Defect Control in the Synthesis of 2 D MoS2 Nanosheets: Polysulfide Trapping in Composite Sulfur Cathodes for Li–S Batteries

Abraham, Alyson; Wang, Lei; Quilty, Calvin D.; Lutz, Diana M.; McCarthy, Alison H.; Tang, Christopher R.; Dunkin, Mikaela R.; Housel, Lisa M.; Takeuchi, Esther S.; Marschilok, Amy C.; Takeuchi, Kenneth J.

doi:10.1002/cssc.201903028

Title: Defect Control in the Synthesis of 2 D MoS₂ Nanosheets: Polysulfide Trapping in Composite Sulfur Cathodes for Li–S Batteries

Journal Article · 07 November 2019 · ChemSusChem

DOI: https://doi.org/10.1002/cssc.201903028 · OSTI ID:1583104

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^[3]; Takeuchi, Kenneth J. ^[1]

Stony Brook Univ., NY (United States)
Department of ChemistryStony Brook University Stony Brook NY 11794 USA
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

One of the inherent challenges with Li–S batteries is polysulfide dissolution, in which soluble polysulfide species can contribute to the active material loss from the cathode and undergo shuttling reactions inhibiting the ability to effectively charge the battery. Prior theoretical studies have proposed the possible benefit of defective 2 D MoS₂ materials as polysulfide trapping agents. Herein the synthesis and thorough characterization of hydrothermally prepared MoS₂ nanosheets that vary in layer number, morphology, lateral size, and defect content are reported. Here, the materials were incorporated into composite sulfur–based cathodes and studied in Li–S batteries with environmentally benign ether–based electrolytes. Through directed synthesis of the MoS₂ additive, the relationship between synthetically induced defects in 2 D MoS₂ materials and resultant electrochemistry was elucidated and described.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704; EE0008208; SC0012673

OSTI ID:: 1583104

Alternate ID(s):: OSTI ID: 1635150; OSTI ID: 1580124

Report Number(s):: BNL--213513-2020-JAAM

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Journal Issue: 6 Vol. 13; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

References (73)

