Single-atom catalysts templated by metal–organic frameworks for electrochemical nitrogen reduction
Abstract
The electrocatalytic nitrogen reduction reaction (NRR) offers much prospect for substituting the energy-consuming Haber–Bosch process. Nevertheless, its sluggish reaction kinetics and the competing hydrogen evolution reaction always result in limited ammonia yield and low faradaic efficiency (FE). Here, an Fe-decorated porphyrinic metal–organic framework (MOF) is employed as a precursor to construct single-atom Fe implanted nitrogen-doped carbon catalysts (Fe1-N-C) through a mixed ligand strategy. Benefiting from the highly dispersed single-atom Fe sites, hierarchically porous structure and good conductivity, Fe1-N-C shows a FE of 4.51% and an ammonia yield rate of 1.56 × 10-11 mol cm-2 s-1 at -0.05 V versus the reversible hydrogen electrode, superior to those of Co1-N-C and Ni1-N-C. Theoretical calculations show that Fe1-N-C shows the lowest energy barrier of the rate-determining step during the NRR process, consistent with its highest activity obtained in experiments. This work reveals the unique potential of single-atom catalysts for the electrochemical NRR and provides in-depth insights into the catalytic mechanism of the NRR.
- Authors:
-
- Univ. of Science and Technology of China, Hefei (China)
- Univ. of Science and Technology of China, Hefei (China); North China Electric Power Univ., Baoding (China)
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Univ. of Science and Technology of China, Hefei (China); Chinese Academy of Sciences (CAS), Fuzhou (China)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1583128
- Grant/Contract Number:
- AC02-76SF00515; 21725101, 21871244, 21521001; 2019TQ0298; WK2060030029
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 46; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Zhang, Rui, Jiao, Long, Yang, Weijie, Wan, Gang, and Jiang, Hai-Long. Single-atom catalysts templated by metal–organic frameworks for electrochemical nitrogen reduction. United States: N. p., 2019.
Web. doi:10.1039/C9TA10206J.
Zhang, Rui, Jiao, Long, Yang, Weijie, Wan, Gang, & Jiang, Hai-Long. Single-atom catalysts templated by metal–organic frameworks for electrochemical nitrogen reduction. United States. https://doi.org/10.1039/C9TA10206J
Zhang, Rui, Jiao, Long, Yang, Weijie, Wan, Gang, and Jiang, Hai-Long. Thu .
"Single-atom catalysts templated by metal–organic frameworks for electrochemical nitrogen reduction". United States. https://doi.org/10.1039/C9TA10206J. https://www.osti.gov/servlets/purl/1583128.
@article{osti_1583128,
title = {Single-atom catalysts templated by metal–organic frameworks for electrochemical nitrogen reduction},
author = {Zhang, Rui and Jiao, Long and Yang, Weijie and Wan, Gang and Jiang, Hai-Long},
abstractNote = {The electrocatalytic nitrogen reduction reaction (NRR) offers much prospect for substituting the energy-consuming Haber–Bosch process. Nevertheless, its sluggish reaction kinetics and the competing hydrogen evolution reaction always result in limited ammonia yield and low faradaic efficiency (FE). Here, an Fe-decorated porphyrinic metal–organic framework (MOF) is employed as a precursor to construct single-atom Fe implanted nitrogen-doped carbon catalysts (Fe1-N-C) through a mixed ligand strategy. Benefiting from the highly dispersed single-atom Fe sites, hierarchically porous structure and good conductivity, Fe1-N-C shows a FE of 4.51% and an ammonia yield rate of 1.56 × 10-11 mol cm-2 s-1 at -0.05 V versus the reversible hydrogen electrode, superior to those of Co1-N-C and Ni1-N-C. Theoretical calculations show that Fe1-N-C shows the lowest energy barrier of the rate-determining step during the NRR process, consistent with its highest activity obtained in experiments. This work reveals the unique potential of single-atom catalysts for the electrochemical NRR and provides in-depth insights into the catalytic mechanism of the NRR.},
doi = {10.1039/C9TA10206J},
journal = {Journal of Materials Chemistry. A},
number = 46,
volume = 7,
place = {United States},
year = {Thu Oct 24 00:00:00 EDT 2019},
month = {Thu Oct 24 00:00:00 EDT 2019}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Reversing nitrogen fixation
journal, September 2018
- Lehnert, Nicolai; Dong, Hai T.; Harland, Jill B.
