Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy Studies of Hole-Selective Molybdenum Oxide Contacts in Silicon Solar Cells

Ali, Haider; Maynau, Céline; Lajaunie, Luc; Gregory, Geoffrey; Wu, Lijun; Looney, John Patrick; Zhu, Yimei; Schneider, Matthew; Schoenfeld, Winston V.; Davis, Kristopher O.

doi:10.1021/acsami.9b12703

Title: Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy Studies of Hole-Selective Molybdenum Oxide Contacts in Silicon Solar Cells

Authors:

Ali, Haider ^[1]; Maynau, Céline ^[2];

^[2]; Gregory, Geoffrey ^[1];

^[3]; Looney, John Patrick ^[3];

^[3]; Schneider, Matthew ^[4]; Schoenfeld, Winston V. ^[1];

^[1]

Univ. of Central Florida, Orlando, FL (United States)
Univ. de Cádiz (Spain)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States

Publication Date:: 2019-10-31

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

OSTI Identifier:: 1583109

Alternate Identifier(s):: OSTI ID: 1608685

Report Number(s):: BNL-213528-2020-JAAM; LA-UR-19-30766
Journal ID: ISSN 1944-8244; TRN: US2101061

Grant/Contract Number:: SC0012704; EE0007533; 89233218CNA000001

Resource Type:: Accepted Manuscript

Journal Name:: ACS Applied Materials and Interfaces

Additional Journal Information:: Journal Volume: 11; Journal Issue: 46; Journal ID: ISSN 1944-8244

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; hole-selective; molybdenum oxide (MoOx); transmission electron microscopy (TEM); electron energy-loss spectroscopy (EELS); silicon

Citation Formats


                    Ali, Haider, Maynau, Céline, Lajaunie, Luc, Gregory, Geoffrey, Wu, Lijun, Looney, John Patrick, Zhu, Yimei, Schneider, Matthew, Schoenfeld, Winston V., and Davis, Kristopher O. Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy Studies of Hole-Selective Molybdenum Oxide Contacts in Silicon Solar Cells.  United States: N. p., 2019. 
Web.  doi:10.1021/acsami.9b12703.

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                    Ali, Haider, Maynau, Céline, Lajaunie, Luc, Gregory, Geoffrey, Wu, Lijun, Looney, John Patrick, Zhu, Yimei, Schneider, Matthew, Schoenfeld, Winston V., & Davis, Kristopher O. Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy Studies of Hole-Selective Molybdenum Oxide Contacts in Silicon Solar Cells.  United States.  https://doi.org/10.1021/acsami.9b12703

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                    Ali, Haider, Maynau, Céline, Lajaunie, Luc, Gregory, Geoffrey, Wu, Lijun, Looney, John Patrick, Zhu, Yimei, Schneider, Matthew, Schoenfeld, Winston V., and Davis, Kristopher O. Thu .  
"Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy Studies of Hole-Selective Molybdenum Oxide Contacts in Silicon Solar Cells".  United States.  https://doi.org/10.1021/acsami.9b12703.  https://www.osti.gov/servlets/purl/1583109.

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@article{osti_1583109,

  title        = {Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy Studies of Hole-Selective Molybdenum Oxide Contacts in Silicon Solar Cells},

  author       = {Ali, Haider and Maynau, Céline and Lajaunie, Luc and Gregory, Geoffrey and Wu, Lijun and Looney, John Patrick and Zhu, Yimei and Schneider, Matthew and Schoenfeld, Winston V. and Davis, Kristopher O.},

  abstractNote = {},

  doi          = {10.1021/acsami.9b12703},

  journal      = {ACS Applied Materials and Interfaces},

  number       = 46,

  volume       = 11,

  place        = {United States},

  year         = {2019},

  month        = {10}

}

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Title: Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy Studies of Hole-Selective Molybdenum Oxide Contacts in Silicon Solar Cells

Citation Formats

Dielectric surface passivation for silicon solar cells: A review journal, June 2017

High-Performance TiO 2 -Based Electron-Selective Contacts for Crystalline Silicon Solar Cells journal, May 2016

Silicon heterojunction solar cell with passivated hole selective MoO x contact journal, March 2014

Hole Selective MoO x Contact for Silicon Solar Cells journal, January 2014

Molybdenum and tungsten oxide: High work function wide band gap contact materials for hole selective contacts of silicon solar cells journal, November 2015

Engineered Interfaces Using Surface and Contact Passivation in Silicon Solar Cells journal, January 2018

Passivated rear contacts for high-efficiency n-type Si solar cells providing high interface passivation quality and excellent transport characteristics journal, January 2014

Improving the a-Si:H(p) rear emitter contact of n-type silicon solar cells journal, November 2012

Simple silicon solar cells featuring an a-Si:H enhanced rear MIS contact journal, July 2015

Development of a-SiO x :H solar cells with very high V oc × FF product : Development of a-SiO journal, December 2014

Passivating Contacts for Crystalline Silicon Solar Cells: From Concepts and Materials to Prospects journal, March 2018

Transmission Electron Microscopy Studies of Electron-Selective Titanium Oxide Contacts in Silicon Solar Cells journal, August 2017

Amorphous silicon passivated contacts for diffused junction silicon solar cells journal, April 2014

Molybdenum oxide MoO x : A versatile hole contact for silicon solar cells journal, December 2014

Transition metal oxides as hole-selective contacts in silicon heterojunctions solar cells journal, February 2016

