Probing Structural Reconstruction of Metal Nanoparticles under Annealing and Water Vapor Conditions: A Theoretical Study

Wang, Zeming; An, Wei; Sun, Yangang; Hybertsen, Mark S.

doi:10.1021/acs.jpcc.9b09678

Title: Probing Structural Reconstruction of Metal Nanoparticles under Annealing and Water Vapor Conditions: A Theoretical Study

Journal Article · 18 November 2019 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.9b09678 · OSTI ID:1581954

Wang, Zeming ^[1];

^[1]; Sun, Yangang ^[1];

^[2]

Shanghai Univ. of Engineering Science (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Knowing the structural reconstruction of metal nanoparticles (NPs) under working conditions is of great importance to catalytic processes. Here, using Wulff construction combined with density functional theory (DFT) and molecular dynamics (MD) simulation, we investigated truncated octahedron-based Rh and Ir NPs (3.5, 5.5, and 9.5 nm in size) with different morphology for their structural reconstruction under annealing and water vapor conditions. Our MD results show that the NPs with lower average atomic coordination number ($$\overline{CN}$$) of surface atoms have lowered structural transformation inertness and thermal stability, resulting in more severe structural transition especially for smaller-sized NPs and Ir NPs. Under water vapor conditions, the competition between the interfacial tension ($$γ^{\overline{int}}_{hkl}$$) of (111) and (110) facets plays a major role in driving the shape evolution of Rh and Ir NPs by minimizing the total surface tension. It is revealed that annealing in vacuum/water vapor condition is an irreversible/reversible process on Rh and Ir NPs. We identified that the total adsorbate–metal ($$γ^{\overline{int}}_{hkl}$$) can serve as a key stability parameter for describing the potential energy surface of adsorbate–metal NP system in a variable gaseous environment (P, T).

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)

Grant/Contract Number:: SC0012704

OSTI ID:: 1581954

Report Number(s):: BNL--213515-2020-JAAM

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 49 Vol. 123; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (78)