- Nature Reviews Chemistry, Vol. 2, Issue 10
Single Pt Atoms Confined into a Metal-Organic Framework for Efficient Photocatalysis
journal, January 2018
- Fang, Xinzuo; Shang, Qichao; Wang, Yu
- Advanced Materials, Vol. 30, Issue 7
Ammonia Synthesis Under Ambient Conditions: Selective Electroreduction of Dinitrogen to Ammonia on Black Phosphorus Nanosheets
journal, January 2019
- Zhang, Lili; Ding, Liang-Xin; Chen, Gao-Feng
- Angewandte Chemie International Edition, Vol. 58, Issue 9
Metal-Organic-Framework-Derived Hollow N-Doped Porous Carbon with Ultrahigh Concentrations of Single Zn Atoms for Efficient Carbon Dioxide Conversion
journal, January 2019
- Yang, Qihao; Yang, Chun-Chuen; Lin, Chia-Her
- Angewandte Chemie International Edition, Vol. 58, Issue 11
Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction
journal, February 2018
- Cheng, Yi; Zhao, Shiyong; Johannessen, Bernt
- Advanced Materials, Vol. 30, Issue 13
TiC- and TiN-Supported Single-Atom Catalysts for Dramatic Improvements in CO 2 Electrochemical Reduction to CH 4
journal, April 2017
- Back, Seoin; Jung, Yousung
- ACS Energy Letters, Vol. 2, Issue 5
A Metal-Organic Framework Based Methane Nano-trap for the Capture of Coal-Mine Methane
journal, May 2019
- Niu, Zheng; Cui, Xili; Pham, Tony
- Angewandte Chemie International Edition, Vol. 58, Issue 30
Electrochemical Ammonia Synthesis via Nitrogen Reduction Reaction on a MoS 2 Catalyst: Theoretical and Experimental Studies
journal, May 2018
- Zhang, Ling; Ji, Xuqiang; Ren, Xiang
- Advanced Materials, Vol. 30, Issue 28
Facile Ammonia Synthesis from Electrocatalytic N 2 Reduction under Ambient Conditions on N-Doped Porous Carbon
journal, January 2018
- Liu, Yanming; Su, Yan; Quan, Xie
- ACS Catalysis, Vol. 8, Issue 2
Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
journal, April 2018
- Liu, Jin-Cheng; Ma, Xue-Lu; Li, Yong
- Nature Communications, Vol. 9, Issue 1
Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis
journal, January 2017
- Yang, Qihao; Xu, Qiang; Jiang, Hai-Long
- Chemical Society Reviews, Vol. 46, Issue 15
Metal–organic frameworks: Structures and functional applications
journal, July 2019
- Jiao, Long; Seow, Joanne Yen Ru; Skinner, William Scott
- Materials Today, Vol. 27
Catalytic conversion of nitrogen to ammonia by an iron model complex
journal, September 2013
- Anderson, John S.; Rittle, Jonathan; Peters, Jonas C.
