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Title: Substrate damage and incorporation of sapphire into barium hexaferrite films deposited by aerosol deposition

Abstract

Barium Hexaferrite (BaM) grown on sapphire substrate by aerosol deposition is investigated in a subtractive wedge series to determine the extent of energetic substrate damage and indentation. Energy dispersive x-ray spectroscopy (EDS) mapping reveals Al2O3 particulates ejected from the substrate surface during growth. The concentration of particles is higher at the substrate-film interface but persists throughout the 6 mu m thick film. An estimate of the indentation depth (similar to 600 nm) was agreed upon using two EDS techniques (line scan analysis and substrate surface reconstruction by areal integration). X-ray diffraction patterns show peak polycrystalline Al2O3 intensity in 1.5 mu m thick wedges and a decrease at higher thicknesses, confirming that Al2O3 particulate density decreases further from the substrate. Here, magnetic characterization showed decreased magnetic moment compared to bulk and thickness dependence consistent with the fractional increase of Al2O3 content in the films. X-ray absorption at the Fe L3 edge suggests a reduction of material close to the surface, but this reduction appears secondary in magnitude to the effect of damage from deposition.

Authors:
 [1];  [1];  [1];  [1];  [2];  [3]; ORCiD logo [4]; ORCiD logo [1]
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  1. Univ. of Alabama, Tuscaloosa, AL (United States)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
  3. Korean Inst. of Materials Science, Changwon (Korea)
  4. Naval Research Lab., Washington, D.C (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
OSTI Identifier:
1582015
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Ceramic Society
Additional Journal Information:
Journal Volume: 103; Journal Issue: 3; Journal ID: ISSN 0002-7820
Publisher:
American Ceramic Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; X-ray absorption spectroscopy; aerosol deposition; electron microscopy; substrate deformation; thin films

Citation Formats

Ranjit, Smriti, Law, Ka Ming, Budhathoki, Sujan, Allred, Jared M., Rosenberg, Richard A., Park, Dong‐Soo, Johnson, Scooter, and Hauser, Adam J. Substrate damage and incorporation of sapphire into barium hexaferrite films deposited by aerosol deposition. United States: N. p., 2019. Web. doi:10.1111/jace.16864.
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Ranjit, Smriti, Law, Ka Ming, Budhathoki, Sujan, Allred, Jared M., Rosenberg, Richard A., Park, Dong‐Soo, Johnson, Scooter, & Hauser, Adam J. Substrate damage and incorporation of sapphire into barium hexaferrite films deposited by aerosol deposition. United States. https://doi.org/10.1111/jace.16864
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Ranjit, Smriti, Law, Ka Ming, Budhathoki, Sujan, Allred, Jared M., Rosenberg, Richard A., Park, Dong‐Soo, Johnson, Scooter, and Hauser, Adam J. Sun . "Substrate damage and incorporation of sapphire into barium hexaferrite films deposited by aerosol deposition". United States. https://doi.org/10.1111/jace.16864. https://www.osti.gov/servlets/purl/1582015.
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@article{osti_1582015,
title = {Substrate damage and incorporation of sapphire into barium hexaferrite films deposited by aerosol deposition},
author = {Ranjit, Smriti and Law, Ka Ming and Budhathoki, Sujan and Allred, Jared M. and Rosenberg, Richard A. and Park, Dong‐Soo and Johnson, Scooter and Hauser, Adam J.},
abstractNote = {Barium Hexaferrite (BaM) grown on sapphire substrate by aerosol deposition is investigated in a subtractive wedge series to determine the extent of energetic substrate damage and indentation. Energy dispersive x-ray spectroscopy (EDS) mapping reveals Al2O3 particulates ejected from the substrate surface during growth. The concentration of particles is higher at the substrate-film interface but persists throughout the 6 mu m thick film. An estimate of the indentation depth (similar to 600 nm) was agreed upon using two EDS techniques (line scan analysis and substrate surface reconstruction by areal integration). X-ray diffraction patterns show peak polycrystalline Al2O3 intensity in 1.5 mu m thick wedges and a decrease at higher thicknesses, confirming that Al2O3 particulate density decreases further from the substrate. Here, magnetic characterization showed decreased magnetic moment compared to bulk and thickness dependence consistent with the fractional increase of Al2O3 content in the films. X-ray absorption at the Fe L3 edge suggests a reduction of material close to the surface, but this reduction appears secondary in magnitude to the effect of damage from deposition.},
doi = {10.1111/jace.16864},
journal = {Journal of the American Ceramic Society},
number = 3,
volume = 103,
place = {United States},
year = {2019},
month = {10}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1111/jace.16864
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Figures / Tables:

