skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on January 3, 2021

Title: Novel carbon-based separation membranes composed of integrated zero- and one-dimensional nanomaterials

Abstract

Zero-dimensional graphene oxide quantum dots and one-dimensional carbon-nanotubes were integrated to form ultrathin membranes for CO 2 capture and water purification.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [1];  [1];  [1];  [3];  [1]
  1. Department of Chemical & Biological Engineering, Rensselaer Polytechnic Institute, Troy, USA
  2. Department of Chemical Engineering and Catalysis for Renewable Fuels Center, University of South Carolina, Columbia, USA
  3. Gas Technology Institute, Des Plaines, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1582475
Grant/Contract Number:  
FE0026383
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 3; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zhou, Fanglei, Tien, Huynh Ngoc, Dong, Qiaobei, Xu, Weiwei L., Sengupta, Bratin, Zha, Shangwen, Jiang, Ji, Behera, Dinesh, Li, Shiguang, and Yu, Miao. Novel carbon-based separation membranes composed of integrated zero- and one-dimensional nanomaterials. United Kingdom: N. p., 2020. Web. doi:10.1039/C9TA12847F.
Zhou, Fanglei, Tien, Huynh Ngoc, Dong, Qiaobei, Xu, Weiwei L., Sengupta, Bratin, Zha, Shangwen, Jiang, Ji, Behera, Dinesh, Li, Shiguang, & Yu, Miao. Novel carbon-based separation membranes composed of integrated zero- and one-dimensional nanomaterials. United Kingdom. doi:10.1039/C9TA12847F.
Zhou, Fanglei, Tien, Huynh Ngoc, Dong, Qiaobei, Xu, Weiwei L., Sengupta, Bratin, Zha, Shangwen, Jiang, Ji, Behera, Dinesh, Li, Shiguang, and Yu, Miao. Wed . "Novel carbon-based separation membranes composed of integrated zero- and one-dimensional nanomaterials". United Kingdom. doi:10.1039/C9TA12847F.
@article{osti_1582475,
title = {Novel carbon-based separation membranes composed of integrated zero- and one-dimensional nanomaterials},
author = {Zhou, Fanglei and Tien, Huynh Ngoc and Dong, Qiaobei and Xu, Weiwei L. and Sengupta, Bratin and Zha, Shangwen and Jiang, Ji and Behera, Dinesh and Li, Shiguang and Yu, Miao},
abstractNote = {Zero-dimensional graphene oxide quantum dots and one-dimensional carbon-nanotubes were integrated to form ultrathin membranes for CO 2 capture and water purification.},
doi = {10.1039/C9TA12847F},
journal = {Journal of Materials Chemistry. A},
number = 3,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on January 3, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Facile Synthetic Method for Pristine Graphene Quantum Dots and Graphene Oxide Quantum Dots: Origin of Blue and Green Luminescence
journal, May 2013


Helical microtubules of graphitic carbon
journal, November 1991


Effect of Lateral Size of Graphene Quantum Dots on Their Properties and Application
journal, January 2016

  • Zhang, Fangwei; Liu, Fei; Wang, Chong
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 3
  • DOI: 10.1021/acsami.5b10602

Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction
journal, February 2009


Fast Mass Transport Through Sub-2-Nanometer Carbon Nanotubes
journal, May 2006


Self-Assembly: A Facile Way of Forming Ultrathin, High-Performance Graphene Oxide Membranes for Water Purification
journal, April 2017


Molecular Layer Deposition-Modified 5A Zeolite for Highly Efficient CO 2 Capture
journal, December 2017

  • Song, Zhuonan; Dong, Qiaobei; Xu, Weiwei L.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 1
  • DOI: 10.1021/acsami.7b16574

Pushing the limits on possibilities for large scale gas separation: which strategies?
journal, August 2000


Strongly green-photoluminescent graphene quantum dots for bioimaging applications
journal, January 2011

  • Zhu, Shoujun; Zhang, Junhu; Qiao, Chunyan
  • Chemical Communications, Vol. 47, Issue 24
  • DOI: 10.1039/c1cc11122a

Facile synthesis of water-soluble, highly fluorescent graphene quantum dots as a robust biological label for stem cells
journal, January 2012

  • Zhang, Mo; Bai, Linling; Shang, Weihu
  • Journal of Materials Chemistry, Vol. 22, Issue 15
  • DOI: 10.1039/c2jm16835a

Single- to Few-Layered, Graphene-Based Separation Membranes
journal, June 2018


Enhanced Performance of a Novel Polyvinyl Amine/Chitosan/Graphene Oxide Mixed Matrix Membrane for CO 2 Capture
journal, July 2015