- Nature, Vol. 501, Issue 7465
Catalysis by Supported Single Metal Atoms
journal, November 2016
- Liu, Jingyue
- ACS Catalysis, Vol. 7, Issue 1
Au Sub-Nanoclusters on TiO 2 toward Highly Efficient and Selective Electrocatalyst for N 2 Conversion to NH 3 at Ambient Conditions
journal, February 2017
- Shi, Miao-Miao; Bao, Di; Wulan, Ba-Ri
- Advanced Materials, Vol. 29, Issue 17
Suppression of Hydrogen Evolution Reaction in Electrochemical N 2 Reduction Using Single-Atom Catalysts: A Computational Guideline
journal, July 2018
- Choi, Changhyeok; Back, Seoin; Kim, Na-Young
- ACS Catalysis, Vol. 8, Issue 8
A Spectroscopic Study on the Nitrogen Electrochemical Reduction Reaction on Gold and Platinum Surfaces
journal, January 2018
- Yao, Yao; Zhu, Shangqian; Wang, Haijiang
- Journal of the American Chemical Society, Vol. 140, Issue 4
Ammonia Electrosynthesis with High Selectivity under Ambient Conditions via a Li + Incorporation Strategy
journal, July 2017
- Chen, Gao-Feng; Cao, Xinrui; Wu, Shunqing
- Journal of the American Chemical Society, Vol. 139, Issue 29
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017
- Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
- Angewandte Chemie International Edition, Vol. 56, Issue 24
Molybdenum Carbide Nanodots Enable Efficient Electrocatalytic Nitrogen Fixation under Ambient Conditions
journal, October 2018
- Cheng, Hui; Ding, Liang-Xin; Chen, Gao-Feng
- Advanced Materials, Vol. 30, Issue 46
Heterogeneous single-atom catalysis
journal, May 2018
- Wang, Aiqin; Li, Jun; Zhang, Tao
- Nature Reviews Chemistry, Vol. 2, Issue 6
Building Up a Picture of the Electrocatalytic Nitrogen Reduction Activity of Transition Metal Single-Atom Catalysts
journal, April 2019
- Liu, Xin; Jiao, Yan; Zheng, Yao
- Journal of the American Chemical Society, Vol. 141, Issue 24
An Amorphous Noble-Metal-Free Electrocatalyst that Enables Nitrogen Fixation under Ambient Conditions
journal, March 2018
- Lv, Chade; Yan, Chunshuang; Chen, Gang
- Angewandte Chemie International Edition, Vol. 57, Issue 21
Template-Directed Growth of Well-Aligned MOF Arrays and Derived Self-Supporting Electrodes for Water Splitting
journal, June 2017
- Cai, Guorui; Zhang, Wang; Jiao, Long
- Chem, Vol. 2, Issue 6
Metal-Organic-Framework-Based Single-Atom Catalysts for Energy Applications
journal, April 2019
- Jiao, Long; Jiang, Hai-Long
- Chem, Vol. 5, Issue 4
Metal-Organic Frameworks as Platforms for Catalytic Applications
journal, November 2017
- Jiao, Long; Wang, Yang; Jiang, Hai-Long
- Advanced Materials, Vol. 30, Issue 37
Metal-Organic Frameworks and Their Composites: Synthesis and Electrochemical Applications
journal, October 2017
- Yi, Fei-Yan; Zhang, Rui; Wang, Hailong
- Small Methods, Vol. 1, Issue 11
High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium
journal, September 2019
- Cheng, Hui; Cui, Peixin; Wang, Fangrui
- Angewandte Chemie International Edition, Vol. 58, Issue 43
Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH 3 ) under ambient conditions
journal, January 2018
- Guo, Chunxian; Ran, Jingrun; Vasileff, Anthony
- Energy & Environmental Science, Vol. 11, Issue 1
Transformation of Metal–Organic Frameworks/Coordination Polymers into Functional Nanostructured Materials: Experimental Approaches Based on Mechanistic Insights
journal, October 2017
- Lee, Kyung Joo; Lee, Jae Hwa; Jeoung, Sungeun
- Accounts of Chemical Research, Vol. 50, Issue 11
Boosting Electrocatalytic Hydrogen Evolution over Metal-Organic Frameworks by Plasmon-Induced Hot-Electron Injection
journal, June 2019
- Wang, Shan-Shan; Jiao, Long; Qian, Yunyang
- Angewandte Chemie International Edition, Vol. 58, Issue 31
Photochemical route for synthesizing atomically dispersed palladium catalysts
journal, May 2016
- Liu, P.; Zhao, Y.; Qin, R.