Figure 1 Figure 1: SEM and EDS analysis of BaM film on a-plane sapphire substrate a) cross-section SEM image showing aerosol deposited film on sapphire substrate, b) Element map of Ba, Fe, Al, O of the area selected on the SEM image, map shows uniform composition of the elements in the filmmore » including few traces of aluminum from the substrate, c)EDS line scan along the white line on the SEM micrograph showing the elements of the sample and Cu resulting from the Cu tape used to mount the sample, and d) Linescan in atomic% showing the concentration of Al mixed in the deposited film.« less
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Works referenced in this record:

Hexagonal ferrites: A review of the synthesis, properties and applications of hexaferrite ceramics
journal, September 2012

Dense nanocrystalline yttrium iron garnet films formed at room temperature by aerosol deposition
journal, April 2016

Effect of gas flow rates and nozzle throat width on deposition of α-alumina films of granule spray in vacuum
journal, July 2017

Assessment of the novel aerosol deposition method for room temperature preparation of metal oxide gas sensor films
journal, June 2009

Aerosol Codeposition of Ceramics: Mixtures of Bi 2 O 3 -TiO 2 and Bi 2 O 3 -V 2 O 5
journal, December 2014

  • Exner, Jörg; Fuierer, Paul; Moos, Ralf
  • Journal of the American Ceramic Society, Vol. 98, Issue 3
  • DOI: 10.1111/jace.13364

Investigation of the microwave absorptive behavior of doped barium ferrites
journal, January 2008

Formation of magnetically-oriented barium hexaferrite films by aerosol deposition
journal, June 2019

  • Johnson, Scooter D.; Park, Dong-Soo; Qadri, Syed B.
  • Journal of Magnetism and Magnetic Materials, Vol. 479
  • DOI: 10.1016/j.jmmm.2019.02.025

Osteoconductive hydroxyapatite coated PEEK for spinal fusion surgery
journal, October 2013

Screen printed thick self-biased, low-loss, barium hexaferrite films by hot-press sintering
journal, August 2006

  • Chen, Yajie; Sakai, Tomokazu; Chen, Taiyang
  • Journal of Applied Physics, Vol. 100, Issue 4
  • DOI: 10.1063/1.2221527

A Bright Future for Integrated Magnetics: Magnetic Components Used in Microwave and mm-Wave Systems, Useful Materials, and Unique Functionalities
journal, June 2019

  • Palmer, William; Kirkwood, David; Gross, Steve
  • IEEE Microwave Magazine, Vol. 20, Issue 6
  • DOI: 10.1109/MMM.2019.2904381

Deposition efficiency of barium hexaferrite by aerosol deposition
journal, December 2017

Magnetic and structural properties of sintered bulk pucks and aerosol deposited films of Ti-doped barium hexaferrite for microwave absorption applications
journal, July 2017

  • Johnson, Scooter D.; Gonzalez, Christopher M.; Anderson, Virginia
  • Journal of Applied Physics, Vol. 122, Issue 2
  • DOI: 10.1063/1.4991808

Growth of self-textured barium hexaferrite ceramics by normal sintering process and their anisotropic magnetic properties
journal, December 2017

Preparation and characterization of piezoelectric ceramic–polymer composite thick films by aerosol deposition for sensor application
journal, June 2009

  • Choi, Jong-Jin; Hahn, Byung-Dong; Ryu, Jungho
  • Sensors and Actuators A: Physical, Vol. 153, Issue 1
  • DOI: 10.1016/j.sna.2009.04.025

Characterization of as-deposited and sintered yttrium iron garnet thick films formed by aerosol deposition
journal, February 2014

