Two-way tuning of structural order in metallic glasses
Abstract
Abstract Metallic glasses are expected to have quite tunable structures in their configuration space, without the strict constraints of a well-defined crystalline symmetry and large energy barriers separating different states in crystals. However, effectively modulating the structure of metallic glasses is rather difficult. Here, using complementary in situ synchrotron x-ray techniques, we reveal thermal-driven structural ordering in a Ce 65 Al 10 Co 25 metallic glass, and a reverse disordering process via a pressure-induced rejuvenation between two states with distinct structural order characteristics. Studies on other metallic glass samples with different compositions also show similar phenomena. Our findings demonstrate the feasibility of two-way structural tuning states in terms of their dramatic ordering and disordering far beyond the nearest-neighbor shells with the combination of temperature and pressure, extending accessible states of metallic glasses to unexplored configuration spaces.
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities; National Key Research and Development Program of China; National Science Foundation (NSF)
- OSTI Identifier:
- 1619733
- Alternate Identifier(s):
- OSTI ID: 1591768
- Grant/Contract Number:
- FG02-94ER14466; AC02-06CH11357; AC02-05CH11231; 51871054; 2016YFB0300501; 2017YFB0903902; EAR-1634415; U1930401; 11790291; EAR-1606856
- Resource Type:
- Published Article
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Name: Nature Communications Journal Volume: 11 Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Lou, Hongbo, Zeng, Zhidan, Zhang, Fei, Chen, Songyi, Luo, Peng, Chen, Xiehang, Ren, Yang, Prakapenka, Vitali B., Prescher, Clemens, Zuo, Xiaobing, Li, Tao, Wen, Jianguo, Wang, Wei-Hua, Sheng, Hongwei, and Zeng, Qiaoshi. Two-way tuning of structural order in metallic glasses. United Kingdom: N. p., 2020.
Web. doi:10.1038/s41467-019-14129-7.
Lou, Hongbo, Zeng, Zhidan, Zhang, Fei, Chen, Songyi, Luo, Peng, Chen, Xiehang, Ren, Yang, Prakapenka, Vitali B., Prescher, Clemens, Zuo, Xiaobing, Li, Tao, Wen, Jianguo, Wang, Wei-Hua, Sheng, Hongwei, & Zeng, Qiaoshi. Two-way tuning of structural order in metallic glasses. United Kingdom. https://doi.org/10.1038/s41467-019-14129-7
Lou, Hongbo, Zeng, Zhidan, Zhang, Fei, Chen, Songyi, Luo, Peng, Chen, Xiehang, Ren, Yang, Prakapenka, Vitali B., Prescher, Clemens, Zuo, Xiaobing, Li, Tao, Wen, Jianguo, Wang, Wei-Hua, Sheng, Hongwei, and Zeng, Qiaoshi. Thu .
"Two-way tuning of structural order in metallic glasses". United Kingdom. https://doi.org/10.1038/s41467-019-14129-7.
@article{osti_1619733,
title = {Two-way tuning of structural order in metallic glasses},
author = {Lou, Hongbo and Zeng, Zhidan and Zhang, Fei and Chen, Songyi and Luo, Peng and Chen, Xiehang and Ren, Yang and Prakapenka, Vitali B. and Prescher, Clemens and Zuo, Xiaobing and Li, Tao and Wen, Jianguo and Wang, Wei-Hua and Sheng, Hongwei and Zeng, Qiaoshi},
abstractNote = {Abstract Metallic glasses are expected to have quite tunable structures in their configuration space, without the strict constraints of a well-defined crystalline symmetry and large energy barriers separating different states in crystals. However, effectively modulating the structure of metallic glasses is rather difficult. Here, using complementary in situ synchrotron x-ray techniques, we reveal thermal-driven structural ordering in a Ce 65 Al 10 Co 25 metallic glass, and a reverse disordering process via a pressure-induced rejuvenation between two states with distinct structural order characteristics. Studies on other metallic glass samples with different compositions also show similar phenomena. Our findings demonstrate the feasibility of two-way structural tuning states in terms of their dramatic ordering and disordering far beyond the nearest-neighbor shells with the combination of temperature and pressure, extending accessible states of metallic glasses to unexplored configuration spaces.},
doi = {10.1038/s41467-019-14129-7},
journal = {Nature Communications},
number = 1,
volume = 11,
place = {United Kingdom},
year = {Thu Jan 16 00:00:00 EST 2020},
month = {Thu Jan 16 00:00:00 EST 2020}
}
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https://doi.org/10.1038/s41467-019-14129-7
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Works referenced in this record:
Evidence of liquid–liquid transition in glass-forming La50Al35Ni15 melt above liquidus temperature
journal, July 2015
- Xu, Wei; Sandor, Magdalena T.; Yu, Yao
- Nature Communications, Vol. 6, Issue 1
Super elastic strain limit in metallic glass films
journal, November 2012
- Jiang, Q. K.; Liu, P.; Ma, Y.