- Science, Vol. 352, Issue 6287
Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis
journal, November 2018
- Niu, Zheng; Bhagya Gunatilleke, Wilarachchige D. C.; Sun, Qi
- Chem, Vol. 4, Issue 11
Metal–organic frameworks as selectivity regulators for hydrogenation reactions
journal, October 2016
- Zhao, Meiting; Yuan, Kuo; Wang, Yun
- Nature, Vol. 539, Issue 7627
Location determination of metal nanoparticles relative to a metal-organic framework
journal, August 2019
- Chen, Yu-Zhen; Gu, Bingchuan; Uchida, Takeyuki
- Nature Communications, Vol. 10, Issue 1
Tuning the Performance of Single-Atom Electrocatalysts: Support-Induced Structural Reconstruction
journal, October 2018
- Wan, Gang; Lin, Xiao-Min; Wen, Jianguo
- Chemistry of Materials, Vol. 30, Issue 21
Platinum single-atom and cluster catalysis of the hydrogen evolution reaction
journal, November 2016
- Cheng, Niancai; Stambula, Samantha; Wang, Da
- Nature Communications, Vol. 7, Issue 1
Adenine Components in Biomimetic Metal-Organic Frameworks for Efficient CO 2 Photoconversion
journal, February 2019
- Li, Ning; Liu, Jiang; Liu, Jing-Jing
- Angewandte Chemie International Edition, Vol. 58, Issue 16
Over 56.55% Faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential
journal, January 2019
- Wang, Mengfan; Liu, Sisi; Qian, Tao
- Nature Communications, Vol. 10, Issue 1
Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions
journal, January 2019
- Luo, Yaru; Chen, Gao-Feng; Ding, Li
- Joule, Vol. 3, Issue 1
The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
journal, July 2017
- Trickett, Christopher A.; Helal, Aasif; Al-Maythalony, Bassem A.
- Nature Reviews Materials, Vol. 2, Issue 8
Single-Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis
journal, September 2017
- Zhang, Huabin; Liu, Guigao; Shi, Li
- Advanced Energy Materials, Vol. 8, Issue 1
Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction
journal, January 2018
- Zhang, Huabin; An, Pengfei; Zhou, Wei
- Science Advances, Vol. 4, Issue 1
A universal principle for a rational design of single-atom electrocatalysts
journal, April 2018
- Xu, Haoxiang; Cheng, Daojian; Cao, Dapeng
- Nature Catalysis, Vol. 1, Issue 5
Catalysts for nitrogen reduction to ammonia
journal, July 2018
- Foster, Shelby L.; Bakovic, Sergio I. Perez; Duda, Royce D.
- Nature Catalysis, Vol. 1, Issue 7
Metal-Organic Frameworks for Energy Applications
journal, January 2017
- Wang, Hailong; Zhu, Qi-Long; Zou, Ruqiang
- Chem, Vol. 2, Issue 1
Graphene Defects Trap Atomic Ni Species for Hydrogen and Oxygen Evolution Reactions
journal, February 2018
- Zhang, Longzhou; Jia, Yi; Gao, Guoping
- Chem, Vol. 4, Issue 2
Nitrogen-coordinated single Fe sites for efficient electrocatalytic N2 fixation in neutral media
journal, July 2019
- Lü, Fang; Zhao, Shunzheng; Guo, Ruijie
- Nano Energy, Vol. 61
Metal–organic framework-based CoP/reduced graphene oxide: high-performance bifunctional electrocatalyst for overall water splitting
journal, January 2016
- Jiao, Long; Zhou, Yu-Xiao; Jiang, Hai-Long
- Chemical Science, Vol. 7, Issue 3
Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation
journal, January 2019
- Han, Lili; Liu, Xijun; Chen, Jinping
- Angewandte Chemie International Edition, Vol. 58, Issue 8
Efficient Electrocatalytic Proton Reduction with Carbon Nanotube-Supported Metal–Organic Frameworks
journal, November 2018
- Micheroni, Daniel; Lan, Guangxu; Lin, Wenbin
- Journal of the American Chemical Society, Vol. 140, Issue 46
Singlet Oxygen-Engaged Selective Photo-Oxidation over Pt Nanocrystals/Porphyrinic MOF: The Roles of Photothermal Effect and Pt Electronic State