The Scherrer Formula for X-Ray Particle Size Determination Patterson, A. L. Physical Review, Vol. 56, Issue 10 https://doi.org/10.1103/PhysRev.56.978	journal	November 1939
Fabrication of 3 D Mesoporous Black TiO ₂ /MoS ₂ /TiO ₂ Nanosheets for Visible-Light-Driven Photocatalysis Liu, Xuefeng; Xing, Zipeng; Zhang, Hang ChemSusChem, Vol. 9, Issue 10 https://doi.org/10.1002/cssc.201600170	journal	April 2016
Sulfur film sandwiched between few-layered MoS ₂ electrocatalysts and conductive reduced graphene oxide as a robust cathode for advanced lithium–sulfur batteries Wei, Yanju; Kong, Zhenkai; Pan, Yankai Journal of Materials Chemistry A, Vol. 6, Issue 14 https://doi.org/10.1039/C8TA00222C	journal	January 2018
Dual functional MoS2/graphene interlayer as an efficient polysulfide barrier for advanced lithium-sulfur batteries Guo, Pengqian; Liu, Dequan; Liu, Zhengjiao Electrochimica Acta, Vol. 256 https://doi.org/10.1016/j.electacta.2017.10.003	journal	December 2017
Three-Dimensional Graphene–Carbon Nanotube–Ni Hierarchical Architecture as a Polysulfide Trap for Lithium–Sulfur Batteries Gnana kumar, G.; Chung, Sheng-Heng; Raj kumar, T. ACS Applied Materials & Interfaces, Vol. 10, Issue 24 https://doi.org/10.1021/acsami.8b06054	journal	May 2018
Probing Titanium Disulfide-Sulfur Composite Materials for Li-S Batteries via In Situ X-ray Diffraction (XRD) Zhang, Qing; Bock, David C.; Takeuchi, Kenneth J. Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.1661704jes	journal	January 2017
Recent Progress on 2D Noble‐Transition‐Metal Dichalcogenides Pi, Lejing; Li, Liang; Liu, Kailang Advanced Functional Materials, Vol. 29, Issue 51 https://doi.org/10.1002/adfm.201904932	journal	October 2019
Cover Picture: Continuous‐Flow Suzuki‐Miyaura and Mizoroki‐Heck Reactions under Microwave Heating Conditions (Chem. Rec. 1/2019) Monguchi, Yasunari; Ichikawa, Tomohiro; Yamada, Tsuyoshi The Chemical Record, Vol. 19, Issue 1 https://doi.org/10.1002/tcr.201980101	journal	October 2018
Defect-Rich MoS ₂ Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution Xie, Junfeng; Zhang, Hao; Li, Shuang Advanced Materials, Vol. 25, Issue 40 https://doi.org/10.1002/adma.201302685	journal	August 2013
Steric Hindrance in Sulfur Vacancy of Monolayer MoS ₂ Boosts Electrochemical Reduction of Carbon Monoxide to Methane Chen, Zhi Wen; Gao, Wang; Zheng, Wei Tao ChemSusChem, Vol. 11, Issue 9 https://doi.org/10.1002/cssc.201702262	journal	April 2018
Multifunctional Heterostructures for Polysulfide Suppression in High-Performance Lithium-Sulfur Cathode Chen, Manfang; Xu, Wentao; Jamil, Sidra Small, Vol. 14, Issue 49 https://doi.org/10.1002/smll.201803134	journal	October 2018
Anisotropic mean-square displacements (MSD) in single-crystals of 2 H - and 3 R -MoS ₂ Schönfeld, B.; Huang, J. J.; Moss, S. C. Acta Crystallographica Section B Structural Science, Vol. 39, Issue 4 https://doi.org/10.1107/S0108768183002645	journal	August 1983
Lightweight Reduced Graphene Oxide@MoS ₂ Interlayer as Polysulfide Barrier for High-Performance Lithium–Sulfur Batteries Tan, Lei; Li, Xinhai; Wang, Zhixing ACS Applied Materials & Interfaces, Vol. 10, Issue 4 https://doi.org/10.1021/acsami.7b18645	journal	January 2018
High Electrochemical Selectivity of Edge versus Terrace Sites in Two-Dimensional Layered MoS ₂ Materials Wang, Haotian; Zhang, Qianfan; Yao, Hongbin Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl503730c	journal	November 2014