Real‐Time Simulation of Nonequilibrium Nanocrystal Transformations Li, Xiao‐Yan; Zhu, Beien; Qi, Rui Advanced Theory and Simulations, Vol. 2, Issue 1 https://doi.org/10.1002/adts.201800127	journal	October 2018
Reconstruction of Supported Metal Nanoparticles in Reaction Conditions Duan, Manyi; Yu, Jian; Meng, Jun Angewandte Chemie, Vol. 130, Issue 22 https://doi.org/10.1002/ange.201800925	journal	May 2018
Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? Xia, Younan; Xiong, Yujie; Lim, Byungkwon Angewandte Chemie International Edition, Vol. 48, Issue 1, p. 60-103 https://doi.org/10.1002/anie.200802248	journal	December 2008
A Reactive Oxide Overlayer on Rhodium Nanoparticles during CO Oxidation and Its Size Dependence Studied by In Situ Ambient-Pressure X-ray Photoelectron Spectroscopy Grass, Michael E.; Zhang, Yawen; Butcher, Derek R. Angewandte Chemie International Edition, Vol. 47, Issue 46 https://doi.org/10.1002/anie.200803574	journal	November 2008
Supported Rhodium Oxide Nanoparticles as Highly Active CO Oxidation Catalysts Ligthart, D. A. J. Michel; van Santen, Rutger A.; Hensen, Emiel J. M. Angewandte Chemie International Edition, Vol. 50, Issue 23 https://doi.org/10.1002/anie.201100190	journal	April 2011
Electrochemical Synthesis of Tetrahexahedral Rhodium Nanocrystals with Extraordinarily High Surface Energy and High Electrocatalytic Activity Yu, Neng-Fei; Tian, Na; Zhou, Zhi-You Angewandte Chemie International Edition https://doi.org/10.1002/anie.201310597	journal	April 2014
Reshaping of Metal Nanoparticles Under Reaction Conditions Zhu, Beien; Meng, Jun; Yuan, Wentao Angewandte Chemie International Edition, Vol. 59, Issue 6 https://doi.org/10.1002/anie.201906799	journal	February 2020
Iridium(1 1 1), Iridium(1 1 0), and Ruthenium(0 0 0 1) Single Crystals as Model Catalysts for the Oxygen Evolution Reaction: Insights into the Electrochemical Oxide Formation and Electrocatalytic Activity Özer, Ebru; Spöri, Camillo; Reier, Tobias ChemCatChem, Vol. 9, Issue 4 https://doi.org/10.1002/cctc.201600423	journal	August 2016
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
Shape-controlled syntheses of rhodium nanocrystals for the enhancement of their catalytic properties Xie, Shuifen; Liu, Xiang Yang; Xia, Younan Nano Research, Vol. 8, Issue 1 https://doi.org/10.1007/s12274-014-0674-x	journal	January 2015
In-situ FTIR study of the electrocatalytic oxidation of ethanol at iridium and rhodium electrodes de Tacconi, N. R.; Lezna, R. O.; Beden, B. Journal of Electroanalytical Chemistry, Vol. 379, Issue 1-2 https://doi.org/10.1016/0022-0728(94)87155-8	journal	December 1994
STM study of rhodium deposition on the TiO2(110)-(1 × 2) surface Berkó, A.; Ménesi, G.; Solymosi, F. Surface Science, Vol. 372, Issue 1-3 https://doi.org/10.1016/S0039-6028(96)01097-7	journal	February 1997
Hydrodeoxygenation of anisole over different Rh surfaces Duong, Nhung N.; Aruho, Darius; Wang, Bin Chinese Journal of Catalysis, Vol. 40, Issue 11 https://doi.org/10.1016/S1872-2067(19)63345-0	journal	November 2019
Synthesis of Rh nano-particles by the microemulsion technology Ojeda, Manuel; Rojas, Sergio; Boutonnet, Magali Applied Catalysis A: General, Vol. 274, Issue 1-2 https://doi.org/10.1016/j.apcata.2004.05.014	journal	October 2004
Influence of particle size on the activity and stability in steam methane reforming of supported Rh nanoparticles Ligthart, D. A. J. M.; van Santen, R. A.; Hensen, E. J. M. Journal of Catalysis, Vol. 280, Issue 2 https://doi.org/10.1016/j.jcat.2011.03.015	journal	June 2011
Understanding the catalytic activity of gold nanoparticles through multi-scale simulations Brodersen, Simon H.; Grønbjerg, Ulrik; Hvolbæk, Britt Journal of Catalysis, Vol. 284, Issue 1 https://doi.org/10.1016/j.jcat.2011.08.016	journal	November 2011
Highly active rhodium/carbon nanocatalysts for ethanol oxidation in alkaline medium Suo, Yange; Hsing, I-Ming Journal of Power Sources, Vol. 196, Issue 19 https://doi.org/10.1016/j.jpowsour.2011.05.048	journal	October 2011
Surface and interface control of noble metal nanocrystals for catalytic and electrocatalytic applications Wu, Binghui; Zheng, Nanfeng Nano Today, Vol. 8, Issue 2 https://doi.org/10.1016/j.nantod.2013.02.006	journal	April 2013