journal, January 2017
- Chen, Yu-Zhen; Wang, Zhiyong U.; Wang, Hengwei
- Journal of the American Chemical Society, Vol. 139, Issue 5
Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation
journal, September 2017
- Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu
- Journal of the American Chemical Society, Vol. 139, Issue 40
Single-Atom Electrocatalysts
journal, October 2017
- Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong
- Angewandte Chemie International Edition, Vol. 56, Issue 45
Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution
journal, November 2016
- Zhao, Shenlong; Wang, Yun; Dong, Juncai
- Nature Energy, Vol. 1, Issue 12
Metal–Organic Frameworks for Photocatalysis and Photothermal Catalysis
journal, December 2018
- Xiao, Juan-Ding; Jiang, Hai-Long
- Accounts of Chemical Research, Vol. 52, Issue 2
Monometallic Catalytic Models Hosted in Stable Metal–Organic Frameworks for Tunable CO 2 Photoreduction
journal, January 2019
- Wang, Xiao-Kun; Liu, Jiang; Zhang, Lei
- ACS Catalysis, Vol. 9, Issue 3
Room-Temperature Methane Conversion by Graphene-Confined Single Iron Atoms
journal, August 2018
- Cui, Xiaoju; Li, Haobo; Wang, Yan
- Chem, Vol. 4, Issue 8
Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts
journal, January 2011
- Ma, Shengqian; Goenaga, Gabriel A.; Call, Ann V.
- Chemistry - A European Journal, Vol. 17, Issue 7
Our journey of developing multifunctional metal-organic frameworks
journal, April 2019
- Lin, Rui-Biao; Xiang, Shengchang; Li, Bin
- Coordination Chemistry Reviews, Vol. 384
The Use of Controls for Consistent and Accurate Measurements of Electrocatalytic Ammonia Synthesis from Dinitrogen
journal, July 2018
- Greenlee, Lauren F.; Renner, Julie N.; Foster, Shelby L.
- ACS Catalysis, Vol. 8, Issue 9
Electrochemical Nitrogen Reduction: Identification and Elimination of Contamination in Electrolyte
journal, August 2019
- Li, Laiquan; Tang, Cheng; Yao, Dazhi
- ACS Energy Letters, Vol. 4, Issue 9
Metal-organic frameworks for catalysis: State of the art, challenges, and opportunities
journal, July 2019
- Li, Dandan; Xu, Hai-Qun; Jiao, Long
- EnergyChem, Vol. 1, Issue 1
Conversion of Dinitrogen to Ammonia by FeN 3 -Embedded Graphene
journal, July 2016
- Li, Xiao-Fei; Li, Qin-Kun; Cheng, Jin
- Journal of the American Chemical Society, Vol. 138, Issue 28
Emerging Multifunctional Metal-Organic Framework Materials
journal, July 2016
- Li, Bin; Wen, Hui-Min; Cui, Yuanjing
- Advanced Materials, Vol. 28, Issue 40
Electrochemical Ammonia Synthesis and Ammonia Fuel Cells
journal, December 2018
- Jiao, Feng; Xu, Bingjun
- Advanced Materials, Vol. 31, Issue 31
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
journal, February 2018
- Yang, Hong Bin; Hung, Sung-Fu; Liu, Song
- Nature Energy, Vol. 3, Issue 2
Front Cover: Single‐Atom Catalysts for the Electrocatalytic Reduction of Nitrogen to Ammonia under Ambient Conditions (Chem. Asian J. 17/2019)
journal, August 2019
- Qiu, Yuan; Peng, Xianyun; Lü, Fang
- Chemistry – An Asian Journal, Vol. 14, Issue 17
Boron-Doped Graphene for Electrocatalytic N2 Reduction
journal, August 2018
- Yu, Xiaomin; Han, Peng; Wei, Zengxi
- Joule, Vol. 2, Issue 8
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
journal, April 2018
- Liu, Lichen; Corma, Avelino
- Chemical Reviews, Vol. 118, Issue 10
Metal–organic framework-derived porous materials for catalysis
journal, May 2018
- Chen, Yu-Zhen; Zhang, Rui; Jiao, Long
- Coordination Chemistry Reviews, Vol. 362
