchiere, Romain; Pullumbi, Pluton
ChemPhysChem, Vol. 13, Issue 15
DOI: 10.1002/cphc.201200455

Ultra-Tuning of the Aperture Size in Stiffened ZIF-8_Cm Frameworks with Mixed-Linker Strategy for Enhanced CO ₂ /CH ₄ Separation
journal, December 2018

Hou, Qianqian; Wu, Ying; Zhou, Sheng
Angewandte Chemie International Edition, Vol. 58, Issue 1
DOI: 10.1002/anie.201811638

Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003

Rosi, Nathaniel L.; Eckert, Juergen; Eddaoudi, Mohamed
Science, Vol. 300, Issue 5622, p. 1127-1129
DOI: 10.1126/science.1083440

The Interaction of Water with MOF-5 Simulated by Molecular Dynamics
journal, August 2006

Greathouse, Jeffery A.; Allendorf, Mark D.
Journal of the American Chemical Society, Vol. 128, Issue 33
DOI: 10.1021/ja063506b

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
Science, Vol. 341, Issue 6149, p. 1230444-1230444
DOI: 10.1126/science.1230444

Multivariate Metal–Organic Frameworks for Dialing-in the Binding and Programming the Release of Drug Molecules
journal, September 2017

Dong, Zhiyue; Sun, Yangzesheng; Chu, Jun
Journal of the American Chemical Society, Vol. 139, Issue 40
DOI: 10.1021/jacs.7b07392

Grid-Type Metal Ion Architectures: Functional Metallosupramolecular Arrays
journal, July 2004

Ruben, Mario; Rojo, Javier; Romero-Salguero, Francisco J.
Angewandte Chemie International Edition, Vol. 43, Issue 28
DOI: 10.1002/anie.200300636

Highly Tunable Molecular Sieving and Adsorption Properties of Mixed-Linker Zeolitic Imidazolate Frameworks
journal, March 2015

Eum, Kiwon; Jayachandrababu, Krishna C.; Rashidi, Fereshteh
Journal of the American Chemical Society, Vol. 137, Issue 12
DOI: 10.1021/jacs.5b00803

Unexpected Diffusion Anisotropy of Carbon Dioxide in the Metal–Organic Framework Zn ₂ (dobpdc)
journal, January 2018

Forse, Alexander C.; Gonzalez, Miguel I.; Siegelman, Rebecca L.
Journal of the American Chemical Society, Vol. 140, Issue 5
DOI: 10.1021/jacs.7b09453

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn₄O(1,4-benzenedicarboxylate)₃ (MOF-5)
journal, November 2007

Kaye, Steven S.; Dailly, Anne; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 129, Issue 46, p. 14176-14177
DOI: 10.1021/ja076877g

Ethane diffusion in mixed linker zeolitic imidazolate framework-7-8 by pulsed field gradient NMR in combination with single crystal IR microscopy
journal, January 2018

Berens, Samuel; Chmelik, Christian; Hillman, Febrian
Physical Chemistry Chemical Physics, Vol. 20, Issue 37
DOI: 10.1039/C8CP04889D

Mixed-linker zeolitic imidazolate framework mixed-matrix membranes for aggressive CO2 separation from natural gas
journal, July 2014

Thompson, Joshua A.; Vaughn, Justin T.; Brunelli, Nicholas A.
Microporous and Mesoporous Materials, Vol. 192
DOI: 10.1016/j.micromeso.2013.06.036

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Title: Precise Control of Molecular Self‐Diffusion in Isoreticular and Multivariate Metal‐Organic Frameworks

Citation Formats

A Simple NMR-Based Method for Studying the Spatial Distribution of Linkers within Mixed-Linker Metal-Organic Frameworks journal, July 2015

Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues journal, July 2015

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“Heterogeneity within Order” in Metal-Organic Frameworks journal, January 2015

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Metal-organic frameworks with high capacity and selectivity for harmful gases journal, August 2008

Homogeneity of flexible metal–organic frameworks containing mixed linkers journal, January 2012

Translational and Rotational Motion of C8 Aromatics Adsorbed in Isotropic Porous Media (MOF-5): NMR Studies and MD Simulations journal, July 2017

Spin Diffusion Measurements: Spin Echoes in the Presence of a Time‐Dependent Field Gradient journal, January 1965

High Magnetic Field Gradient PGSE NMR in the Presence of a Large Polarizing Field journal, July 1998

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal, January 2002

Chromatography in a Single Metal−Organic Framework (MOF) Crystal journal, November 2010

Mapping of Functional Groups in Metal-Organic Frameworks journal, July 2013

Pulsed-field gradient nuclear magnetic resonance as a tool for studying translational diffusion: Part II. Experimental aspects journal, January 1998

Introduction of Functionality, Selection of Topology, and Enhancement of Gas Adsorption in Multivariate Metal–Organic Framework-177 journal, February 2015

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks journal, February 2006

Construction and calibration of a 50 T/m z-gradient coil for quantitative diffusion microimaging journal, May 2007