Unveiling the Structural Evolution of Ag _1.2 Mn ₈ O ₁₆ under Coulombically Controlled (De)Lithiation Huang, Jianping; Hu, Xiaobing; Brady, Alexander B. Chemistry of Materials, Vol. 30, Issue 2 https://doi.org/10.1021/acs.chemmater.7b03599	journal	January 2018
MoS ₂ -Carbon Nanotube Porous 3 D Network for Enhanced Oxygen Reduction Reaction Lee, Cheesung; Ozden, Sehmus; Tewari, Chandra S. ChemSusChem, Vol. 11, Issue 17 https://doi.org/10.1002/cssc.201800982	journal	July 2018
Thin-Layered Molybdenum Disulfide Nanoparticles as an Effective Polysulfide Mediator in Lithium–Sulfur Batteries Han, Pauline; Chung, Sheng-Heng; Manthiram, Arumugam ACS Applied Materials & Interfaces, Vol. 10, Issue 27 https://doi.org/10.1021/acsami.8b05397	journal	June 2018
MoS ₂ Quantum Dots-Modified Covalent Triazine-Based Frameworks for Enhanced Photocatalytic Hydrogen Evolution Jiang, Qianqian; Sun, Long; Bi, Jinhong ChemSusChem, Vol. 11, Issue 6 https://doi.org/10.1002/cssc.201702220	journal	February 2018
Surface functionalization of bulk MoS2 sheets for efficient liquid phase exfoliation in polar micromolecular solvents Yin, Xianglu; Li, Yuewei; Meng, Hong Applied Surface Science, Vol. 486 https://doi.org/10.1016/j.apsusc.2019.05.052	journal	August 2019
Fabrication of rechargeable lithium ion batteries using water-based inkjet printed cathodes Gu, Yuan; Wu, Aide; Sohn, Hiesang Journal of Manufacturing Processes, Vol. 20 https://doi.org/10.1016/j.jmapro.2015.08.003	journal	October 2015
Interaction of FeS ₂ and Sulfur in Li-S Battery System Sun, Ke; Cama, Christina A.; DeMayo, Rachel A. Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0041701jes	journal	September 2016
Metal-Organic-Compound-Modified MoS ₂ with Enhanced Solubility for High-Performance Perovskite Solar Cells Dai, Ruina; Wang, Yangyang; Wang, Jie ChemSusChem, Vol. 10, Issue 14 https://doi.org/10.1002/cssc.201700603	journal	June 2017
Lignin-assisted exfoliation of molybdenum disulfide in aqueous media and its application in lithium ion batteries Liu, Wanshuang; Zhao, Chenyang; Zhou, Rui Nanoscale, Vol. 7, Issue 21 https://doi.org/10.1039/C5NR01891A	journal	January 2015
Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer Su, Yu-Sheng; Manthiram, Arumugam Nature Communications, Vol. 3, Article No. 1166 https://doi.org/10.1038/ncomms2163	journal	January 2012
Interphases in Lithium–Sulfur Batteries: Toward Deployable Devices with Competitive Energy Density and Stability Zhao, Qing; Zheng, Jingxu; Archer, Lynden ACS Energy Letters, Vol. 3, Issue 9 https://doi.org/10.1021/acsenergylett.8b01001	journal	August 2018
Donor Polymer Can Assist Electron Transport in Bulk Heterojunction Blends with Small Energetic Offsets Yin, Hang; Ma, Lik‐Kuen; Wang, Yilin Advanced Materials, Vol. 31, Issue 44 https://doi.org/10.1002/adma.201903998	journal	September 2019
New Insight into the “Shuttle Mechanism” of Rechargeable Lithium‐Sulfur Batteries Liu, Jingdong; Chen, Hui; Chen, Wenda ChemElectroChem, Vol. 6, Issue 10 https://doi.org/10.1002/celc.201900420	journal	April 2019
Rational design of a multidimensional N-doped porous carbon/MoS ₂ /CNT nano-architecture hybrid for high performance lithium–sulfur batteries Ren, Juan; Zhou, Yibei; Xia, Li Journal of Materials Chemistry A, Vol. 6, Issue 28 https://doi.org/10.1039/C8TA04675A	journal	January 2018
Elemental Sulfur and Molybdenum Disulfide Composites for Li–S Batteries with Long Cycle Life and High-Rate Capability Dirlam, Philip T.; Park, Jungjin; Simmonds, Adam G. ACS Applied Materials & Interfaces, Vol. 8, Issue 21 https://doi.org/10.1021/acsami.6b03200	journal	May 2016