How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully
journal, January 2019
- Tang, Cheng; Qiao, Shi-Zhang
- Chemical Society Reviews, Vol. 48, Issue 12
From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media
journal, June 2018
- Jiao, Long; Wan, Gang; Zhang, Rui
- Angewandte Chemie International Edition, Vol. 57, Issue 28
A theoretical evaluation of possible transition metal electro-catalysts for N 2 reduction
journal, January 2012
- Skúlason, Egill; Bligaard, Thomas; Gudmundsdóttir, Sigrídur
- Phys. Chem. Chem. Phys., Vol. 14, Issue 3
Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis
journal, February 2016
- Fan, Lili; Liu, Peng Fei; Yan, Xuecheng
- Nature Communications, Vol. 7, Issue 1
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
- Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
- Angewandte Chemie International Edition, Vol. 51, Issue 41
A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions
journal, May 2018
- Cui, Xiaoyang; Tang, Cheng; Zhang, Qiang
- Advanced Energy Materials, Vol. 8, Issue 22
Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf
journal, February 2019
- Martín, Antonio José; Shinagawa, Tatsuya; Pérez-Ramírez, Javier
- Chem, Vol. 5, Issue 2
Rational Design of Fe–N/C Hybrid for Enhanced Nitrogen Reduction Electrocatalysis under Ambient Conditions in Aqueous Solution
journal, November 2018
- Wang, Ying; Cui, Xiaoqiang; Zhao, Jingxiang
- ACS Catalysis, Vol. 9, Issue 1
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017
- Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
- Angewandte Chemie, Vol. 129, Issue 24
An Amorphous Noble-Metal-Free Electrocatalyst that Enables Nitrogen Fixation under Ambient Conditions
journal, March 2018
- Lv, Chade; Yan, Chunshuang; Chen, Gang
- Angewandte Chemie, Vol. 130, Issue 21
From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media
journal, June 2018
- Jiao, Long; Wan, Gang; Zhang, Rui
- Angewandte Chemie, Vol. 130, Issue 28
Adenine Components in Biomimetic Metal–Organic Frameworks for Efficient CO 2 Photoconversion
journal, February 2019
- Li, Ning; Liu, Jiang; Liu, Jing‐Jing
- Angewandte Chemie, Vol. 131, Issue 16
Boosting Electrocatalytic Hydrogen Evolution over Metal–Organic Frameworks by Plasmon‐Induced Hot‐Electron Injection
journal, June 2019
- Wang, Shan‐Shan; Jiao, Long; Qian, Yunyang
- Angewandte Chemie, Vol. 131, Issue 31
High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium
journal, September 2019
- Cheng, Hui; Cui, Peixin; Wang, Fangrui
- Angewandte Chemie, Vol. 131, Issue 43
Ammonia Synthesis Under Ambient Conditions: Selective Electroreduction of Dinitrogen to Ammonia on Black Phosphorus Nanosheets
journal, January 2019
- Zhang, Lili; Ding, Liang‐Xin; Chen, Gao‐Feng
- Angewandte Chemie, Vol. 131, Issue 9
Metal-Organic-Framework-Derived Hollow N-Doped Porous Carbon with Ultrahigh Concentrations of Single Zn Atoms for Efficient Carbon Dioxide Conversion
journal, January 2019
- Yang, Qihao; Yang, Chun-Chuen; Lin, Chia-Her
- Angewandte Chemie, Vol. 131, Issue 11
A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane
journal, May 2019
- Niu, Zheng; Cui, Xili; Pham, Tony
- Angewandte Chemie, Vol. 131, Issue 30
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
- Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
- Angewandte Chemie, Vol. 124, Issue 41, p. 10453-10456
Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation
journal, January 2019
- Han, Lili; Liu, Xijun; Chen, Jinping
- Angewandte Chemie, Vol. 131, Issue 8
Figures / Tables found in this record: