Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition
Abstract
Pt-Pd bimetallic nanoparticles were synthesized on TiO2 support on the planar substrate as well as on high surface area SiO2 gel by atomic layer deposition to identify the catalytic performance improvement after the formation of Pt-Pd bimetallic nanoparticles by surface analysis techniques. From X-ray absorption near edge spectra of Pt-Pd bimetallic nanoparticles, d-orbital hybridization between Pt 5d and Pd 4d was observed, which is responsible for charge transfer from Pt to Pd. Moreover, it was found from the in situ grazing incidence X-ray absorption spectroscopy study that Pt-Pd nanoparticles have a Pd shell/Pt core structure with CO adsorption. Here, resonant photoemission spectroscopy on Pt-Pd bimetallic nanoparticles showed that Pd resonant intensity is enhanced compared to that of Pd monometallic nanoparticles because of d-orbital hybridization and electronic states broadening of Pt and Pd compared monometallic catalysts, which results in catalytic performance improvement.
- Authors:
-
- Univ. of Alabama, Huntsville, AL (United States)
- Louisiana State Univ., Baton Rouge, LA (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); American Chemical Society - Petroleum Research Fund
- OSTI Identifier:
- 1591762
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Chemical Physics
- Additional Journal Information:
- Journal Volume: 152; Journal Issue: 2; Journal ID: ISSN 0021-9606
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Jang, Moon-Hyung, Kizilkaya, Orhan, Kropf, A. Jeremy, Kurtz, Richard L., Elam, Jeffrey W., and Lei, Yu. Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition. United States: N. p., 2020.
Web. doi:10.1063/1.5128740.
Jang, Moon-Hyung, Kizilkaya, Orhan, Kropf, A. Jeremy, Kurtz, Richard L., Elam, Jeffrey W., & Lei, Yu. Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition. United States. https://doi.org/10.1063/1.5128740
Jang, Moon-Hyung, Kizilkaya, Orhan, Kropf, A. Jeremy, Kurtz, Richard L., Elam, Jeffrey W., and Lei, Yu. Tue .
"Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition". United States. https://doi.org/10.1063/1.5128740. https://www.osti.gov/servlets/purl/1591762.
@article{osti_1591762,
title = {Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition},
author = {Jang, Moon-Hyung and Kizilkaya, Orhan and Kropf, A. Jeremy and Kurtz, Richard L. and Elam, Jeffrey W. and Lei, Yu},
abstractNote = {Pt-Pd bimetallic nanoparticles were synthesized on TiO2 support on the planar substrate as well as on high surface area SiO2 gel by atomic layer deposition to identify the catalytic performance improvement after the formation of Pt-Pd bimetallic nanoparticles by surface analysis techniques. From X-ray absorption near edge spectra of Pt-Pd bimetallic nanoparticles, d-orbital hybridization between Pt 5d and Pd 4d was observed, which is responsible for charge transfer from Pt to Pd. Moreover, it was found from the in situ grazing incidence X-ray absorption spectroscopy study that Pt-Pd nanoparticles have a Pd shell/Pt core structure with CO adsorption. Here, resonant photoemission spectroscopy on Pt-Pd bimetallic nanoparticles showed that Pd resonant intensity is enhanced compared to that of Pd monometallic nanoparticles because of d-orbital hybridization and electronic states broadening of Pt and Pd compared monometallic catalysts, which results in catalytic performance improvement.},
doi = {10.1063/1.5128740},
journal = {Journal of Chemical Physics},
number = 2,
volume = 152,
place = {United States},
year = {2020},
month = {1}
}
Works referenced in this record:
Structural transformation of PdPt nanoparticles probed with X-ray absorption near edge structure
journal, September 2004
- Cho, Sung June; Kang, Sung Kyu
- Catalysis Today, Vol. 93-95
In situ X-ray probing reveals fingerprints of surface platinum oxide
journal, January 2011
- Friebel, Daniel; Miller, Daniel J.; O’Grady, Christopher P.
