Characterization of catalytic fast pyrolysis oils: The importance of solvent selection for analytical method development

Harman-Ware, Anne E.; Ferrell, III, Jack R.

doi:10.1016/j.jaap.2018.02.021

Title: Characterization of catalytic fast pyrolysis oils: The importance of solvent selection for analytical method development

Full Record
Other Related Research

Authors:: Harman-Ware, Anne E.; Ferrell, III, Jack R.

Publication Date:: 2018-06-01

Sponsoring Org.:: USDOE

OSTI Identifier:: 1582944

Grant/Contract Number:: AC36-08GO28308

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Analytical and Applied Pyrolysis

Additional Journal Information:: Journal Name: Journal of Analytical and Applied Pyrolysis Journal Volume: 132 Journal Issue: C; Journal ID: ISSN 0165-2370

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Harman-Ware, Anne E., and Ferrell, III, Jack R. Characterization of catalytic fast pyrolysis oils: The importance of solvent selection for analytical method development.  Netherlands: N. p., 2018. 
Web.  https://doi.org/10.1016/j.jaap.2018.02.021.

Copy to clipboard


                    Harman-Ware, Anne E., & Ferrell, III, Jack R. Characterization of catalytic fast pyrolysis oils: The importance of solvent selection for analytical method development.  Netherlands.  https://doi.org/10.1016/j.jaap.2018.02.021

Copy to clipboard


                    Harman-Ware, Anne E., and Ferrell, III, Jack R. Fri .  
"Characterization of catalytic fast pyrolysis oils: The importance of solvent selection for analytical method development".  Netherlands.  https://doi.org/10.1016/j.jaap.2018.02.021.

Copy to clipboard


                    
@article{osti_1582944,

  title        = {Characterization of catalytic fast pyrolysis oils: The importance of solvent selection for analytical method development},

  author       = {Harman-Ware, Anne E. and Ferrell, III, Jack R.},

  abstractNote = {},

  doi          = {10.1016/j.jaap.2018.02.021},

  journal      = {Journal of Analytical and Applied Pyrolysis},

  number       = C,

  volume       = 132,

  place        = {Netherlands},

  year         = {2018},

  month        = {6}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.jaap.2018.02.021

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Characterization of Catalytic Fast Pyrolysis Oils: The Importance of Solvent Selection for Analytical Method Development

Journal Article Ferrell, Jack R ; Ware, Anne E - Journal of Analytical and Applied Pyrolysis

Two catalytic fast pyrolysis (CFP) oils (bottom/heavy fraction) were analyzed in various solvents that are used in common analytical methods (nuclear magnetic resonance - NMR, gas chromatography - GC, gel permeation chromatography - GPC, thermogravimetric analysis - TGA) for oil characterization and speciation. A more accurate analysis of the CFP oils can be obtained by identification and exploitation of solvent miscibility characteristics. Acetone and tetrahydrofuran can be used to completely solubilize CFP oils for analysis by GC and tetrahydrofuran can be used for traditional organic GPC analysis of the oils. DMSO-d6 can be used to solubilize CFP oils for analysismore »« less
https://doi.org/10.1016/j.jaap.2018.02.021
Molecular Weight Distribution of Raw and Catalytic Fast Pyrolysis Oils: Comparison of Analytical Methodologies

Journal Article Ware, Anne E ; Orton, Kellene A ; Deng, Chris ; ... - RSC Advances

Comprehensive analysis of the molecular weight distribution of raw and catalytic fast pyrolysis oils derived from biomass remains a key technical hurdle to understanding oil quality as it relates to downstream use and multiple methods may be necessary to accurately represent all components present. Here, we report the molecular weight distribution metrics of fast pyrolysis (FP) and catalytic fast pyrolysis (CFP) oils as determined by gel permeation chromatography (GPC) combined with UV-diode array (UV), differential refractive index (RI), and multi-angle laser light scattering (MALS) detection. The measured molar mass distributions revealed that FP oil consisted of a higher proportion ofmore »« less
https://doi.org/10.1039/C9RA09726K
Characterization of upgraded fast pyrolysis oak oil distillate fractions from sulfided and non-sulfided catalytic hydrotreating

Journal Article Olarte, Mariefel V. ; Padmaperuma, Asanga B. ; Ferrell, III, Jack R. ; ... - Fuel

We consider catalytic hydroprocessing of pyrolysis oils from biomass which produces hydrocarbons for liquid fuel production. This process requires removal of oxygen and cracking of the heavier molecular weight bio-oil constituents into smaller fragments at high temperatures and pressures under hydrogen. Here, we present in this paper the characterization of a group of five distillate fractions from each of two types of hydroprocessed oils from oak pyrolysis oil: a low oxygen content (LOC, 1.8% O, wet basis) oil and a medium oxygen content (MOC, 6.4% O, wet basis) oil. The LOC oil was generated using a sulfided hydrotreating system consistingmore »« less
Cited by 14
https://doi.org/10.1016/j.fuel.2017.03.051

Full Text Available
Recent Advances in Heterogeneous Catalysts for Bio-Oil Upgrading via 'Ex-situ Catalytic Fast Pyrolysis': Catalyst Development through the Study of Model Compounds

Journal Article Ruddy, D. A. ; Schaidle, J. A. ; Ferrell, J. R. ; ... - Green Chemistry
https://doi.org/10.1039/C3GC41354C
Aqueous stream characterization from biomass fast pyrolysis and catalytic fast pyrolysis

Journal Article Black, Brenna A. ; Michener, William E. ; Ramirez, Kelsey J. ; ... - ACS Sustainable Chemistry & Engineering

Here, biomass pyrolysis offers a promising means to rapidly depolymerize lignocellulosic biomass for subsequent catalytic upgrading to renewable fuels. Substantial efforts are currently ongoing to optimize pyrolysis processes including various fast pyrolysis and catalytic fast pyrolysis schemes. In all cases, complex aqueous streams are generated containing solubilized organic compounds that are not converted to target fuels or chemicals and are often slated for wastewater treatment, in turn creating an economic burden on the biorefinery. Valorization of the species in these aqueous streams, however, offers significant potential for substantially improving the economics and sustainability of thermochemical biorefineries. To that end, heremore »« less
Cited by 7
https://doi.org/10.1021/acssuschemeng.6b01766

Full Text Available

Similar Records