- Scientific Reports, Vol. 2, Issue 1
Crystallization process and glass stability of an Fe 48 Cr 15 Mo 14 C 15 B 6 Tm 2 bulk metallic glass
journal, October 2008
- Hirata, Akihiko; Hirotsu, Yoshihiko; Amiya, Kenji
- Physical Review B, Vol. 78, Issue 14
Structural Origins of the Excellent Glass Forming Ability of
journal, April 2012
- Guan, P. F.; Fujita, T.; Hirata, A.
- Physical Review Letters, Vol. 108, Issue 17
High stored energy of metallic glasses induced by high pressure
journal, March 2017
- Wang, C.; Yang, Z. Z.; Ma, T.
- Applied Physics Letters, Vol. 110, Issue 11
Polyamorphism in a metallic glass
journal, February 2007
- Sheng, H. W.; Liu, H. Z.; Cheng, Y. Q.
- Nature Materials, Vol. 6, Issue 3
Systematic Mapping of Icosahedral Short-Range Order in a Melt-Spun Metallic Glass
journal, May 2013
- Liu, A. C. Y.; Neish, M. J.; Stokol, G.
- Physical Review Letters, Vol. 110, Issue 20
Hierarchical densification and negative thermal expansion in Ce-based metallic glass under high pressure
journal, February 2015
- Luo, Qiang; Garbarino, Gaston; Sun, Baoan
- Nature Communications, Vol. 6, Issue 1
Structural relaxation and rejuvenation in a metallic glass induced by shot-peening
journal, December 2009
- Concustell, A.; Méar, F. O.; Suriñach, S.
- Philosophical Magazine Letters, Vol. 89, Issue 12
Correlation between Local Structure Order and Spatial Heterogeneity in a Metallic Glass
journal, November 2017
- Zhu, Fan; Hirata, Akihiko; Liu, Pan
- Physical Review Letters, Vol. 119, Issue 21
PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions
journal, March 2013
- Juhás, P.; Davis, T.; Farrow, C. L.
- Journal of Applied Crystallography, Vol. 46, Issue 2
Multiple Glassy States in a Simple Model System
journal, April 2002
- Pham, K. N.
- Science, Vol. 296, Issue 5565
Structural behaviour of Pd40Cu30Ni10P20 metallic glass under high pressure
journal, July 2013
- Mattern, Norbert; Bednarcik, Jozef; Liermann, Hans-Peter
- Intermetallics, Vol. 38
High temperature melt viscosity and fragile to strong transition in Zr–Cu–Ni–Al–Nb(Ti) and Cu47Ti34Zr11Ni8 bulk metallic glasses
journal, July 2012
- Evenson, Zach; Schmitt, Tobias; Nicola, Mathias
- Acta Materialia, Vol. 60, Issue 12
A Topographic View of Supercooled Liquids and Glass Formation
journal, March 1995
- Stillinger, F. H.
- Science, Vol. 267, Issue 5206
Nucleation of shear bands in amorphous alloys
journal, March 2014
- Perepezko, J. H.; Imhoff, S. D.; Chen, M. -W.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 11
Atomic packing and short-to-medium-range order in metallic glasses
journal, January 2006
- Sheng, H. W.; Luo, W. K.; Alamgir, F. M.
- Nature, Vol. 439, Issue 7075
Origin of Pressure-Induced Polyamorphism in Metallic Glass
journal, March 2010
- Zeng, Qiao-shi; Ding, Yang; Mao, Wendy L.
- Physical Review Letters, Vol. 104, Issue 10
Nanoscale Structure and Structural Relaxation in Bulk Metallic Glass
journal, May 2012
- Hwang, Jinwoo; Melgarejo, Z. H.; Kalay, Y. E.
- Physical Review Letters, Vol. 108, Issue 19
Atomic Level Structure in Multicomponent Bulk Metallic Glass
journal, June 2009
- Cheng, Y. Q.; Ma, E.; Sheng, H. W.
- Physical Review Letters, Vol. 102, Issue 24
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration
journal, May 2015
- Prescher, Clemens; Prakapenka, Vitali B.
- High Pressure Research, Vol. 35, Issue 3
Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009
- Ilavsky, Jan; Jemian, Peter R.
- Journal of Applied Crystallography, Vol. 42, Issue 2
Fractal growth of the dense-packing phase in annealed metallic glass imaged by high-resolution atomic force microscopy
journal, August 2012
- Yang, Y.; Zeng, J. F.; Volland, A.
- Acta Materialia, Vol. 60, Issue 13-14
Thermomechanical processing of metallic glasses: extending the range of the glassy state
journal, June 2016
- Sun, Yonghao; Concustell, Amadeu; Greer, A. Lindsay
- Nature Reviews Materials, Vol. 1, Issue 9
Bulk Glass-Forming Metallic Alloys: Science and Technology
journal, October 1999
- Johnson, William L.
- MRS Bulletin, Vol. 24, Issue 10
Bulk Metallic Glasses: At the Cutting Edge of Metals Research
journal, August 2007
- Greer, A. L.; Ma, E.
- MRS Bulletin, Vol. 32, Issue 8
Atomic structure of Pd81Si19 glassy alloy under high pressure
journal, December 2014
- Lou, H. B.; Xiong, L. H.; Ahmad, A. S.
- Acta Materialia, Vol. 81
Fractal atomic-level percolation in metallic glasses
journal, September 2015
- Chen, D. Z.; Shi, C. Y.; An, Q.
- Science, Vol. 349, Issue 6254
Ultrastable metallic glasses formed on cold substrates
journal, April 2018
- Luo, P.; Cao, C. R.; Zhu, F.
- Nature Communications, Vol. 9, Issue 1
Spatially Resolved Distribution Function and the Medium-Range Order in Metallic Liquid and Glass
journal, December 2011
- Fang, X. W.; Wang, C. Z.; Hao, S. G.
- Scientific Reports, Vol. 1, Issue 1
Evaluation of the Particle Growth of Amorphous Calcium Carbonate in Water by Means of the Porod Invariant from SAXS
journal, November 2010
- Liu, J.; Pancera, S.; Boyko, V.
- Langmuir, Vol. 26, Issue 22
Structural changes during a liquid-liquid transition in the deeply undercooled Z r 58.5 C u 15.6 N i 12.8 A l 10.3 N b 2.8 bulk metallic glass forming melt
journal, January 2016
- Stolpe, Moritz; Jonas, Isabell; Wei, Shuai
- Physical Review B, Vol. 93, Issue 1
Long-Range Topological Order in Metallic Glass
journal, June 2011
- Zeng, Q.; Sheng, H.; Ding, Y.
- Science, Vol. 332, Issue 6036
A structural model for metallic glasses
journal, September 2004
- Miracle, Daniel B.
- Nature Materials, Vol. 3, Issue 10
The Glass-to-Glass Transition and Its End Point in a Copolymer Micellar System
journal, April 2003
- Chen, S. -H.
- Science, Vol. 300, Issue 5619
Polyamorphism in cerium based bulk metallic glasses: Electronic and structural properties under pressure and temperature by x-ray absorption techniques
journal, September 2013
- Belhadi, L.; Decremps, F.; Pascarelli, S.
- Applied Physics Letters, Vol. 103, Issue 11
Rejuvenation of metallic glasses by non-affine thermal strain
journal, August 2015
- Ketov, S. V.; Sun, Y. H.; Nachum, S.
- Nature, Vol. 524, Issue 7564
Our thoughts are ours, their ends none of our own: Are there ways to synthesize materials beyond the limitations of today?
journal, November 2008
- Gleiter, Herbert
- Acta Materialia, Vol. 56, Issue 19
A re-entrant glass transition in colloidal disks with adsorbing polymer
journal, January 2012
- Atmuri, Anand K.; Peklaris, George A.; Kishore, Suhasini
- Soft Matter, Vol. 8, Issue 34
Hidden amorphous phase and reentrant supercooled liquid in Pd-Ni-P metallic glasses
journal, March 2017
- Lan, S.; Ren, Y.; Wei, X. Y.
- Nature Communications, Vol. 8, Issue 1
Structural rejuvenation in bulk metallic glasses
journal, March 2015
- Tong, Y.; Iwashita, T.; Dmowski, W.
