Seed-mediated evolution of hierarchical metal–organic framework quaternary superstructures

Feng, Liang; Wang, Kun-Yu; Yan, Tian-Hao; Zhou, Hong-Cai

doi:10.1039/C9SC06064B

Title: Seed-mediated evolution of hierarchical metal–organic framework quaternary superstructures

Abstract

Varying levels of hierarchy in metal–organic framework (MOF) superstructures are achieved through seed-mediated evolution of multiple MOF modules.

Authors:

^[1]; Wang, Kun-Yu ^[1]; Yan, Tian-Hao ^[1];

^[2]

Department of Chemistry, Texas A&M University College Station, USA
Department of Chemistry, Texas A&M University College Station, USA, Department of Materials Science and Engineering, Texas A&M University College Station

Publication Date:: 2020-02-12

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Univ. of California, Oakland, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1582075

Alternate Identifier(s):: OSTI ID: 1624986

Grant/Contract Number:: SC0001015

Resource Type:: Published Article

Journal Name:: Chemical Science

Additional Journal Information:: Journal Name: Chemical Science Journal Volume: 11 Journal Issue: 6; Journal ID: ISSN 2041-6520

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Subject:: Chemistry

Citation Formats


                    Feng, Liang, Wang, Kun-Yu, Yan, Tian-Hao, and Zhou, Hong-Cai. Seed-mediated evolution of hierarchical metal–organic framework quaternary superstructures.  United Kingdom: N. p., 2020. 
Web.  doi:10.1039/C9SC06064B.

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                    Feng, Liang, Wang, Kun-Yu, Yan, Tian-Hao, & Zhou, Hong-Cai. Seed-mediated evolution of hierarchical metal–organic framework quaternary superstructures.  United Kingdom.  https://doi.org/10.1039/C9SC06064B

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                    Feng, Liang, Wang, Kun-Yu, Yan, Tian-Hao, and Zhou, Hong-Cai. Wed .  
"Seed-mediated evolution of hierarchical metal–organic framework quaternary superstructures".  United Kingdom.  https://doi.org/10.1039/C9SC06064B.

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@article{osti_1582075,

  title        = {Seed-mediated evolution of hierarchical metal–organic framework quaternary superstructures},

  author       = {Feng, Liang and Wang, Kun-Yu and Yan, Tian-Hao and Zhou, Hong-Cai},

  abstractNote = {Varying levels of hierarchy in metal–organic framework (MOF) superstructures are achieved through seed-mediated evolution of multiple MOF modules.},

  doi          = {10.1039/C9SC06064B},

  journal      = {Chemical Science},

  number       = 6,

  volume       = 11,

  place        = {United Kingdom},

  year         = {2020},

  month        = {2}

}

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Figures / Tables:

Fig. 1: Secondary epitaxial growth of MOF-74-III outside MOF-74-III spherulite seeds. (a) Illustration of epitaxial growth of MOF-74-III spherulites; (b) optical images of MOF-74-III spherulite seeds; (c and e) optical images of MOF-74-III@MOF-74-III spherulites after secondary growth; (f) optical images of MOF-74-III@MOF-74-III spherulites after secondary growth under polarized light; (d)more »

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Title: Seed-mediated evolution of hierarchical metal–organic framework quaternary superstructures

Abstract

Citation Formats

Figures / Tables:

Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks journal, February 2010

Isotropic and Anisotropic Growth of Metal–Organic Framework (MOF) on MOF: Logical Inference on MOF Structure Based on Growth Behavior and Morphological Feature journal, October 2016

Modular Programming of Hierarchy and Diversity in Multivariate Polymer/Metal–Organic Framework Hybrid Composites journal, May 2019

Rising Up: Hierarchical Metal–Organic Frameworks in Experiments and Simulations journal, May 2019

Seed-Mediated Synthesis of Metal–Organic Frameworks journal, January 2016

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites journal, March 2012

Metal–organic framework materials as catalysts journal, January 2009

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal, January 2002

Multivariate Stratified Metal–Organic Frameworks: Diversification Using Domain Building Blocks journal, January 2019

Uncovering Two Principles of Multivariate Hierarchical Metal–Organic Framework Synthesis via Retrosynthetic Design journal, December 2018

Metal–Organic Frameworks (MOFs) journal, January 2014

From fundamentals to applications: a toolbox for robust and multifunctional MOF materials journal, January 2018

