Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex

Fisher, Katherine J.; Feuer, Margalit L.; Lant, Hannah M. C.; Mercado, Brandon Q.; Crabtree, Robert H.; Brudvig, Gary W.

doi:10.1039/C9SC05565G

Title: Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex

Journal Article · 12 February 2020 · Chemical Science

DOI: https://doi.org/10.1039/C9SC05565G · OSTI ID:1582476

Fisher, Katherine J. ^[1]; Feuer, Margalit L. ^[1]; Lant, Hannah M. C. ^[1]; Mercado, Brandon Q. ^[1];

^[1];

^[1]

Department of Chemistry, Yale University, New Haven, USA

A high-valent nickel(III) compound performs fast concerted proton–electron transfer on O–H and C–H bonds. Thermodynamic analysis suggests that the oxidizing power of the compound and the formation of a strong ligand O–H bond lead to high reactivity.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Light Energy Activated Redox Processes (LEAP); Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0001059

OSTI ID:: 1582476

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 6 Vol. 11; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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