Transition Metal Oxide Work Functions: The Influence of Cation Oxidation State and Oxygen Vacancies journal, June 2012

Systematic Study of Oxygen Vacancy Tunable Transport Properties of Few‐Layer MoO 3− x Enabled by Vapor‐Based Synthesis journal, March 2017

22.5% efficient silicon heterojunction solar cell with molybdenum oxide hole collector journal, August 2015

ITO/MoOx/a-Si:H(i) Hole-Selective Contacts for Silicon Heterojunction Solar Cells: Degradation Mechanisms and Cell Integration journal, November 2017

Quantitative use of electron energy-loss spectroscopy Mo-M2,3 edges for the study of molybdenum oxides journal, February 2015

In situ x-ray photoelectron emission analysis of the thermal stability of atomic layer deposited WO x as hole-selective contacts for Si solar cells journal, May 2018

Origin of passivation in hole-selective transition metal oxides for crystalline silicon heterojunction solar cells journal, December 2016

Advanced spectroscopic analyses on a:C-H materials: Revisiting the EELS characterization and its coupling with multi-wavelength Raman spectroscopy journal, February 2017

Nanotubes from Oxide-Based Misfit Family: The Case of Calcium Cobalt Oxide journal, May 2016

Investigation on Molybdenum and Its Conductive Oxides as p-type Metal Gate Candidates journal, September 2007

MoO3 Films Spin-Coated from a Nanoparticle Suspension for Efficient Hole-Injection in Organic Electronics journal, October 2010

Selectivity issues of MoOx based hole contacts journal, September 2017

A new simulation software of solar cells—wxAMPS journal, March 2012

Numerical Simulation of Silicon Heterojunction Solar Cells Featuring Metal Oxides as Carrier-Selective Contacts journal, March 2018

Origin of the high work function and high conductivity of MoO 3 journal, December 2014

Toward Annealing-Stable Molybdenum-Oxide-Based Hole-Selective Contacts For Silicon Photovoltaics journal, February 2018

Dielectric surface passivation for silicon solar cells: A review
journal, June 2017

High-Performance TiO ₂ -Based Electron-Selective Contacts for Crystalline Silicon Solar Cells
journal, May 2016

Silicon heterojunction solar cell with passivated hole selective MoO _x contact
journal, March 2014

Hole Selective MoO _x Contact for Silicon Solar Cells
journal, January 2014

Molybdenum and tungsten oxide: High work function wide band gap contact materials for hole selective contacts of silicon solar cells
journal, November 2015

Engineered Interfaces Using Surface and Contact Passivation in Silicon Solar Cells
journal, January 2018

Passivated rear contacts for high-efficiency n-type Si solar cells providing high interface passivation quality and excellent transport characteristics
journal, January 2014

Improving the a-Si:H(p) rear emitter contact of n-type silicon solar cells
journal, November 2012

Simple silicon solar cells featuring an a-Si:H enhanced rear MIS contact
journal, July 2015

Development of a-SiO _x :H solar cells with very high V _oc × FF product : Development of a-SiO
journal, December 2014

Passivating Contacts for Crystalline Silicon Solar Cells: From Concepts and Materials to Prospects
journal, March 2018

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journal, August 2017

Amorphous silicon passivated contacts for diffused junction silicon solar cells
journal, April 2014

Molybdenum oxide MoO _x : A versatile hole contact for silicon solar cells
journal, December 2014

Transition metal oxides as hole-selective contacts in silicon heterojunctions solar cells
journal, February 2016

Transition Metal Oxide Work Functions: The Influence of Cation Oxidation State and Oxygen Vacancies
journal, June 2012

Systematic Study of Oxygen Vacancy Tunable Transport Properties of Few‐Layer MoO ₃₋ _x Enabled by Vapor‐Based Synthesis
journal, March 2017

22.5% efficient silicon heterojunction solar cell with molybdenum oxide hole collector
journal, August 2015

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journal, November 2017

Quantitative use of electron energy-loss spectroscopy Mo-M2,3 edges for the study of molybdenum oxides
journal, February 2015

In situ x-ray photoelectron emission analysis of the thermal stability of atomic layer deposited WO _x as hole-selective contacts for Si solar cells
journal, May 2018

Origin of passivation in hole-selective transition metal oxides for crystalline silicon heterojunction solar cells
journal, December 2016

Advanced spectroscopic analyses on a:C-H materials: Revisiting the EELS characterization and its coupling with multi-wavelength Raman spectroscopy
journal, February 2017

Nanotubes from Oxide-Based Misfit Family: The Case of Calcium Cobalt Oxide
journal, May 2016

Investigation on Molybdenum and Its Conductive Oxides as p-type Metal Gate Candidates
journal, September 2007

MoO3 Films Spin-Coated from a Nanoparticle Suspension for Efficient Hole-Injection in Organic Electronics
journal, October 2010

Selectivity issues of MoOx based hole contacts
journal, September 2017

A new simulation software of solar cells—wxAMPS
journal, March 2012

Numerical Simulation of Silicon Heterojunction Solar Cells Featuring Metal Oxides as Carrier-Selective Contacts
journal, March 2018

Origin of the high work function and high conductivity of MoO ₃
journal, December 2014

Toward Annealing-Stable Molybdenum-Oxide-Based Hole-Selective Contacts For Silicon Photovoltaics
journal, February 2018