- Acta Materialia, Vol. 86
Calorimetric evidence for the micro-quasicrystalline structure of 'amorphous' Al/transition metal alloys
journal, November 1988
- Chen, L. C.; Spaepen, F.
- Nature, Vol. 336, Issue 6197
Polyamorphic transitions in Ce-based metallic glasses by synchrotron radiation
journal, December 2011
- Duarte, M. J.; Bruna, P.; Pineda, E.
- Physical Review B, Vol. 84, Issue 22
Properties of polyamorphous Ce 75 Al 25 metallic glasses
journal, August 2010
- Zeng, Q. S.; Struzhkin, V. V.; Fang, Y. Z.
- Physical Review B, Vol. 82, Issue 5
Characterization of Nanoscale Mechanical Heterogeneity in a Metallic Glass by Dynamic Force Microscopy
journal, March 2011
- Liu, Y. H.; Wang, D.; Nakajima, K.
- Physical Review Letters, Vol. 106, Issue 12
Direct observation of local atomic order in a metallic glass
journal, November 2010
- Hirata, Akihiko; Guan, Pengfei; Fujita, Takeshi
- Nature Materials, Vol. 10, Issue 1
Local elastic properties of a metallic glass
journal, May 2011
- Wagner, Hannes; Bedorf, Dennis; Küchemann, Stefan
- Nature Materials, Vol. 10, Issue 6
Extreme rejuvenation and softening in a bulk metallic glass
journal, February 2018
- Pan, J.; Wang, Y. X.; Guo, Q.
- Nature Communications, Vol. 9, Issue 1
Structural rejuvenation in a bulk metallic glass induced by severe plastic deformation
journal, January 2010
- Dmowski, W.; Yokoyama, Y.; Chuang, A.
- Acta Materialia, Vol. 58, Issue 2
Glass temperature, formation and stability of Fe, Co, Ni, Pd and Pt based glasses
journal, May 1976
- Chen, H. S.
- Materials Science and Engineering, Vol. 23, Issue 2-3
Are there two glass transitions in Fe–M–Y–B (M=Mo, W, Nb) bulk metallic glasses?
journal, February 2009
- Huang, X.; Wang, X.; He, Y.
- Scripta Materialia, Vol. 60, Issue 3
Structural evolution in the supercooled liquid of Zr36Ti24Be40 metallic glass
journal, March 2006
- Kumar, G.; Nagahama, D.; Ohnuma, M.
- Scripta Materialia, Vol. 54, Issue 5
Anomalous compression behavior in lanthanum/cerium-based metallic glass under high pressure
journal, August 2007
- Zeng, Q. S.; Li, Y. C.; Feng, C. M.
- Proceedings of the National Academy of Sciences, Vol. 104, Issue 34
Atomic Structure and Structural Stability of Sc 75 Fe 25 Nanoglasses
journal, December 2011
- Fang, J. X.; Vainio, U.; Puff, W.
- Nano Letters, Vol. 12, Issue 1
Ion irradiation enhances the mechanical performance of metallic glasses
journal, April 2010
- Raghavan, R.; Boopathy, K.; Ghisleni, R.
- Scripta Materialia, Vol. 62, Issue 7
Power-law scaling and fractal nature of medium-range order in metallic glasses
journal, December 2008
- Ma, D.; Stoica, A. D.; Wang, X. -L.
- Nature Materials, Vol. 8, Issue 1
Formation of Glasses from Liquids and Biopolymers
journal, March 1995
- Angell, C. A.
- Science, Vol. 267, Issue 5206
Liquid–liquid transition in a strong bulk metallic glass-forming liquid
journal, July 2013
- Wei, Shuai; Yang, Fan; Bednarcik, Jozef
- Nature Communications, Vol. 4, Issue 1
Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996
- Hammersley, A. P.; Svensson, S. O.; Hanfland, M.
- High Pressure Research, Vol. 14, Issue 4-6, p. 235-248
Stored energy in metallic glasses due to strains within the elastic limit
journal, April 2016
- Greer, A. L.; Sun, Y. H.
- Philosophical Magazine, Vol. 96, Issue 16
Highly Ordered Noncrystalline Metallic Phase
journal, July 2013
- Long, Gabrielle G.; Chapman, Karena W.; Chupas, Peter J.
- Physical Review Letters, Vol. 111, Issue 1
Ultrastable Metallic Glass
journal, August 2013
- Yu, Hai-Bin; Luo, Yuansu; Samwer, Konrad
- Advanced Materials, Vol. 25, Issue 41