- Phys. Chem. Chem. Phys., Vol. 13, Issue 1
Combining Electronic and Geometric Effects of ZnO-Promoted Pt Nanocatalysts for Aqueous Phase Reforming of 1-Propanol
journal, April 2016
- Lei, Yu; Lee, Sungsik; Low, Ke-Bin
- ACS Catalysis, Vol. 6, Issue 6
Synthesis of Pt–Pd Core–Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene
journal, September 2012
- Lei, Yu; Liu, Bin; Lu, Junling
- Chemistry of Materials, Vol. 24, Issue 18
Design and synthesis of model and practical palladium catalysts using atomic layer deposition
journal, January 2016
- Lu, Zheng; Kizilkaya, Orhan; Kropf, A. Jeremy
- Catalysis Science & Technology, Vol. 6, Issue 18
Microstructure-Dependent Nucleation in Atomic Layer Deposition of Pt on TiO 2
journal, December 2011
- Lee, Han-Bo-Ram; Bent, Stacey F.
- Chemistry of Materials, Vol. 24, Issue 2
Effect of space velocity on the hydrocracking of Light Cycle Oil over a Pt–Pd/HY zeolite catalyst
journal, March 2012
- Gutiérrez, Alazne; Arandes, José M.; Castaño, Pedro
- Fuel Processing Technology, Vol. 95
Effect of CeO2 loading on the surface and catalytic behaviors of CeO2-Al2O3-supported Pt catalysts
journal, October 2003
- Damyanova, S.; Bueno, J. M. C.
- Applied Catalysis A: General, Vol. 253, Issue 1
Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices
journal, August 2008
- Guo, Yu-Guo; Hu, Jin-Song; Wan, Li-Jun
- Advanced Materials, Vol. 20, Issue 15
Structural and Optical Interplay of Palladium-Modified TiO 2 Nanoheterostructure
journal, January 2015
- Li, Jun; Sham, Tsun-Kong; Ye, Yifan
- The Journal of Physical Chemistry C, Vol. 119, Issue 4
Catalytic and Mechanistic Insights of the Low-Temperature Selective Oxidation of Methane over Cu-Promoted Fe-ZSM-5
journal, November 2012
- Hammond, Ceri; Jenkins, Robert L.; Dimitratos, Nikolaos
- Chemistry - A European Journal, Vol. 18, Issue 49
Synthesis and Stabilization of Supported Metal Catalysts by Atomic Layer Deposition
journal, March 2013
- Lu, Junling; Elam, Jeffrey W.; Stair, Peter C.
- Accounts of Chemical Research, Vol. 46, Issue 8
Surface studies of supported model catalysts
journal, January 1998
- Henry, Claude R.
- Surface Science Reports, Vol. 31, Issue 7-8
Leed and thermal desorption studies of small molecules (H2, O2, CO, CO2, NO, C2H4, C2H2 AND C) chemisorbed on the rhodium (111) and (100) surfaces
journal, February 1978
- Castner, D. G.; Sexton, B. A.; Somorjai, G. A.
- Surface Science, Vol. 71, Issue 3
Synthesis of Highly Dispersed and Highly Stable Supported Au–Pt Bimetallic Catalysts by a Two-Step Method
journal, November 2016
- Wang, Xiaofeng; Zhao, Haiyan; Wu, Tianpin
- Catalysis Letters, Vol. 146, Issue 12
Effects of composition and metal particle size on ethane dehydrogenation over PtxSn100−x/Mg(Al)O (70⩽x⩽100)
journal, March 2014
- Wu, Jason; Peng, Zhenmeng; Bell, Alexis T.
- Journal of Catalysis, Vol. 311
Structure and reactivity of single site Ti catalysts for propylene epoxidation
journal, September 2019
- Lu, Zheng; Liu, Xiaoyang; Zhang, Bin
- Journal of Catalysis, Vol. 377
Application of Atomic Layer Deposition of Platinum to Solid Oxide Fuel Cells
journal, June 2008
- Jiang, Xirong; Huang, Hong; Prinz, Friedrich B.
- Chemistry of Materials, Vol. 20, Issue 12
Atomic Surface Segregation and Structural Characterization of PdPt Bimetallic Nanoparticles
journal, October 2018
- Rodríguez-Proenza, Carlos; Palomares-Báez, Juan; Chávez-Rojo, Marco
- Materials, Vol. 11, Issue 10
Interface Tailoring of Heterogeneous Catalysts by Atomic Layer Deposition
journal, September 2018
- Zhang, Bin; Qin, Yong
- ACS Catalysis, Vol. 8, Issue 11
Supported Core/Shell Bimetallic Nanoparticles Synthesis by Atomic Layer Deposition
journal, August 2012
- Weber, Matthieu J.; Mackus, Adriaan J. M.; Verheijen, Marcel A.