Rational design of exfoliated 1T MoS ₂ @CNT-based bifunctional separators for lithium sulfur batteries Jeong, Y. C.; Kim, J. H.; Kwon, S. H. Journal of Materials Chemistry A, Vol. 5, Issue 45 https://doi.org/10.1039/C7TA08153G	journal	January 2017
In situ crystallization kinetics of two-dimensional MoS ₂ Vilá, Rafael A.; Rao, Rahul; Muratore, Christopher 2D Materials, Vol. 5, Issue 1 https://doi.org/10.1088/2053-1583/aa9674	journal	November 2017
Defect-induced conductivity anisotropy in MoS 2 monolayers Ghorbani-Asl, Mahdi; Enyashin, Andrey N.; Kuc, Agnieszka Physical Review B, Vol. 88, Issue 24 https://doi.org/10.1103/PhysRevB.88.245440	journal	December 2013
A top-down approach to build Li2S@rGO cathode composites for high-loading lithium–sulfur batteries in carbonate-based electrolyte Zensich, Maximiliano; Jaumann, Tony; Morales, Gustavo M. Electrochimica Acta, Vol. 296 https://doi.org/10.1016/j.electacta.2018.10.184	journal	February 2019
Improving the Performance of Lithium–Sulfur Batteries by Conductive Polymer Coating Yang, Yuan; Yu, Guihua; Cha, Judy J. ACS Nano, Vol. 5, Issue 11, p. 9187-9193 https://doi.org/10.1021/nn203436j	journal	October 2011
MoS ₂ Quantum Dots@TiO ₂ Nanotube Arrays: An Extended-Spectrum-Driven Photocatalyst for Solar Hydrogen Evolution Wang, Qun; Huang, Jianying; Sun, Hongtao ChemSusChem, Vol. 11, Issue 10 https://doi.org/10.1002/cssc.201800379	journal	May 2018
Mesoscale Physicochemical Interactions in Lithium–Sulfur Batteries: Progress and Perspective Liu, Zhixiao; Mistry, Aashutosh; Mukherjee, Partha P. Journal of Electrochemical Energy Conversion and Storage, Vol. 15, Issue 1 https://doi.org/10.1115/1.4037785	journal	October 2017
Three-dimensional MoS2/rGO foams as efficient sulfur hosts for high-performance lithium-sulfur batteries You, Yu; Ye, Yangwei; Wei, Mengli Chemical Engineering Journal, Vol. 355 https://doi.org/10.1016/j.cej.2018.08.176	journal	January 2019
Rational Fabrication of Nitrogen and Sulfur Codoped Carbon Nanotubes/MoS ₂ for High‐Performance Lithium–Sulfur Batteries Xiang, Kaixiong; Wen, Xiaoyu; Hu, Jun ChemSusChem, Vol. 12, Issue 15 https://doi.org/10.1002/cssc.201900929	journal	June 2019
Electrocatalysis of polysulfide conversion by sulfur-deficient MoS ₂ nanoflakes for lithium–sulfur batteries Lin, Haibin; Yang, Liuqing; Jiang, Xi Energy & Environmental Science, Vol. 10, Issue 6 https://doi.org/10.1039/C7EE01047H	journal	January 2017
Discovery of Amorphous Iron Hydrides via Novel Quiescent Reaction in Aqueous Solution Taguchi, Kohei; Shinozaki, Kazuteru; Okumura, Hideyuki Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-63124-2	journal	April 2020
Visualization of lithium-ion transport and phase evolution within and between manganese oxide nanorods Xu, Feng; Wu, Lijun; Meng, Qingping Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15400	journal	May 2017
High performance lithium sulfur batteries with a cassava-derived carbon sheet as a polysulfides inhibitor Qin, Furong; Zhang, Kai; Fang, Jing New J. Chem., Vol. 38, Issue 9 https://doi.org/10.1039/C4NJ00701H	journal	January 2014
Gel based sulfur cathodes with a high sulfur content and large mass loading for high-performance lithium–sulfur batteries Li, Shiqi; Mou, Tong; Ren, Guofeng Journal of Materials Chemistry A, Vol. 5, Issue 4 https://doi.org/10.1039/C6TA09841J	journal	January 2017
Synthesis of Grain-like MoS ₂ for High-Performance Sodium-Ion Batteries Yao, Kai; Xu, Zhanwei; Li, Zhi ChemSusChem, Vol. 11, Issue 13 https://doi.org/10.1002/cssc.201800512	journal	June 2018
