The role of water in extraction and separation of rare earth elements in supercritical carbon dioxide

Sinclair, L. K.; Tester, J. W.; Thompson, J. F. H.; Fox, R. V.

doi:10.1016/j.supflu.2018.02.009

Title: The role of water in extraction and separation of rare earth elements in supercritical carbon dioxide

Journal Article · 01 June 2018 · Journal of Supercritical Fluids

DOI: https://doi.org/10.1016/j.supflu.2018.02.009 · OSTI ID:1582715

Sinclair, L. K.; Tester, J. W.; Thompson, J. F. H.; Fox, R. V.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1582715

Journal Information:: Journal of Supercritical Fluids, Journal Name: Journal of Supercritical Fluids Vol. 136 Journal Issue: C; ISSN 0896-8446

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (35)

Rare Earth Elements: Overview of Mining, Mineralogy, Uses, Sustainability and Environmental Impact Haque, Nawshad; Hughes, Anthony; Lim, Seng Resources, Vol. 3, Issue 4 https://doi.org/10.3390/resources3040614	journal	October 2014
Spectrophotometric studies on solubility of lanthanoid(III) complexes with fluorinated β-diketonates in supercritical carbon dioxide Hwang, DongKi; Tsukahara, Takehiko; Miyamoto, Naomi The Journal of Supercritical Fluids, Vol. 110 https://doi.org/10.1016/j.supflu.2015.12.002	journal	April 2016
Molecular dynamics simulations on europium nitrate complexes with neutral organophosphorus ligands. What governs the stoichiometry and extractability of the complex? Beudaert, Philippe; Lamare, Véronique; Dozol, Jean-François Journal of the Chemical Society, Perkin Transactions 2, Issue 11 https://doi.org/10.1039/a905063i	journal	January 1999
Understanding the nitrate coordination to Eu3+ ions in solution by potential of mean force calculations Duvail, Magali; Guilbaud, Philippe Physical Chemistry Chemical Physics, Vol. 13, Issue 13 https://doi.org/10.1039/c0cp02535f	journal	January 2011
Supercritical Fluid Extraction of Lanthanides with Fluorinated .beta.-Diketones and Tributyl Phosphate Lin, Yuehe.; Wai, C. M. Analytical Chemistry, Vol. 66, Issue 13 https://doi.org/10.1021/ac00085a008	journal	July 1994
Experimental determination and model correlation for the solubilities of trialkyl phosphates in supercritical carbon dioxide Pitchaiah, K. C.; Sivaraman, N.; Lamba, Neha RSC Advances, Vol. 6, Issue 56 https://doi.org/10.1039/C6RA10897K	journal	January 2016
Complexation of Eu(III) with Dibutyl Phosphate and Tributyl Phosphate Zhang, Ping; Kimura, Takaumi Solvent Extraction and Ion Exchange, Vol. 24, Issue 2 https://doi.org/10.1080/07366290500464276	journal	May 2006
Aqueous Binary Lanthanide(III) Nitrate Ln(NO ₃ ) ₃ Electrolytes Revisited: Extended Pitzer and Bromley Treatments Chatterjee, Sayandev; Campbell, Emily L.; Neiner, Doinita Journal of Chemical & Engineering Data, Vol. 60, Issue 10 https://doi.org/10.1021/acs.jced.5b00392	journal	September 2015
Extraction of water by tri-n-butyl phosphate Hardy, C. J.; Fairhurst, D.; McKay, H. A. C. Transactions of the Faraday Society, Vol. 60 https://doi.org/10.1039/tf9646001626	journal	January 1964
Solubility of metal chelates and their extraction from an aqueous environment via supercritical CO2 Ashraf-Khorassani, Mehdi; Combs, Michael T.; Taylor, Larry T. Talanta, Vol. 44, Issue 5 https://doi.org/10.1016/S0039-9140(96)02075-9	journal	May 1997
Solubility of organometallic complexes in supercritical carbon dioxide: A review Teoh, Wen Hui; Mammucari, Raffaella; Foster, Neil R. Journal of Organometallic Chemistry, Vol. 724 https://doi.org/10.1016/j.jorganchem.2012.10.005	journal	January 2013