- Chemistry of Materials, Vol. 24, Issue 15
Correlating Sulfur Reactivity of Pt x Pd 1– x Nanoparticles with a Bimetallic Interaction Effect
journal, June 2011
- Bernardi, Fabiano; Traverse, Agnès; Olivi, Luca
- The Journal of Physical Chemistry C, Vol. 115, Issue 25
Improved Thermal Stability and Methane-Oxidation Activity of Pd/Al 2 O 3 Catalysts by Atomic Layer Deposition of ZrO 2
journal, August 2015
- Onn, Tzia Ming; Zhang, Shuyi; Arroyo-Ramirez, Lisandra
- ACS Catalysis, Vol. 5, Issue 10
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010
- Lei, Y.; Mehmood, F.; Lee, S.
- Science, Vol. 328, Issue 5975, p. 224-228
Atomic-Level Pd−Pt Alloying and Largely Enhanced Hydrogen-Storage Capacity in Bimetallic Nanoparticles Reconstructed from Core/Shell Structure by a Process of Hydrogen Absorption/Desorption
journal, April 2010
- Kobayashi, Hirokazu; Yamauchi, Miho; Kitagawa, Hiroshi
- Journal of the American Chemical Society, Vol. 132, Issue 16
Bimetallic Pt–Pd/silica–alumina hydrotreating catalysts – Part I: Physicochemical characterization
journal, August 2012
- Yu, Yanzhe; Fonfé, Benjamin; Jentys, Andreas
- Journal of Catalysis, Vol. 292
Oscillatory Kinetics in Heterogeneous Catalysis
journal, May 1995
- Imbihl, Ronald.; Ertl, Gerhard.
- Chemical Reviews, Vol. 95, Issue 3
Effect of Particle Size and Adsorbates on the L3, L2 and L1 X-ray Absorption Near Edge Structure of Supported Pt Nanoparticles
journal, February 2011
- Lei, Yu; Jelic, Jelena; Nitsche, Ludwig C.
- Topics in Catalysis, Vol. 54, Issue 5-7
Metal deposits on well-ordered oxide films
journal, August 1999
- Bäumer, Marcus; Freund, Hans-Joachim
- Progress in Surface Science, Vol. 61, Issue 7-8
TiO 2 /SiO 2 supported vanadia catalysts for the ODH of propane
journal, October 2015
- Chakraborty, Soumik; Nayak, Sudhir C.; Deo, Goutam
- Catalysis Today, Vol. 254
Role of Strain and Ligand Effects in the Modification of the Electronic and Chemical Properties of Bimetallic Surfaces
journal, October 2004
- Kitchin, J. R.; Nørskov, J. K.; Barteau, M. A.
- Physical Review Letters, Vol. 93, Issue 15
Combinations of platinum and palladium on alumina supports as oxidation catalysts
journal, October 1991
- Skoglundh, M.; Löwendahl, L. O.; Otterated, J. -E.
- Applied Catalysis, Vol. 77, Issue 1
Catalyst Design with Atomic Layer Deposition
journal, February 2015
- O’Neill, Brandon J.; Jackson, David H. K.; Lee, Jechan
- ACS Catalysis, Vol. 5, Issue 3
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition
journal, May 2015
- Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J.
- ACS Nano, Vol. 9, Issue 6
Toward atomically-precise synthesis of supported bimetallic nanoparticles using atomic layer deposition
journal, February 2014
- Lu, Junling; Low, Ke-Bin; Lei, Yu
- Nature Communications, Vol. 5, Issue 1
In situ XAFS analysis of Pd–Pt catalysts during hydrotreatment of model oil
journal, February 2006
- Bando, Kyoko K.; Kawai, Toshihide; Asakura, Kiyotaka
- Catalysis Today, Vol. 111, Issue 3-4
Nano/Subnanometer Pd Nanoparticles on Oxide Supports Synthesized by AB-type and Low-Temperature ABC-type Atomic Layer Deposition: Growth and Morphology †
journal, November 2010
- Lu, Junling; Stair, Peter C.
- Langmuir, Vol. 26, Issue 21
Structure and reactivity of Pt–In intermetallic alloy nanoparticles: Highly selective catalysts for ethane dehydrogenation
journal, January 2018
- Wegener, Evan C.; Wu, Zhenwei; Tseng, Han-Ting
- Catalysis Today, Vol. 299
Ultrathin metal films and particles on oxide surfaces: structural, electronic and chemisorptive properties
journal, January 1997
- Campbell, Charles T.