Icosahedral nanocrystals of noble metals: Synthesis and applications Wang, Helan; Zhou, Shan; Gilroy, Kyle D. Nano Today, Vol. 15 https://doi.org/10.1016/j.nantod.2017.06.011	journal	August 2017
Dynamic behavior of metal nanoparticles for catalysis Zhou, Yan; Jin, Chuanchuan; Li, Yong Nano Today, Vol. 20 https://doi.org/10.1016/j.nantod.2018.04.005	journal	June 2018
Water adsorption and the wetting of metal surfaces Hodgson, A.; Haq, S. Surface Science Reports, Vol. 64, Issue 9 https://doi.org/10.1016/j.surfrep.2009.07.001	journal	September 2009
Stability and Reactivity: Positive and Negative Aspects for Nanoparticle Processing Xu, Liang; Liang, Hai-Wei; Yang, Yuan Chemical Reviews, Vol. 118, Issue 7 https://doi.org/10.1021/acs.chemrev.7b00208	journal	February 2018
CO Adsorption on Reconstructed Ir(100) Surfaces from UHV to mbar Pressure: A LEED, TPD, and PM-IRAS Study Anic, Kresimir; Bukhtiyarov, Andrey V.; Li, Hao The Journal of Physical Chemistry C, Vol. 120, Issue 20 https://doi.org/10.1021/acs.jpcc.5b12494	journal	May 2016
Interfacial and Alloying Effects on Activation of Ethanol from First-Principles An, Wei; Men, Yong; Wang, Jinguo The Journal of Physical Chemistry C, Vol. 121, Issue 10 https://doi.org/10.1021/acs.jpcc.6b12720	journal	March 2017
Structural Stability of Ruthenium Nanoparticles: A Density Functional Theory Study Nanba, Yusuke; Ishimoto, Takayoshi; Koyama, Michihisa The Journal of Physical Chemistry C, Vol. 121, Issue 49 https://doi.org/10.1021/acs.jpcc.7b08672	journal	December 2017
Stability and Electronic Properties of PtPd Nanoparticles via MD and DFT Calculations Chepkasov, I. V.; Visotin, M. A.; Kovaleva, E. A. The Journal of Physical Chemistry C, Vol. 122, Issue 31 https://doi.org/10.1021/acs.jpcc.8b04177	journal	July 2018
Shape Evolution of Metal Nanoparticles in Water Vapor Environment Zhu, Beien; Xu, Zhen; Wang, Chunlei Nano Letters, Vol. 16, Issue 4 https://doi.org/10.1021/acs.nanolett.6b00254	journal	March 2016
Formation of Second-Generation Nanoclusters on Metal Nanoparticles Driven by Reactant Gases Tao, Franklin Feng; Nguyen, Luan; Zhang, Shiran Nano Letters, Vol. 16, Issue 8 https://doi.org/10.1021/acs.nanolett.6b01718	journal	July 2016
Controlled Growth of Ceria Nanoarrays on Anatase Titania Powder: A Bottom-up Physical Picture Kim, Hyun You; Hybertsen, Mark S.; Liu, Ping Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04218	journal	December 2016
Three-Dimensional Quantification of the Facet Evolution of Pt Nanoparticles in a Variable Gaseous Environment Altantzis, Thomas; Lobato, Ivan; De Backer, Annick Nano Letters, Vol. 19, Issue 1 https://doi.org/10.1021/acs.nanolett.8b04303	journal	December 2018
Rationalization of Au Concentration and Distribution in AuNi@Pt Core–Shell Nanoparticles for Oxygen Reduction Reaction An, Wei; Liu, Ping ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01656	journal	September 2015
Atomic-Scale Structural Evolution of Rh(110) during Catalysis Nguyen, Luan; Liu, Lacheng; Assefa, Solomon ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02006	journal	December 2016
Reshaping Dynamics of Gold Nanoparticles under H ₂ and O ₂ at Atmospheric Pressure Chmielewski, Adrian; Meng, Jun; Zhu, Beien ACS Nano https://doi.org/10.1021/acsnano.8b08530	journal	January 2019
Chemistry and Properties of Nanocrystals of Different Shapes Burda, Clemens; Chen, Xiaobo; Narayanan, Radha Chemical Reviews, Vol. 105, Issue 4 https://doi.org/10.1021/cr030063a	journal	April 2005
Atomic-Scale Observations of Catalyst Structures under Reaction Conditions and during Catalysis Tao, Franklin (Feng); Crozier, Peter A. Chemical Reviews, Vol. 116, Issue 6 https://doi.org/10.1021/cr5002657	journal	March 2016
Advances in the Rational Design of Rhodium Nanoparticle Catalysts: Control via Manipulation of the Nanoparticle Core and Stabilizer Yuan, Yuan; Yan, Ning; Dyson, Paul J. ACS Catalysis, Vol. 2, Issue 6 https://doi.org/10.1021/cs300142u	journal	April 2012
Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs3003098	journal	July 2012
Shape-Dependent Catalytic Properties of Pt Nanoparticles Mostafa, Simon; Behafarid, Farzad; Croy, Jason R. Journal of the American Chemical Society, Vol. 132, Issue 44 https://doi.org/10.1021/ja106679z	journal	November 2010
