Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition

doi:10.1063/1.5128740

Title: Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition

Abstract

Pt-Pd bimetallic nanoparticles were synthesized on TiO₂ support on the planar substrate as well as on high surface area SiO₂ gel by atomic layer deposition to identify the catalytic performance improvement after the formation of Pt-Pd bimetallic nanoparticles by surface analysis techniques. From X-ray absorption near edge spectra of Pt-Pd bimetallic nanoparticles, d-orbital hybridization between Pt 5d and Pd 4d was observed, which is responsible for charge transfer from Pt to Pd. Moreover, it was found from the in situ grazing incidence X-ray absorption spectroscopy study that Pt-Pd nanoparticles have a Pd shell/Pt core structure with CO adsorption. Here, resonant photoemission spectroscopy on Pt-Pd bimetallic nanoparticles showed that Pd resonant intensity is enhanced compared to that of Pd monometallic nanoparticles because of d-orbital hybridization and electronic states broadening of Pt and Pd compared monometallic catalysts, which results in catalytic performance improvement.

Authors:

^[1]; Kizilkaya, Orhan ^[2]; Kropf, A. Jeremy ^[3]; Kurtz, Richard L. ^[2]; Elam, Jeffrey W. ^[3];

^[1]

Univ. of Alabama, Huntsville, AL (United States)
Louisiana State Univ., Baton Rouge, LA (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Publication Date:: 2020-01-14

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); American Chemical Society - Petroleum Research Fund

OSTI Identifier:: 1591762

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Chemical Physics

Additional Journal Information:: Journal Volume: 152; Journal Issue: 2; Journal ID: ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Jang, Moon-Hyung, Kizilkaya, Orhan, Kropf, A. Jeremy, Kurtz, Richard L., Elam, Jeffrey W., and Lei, Yu. Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition.  United States: N. p., 2020. 
        Web.  doi:10.1063/1.5128740.

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                    Jang, Moon-Hyung, Kizilkaya, Orhan, Kropf, A. Jeremy, Kurtz, Richard L., Elam, Jeffrey W., & Lei, Yu. Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition.  United States.  doi:10.1063/1.5128740.

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                    Jang, Moon-Hyung, Kizilkaya, Orhan, Kropf, A. Jeremy, Kurtz, Richard L., Elam, Jeffrey W., and Lei, Yu. Tue .  
        "Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition".  United States.  doi:10.1063/1.5128740.  https://www.osti.gov/servlets/purl/1591762.

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@article{osti_1591762,

  title        = {Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition},

  author       = {Jang, Moon-Hyung and Kizilkaya, Orhan and Kropf, A. Jeremy and Kurtz, Richard L. and Elam, Jeffrey W. and Lei, Yu},

  abstractNote = {Pt-Pd bimetallic nanoparticles were synthesized on TiO2 support on the planar substrate as well as on high surface area SiO2 gel by atomic layer deposition to identify the catalytic performance improvement after the formation of Pt-Pd bimetallic nanoparticles by surface analysis techniques. From X-ray absorption near edge spectra of Pt-Pd bimetallic nanoparticles, d-orbital hybridization between Pt 5d and Pd 4d was observed, which is responsible for charge transfer from Pt to Pd. Moreover, it was found from the in situ grazing incidence X-ray absorption spectroscopy study that Pt-Pd nanoparticles have a Pd shell/Pt core structure with CO adsorption. Here, resonant photoemission spectroscopy on Pt-Pd bimetallic nanoparticles showed that Pd resonant intensity is enhanced compared to that of Pd monometallic nanoparticles because of d-orbital hybridization and electronic states broadening of Pt and Pd compared monometallic catalysts, which results in catalytic performance improvement.},

  doi          = {10.1063/1.5128740},

  journal      = {Journal of Chemical Physics},

  number       = 2,

  volume       = 152,

  place        = {United States},

  year         = {2020},

  month        = {1}

}

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Title: Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition

Abstract

Citation Formats

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Atomic layer deposition of transition metals journal, October 2003

Revealing the Synergy of Mono/Bimetallic PdPt/TiO 2 Heterostructure for Enhanced Photoresponse Performance journal, October 2017

The activity of ALD-prepared PtCo catalysts for ethanol oxidation in alkaline media journal, January 2014

Atomic Layer Deposition: An Overview journal, January 2010

Many-body effects in interband resonances observed in photoemission from Pd(111) journal, August 1981

Hydrogenation of Aromatics on Sulfur-Resistant PtPd Bimetallic Catalysts journal, January 2000

Model Studies in Catalysis Using Surface Science Probes journal, May 1995

The Surface Chemistry of Atomic Layer Depositions of Solid Thin Films journal, May 2012

Synthesis and Oxygen Reduction Electrocatalytic Property of Pt-on-Pd Bimetallic Heteronanostructures journal, June 2009

Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition journal, August 2010

The surface science of titanium dioxide journal, January 2003

Effect of Co Loading on the Activity and Selectivity of PtCo Aqueous Phase Reforming Catalysts journal, December 2013

Controlling Nanoscale Properties of Supported Platinum Catalysts through Atomic Layer Deposition journal, January 2015

Bimetallic Pt–Pd nano-catalyst: size, shape and composition matter journal, May 2019

Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts journal, August 2012

Synthesis of palladium nanoparticles on TiO 2 (110) using a beta-diketonate precursor journal, January 2015

Structural transformation of PdPt nanoparticles probed with X-ray absorption near edge structure
journal, September 2004

In situ X-ray probing reveals fingerprints of surface platinum oxide
journal, January 2011

Combining Electronic and Geometric Effects of ZnO-Promoted Pt Nanocatalysts for Aqueous Phase Reforming of 1-Propanol
journal, April 2016

Synthesis of Pt–Pd Core–Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene
journal, September 2012

Design and synthesis of model and practical palladium catalysts using atomic layer deposition
journal, January 2016

Microstructure-Dependent Nucleation in Atomic Layer Deposition of Pt on TiO ₂
journal, December 2011

Effect of space velocity on the hydrocracking of Light Cycle Oil over a Pt–Pd/HY zeolite catalyst
journal, March 2012

Effect of CeO2 loading on the surface and catalytic behaviors of CeO2-Al2O3-supported Pt catalysts
journal, October 2003

Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices
journal, August 2008

Structural and Optical Interplay of Palladium-Modified TiO ₂ Nanoheterostructure
journal, January 2015

Catalytic and Mechanistic Insights of the Low-Temperature Selective Oxidation of Methane over Cu-Promoted Fe-ZSM-5
journal, November 2012

Synthesis and Stabilization of Supported Metal Catalysts by Atomic Layer Deposition
journal, March 2013

Surface studies of supported model catalysts
journal, January 1998

Leed and thermal desorption studies of small molecules (H2, O2, CO, CO2, NO, C2H4, C2H2 AND C) chemisorbed on the rhodium (111) and (100) surfaces
journal, February 1978

Synthesis of Highly Dispersed and Highly Stable Supported Au–Pt Bimetallic Catalysts by a Two-Step Method
journal, November 2016

Effects of composition and metal particle size on ethane dehydrogenation over PtxSn100−x/Mg(Al)O (70⩽x⩽100)
journal, March 2014

Structure and reactivity of single site Ti catalysts for propylene epoxidation
journal, September 2019

Application of Atomic Layer Deposition of Platinum to Solid Oxide Fuel Cells
journal, June 2008

Atomic Surface Segregation and Structural Characterization of PdPt Bimetallic Nanoparticles
journal, October 2018

Interface Tailoring of Heterogeneous Catalysts by Atomic Layer Deposition
journal, September 2018

Supported Core/Shell Bimetallic Nanoparticles Synthesis by Atomic Layer Deposition
journal, August 2012

