skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Interaction of Np( v ) with borate in alkaline, dilute-to-concentrated, NaCl and MgCl 2 solutions

Abstract

The formation of sparingly soluble ternary Na/Mg–Np( v )–borate(s) solid phases in alkaline, dilute-to-concentrated, NaCl and MgCl 2 solutions is confirmed by a multimethod experimental approach.

Authors:
 [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1]; ORCiD logo [1];  [1];  [2];  [3]; ORCiD logo [2];  [1];  [1]
  1. Institute for Nuclear Waste Disposal, Karlsruhe Institute of Technology, Germany
  2. Department of Chemistry and Biochemistry, Florida State University, USA
  3. Los Alamos National Laboratory, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1582687
Grant/Contract Number:  
SC0016568
Resource Type:
Published Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Hinz, K., Fellhauer, D., Gaona, X., Vespa, M., Dardenne, K., Schild, D., Yokosawa, T., Silver, M. A., Reed, D. T., Albrecht-Schmitt, T. E., Altmaier, M., and Geckeis, H. Interaction of Np( v ) with borate in alkaline, dilute-to-concentrated, NaCl and MgCl 2 solutions. United Kingdom: N. p., 2020. Web. doi:10.1039/C9DT04430B.
Hinz, K., Fellhauer, D., Gaona, X., Vespa, M., Dardenne, K., Schild, D., Yokosawa, T., Silver, M. A., Reed, D. T., Albrecht-Schmitt, T. E., Altmaier, M., & Geckeis, H. Interaction of Np( v ) with borate in alkaline, dilute-to-concentrated, NaCl and MgCl 2 solutions. United Kingdom. doi:10.1039/C9DT04430B.
Hinz, K., Fellhauer, D., Gaona, X., Vespa, M., Dardenne, K., Schild, D., Yokosawa, T., Silver, M. A., Reed, D. T., Albrecht-Schmitt, T. E., Altmaier, M., and Geckeis, H. Wed . "Interaction of Np( v ) with borate in alkaline, dilute-to-concentrated, NaCl and MgCl 2 solutions". United Kingdom. doi:10.1039/C9DT04430B.
@article{osti_1582687,
title = {Interaction of Np( v ) with borate in alkaline, dilute-to-concentrated, NaCl and MgCl 2 solutions},
author = {Hinz, K. and Fellhauer, D. and Gaona, X. and Vespa, M. and Dardenne, K. and Schild, D. and Yokosawa, T. and Silver, M. A. and Reed, D. T. and Albrecht-Schmitt, T. E. and Altmaier, M. and Geckeis, H.},
abstractNote = {The formation of sparingly soluble ternary Na/Mg–Np( v )–borate(s) solid phases in alkaline, dilute-to-concentrated, NaCl and MgCl 2 solutions is confirmed by a multimethod experimental approach.},
doi = {10.1039/C9DT04430B},
journal = {Dalton Transactions},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9DT04430B

Save / Share:

Works referenced in this record:

Crystal Chemistry of the Potassium and Rubidium Uranyl Borate Families Derived from Boric Acid Fluxes
journal, July 2010

  • Wang, Shuao; Alekseev, Evgeny V.; Stritzinger, Jared T.
  • Inorganic Chemistry, Vol. 49, Issue 14
  • DOI: 10.1021/ic100728s

Solid-liquid equilibria of Mg(OH)2(cr) and Mg2(OH)3Cl·4H2O(cr) in the system Mg-Na-H-OH-Cl-H2O at 25°C
journal, October 2003


The prediction of borate mineral equilibria in natural waters: Application to Searles Lake, California
journal, December 1986


Interaction of Nd( iii ) and Cm( iii ) with borate in dilute to concentrated alkaline NaCl, MgCl 2 and CaCl 2 solutions: solubility and TRLFS studies
journal, January 2015

  • Hinz, Katja; Altmaier, Marcus; Gaona, Xavier
  • New Journal of Chemistry, Vol. 39, Issue 2
  • DOI: 10.1039/C4NJ01203H