Toward Environmentally Friendly Lithium Sulfur Batteries: Probing the Role of Electrode Design in MoS ₂ -Containing Li–S Batteries with a Green Electrolyte Wang, Lei; Abraham, Alyson; Lutz, Diana M. ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 5 https://doi.org/10.1021/acssuschemeng.8b06141	journal	February 2019
Metal Sulfide-Blended Sulfur Cathodes in High Energy Lithium-Sulfur Cells Bugga, Ratnakumar V.; Jones, Simon C.; Pasalic, Jasmina Journal of The Electrochemical Society, Vol. 164, Issue 2 https://doi.org/10.1149/2.0941702jes	journal	December 2016
Anomalous Lattice Vibrations of Single- and Few-Layer MoS ₂ Lee, Changgu; Yan, Hugen; Brus, Louis E. ACS Nano, Vol. 4, Issue 5 https://doi.org/10.1021/nn1003937	journal	March 2010
Self-Stacked, Small-Sized MoS ₂ Nanosheets for High-Performance Lithium-Ion Batteries Liu, Hong; Yi, Min; Liu, Lei Energy Technology, Vol. 5, Issue 11 https://doi.org/10.1002/ente.201700152	journal	August 2017
The Composition of the Continental Crust Wedepohl, K. H. Mineralogical Magazine, Vol. 58A, Issue 2 https://doi.org/10.1180/minmag.1994.58a.2.234	journal	January 1994
Interaction of TiS ₂ and Sulfur in Li-S Battery System Sun, Ke; Zhang, Qing; Bock, David C. Journal of The Electrochemical Society, Vol. 164, Issue 6 https://doi.org/10.1149/2.1631706jes	journal	January 2017
Fabrication of defect-rich MoS ₂ ultrathin nanosheets for application in lithium-ion batteries and supercapacitors Wu, Zhengcui; Li, Baoer; Xue, Yejing Journal of Materials Chemistry A, Vol. 3, Issue 38 https://doi.org/10.1039/C5TA04549E	journal	January 2015
Awakening Solar Hydrogen Evolution of MoS ₂ in Alkalescent Electrolyte through Doping with Co Jia, Yulong; Wang, Zhonghao; Wang, Luyang ChemSusChem, Vol. 12, Issue 14 https://doi.org/10.1002/cssc.201900936	journal	June 2019
2D MoS2 as an efficient protective layer for lithium metal anodes in high-performance Li–S batteries Cha, Eunho; Patel, Mumukshu D.; Park, Juhong Nature Nanotechnology, Vol. 13, Issue 4 https://doi.org/10.1038/s41565-018-0061-y	journal	February 2018
Defect engineering of two-dimensional transition metal dichalcogenides Lin, Zhong; Carvalho, Bruno R.; Kahn, Ethan 2D Materials, Vol. 3, Issue 2 https://doi.org/10.1088/2053-1583/3/2/022002	journal	April 2016
Hybrid Lithium-Sulfur Batteries with an Advanced Gel Cathode and Stabilized Lithium-Metal Anode Xu, Henghui; Wang, Shaofei; Manthiram, Arumugam Advanced Energy Materials, Vol. 8, Issue 23 https://doi.org/10.1002/aenm.201800813	journal	May 2018
Anomalous Lattice Vibrations of Single and Few-Layer MoS2 Lee, Changgu; Yan, Hugen; Brus, Louis E. arXiv https://doi.org/10.48550/arxiv.1005.2509	text	January 2010
Rechargeable Batteries: Grasping for the Limits of Chemistry Berg, Erik J.; Villevieille, Claire; Streich, Daniel Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0081514jes	journal	January 2015
2D Electrocatalysts for Converting Earth‐Abundant Simple Molecules into Value‐Added Commodity Chemicals: Recent Progress and Perspectives Yin, Huajie; Dou, Yuhai; Chen, Shan Advanced Materials https://doi.org/10.1002/adma.201904870	journal	October 2019
Unveiling Electrochemical Reaction Pathways of CO ₂ Reduction to C _N Species at S‐Vacancies of MoS ₂ Kang, Sungwoo; Han, Seungwu; Kang, Youngho ChemSusChem, Vol. 12, Issue 12 https://doi.org/10.1002/cssc.201900779	journal	May 2019
Experimental and Theoretical Analysis of Products and Reaction Intermediates of Lithium–Sulfur Batteries Cañas, Natalia A.; Fronczek, David N.; Wagner, Norbert The Journal of Physical Chemistry C, Vol. 118, Issue 23 https://doi.org/10.1021/jp5013208	journal	May 2014