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Ethene/ethane mixture diffusion in the MOF sieve ZIF-8 studied by MAS PFG NMR diffusometry journal, January 2012

A Simple NMR-Based Method for Studying the Spatial Distribution of Linkers within Mixed-Linker Metal-Organic Frameworks journal, July 2015

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“Heterogenität innerhalb von Ordnung” in Metall-organischen Gerüsten journal, January 2015

NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5 journal, March 2006

How Can a Hydrophobic MOF be Water-Unstable? Insight into the Hydration Mechanism of IRMOFs journal, July 2012

Ultra-Tuning of the Aperture Size in Stiffened ZIF-8_Cm Frameworks with Mixed-Linker Strategy for Enhanced CO 2 /CH 4 Separation journal, December 2018

Hydrogen Storage in Microporous Metal-Organic Frameworks journal, May 2003

The Interaction of Water with MOF-5 Simulated by Molecular Dynamics journal, August 2006

The Chemistry and Applications of Metal-Organic Frameworks journal, August 2013

Multivariate Metal–Organic Frameworks for Dialing-in the Binding and Programming the Release of Drug Molecules journal, September 2017

Grid-Type Metal Ion Architectures: Functional Metallosupramolecular Arrays journal, July 2004

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Unexpected Diffusion Anisotropy of Carbon Dioxide in the Metal–Organic Framework Zn 2 (dobpdc) journal, January 2018

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5) journal, November 2007

Ethane diffusion in mixed linker zeolitic imidazolate framework-7-8 by pulsed field gradient NMR in combination with single crystal IR microscopy journal, January 2018

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Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
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Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
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journal, June 2018

Heterogeneous heck coupling in multivariate metal–organic frameworks for enhanced selectivity
journal, May 2015

“Heterogeneity within Order” in Metal-Organic Frameworks
journal, January 2015

NMR-Untersuchungen zur Diffusion von Kohlenwasserstoffen im metall-organischen Netzwerk MOF-5
journal, March 2006

Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008

Homogeneity of flexible metal–organic frameworks containing mixed linkers
journal, January 2012

Translational and Rotational Motion of C8 Aromatics Adsorbed in Isotropic Porous Media (MOF-5): NMR Studies and MD Simulations
journal, July 2017

Spin Diffusion Measurements: Spin Echoes in the Presence of a Time‐Dependent Field Gradient
journal, January 1965

High Magnetic Field Gradient PGSE NMR in the Presence of a Large Polarizing Field
journal, July 1998

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

Chromatography in a Single Metal−Organic Framework (MOF) Crystal
journal, November 2010

Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013

Pulsed-field gradient nuclear magnetic resonance as a tool for studying translational diffusion: Part II. Experimental aspects
journal, January 1998

Introduction of Functionality, Selection of Topology, and Enhancement of Gas Adsorption in Multivariate Metal–Organic Framework-177
journal, February 2015

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks
journal, February 2006

Construction and calibration of a 50 T/m z-gradient coil for quantitative diffusion microimaging
journal, May 2007

Characterization of interfacial water in MOF-5 (Zn4(O)(BDC)3)—a combined spectroscopic and theoretical study
journal, January 2008

Ethene/ethane mixture diffusion in the MOF sieve ZIF-8 studied by MAS PFG NMR diffusometry
journal, January 2012

A Simple NMR-Based Method for Studying the Spatial Distribution of Linkers within Mixed-Linker Metal-Organic Frameworks
journal, July 2015

Applications of metal-organic frameworks in adsorption/separation processes via hydrogen bonding interactions
journal, February 2017

“Heterogenität innerhalb von Ordnung” in Metall-organischen Gerüsten
journal, January 2015

NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5
journal, March 2006

How Can a Hydrophobic MOF be Water-Unstable? Insight into the Hydration Mechanism of IRMOFs
journal, July 2012

Ultra-Tuning of the Aperture Size in Stiffened ZIF-8_Cm Frameworks with Mixed-Linker Strategy for Enhanced CO ₂ /CH ₄ Separation
journal, December 2018

Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003

The Interaction of Water with MOF-5 Simulated by Molecular Dynamics
journal, August 2006

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

Multivariate Metal–Organic Frameworks for Dialing-in the Binding and Programming the Release of Drug Molecules
journal, September 2017

Grid-Type Metal Ion Architectures: Functional Metallosupramolecular Arrays
journal, July 2004

Highly Tunable Molecular Sieving and Adsorption Properties of Mixed-Linker Zeolitic Imidazolate Frameworks
journal, March 2015

Unexpected Diffusion Anisotropy of Carbon Dioxide in the Metal–Organic Framework Zn ₂ (dobpdc)
journal, January 2018

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn₄O(1,4-benzenedicarboxylate)₃ (MOF-5)
journal, November 2007

Ethane diffusion in mixed linker zeolitic imidazolate framework-7-8 by pulsed field gradient NMR in combination with single crystal IR microscopy
journal, January 2018

Mixed-linker zeolitic imidazolate framework mixed-matrix membranes for aggressive CO2 separation from natural gas
journal, July 2014