Structure du borate d`uranium UB2O6
journal, November 1987

  • Gasperin, M.
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 11
  • DOI: 10.1107/S0108270187089121

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005


Retention of uranium in cement systems: effects of cement degradation and complexing ligands
journal, January 2018

  • Ochs, Michael; Vriens, Bas; Tachi, Yukio
  • Progress in Nuclear Science and Technology, Vol. 5, Issue 0
  • DOI: 10.15669/pnst.5.208

Solubility and hydrolysis of Np(V) in dilute to concentrated alkaline NaCl solutions: formation of Na–Np(V)–OH solid phases at 22 °C
journal, January 2017

  • Petrov, Vladimir G.; Fellhauer, David; Gaona, Xavier
  • Radiochimica Acta, Vol. 105, Issue 1
  • DOI: 10.1515/ract-2016-2614

Cation–Cation Interactions between Neptunyl(VI) Units
journal, June 2012

  • Wang, Shuao; Diwu, Juan; Alekseev, Evgeny V.
  • Inorganic Chemistry, Vol. 51, Issue 13
  • DOI: 10.1021/ic3009305

Parallel calculation of electron multiple scattering using Lanczos algorithms
journal, February 2002


Complexation of Nd(III) with tetraborate ion and its effect on actinide(III) solubility in WIPP brine
journal, January 2010

  • Borkowski, Marian; Richmann, Michael; Reed, Donald T.
  • Radiochimica Acta, Vol. 98, Issue 9-11
  • DOI: 10.1524/ract.2010.1756

Boron isotope geochemistry of metasedimentary rocks and tourmalines in a subduction zone metamorphic suite
journal, December 2001


Surprising Coordination for Plutonium in the First Plutonium(III) Borate
journal, March 2011

  • Wang, Shuao; Alekseev, Evgeny V.; Depmeier, Wulf
  • Inorganic Chemistry, Vol. 50, Issue 6
  • DOI: 10.1021/ic200064n

Synthèse et structure du borouranate de lithium LiBUO5
journal, March 1990

  • Gasperin, M.
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 46, Issue 3
  • DOI: 10.1107/S0108270189007948

Recent Advances in Aqueous Actinide Chemistry and Thermodynamics
journal, October 2012

  • Altmaier, Marcus; Gaona, Xavier; Fanghänel, Thomas
  • Chemical Reviews, Vol. 113, Issue 2
  • DOI: 10.1021/cr300379w

Formation of a Eu( iii ) borate solid species from a weak Eu( iii ) borate complex in aqueous solution
journal, January 2014

  • Schott, Juliane; Kretzschmar, Jerome; Acker, Margret
  • Dalton Trans., Vol. 43, Issue 30
  • DOI: 10.1039/C4DT00843J

Recent progress in actinide borate chemistry
journal, January 2011

  • Wang, Shuao; Alekseev, Evgeny V.; Depmeier, Wulf
  • Chemical Communications, Vol. 47, Issue 39
  • DOI: 10.1039/c1cc14023j

Boronic Acid Flux Synthesis and Crystal Growth of Uranium and Neptunium Boronates and Borates: A Low-Temperature Route to the First Neptunium(V) Borate
journal, November 2010

  • Wang, Shuao; Alekseev, Evgeny V.; Miller, Hannah M.
  • Inorganic Chemistry, Vol. 49, Issue 21
  • DOI: 10.1021/ic101678d

Equilibrium Studies of Polyanions. II. Polyborates in NaClO4 Medium.
journal, January 1957


New Neptunium(V) Borates That Exhibit the Alexandrite Effect
journal, December 2011

  • Wang, Shuao; Alekseev, Evgeny V.; Depmeier, Wulf
  • Inorganic Chemistry, Vol. 51, Issue 1
  • DOI: 10.1021/ic201682s

Formation of a ternary neptunyl(V) biscarbonato inner-sphere sorption complex inhibits calcite growth rate
journal, June 2011

