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Title: High temperature oxidation of Ni alloys in CO2 containing impurities

Abstract

Next-generation power systems need structural alloys resistant to high-temperature oxidation in CO2 containing combustion impurities. In this report we evaluate the oxidation performance of several commercial Ni alloys exposed to 95%CO2-4%H2O-1%O2, with/without 0.1% SO2, at 750°C and 1 atm. All alloys formed protective chromia layers and showed no signs of carburization or sulfidation, and minimal chromia volatilization. The microstructural evolution of the alloy surface, secondary oxidants, and minor alloy additions all played a part in promoting protective chromia formation/growth. The results show that Ni alloys are promising candidates for high-temperature portions of next-generation CO2-based power systems.

Authors:
 [1];  [2];  [2];  [2]
  1. National Energy Technology Lab. (NETL), Albany, OR (United States); Leidos, Pittsburgh, PA (United States)
  2. National Energy Technology Lab. (NETL), Albany, OR (United States)
Publication Date:
Research Org.:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)
Sponsoring Org.:
USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1582376
Alternate Identifier(s):
OSTI ID: 1775691
Report Number(s):
NA
Journal ID: ISSN 0010-938X
Grant/Contract Number:  
89243318CFE000003
Resource Type:
Accepted Manuscript
Journal Name:
Corrosion Science
Additional Journal Information:
Journal Volume: 157; Journal Issue: C; Journal ID: ISSN 0010-938X
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Oleksak, Richard P., Tylczak, Joseph H., Holcomb, Gordon R., and Doğan, Ömer N.. High temperature oxidation of Ni alloys in CO2 containing impurities. United States: N. p., 2019. Web. https://doi.org/10.1016/j.corsci.2019.05.019.
Oleksak, Richard P., Tylczak, Joseph H., Holcomb, Gordon R., & Doğan, Ömer N.. High temperature oxidation of Ni alloys in CO2 containing impurities. United States. https://doi.org/10.1016/j.corsci.2019.05.019
Oleksak, Richard P., Tylczak, Joseph H., Holcomb, Gordon R., and Doğan, Ömer N.. Wed . "High temperature oxidation of Ni alloys in CO2 containing impurities". United States. https://doi.org/10.1016/j.corsci.2019.05.019. https://www.osti.gov/servlets/purl/1582376.
@article{osti_1582376,
title = {High temperature oxidation of Ni alloys in CO2 containing impurities},
author = {Oleksak, Richard P. and Tylczak, Joseph H. and Holcomb, Gordon R. and Doğan, Ömer N.},
abstractNote = {Next-generation power systems need structural alloys resistant to high-temperature oxidation in CO2 containing combustion impurities. In this report we evaluate the oxidation performance of several commercial Ni alloys exposed to 95%CO2-4%H2O-1%O2, with/without 0.1% SO2, at 750°C and 1 atm. All alloys formed protective chromia layers and showed no signs of carburization or sulfidation, and minimal chromia volatilization. The microstructural evolution of the alloy surface, secondary oxidants, and minor alloy additions all played a part in promoting protective chromia formation/growth. The results show that Ni alloys are promising candidates for high-temperature portions of next-generation CO2-based power systems.},
doi = {10.1016/j.corsci.2019.05.019},
journal = {Corrosion Science},
number = C,
volume = 157,
place = {United States},
year = {2019},
month = {5}
}

Journal Article:

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Cited by: 3 works
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    Works referencing / citing this record:

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