  • Johnson, Scooter D.; Glaser, Evan R.; Cheng, Shu-Fan
  • Applied Physics Express, Vol. 7, Issue 3
  • DOI: 10.7567/APEX.7.035501

Dielectric and Insulating Properties of Embedded Capacitor for Flexible Electronics Prepared by Aerosol-Type Nanoparticle Deposition
journal, May 2013

  • Imanaka, Yoshihiko; Amada, Hideyuki; Kumasaka, Fumiaki
  • Japanese Journal of Applied Physics, Vol. 52, Issue 5S1
  • DOI: 10.7567/JJAP.52.05DA02

M-hexaferrites with planar magnetic anisotropy and their application to high-frequency microwave absorbers
journal, January 1999

  • Han-Shin Cho,
  • IEEE Transactions on Magnetics, Vol. 35, Issue 5
  • DOI: 10.1109/20.801111

Ba-hexaferrite films for next generation microwave devices (invited)
journal, April 2006

  • Harris, V. G.; Chen, Zhaohui; Chen, Yajie
  • Journal of Applied Physics, Vol. 99, Issue 8
  • DOI: 10.1063/1.2165145

Fabrication and characterization of aluminum nitride thick film coated on aluminum substrate for heat dissipation
journal, December 2016

Design and Implementation of a Magnetic Press System for Creating Magnetically Oriented Barium Hexaferrite Pucks
journal, July 2019

  • Johnson, Scooter D.; Patterson, Eric A.; Xing, Jeffrey
  • IEEE Transactions on Magnetics, Vol. 55, Issue 7
  • DOI: 10.1109/TMAG.2019.2900241

Sol–gel synthesis of copper(II) and titanium(IV) ions co-doped barium ferrite submicrometer crystals and their microwave absorption performance
journal, April 2015

  • Li, Shengnan; Xiong, Kun; Meng, Pingyuan
  • Journal of Materials Science: Materials in Electronics, Vol. 26, Issue 7
  • DOI: 10.1007/s10854-015-3068-2

Effect of raw powder particle size on microstructure and light transmittance of α-alumina films deposited by granule spray in vacuum
journal, February 2016

Enhancement of interface anchoring and densification of Y 2 O 3 coating by metal substrate manipulation in aerosol deposition process
journal, January 2015

  • Kim, Jinwoo; Lee, Je In; Park, Dong Soo
  • Journal of Applied Physics, Vol. 117, Issue 1
  • DOI: 10.1063/1.4905241

Magnetic Properties and Electromagnetic Wave Suppression Properties of Fe–Ferrite Films Prepared by Aerosol Deposition Method
journal, April 2008

  • Kato, Yoshihiro; Sugimoto, Satoshi; Akedo, Jun
  • Japanese Journal of Applied Physics, Vol. 47, Issue 4
  • DOI: 10.1143/JJAP.47.2127

Room-temperature growth of Ni-Zn-Cu ferrite/PTFE composite thick films on PET via aerosol deposition
journal, November 2013

Flexible Dielectric Bi 1.5 Zn 1.0 Nb 1.5 O 7 Thin Films on a Cu-Polyimide Foil
journal, February 2009

Capacitive soot sensor for diesel exhausts
journal, November 2016

Microwave magnetic and absorption properties of M-type ferrite BaCoxTixFe12−2xO19 in the Ka band
journal, March 2014

ZnS/diamond composite coatings for infrared transmission applications formed by the aerosol deposition method
conference, June 2013

  • Johnson, Scooter D.; Kub, Fritz J.; Eddy, Charles R.
  • SPIE Defense, Security, and Sensing, SPIE Proceedings
  • DOI: 10.1117/12.2029717

Aerosol Deposition of Yttrium Iron Garnet for Fabrication of Ferrite-Integrated On-Chip Inductors
journal, May 2015

  • Johnson, Scooter D.; Newman, Harvey S.; Glaser, Evan R.
  • IEEE Transactions on Magnetics, Vol. 51, Issue 5
  • DOI: 10.1109/TMAG.2014.2369376

Nonlinear magnetoelectric effects in Al-substituted strontium hexaferrite
journal, April 2021

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