  • Heberling, Frank; Scheinost, Andreas C.; Bosbach, Dirk
  • Journal of Contaminant Hydrology, Vol. 124, Issue 1-4
  • DOI: 10.1016/j.jconhyd.2011.02.002

Hexapotassium (cyclo-octahydroxotetracosaoxohexadecarborato)dioxouranate(VI) dodecahydrate, K6[UO2{B16O24(OH)8}].12H2O
journal, May 1985

  • Behm, H.
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 41, Issue 5
  • DOI: 10.1107/S0108270185004942

Experimental Determination of Solubilities of Brucite [Mg(OH)2(cr)] in Na2SO4 Solutions with Borate to High Ionic Strengths: Interactions of MgB(OH) 4 + with Na2SO4
journal, April 2018

  • Xiong, Yongliang; Kirkes, Leslie; Westfall, Terry
  • Journal of Solution Chemistry, Vol. 47, Issue 4
  • DOI: 10.1007/s10953-018-0742-z

Role of Anions and Reaction Conditions in the Preparation of Uranium(VI), Neptunium(VI), and Plutonium(VI) Borates
journal, March 2011

  • Wang, Shuao; Villa, Eric M.; Diwu, Juan
  • Inorganic Chemistry, Vol. 50, Issue 6
  • DOI: 10.1021/ic102356d

Neptunium Diverges Sharply from Uranium and Plutonium in Crystalline Borate Matrixes: Insights into the Complex Behavior of the Early Actinides Relevant to Nuclear Waste Storage
journal, January 2010

  • Wang, Shuao; Alekseev, Evgeny V.; Ling, Jie
  • Angewandte Chemie International Edition, Vol. 49, Issue 7
  • DOI: 10.1002/anie.200906127

The interaction of Eu( iii ) with organoborates – a further approach to understand the complexation in the An/Ln( iii )–borate system
journal, January 2015

  • Schott, Juliane; Kretzschmar, Jerome; Tsushima, Satoru
  • Dalton Transactions, Vol. 44, Issue 24
  • DOI: 10.1039/C5DT00213C

Further insights into intermediate- and mixed-valency in neptunium oxoanion compounds: structure and absorption spectroscopy of K2[(NpO2)3B10O16(OH)2(NO3)2]
journal, January 2010

  • Wang, Shuao; Alekseev, Evgeny V.; Depmeier, Wulf
  • Chemical Communications, Vol. 46, Issue 22
  • DOI: 10.1039/c002588g

JCPDS-ICDD Research Associateship (cooperative program with NBS/NIST)
journal, November 2001

  • Wong-Ng, W.; McMurdie, H. F.; Hubbard, C. R.
  • Journal of Research of the National Institute of Standards and Technology, Vol. 106, Issue 6
  • DOI: 10.6028/jres.106.052

Solubility and Hydrolysis Behaviour of Neptunium(V)
journal, January 1992


Mixed Hydroxo-Carbonate Complexes of Neptunium(V)
journal, January 1997


Structure−Property Relationships in Lithium, Silver, and Cesium Uranyl Borates
journal, November 2010

  • Wang, Shuao; Alekseev, Evgeny V.; Stritzinger, Jared T.
  • Chemistry of Materials, Vol. 22, Issue 21
  • DOI: 10.1021/cm1022135

Synthèse et structure du diborouranate de magnésium, MgB2UO7
journal, December 1987

  • Gasperin, M.
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 12
  • DOI: 10.1107/S0108270187088139

The INE-Beamline for actinide science at ANKA
journal, April 2012

  • Rothe, J.; Butorin, S.; Dardenne, K.
  • Review of Scientific Instruments, Vol. 83, Issue 4
  • DOI: 10.1063/1.3700813

Influence of the local atomic structure in the X-ray absorption near edge spectroscopy of neptunium oxo ions
journal, January 2009

  • Lozano, Janeth M.; Clark, David L.; Conradson, Steven D.
  • Physical Chemistry Chemical Physics, Vol. 11, Issue 44
  • DOI: 10.1039/b911731h