Correlation of separation factor versus permeability for polymeric membranes
journal, October 1991


An Electrochemical Avenue to Green-Luminescent Graphene Quantum Dots as Potential Electron-Acceptors for Photovoltaics
journal, December 2010


Chemical doping of graphene
journal, January 2011

  • Liu, Hongtao; Liu, Yunqi; Zhu, Daoben
  • J. Mater. Chem., Vol. 21, Issue 10
  • DOI: 10.1039/C0JM02922J

Selective Gas Transport Through Few-Layered Graphene and Graphene Oxide Membranes
journal, October 2013


Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Laminar MoS2 membranes for molecule separation
journal, January 2013

  • Sun, Luwei; Huang, Hubiao; Peng, Xinsheng
  • Chemical Communications, Vol. 49, Issue 91
  • DOI: 10.1039/c3cc46136j

Single and Multiple Doping in Graphene Quantum Dots: Unraveling the Origin of Selectivity in the Oxygen Reduction Reaction
journal, November 2014

  • Favaro, Marco; Ferrighi, Lara; Fazio, Gianluca
  • ACS Catalysis, Vol. 5, Issue 1
  • DOI: 10.1021/cs501211h

Upconversion and Downconversion Fluorescent Graphene Quantum Dots: Ultrasonic Preparation and Photocatalysis
journal, January 2012

  • Zhuo, Shujuan; Shao, Mingwang; Lee, Shuit-Tong
  • ACS Nano, Vol. 6, Issue 2
  • DOI: 10.1021/nn2040395

Controllable graphene N-doping with ammonia plasma
journal, March 2010

  • Lin, Yung-Chang; Lin, Chih-Yueh; Chiu, Po-Wen
  • Applied Physics Letters, Vol. 96, Issue 13
  • DOI: 10.1063/1.3368697

MXene molecular sieving membranes for highly efficient gas separation
journal, January 2018


Membrane Gas Separation: A Review/State of the Art
journal, May 2009

  • Bernardo, P.; Drioli, E.; Golemme, G.
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 10
  • DOI: 10.1021/ie8019032

Emissive ZnO–graphene quantum dots for white-light-emitting diodes
journal, May 2012

  • Son, Dong Ick; Kwon, Byoung Wook; Park, Dong Hee
  • Nature Nanotechnology, Vol. 7, Issue 7
  • DOI: 10.1038/nnano.2012.71

The solution-diffusion model: a review
journal, November 1995


A highly permeable graphene oxide membrane with fast and selective transport nanochannels for efficient carbon capture
journal, January 2016

  • Wang, Shaofei; Wu, Yingzhen; Zhang, Ning
  • Energy & Environmental Science, Vol. 9, Issue 10
  • DOI: 10.1039/C6EE01984F

CO2 capture by alkanolamine solutions containing diethylenetriamine and piperazine in a rotating packed bed
journal, July 2012

  • Yu, Cheng-Hsiu; Cheng, Hsu-Hsiang; Tan, Chung-Sung
  • International Journal of Greenhouse Gas Control, Vol. 9
  • DOI: 10.1016/j.ijggc.2012.03.015

Graphene quantum dots: an emerging material for energy-related applications and beyond
journal, January 2012

  • Zhang, Zhipan; Zhang, Jing; Chen, Nan
  • Energy & Environmental Science, Vol. 5, Issue 10
  • DOI: 10.1039/c2ee22982j

Graphene Quantum Dots
journal, November 2013

  • Bacon, Mitchell; Bradley, Siobhan J.; Nann, Thomas
  • Particle & Particle Systems Characterization, Vol. 31, Issue 4
  • DOI: 10.1002/ppsc.201300252

Large, Solution-Processable Graphene Quantum Dots as Light Absorbers for Photovoltaics
journal, May 2010

  • Yan, Xin; Cui, Xiao; Li, Binsong
  • Nano Letters, Vol. 10, Issue 5
  • DOI: 10.1021/nl101060h

Applications of carbon quantum dots (CQDs) in membrane technologies: A review
journal, December 2018


Materials for next-generation molecularly selective synthetic membranes
journal, January 2017

  • Koros, William J.; Zhang, Chen
  • Nature Materials, Vol. 16, Issue 3
  • DOI: 10.1038/nmat4805

Nitrogen-Doped Graphene Quantum Dots with Oxygen-Rich Functional Groups
journal, December 2011