Effects of Different Gases on the Morphology of Ir Nanoparticles Supported on the TiO ₂ (110)-(1×2) Surface Berkó, A.; Solymosi, F. The Journal of Physical Chemistry B, Vol. 104, Issue 44 https://doi.org/10.1021/jp002065u	journal	November 2000
Thermal Stability and Shape Evolution of Tetrahexahedral Au–Pd Core–Shell Nanoparticles with High-Index Facets Huang, Rao; Wen, Yu-Hua; Shao, Gui-Fang The Journal of Physical Chemistry C, Vol. 117, Issue 13 https://doi.org/10.1021/jp401423z	journal	March 2013
Size and Shape Effects of Pd@Pt Core–Shell Nanoparticles: Unique Role of Surface Contraction and Local Structural Flexibility An, Wei; Liu, Ping The Journal of Physical Chemistry C, Vol. 117, Issue 31 https://doi.org/10.1021/jp4057785	journal	July 2013
Direct Observation of the Reversible Changes of the Morphology of Pt Nanoparticles under Gas Environment Cabié, M.; Giorgio, S.; Henry, C. R. The Journal of Physical Chemistry C, Vol. 114, Issue 5 https://doi.org/10.1021/jp906721g	journal	January 2010
Rhodium Nanoparticles from Cluster Seeds: Control of Size and Shape by Precursor Addition Rate Humphrey, Simon M.; Grass, Michael E.; Habas, Susan E. Nano Letters, Vol. 7, Issue 3 https://doi.org/10.1021/nl070035y	journal	March 2007
Controlling the Morphology of Rhodium Nanocrystals by Manipulating the Growth Kinetics with a Syringe Pump Zhang, Hui; Li, Weiyang; Jin, Mingshang Nano Letters, Vol. 11, Issue 2 https://doi.org/10.1021/nl104347j	journal	February 2011
Sensing the Charge State of Single Gold Nanoparticles via Work Function Measurements Zhang, Yingjie; Pluchery, Olivier; Caillard, Louis Nano Letters, Vol. 15, Issue 1 https://doi.org/10.1021/nl503782s	journal	December 2014
The Solvent Matters: Kinetic versus Thermodynamic Shape Control in the Polyol Synthesis of Rhodium Nanoparticles Biacchi, Adam J.; Schaak, Raymond E. ACS Nano, Vol. 5, Issue 10 https://doi.org/10.1021/nn2026758	journal	September 2011
A molecular perspective of water at metal interfaces Carrasco, Javier; Hodgson, Andrew; Michaelides, Angelos Nature Materials, Vol. 11, Issue 8 https://doi.org/10.1038/nmat3354	journal	July 2012
Visualization of oscillatory behaviour of Pt nanoparticles catalysing CO oxidation Vendelbo, S. B.; Elkjær, C. F.; Falsig, H. Nature Materials, Vol. 13, Issue 9 https://doi.org/10.1038/nmat4033	journal	July 2014
Understanding the reactivity of metallic nanoparticles: beyond the extended surface model for catalysis Viñes, Francesc; Gomes, José R. B.; Illas, Francesc Chem. Soc. Rev., Vol. 43, Issue 14 https://doi.org/10.1039/C3CS60421G	journal	January 2014
Thermal and shape stability of high-index-faceted rhodium nanoparticles: a molecular dynamics investigation Zeng, Xiang-Ming; Huang, Rao; Wen, Yu-Hua Physical Chemistry Chemical Physics, Vol. 17, Issue 8 https://doi.org/10.1039/C4CP05032K	journal	January 2015
The role of synergic interaction in transition state formation for the aldol reaction on a metal oxide catalyst: a DFT investigation An, Wei Physical Chemistry Chemical Physics, Vol. 17, Issue 35 https://doi.org/10.1039/C5CP03478G	journal	January 2015
Hydrodeoxygenation of microalgae oil to green diesel over Pt, Rh and presulfided NiMo catalysts Zhou, Lin; Lawal, Adeniyi Catalysis Science & Technology, Vol. 6, Issue 5 https://doi.org/10.1039/C5CY01307K	journal	January 2016
Size- and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts Cao, Shaowen; Tao, Franklin (Feng); Tang, Yu Chemical Society Reviews, Vol. 45, Issue 17 https://doi.org/10.1039/C6CS00094K	journal	January 2016
Promoting the oxygen reduction reaction with gold at step/edge sites of Ni@AuPt core–shell nanoparticles Wang, Hao; An, Wei Catalysis Science & Technology, Vol. 7, Issue 3 https://doi.org/10.1039/C6CY02344D	journal	January 2017
Modeling the atomistic growth behavior of gold nanoparticles in solution Turner, C. Heath; Lei, Yu; Bao, Yuping Nanoscale, Vol. 8, Issue 17 https://doi.org/10.1039/C6NR01881E	journal	January 2016
Unexpected refacetting of palladium nanoparticles under atmospheric N ₂ conditions Zhang, Xun; Meng, Jun; Zhu, Beien Chemical Communications, Vol. 54, Issue 62 https://doi.org/10.1039/C8CC04574G	journal	January 2018