- Surface Science Reports, Vol. 27, Issue 1-3
Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition
journal, March 2012
- Lu, Junling; Fu, Baosong; Kung, Mayfair C.
- Science, Vol. 335, Issue 6073
The Promotional Effect of Gold in Catalysis by Palladium-Gold
journal, October 2005
- Chen, M.
- Science, Vol. 310, Issue 5746
Glycerol hydrogenolysis on carbon-supported PtRu and AuRu bimetallic catalysts
journal, October 2007
- Maris, E.; Ketchie, W.; Murayama, M.
- Journal of Catalysis, Vol. 251, Issue 2
Atomic layer deposition of transition metals
journal, October 2003
- Lim, Booyong S.; Rahtu, Antti; Gordon, Roy G.
- Nature Materials, Vol. 2, Issue 11
Revealing the Synergy of Mono/Bimetallic PdPt/TiO 2 Heterostructure for Enhanced Photoresponse Performance
journal, October 2017
- Li, Jun; Liu, Chang-Hai; Banis, Mohammad Norouzi
- The Journal of Physical Chemistry C, Vol. 121, Issue 44
The activity of ALD-prepared PtCo catalysts for ethanol oxidation in alkaline media
journal, January 2014
- Santasalo-Aarnio, A.; Sairanen, E.; Arán-Ais, R. M.
- Journal of Catalysis, Vol. 309
Atomic Layer Deposition: An Overview
journal, January 2010
- George, Steven M.
- Chemical Reviews, Vol. 110, Issue 1, p. 111-131
Many-body effects in interband resonances observed in photoemission from Pd(111)
journal, August 1981
- Nilsson, P. O.; Larsson, C. G.; Eberhardt, W.
- Physical Review B, Vol. 24, Issue 4
Hydrogenation of Aromatics on Sulfur-Resistant PtPd Bimetallic Catalysts
journal, January 2000
- Navarro, R. M.; Pawelec, B.; Trejo, J. M.
- Journal of Catalysis, Vol. 189, Issue 1
Model Studies in Catalysis Using Surface Science Probes
journal, May 1995
- Goodman, D. Wayne.
- Chemical Reviews, Vol. 95, Issue 3
The Surface Chemistry of Atomic Layer Depositions of Solid Thin Films
journal, May 2012
- Zaera, Francisco
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 10
Synthesis and Oxygen Reduction Electrocatalytic Property of Pt-on-Pd Bimetallic Heteronanostructures
journal, June 2009
- Peng, Zhenmeng; Yang, Hong
- Journal of the American Chemical Society, Vol. 131, Issue 22
Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition
journal, August 2010
- Christensen, Steven T.; Feng, Hao; Libera, Joseph L.
- Nano Letters, Vol. 10, Issue 8
The surface science of titanium dioxide
journal, January 2003
- Diebold, Ulrike
- Surface Science Reports, Vol. 48, Issue 5-8
Effect of Co Loading on the Activity and Selectivity of PtCo Aqueous Phase Reforming Catalysts
journal, December 2013
- Dietrich, Paul J.; Akatay, M. Cem; Sollberger, Fred G.
- ACS Catalysis, Vol. 4, Issue 2
Controlling Nanoscale Properties of Supported Platinum Catalysts through Atomic Layer Deposition
journal, January 2015
- Gould, Troy D.; Lubers, Alia M.; Corpuz, April R.
- ACS Catalysis, Vol. 5, Issue 2
Bimetallic Pt–Pd nano-catalyst: size, shape and composition matter
journal, May 2019
- Mendoza-Pérez, Rafael; Guisbiers, Grégory
- Nanotechnology, Vol. 30, Issue 30
Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts
journal, August 2012
- Yu, Weiting; Porosoff, Marc D.; Chen, Jingguang G.
- Chemical Reviews, Vol. 112, Issue 11, p. 5780-5817
Synthesis of palladium nanoparticles on TiO 2 (110) using a beta-diketonate precursor
journal, January 2015
- Lei, Yu; Liu, Bin; Lu, Junling
- Physical Chemistry Chemical Physics, Vol. 17, Issue 9
Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices
journal, December 2008
- Guo, Yu-Guo; Hu, Jin-Song; Wan, Li-Jun
- Advanced Materials, Vol. 20, Issue 23