  • Li, Yan; Zhao, Yang; Cheng, Huhu
  • Journal of the American Chemical Society, Vol. 134, Issue 1
  • DOI: 10.1021/ja206030c

Graphene Oxide: A Novel 2-Dimensional Material in Membrane Separation for Water Purification
journal, January 2017

  • Fathizadeh, Mahdi; Xu, Weiwei L.; Zhou, Fanglei
  • Advanced Materials Interfaces, Vol. 4, Issue 5
  • DOI: 10.1002/admi.201600918

Aligned Multiwalled Carbon Nanotube Membranes
journal, January 2004


Efficient CO 2 Capture by Functionalized Graphene Oxide Nanosheets as Fillers To Fabricate Multi-Permselective Mixed Matrix Membranes
journal, February 2015

  • Li, Xueqin; Cheng, Youdong; Zhang, Haiyang
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 9
  • DOI: 10.1021/acsami.5b00106

A novel cross-linked nano-coating for carbon dioxide capture
journal, January 2016

  • Fu, Qiang; Kim, Jinguk; Gurr, Paul A.
  • Energy & Environmental Science, Vol. 9, Issue 2
  • DOI: 10.1039/C5EE02433A

PEBAX® with PEG functionalized POSS as nanocomposite membranes for CO2 separation
journal, June 2013


A Two-Dimensional Lamellar Membrane: MXene Nanosheet Stacks
journal, January 2017

  • Ding, Li; Wei, Yanying; Wang, Yanjie
  • Angewandte Chemie International Edition, Vol. 56, Issue 7
  • DOI: 10.1002/anie.201609306

Luminscent Graphene Quantum Dots for Organic Photovoltaic Devices
journal, July 2011

  • Gupta, Vinay; Chaudhary, Neeraj; Srivastava, Ritu
  • Journal of the American Chemical Society, Vol. 133, Issue 26
  • DOI: 10.1021/ja2036749

High-Performance Membranes with Multi-permselectivity for CO2 Separation
journal, May 2012


Solubility of carbon dioxide in aqueous 2.5 M of diethylenetriamine (DETA) solution
journal, January 2011


Ultrathin, ethylenediamine-functionalized graphene oxide membranes on hollow fibers for CO2 capture
journal, March 2019


Surface Chemistry Routes to Modulate the Photoluminescence of Graphene Quantum Dots: From Fluorescence Mechanism to Up-Conversion Bioimaging Applications
journal, July 2012

  • Zhu, Shoujun; Zhang, Junhu; Tang, Shijia
  • Advanced Functional Materials, Vol. 22, Issue 22
  • DOI: 10.1002/adfm.201201499

Tuning Water Nanofiltration Performance of Few-Layered, Reduced Graphene Oxide Membranes by Oxygen Plasma
journal, June 2018

  • Xu, Weiwei L.; Zhou, Fanglei; Yu, Miao
  • Industrial & Engineering Chemistry Research, Vol. 57, Issue 47
  • DOI: 10.1021/acs.iecr.8b02206

Ultrathin, fine-tuned microporous coating modified 5A zeolite for propane/propylene adsorptive separation
journal, June 2019


Nitrogen-Doped Graphene Oxide Quantum Dots as Photocatalysts for Overall Water-Splitting under Visible Light Illumination
journal, February 2014

  • Yeh, Te-Fu; Teng, Chiao-Yi; Chen, Shean-Jen
  • Advanced Materials, Vol. 26, Issue 20
  • DOI: 10.1002/adma.201305299

Polyamide/nitrogen-doped graphene oxide quantum dots (N-GOQD) thin film nanocomposite reverse osmosis membranes for high flux desalination
journal, February 2019


Membranes with Fast and Selective Gas-Transport Channels of Laminar Graphene Oxide for Efficient CO 2 Capture
journal, November 2014


The upper bound revisited
journal, July 2008


Graphene Quantum Dots Derived from Carbon Fibers
journal, January 2012

  • Peng, Juan; Gao, Wei; Gupta, Bipin Kumar
  • Nano Letters, Vol. 12, Issue 2
  • DOI: 10.1021/nl2038979

Experimental study on mass transfer and prediction using artificial neural network for CO2 absorption into aqueous DETA
journal, August 2013


Ultrathin graphene oxide-based hollow fiber membranes with brush-like CO2-philic agent for highly efficient CO2 capture
journal, December 2017


Highly permeable polymers for gas separation membranes
journal, January 2010

  • Budd, Peter M.; McKeown, Neil B.
  • Polymer Chemistry, Vol. 1, Issue 1
  • DOI: 10.1039/b9py00319c