A genomic characterisation of monometallic nanoparticles Rossi, Kevin; Asara, Gian Giacomo; Baletto, Francesca Physical Chemistry Chemical Physics, Vol. 21, Issue 9 https://doi.org/10.1039/C8CP05720F	journal	January 2019
Multiscale atomistic simulation of metal nanoparticles under working conditions Du, Jifeng; Meng, Jun; Li, Xiao-Yan Nanoscale Advances, Vol. 1, Issue 7 https://doi.org/10.1039/C9NA00196D	journal	January 2019
Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas Spivey, James J.; Egbebi, Adefemi Chemical Society Reviews, Vol. 36, Issue 9 https://doi.org/10.1039/b414039g	journal	January 2007
Nanomaterials of high surface energy with exceptional properties in catalysis and energy storage Zhou, Zhi-You; Tian, Na; Li, Jun-Tao Chemical Society Reviews, Vol. 40, Issue 7 https://doi.org/10.1039/c0cs00176g	journal	January 2011
Silver nanoparticles with tunable work functions Wang, Pangpang; Tanaka, Daisuke; Ryuzaki, Sou Applied Physics Letters, Vol. 107, Issue 15 https://doi.org/10.1063/1.4933253	journal	October 2015
Hydration of metal surfaces can be dynamically heterogeneous and hydrophobic Limmer, David T.; Willard, Adam P.; Madden, Paul Proceedings of the National Academy of Sciences, Vol. 110, Issue 11 https://doi.org/10.1073/pnas.1301596110	journal	February 2013
Review of Chemical Reactions in the NO Reduction by CO on Rhodium/Alumina Catalysts Srinivasan, Anand; Depcik, Christopher Catalysis Reviews, Vol. 52, Issue 4 https://doi.org/10.1080/01614940.2010.522485	journal	October 2010
Extracting convergent surface energies from slab calculations Fiorentini, Vincenzo; Methfessel, M. Journal of Physics: Condensed Matter, Vol. 8, Issue 36 https://doi.org/10.1088/0953-8984/8/36/005	journal	September 1996
Visualization and analysis of atomistic simulation data with OVITO–the Open Visualization Tool Stukowski, Alexander Modelling and Simulation in Materials Science and Engineering, Vol. 18, Issue 1 https://doi.org/10.1088/0965-0393/18/1/015012	journal	December 2009
Ideal versus real: simulated annealing of experimentally derived and geometric platinum nanoparticles Ellaby, Tom; Aarons, Jolyon; Varambhia, Aakash Journal of Physics: Condensed Matter, Vol. 30, Issue 15 https://doi.org/10.1088/1361-648X/aab251	journal	March 2018
Canonical dynamics: Equilibrium phase-space distributions Hoover, William G. Physical Review A, Vol. 31, Issue 3 https://doi.org/10.1103/PhysRevA.31.1695	journal	March 1985
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation Perdew, John P.; Chevary, J. A.; Vosko, S. H. Physical Review B, Vol. 46, Issue 11 https://doi.org/10.1103/PhysRevB.46.6671	journal	September 1992
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Highly optimized embedded-atom-method potentials for fourteen fcc metals Sheng, H. W.; Kramer, M. J.; Cadien, A. Physical Review B, Vol. 83, Issue 13 https://doi.org/10.1103/PhysRevB.83.134118	journal	April 2011
Van der Waals density functionals applied to solids Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos Physical Review B, Vol. 83, Issue 19 https://doi.org/10.1103/PhysRevB.83.195131	journal	May 2011
Dependence on CO adsorption of the shapes of multifaceted gold nanoparticles: A density functional theory Barmparis, Georgios D.; Remediakis, Ioannis N. Physical Review B, Vol. 86, Issue 8 https://doi.org/10.1103/PhysRevB.86.085457	journal	August 2012
Structural Evolution of Smaller Gold Nanocrystals: The Truncated Decahedral Motif Cleveland, Charles L.; Landman, Uzi; Schaaff, Thomas G. Physical Review Letters, Vol. 79, Issue 10 https://doi.org/10.1103/PhysRevLett.79.1873	journal	September 1997
Adsorption-Induced Step Formation Thostrup, P.; Christoffersen, E.; Lorensen, H. T. Physical Review Letters, Vol. 87, Issue 12 https://doi.org/10.1103/PhysRevLett.87.126102	journal	August 2001
Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals Hansen, P. L. Science, Vol. 295, Issue 5562 https://doi.org/10.1126/science.1069325	journal	March 2002
NIST Chemistry WebBook, NIST Standard Reference Database 69 Linstrom, Peter National Institute of Standards and Technology https://doi.org/10.18434/t4d303	dataset	January 1997

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