Solvent Extraction of Lanthanides from Their Oxides with TBP in Supercritical Carbon Dioxide Tomioka, Osamu; Enokida, Youichi; Yamamoto, Ichiro Journal of Nuclear Science and Technology, Vol. 35, Issue 7 https://doi.org/10.1080/18811248.1998.9733901	journal	July 1998
Interactions in Aqueous 3–1 Rare Earth Electrolyte Quaternary Systems and Their Ternary Subsystems to Very High Concentrations He, Mei; Dong, Ling; Li, Biao Journal of Chemical & Engineering Data, Vol. 56, Issue 11 https://doi.org/10.1021/je200497g	journal	October 2011
Near-infrared spectroscopic investigation of water in supercritical CO2 and the effect of CaCl2 Wang, Zheming; Felmy, Andrew R.; Thompson, Christopher J. Fluid Phase Equilibria, Vol. 338 https://doi.org/10.1016/j.fluid.2012.11.012	journal	January 2013
On the hydration of the inner sphere of lanthanide complexes in the TBP solvent extraction system Navon, Samuel; Stavola, Michael; Sceats, Mark G. Journal of Inorganic and Nuclear Chemistry, Vol. 43, Issue 3 https://doi.org/10.1016/0022-1902(81)80505-2	journal	January 1981
A critical review on solvent extraction of rare earths from aqueous solutions Xie, Feng; Zhang, Ting An; Dreisinger, David Minerals Engineering, Vol. 56 https://doi.org/10.1016/j.mineng.2013.10.021	journal	February 2014
Correlation between Extraction Equilibrium of Uranium(VI) and Density of CO ₂ Medium in a HNO ₃ /Supercritical CO ₂ −Tributyl Phosphate System Meguro, Yoshihiro; Iso, Shuichi; Yoshida, Zenko Analytical Chemistry, Vol. 70, Issue 7 https://doi.org/10.1021/ac970818b	journal	April 1998
Extraction of lanthanides from acidic solution using tributyl phosphate modified supercritical carbon dioxide Laintz, K. E.; Tachikawa, E. Analytical Chemistry, Vol. 66, Issue 13 https://doi.org/10.1021/ac00085a040	journal	July 1994
Competition between lanthanides in extraction with tri-n-butyl phosphate in supercritical CO₂ from solid nitrates Zhu, L. Y.; Wang, Z. F.; He, H. RSC Advances, Vol. 6, Issue 99 https://doi.org/10.1039/C6RA20687E	journal	January 2016
Kinetics of Reactive Extraction of Nd from Nd2O3 with TBP-HNO3 Complex in Supercritical Carbon Dioxide Zhu, Liyang; Duan, Wuhua; Xu, Jingming Chinese Journal of Chemical Engineering, Vol. 17, Issue 2 https://doi.org/10.1016/S1004-9541(08)60196-2	journal	April 2009
Luminescence Study on the Inner‐Sphere Hydration Number of Lanthanide(III) Ions in Neutral Organo‐Phosphorus Complexes Zhang, Ping; Kimura, Takaumi; Yoshida, Zenko Solvent Extraction and Ion Exchange, Vol. 22, Issue 6 https://doi.org/10.1081/SEI-200037439	journal	December 2004
Praseodymium nitrate and neodymium nitrate complexation with organophosphorus reagents in supercritical carbon dioxide solvent Fox, Robert V.; Ball, R. Duane; Harrington, Peter de B. The Journal of Supercritical Fluids, Vol. 31, Issue 3 https://doi.org/10.1016/j.supflu.2003.11.006	journal	November 2004
Solubilities of Cerium(IV), Terbium(III), and Iron(III) β-Diketonates in Supercritical Carbon Dioxide Andersen, Wendy C.; Sievers, Robert E.; Lagalante, Anthony F. Journal of Chemical & Engineering Data, Vol. 46, Issue 5 https://doi.org/10.1021/je000257c	journal	March 2001
Isopiestic determination of the activity coefficients of some aqueous rare earth electrolyte solutions at 25.degree. C. 4. Lanthanumnitrate, praseodymium nitrate, and neodymium nitrate Rard, Joseph A.; Miller, Donald G.; Spedding, Frank H. Journal of Chemical & Engineering Data, Vol. 24, Issue 4 https://doi.org/10.1021/je60083a028	journal	October 1979
Recovery of rare earth elements, uranium, and thorium from monazite concentrate by supercritical fluid extraction Samsonov, M. D.; Trofimov, T. I.; Kulyako, Yu. M. Radiochemistry, Vol. 57, Issue 4 https://doi.org/10.1134/S1066362215040025	journal	July 2015