The Origin of High Activity of Amorphous MoS ₂ in the Hydrogen Evolution Reaction Wu, Longfei; Longo, Alessandro; Dzade, Nelson Y. ChemSusChem, Vol. 12, Issue 19 https://doi.org/10.1002/cssc.201901811	journal	August 2019
Gram-Scale Aqueous Synthesis of Stable Few-Layered 1T-MoS ₂ : Applications for Visible-Light-Driven Photocatalytic Hydrogen Evolution Liu, Qin; Li, Xiuling; He, Qun Small, Vol. 11, Issue 41 https://doi.org/10.1002/smll.201501822	journal	August 2015
Long-Chain Polysulfide Retention at the Cathode of Li–S Batteries Kamphaus, Ethan P.; Balbuena, Perla B. The Journal of Physical Chemistry C, Vol. 120, Issue 8 https://doi.org/10.1021/acs.jpcc.5b12538	journal	February 2016
Catalytic oxidation of Li ₂ S on the surface of metal sulfides for Li−S batteries Zhou, Guangmin; Tian, Hongzhen; Jin, Yang Proceedings of the National Academy of Sciences, Vol. 114, Issue 5 https://doi.org/10.1073/pnas.1615837114	journal	January 2017
High conductivity graphene-like MoS2/polyaniline nanocomposites and its application in supercapacitor Wang, Jin; Wu, Zongchao; Hu, Kunhong Journal of Alloys and Compounds, Vol. 619 https://doi.org/10.1016/j.jallcom.2014.09.008	journal	January 2015
Interaction of CuS and Sulfur in Li-S Battery System Sun, Ke; Su, Dong; Zhang, Qing Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.1021514jes	journal	January 2015
A Lithium-Ion Battery using a 3 D-Array Nanostructured Graphene-Sulfur Cathode and a Silicon Oxide-Based Anode Benítez, Almudena; Di Lecce, Daniele; Elia, Giuseppe Antonio ChemSusChem, Vol. 11, Issue 9 https://doi.org/10.1002/cssc.201800242	journal	April 2018
The composition of the continental crust Hans Wedepohl, K. Geochimica et Cosmochimica Acta, Vol. 59, Issue 7 https://doi.org/10.1016/0016-7037(95)00038-2	journal	April 1995
Thermoelectric performance of restacked MoS ₂ nanosheets thin-film Wang, Tongzhou; Liu, Congcong; Xu, Jingkun Nanotechnology, Vol. 27, Issue 28 https://doi.org/10.1088/0957-4484/27/28/285703	journal	June 2016
Harnessing the unique properties of 2D materials for advanced lithium–sulfur batteries Li, Bin; Xu, Hongfei; Ma, Yang Nanoscale Horizons, Vol. 4, Issue 1 https://doi.org/10.1039/C8NH00170G	journal	January 2019
MoS ₂ /MoO _x -Nanostructure-Decorated Activated Carbon Cloth for Enhanced Supercapacitor Performance Sari, Fitri Nur Indah; Ting, Jyh-Ming ChemSusChem, Vol. 11, Issue 5 https://doi.org/10.1002/cssc.201702295	journal	February 2018
From Bulk to Monolayer MoS2: Evolution of Raman Scattering Li, Hong; Zhang, Qing; Yap, Chin Chong Ray Advanced Functional Materials, Vol. 22, Issue 7 https://doi.org/10.1002/adfm.201102111	journal	January 2012
Mesoscale Elucidation of Self-Discharge-Induced Performance Decay in Lithium–Sulfur Batteries Hao, Feng; Liu, Zhixiao; Balbuena, Perla B. ACS Applied Materials & Interfaces, Vol. 11, Issue 14 https://doi.org/10.1021/acsami.9b02282	journal	March 2019

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25 ENERGY STORAGE
defect control
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molybdenum sulfide
sulfur cathode

Title: Defect Control in the Synthesis of 2 D MoS2 Nanosheets: Polysulfide Trapping in Composite Sulfur Cathodes for Li–S Batteries

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Title: Defect Control in the Synthesis of 2 D MoS₂ Nanosheets: Polysulfide Trapping in Composite Sulfur Cathodes for Li–S Batteries