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Title: The first-order magnetoelastic transition in Eu2In: A 151Eu Mössbauer study

Abstract

Our 151Eu Mössbauer investigation of Eu2In and Eu2Sn shows that the europium in both materials is fully divalent. We confirm the distinct thermodynamic orders of the magnetic transitions and reveal a remarkable difference between the magnetic environments of the europium atoms in the two compounds. Possible structural and electronic origins for these differences are discussed using DFT calculations.

Authors:
ORCiD logo [1];  [2];  [2]; ORCiD logo [2];  [3];  [4]
  1. McGill Univ., Montreal, QC (Canada)
  2. Ames Lab., Ames, IA (United States)
  3. State Univ. of New York (SUNY), Buffalo, NY (United States)
  4. Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Lab., Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1591615
Alternate Identifier(s):
OSTI ID: 1580300
Report Number(s):
IS-J-10134
Journal ID: ISSN 2158-3226; TRN: US2100773
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Ryan, D. H., Paudyal, Durga, Guillou, Francois, Mudryk, Yaroslav, Pathak, Arjun K., and Pecharsky, Vitalij K. The first-order magnetoelastic transition in Eu2In: A 151Eu Mössbauer study. United States: N. p., 2019. Web. doi:10.1063/1.5129683.
Ryan, D. H., Paudyal, Durga, Guillou, Francois, Mudryk, Yaroslav, Pathak, Arjun K., & Pecharsky, Vitalij K. The first-order magnetoelastic transition in Eu2In: A 151Eu Mössbauer study. United States. https://doi.org/10.1063/1.5129683
Ryan, D. H., Paudyal, Durga, Guillou, Francois, Mudryk, Yaroslav, Pathak, Arjun K., and Pecharsky, Vitalij K. Tue . "The first-order magnetoelastic transition in Eu2In: A 151Eu Mössbauer study". United States. https://doi.org/10.1063/1.5129683. https://www.osti.gov/servlets/purl/1591615.
@article{osti_1591615,
title = {The first-order magnetoelastic transition in Eu2In: A 151Eu Mössbauer study},
author = {Ryan, D. H. and Paudyal, Durga and Guillou, Francois and Mudryk, Yaroslav and Pathak, Arjun K. and Pecharsky, Vitalij K.},
abstractNote = {Our 151Eu Mössbauer investigation of Eu2In and Eu2Sn shows that the europium in both materials is fully divalent. We confirm the distinct thermodynamic orders of the magnetic transitions and reveal a remarkable difference between the magnetic environments of the europium atoms in the two compounds. Possible structural and electronic origins for these differences are discussed using DFT calculations.},
doi = {10.1063/1.5129683},
journal = {AIP Advances},
number = 12,
volume = 9,
place = {United States},
year = {Tue Dec 24 00:00:00 EST 2019},
month = {Tue Dec 24 00:00:00 EST 2019}
}

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Works referenced in this record:

Filiation structurale des composés de formule générale AB2: Etude comparée des types Co2Si, Co2P, PbCl2, et SbSl
journal, May 1980


The phase diagram of the Eu–Sn system
journal, October 1998


151 Eu hyperfine fields, isomer shifts and moments in Eu-based EuT 2 X 2 intermetallic compounds
journal, October 2013


A complete solution to the Mössbauer problem, all in one place
journal, December 2006


Non-hysteretic first-order phase transition with large latent heat and giant low-field magnetocaloric effect
journal, July 2018