Extraction of lanthanide ions from aqueous solution by modified supercritical CO2: tri-n-butylphosphate+CO2 and bis-2-ethylhexyl phosphoric acid+CO2 Joung, Seung Nam; Yoon, Sang Jun; Kim, Sun Young The Journal of Supercritical Fluids, Vol. 18, Issue 2 https://doi.org/10.1016/S0896-8446(00)00063-2	journal	September 2000
Studies on solubility of uranyl complexes in supercritical carbon dioxide and its controlling factors using UV-visible and¹⁷O- and¹⁹F-NMR spectroscopy Miyamoto, Naomi; Tsukahara, Takehiko; Kachi, Yoshihiro Journal of Nuclear Science and Technology, Vol. 49, Issue 1 https://doi.org/10.1080/18811248.2011.636531	journal	January 2012
Isopiestic determination of the activity coefficients of some aqueous rare-earth electrolyte solutions at 25.degree.C. 5. Dysprosium trinitrate, holmium trinitrate, and lutetium trinitrate Rard, Joseph A.; Spedding, Frank K. Journal of Chemical & Engineering Data, Vol. 26, Issue 4 https://doi.org/10.1021/je00026a013	journal	October 1981
Extraction and separation of lanthanides using dense gas CO2 modified with tributyl phosphate and di(2-ethyl hexyl)phosphoric acid Dehghani, F.; Wells, T.; Cotton, N. J. The Journal of Supercritical Fluids, Vol. 9, Issue 4 https://doi.org/10.1016/S0896-8446(96)90057-1	journal	December 1996
Modeling of Aqueous 3–1 Rare Earth Electrolytes and Their Mixtures to Very High Concentrations Wang, Zhi-Chang; He, Mei; Wang, Jun Journal of Solution Chemistry, Vol. 35, Issue 8 https://doi.org/10.1007/s10953-006-9050-0	journal	July 2006
Structural study of complexes formed by acidic and neutral organophosphorus reagents Braatz, Alexander D.; Antonio, Mark R.; Nilsson, Mikael Dalton Transactions, Vol. 46, Issue 4 https://doi.org/10.1039/C6DT04305D	journal	January 2017
Competitive complexation of solid lanthanide nitrates with tri-n-butyl phosphate in n-hexane Wang, Zhuangfei; Liu, Tingting; He, Xihong Journal of Radioanalytical and Nuclear Chemistry, Vol. 311, Issue 1 https://doi.org/10.1007/s10967-016-5027-7	journal	September 2016
High-pressure (vapor+liquid) equilibrium in binary mixtures of (carbon dioxide+water or acetic acid) at temperatures from 313 to 353 K Bamberger, A.; Sieder, G.; Maurer, G. The Journal of Supercritical Fluids, Vol. 17, Issue 2 https://doi.org/10.1016/S0896-8446(99)00054-6	journal	April 2000
Thermodynamics of Electrolytes. 13. Ionic Strength Dependence of Higher-Order Terms; Equations for CaCl2 and MgCl2 Pitzer, Kenneth S.; Wang, Peiming; Rard, Joseph A. Journal of Solution Chemistry, Vol. 28, Issue 4 https://doi.org/10.1023/A:1022695525943	journal	April 1999
Holmium nitrate complexation with tri-n-butyl phosphate in supercritical carbon dioxide Fox, Robert V.; Ball, R. Duane; Harrington, Peter de B. The Journal of Supercritical Fluids, Vol. 36, Issue 2 https://doi.org/10.1016/j.supflu.2005.05.003	journal	December 2005

Similar Records

Rare earth element extraction from pretreated bastnäsite in supercritical carbon dioxide

Journal Article · 2017 · Journal of Supercritical Fluids · OSTI ID:1470332

Sinclair, L. K.; Baek, Donna L.; Thompson, J.; +2 more

Extraction of rare earth oxides using supercritical carbon dioxide modified with Tri-n-butyl phosphate–nitric acid adducts

Journal Article · 2016 · Industrial and Engineering Chemistry Research · OSTI ID:1259494

Baek, Donna L.; Fox, Robert V.; Case, Mary E.; +5 more

Extraction of Rare Earth Elements from Chloride Media with Tetrabutyl Diglycolamide in 1-Octanol Modified Carbon Dioxide

Journal Article · 2019 · Metals · OSTI ID:1514897

Case, Mary; Fox, Robert; Baek, Donna; +1 more

Title: The role of water in extraction and separation of rare earth elements in supercritical carbon dioxide

Citation Formats

References (35)

Similar Records

Related Subjects