Seed-Mediated Growth of Colloidal Metal Nanocrystals journal, December 2016

Nature’s hierarchical materials journal, November 2007

Uncovering two kinetic factors in the controlled growth of topologically distinct core–shell metal–organic frameworks journal, January 2019

Superlong Single-Crystal Metal–Organic Framework Nanotubes journal, October 2018

The Rise of Hierarchical Nanostructured Materials from Renewable Sources: Learning from Nature journal, July 2018

The chemistry of multi-component and hierarchical framework compounds journal, January 2019

Template-Free Synthesis of Hierarchical Porous Metal–Organic Frameworks journal, June 2013

Fabrication of a Spherical Superstructure of Carbon Nanorods journal, April 2019

Design and synthesis of an exceptionally stable and highly porous metal-organic framework journal, November 1999

A Working Hypothesis for Broadening Framework Types of Zeolites in Seed-Assisted Synthesis without Organic Structure-Directing Agent journal, July 2012

In Situ Coupling of Multidimensional MOFs for Heterogeneous Metal-Oxide Architectures: Toward Sensitive Chemiresistors journal, June 2018

Temperature-Controlled Evolution of Nanoporous MOF Crystallites into Hierarchically Porous Superstructures journal, May 2019

A spray-drying strategy for synthesis of nanoscale metal–organic frameworks and their assembly into hollow superstructures journal, February 2013

Morphological and Structural Evolutions of Metal-Organic Framework Particles from Amorphous Spheres to Crystalline Hexagonal Rods journal, July 2015

Onset of heterogeneous crystal nucleation in colloidal suspensions journal, March 2004

Large-Pore Apertures in a Series of Metal-Organic Frameworks journal, May 2012

Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010

Isotropic and Anisotropic Growth of Metal–Organic Framework (MOF) on MOF: Logical Inference on MOF Structure Based on Growth Behavior and Morphological Feature
journal, October 2016

Modular Programming of Hierarchy and Diversity in Multivariate Polymer/Metal–Organic Framework Hybrid Composites
journal, May 2019

Rising Up: Hierarchical Metal–Organic Frameworks in Experiments and Simulations
journal, May 2019

Seed-Mediated Synthesis of Metal–Organic Frameworks
journal, January 2016

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
journal, March 2012

Metal–organic framework materials as catalysts
journal, January 2009

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

Multivariate Stratified Metal–Organic Frameworks: Diversification Using Domain Building Blocks
journal, January 2019

Uncovering Two Principles of Multivariate Hierarchical Metal–Organic Framework Synthesis via Retrosynthetic Design
journal, December 2018

Metal–Organic Frameworks (MOFs)
journal, January 2014

From fundamentals to applications: a toolbox for robust and multifunctional MOF materials
journal, January 2018

Seed-Mediated Growth of Colloidal Metal Nanocrystals
journal, December 2016

Nature’s hierarchical materials
journal, November 2007

Uncovering two kinetic factors in the controlled growth of topologically distinct core–shell metal–organic frameworks
journal, January 2019

Superlong Single-Crystal Metal–Organic Framework Nanotubes
journal, October 2018

The Rise of Hierarchical Nanostructured Materials from Renewable Sources: Learning from Nature
journal, July 2018

The chemistry of multi-component and hierarchical framework compounds
journal, January 2019

Template-Free Synthesis of Hierarchical Porous Metal–Organic Frameworks
journal, June 2013

Fabrication of a Spherical Superstructure of Carbon Nanorods
journal, April 2019

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

A Working Hypothesis for Broadening Framework Types of Zeolites in Seed-Assisted Synthesis without Organic Structure-Directing Agent
journal, July 2012

In Situ Coupling of Multidimensional MOFs for Heterogeneous Metal-Oxide Architectures: Toward Sensitive Chemiresistors
journal, June 2018

Temperature-Controlled Evolution of Nanoporous MOF Crystallites into Hierarchically Porous Superstructures
journal, May 2019

A spray-drying strategy for synthesis of nanoscale metal–organic frameworks and their assembly into hollow superstructures
journal, February 2013

Morphological and Structural Evolutions of Metal-Organic Framework Particles from Amorphous Spheres to Crystalline Hexagonal Rods
journal, July 2015

Onset of heterogeneous crystal nucleation in colloidal suspensions
journal, March 2004

Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012