Correlating Sulfur Reactivity of Pt x Pd 1– x Nanoparticles with a Bimetallic Interaction Effect
journal, June 2011

Improved Thermal Stability and Methane-Oxidation Activity of Pd/Al ₂ O ₃ Catalysts by Atomic Layer Deposition of ZrO ₂
journal, August 2015

Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010

Atomic-Level Pd−Pt Alloying and Largely Enhanced Hydrogen-Storage Capacity in Bimetallic Nanoparticles Reconstructed from Core/Shell Structure by a Process of Hydrogen Absorption/Desorption
journal, April 2010

Bimetallic Pt–Pd/silica–alumina hydrotreating catalysts – Part I: Physicochemical characterization
journal, August 2012

Oscillatory Kinetics in Heterogeneous Catalysis
journal, May 1995

Effect of Particle Size and Adsorbates on the L3, L2 and L1 X-ray Absorption Near Edge Structure of Supported Pt Nanoparticles
journal, February 2011

Metal deposits on well-ordered oxide films
journal, August 1999

TiO 2 /SiO 2 supported vanadia catalysts for the ODH of propane
journal, October 2015

Role of Strain and Ligand Effects in the Modification of the Electronic and Chemical Properties of Bimetallic Surfaces
journal, October 2004

Combinations of platinum and palladium on alumina supports as oxidation catalysts
journal, October 1991

Catalyst Design with Atomic Layer Deposition
journal, February 2015

Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition
journal, May 2015

Toward atomically-precise synthesis of supported bimetallic nanoparticles using atomic layer deposition
journal, February 2014

In situ XAFS analysis of Pd–Pt catalysts during hydrotreatment of model oil
journal, February 2006

Nano/Subnanometer Pd Nanoparticles on Oxide Supports Synthesized by AB-type and Low-Temperature ABC-type Atomic Layer Deposition: Growth and Morphology ^†
journal, November 2010

Structure and reactivity of Pt–In intermetallic alloy nanoparticles: Highly selective catalysts for ethane dehydrogenation
journal, January 2018

Ultrathin metal films and particles on oxide surfaces: structural, electronic and chemisorptive properties
journal, January 1997

Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition
journal, March 2012

The Promotional Effect of Gold in Catalysis by Palladium-Gold
journal, October 2005

Glycerol hydrogenolysis on carbon-supported PtRu and AuRu bimetallic catalysts
journal, October 2007

Atomic layer deposition of transition metals
journal, October 2003

Revealing the Synergy of Mono/Bimetallic PdPt/TiO 2 Heterostructure for Enhanced Photoresponse Performance
journal, October 2017

The activity of ALD-prepared PtCo catalysts for ethanol oxidation in alkaline media
journal, January 2014

Atomic Layer Deposition: An Overview
journal, January 2010

Many-body effects in interband resonances observed in photoemission from Pd(111)
journal, August 1981

Hydrogenation of Aromatics on Sulfur-Resistant PtPd Bimetallic Catalysts
journal, January 2000

Model Studies in Catalysis Using Surface Science Probes
journal, May 1995

The Surface Chemistry of Atomic Layer Depositions of Solid Thin Films
journal, May 2012

Synthesis and Oxygen Reduction Electrocatalytic Property of Pt-on-Pd Bimetallic Heteronanostructures
journal, June 2009

Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition
journal, August 2010

The surface science of titanium dioxide
journal, January 2003

Effect of Co Loading on the Activity and Selectivity of PtCo Aqueous Phase Reforming Catalysts
journal, December 2013

Controlling Nanoscale Properties of Supported Platinum Catalysts through Atomic Layer Deposition
journal, January 2015

Bimetallic Pt–Pd nano-catalyst: size, shape and composition matter
journal, May 2019

Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts
journal, August 2012

Synthesis of palladium nanoparticles on TiO ₂ (110) using a beta-diketonate precursor
journal, January 2015