This content will become publicly available on December 30, 2020
The interplay of thermodynamics and kinetics: imparting hierarchical control over film formation of self-stratified blends
Abstract
Neutron reflectivity provide a thorough understanding of the balance of thermodynamic and kinetic factors that influence the stratification of spin cast polymer blend thin films, including blend composition, polymer chain length, and casting speed.
- Authors:
-
[1];
[3]
- Department of Chemistry, University of Tennessee, Knoxville, USA
- NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, USA, University of Georgetown
- Department of Chemistry, University of Tennessee, Knoxville, USA, Chemical Sciences Division
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1581832
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Soft Matter
- Additional Journal Information:
- Journal Name: Soft Matter; Journal ID: ISSN 1744-683X
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Rinehart, Samantha J., Yuan, Guangcui, and Dadmun, Mark D. The interplay of thermodynamics and kinetics: imparting hierarchical control over film formation of self-stratified blends. United Kingdom: N. p., 2020.
Web. doi:10.1039/C9SM01147A.
Rinehart, Samantha J., Yuan, Guangcui, & Dadmun, Mark D. The interplay of thermodynamics and kinetics: imparting hierarchical control over film formation of self-stratified blends. United Kingdom. doi:10.1039/C9SM01147A.
Rinehart, Samantha J., Yuan, Guangcui, and Dadmun, Mark D. Wed .
"The interplay of thermodynamics and kinetics: imparting hierarchical control over film formation of self-stratified blends". United Kingdom. doi:10.1039/C9SM01147A.
@article{osti_1581832,
title = {The interplay of thermodynamics and kinetics: imparting hierarchical control over film formation of self-stratified blends},
author = {Rinehart, Samantha J. and Yuan, Guangcui and Dadmun, Mark D.},
abstractNote = {Neutron reflectivity provide a thorough understanding of the balance of thermodynamic and kinetic factors that influence the stratification of spin cast polymer blend thin films, including blend composition, polymer chain length, and casting speed.},
doi = {10.1039/C9SM01147A},
journal = {Soft Matter},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}
Free Publicly Available Full Text
This content will become publicly available on December 30, 2020
Publisher's Version of Record
DOI: 10.1039/C9SM01147A
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Controlled Fabrication of Polyelectrolyte Multilayer Thin Films Using Spin-Assembly
journal, August 2001
- Chiarelli, P. A.; Johal, M. S.; Casson, J. L.
- Advanced Materials, Vol. 13, Issue 15
Propagating topological transformations in thin immiscible bilayer films
journal, March 2014
- Hennessy, M. G.; Burlakov, V. M.; Münch, A.
- EPL (Europhysics Letters), Vol. 105, Issue 6
Insights into the Influence of Solvent Polarity on the Crystallization of Poly(ethylene oxide) Spin-Coated Thin Films via in Situ Grazing Incidence Wide-Angle X-ray Scattering
journal, June 2016
- Toolan, Daniel T. W.; Isakova, Anna; Hodgkinson, Richard
- Macromolecules, Vol. 49, Issue 12
Design and development of self-stratifying systems as sustainable coatings
journal, January 2015
- Baghdachi, J.; Perez, H.; Talapatcharoenkit, Punthip
- Progress in Organic Coatings, Vol. 78
Device performance and polymer morphology in polymer light emitting diodes: The control of thin film morphology and device quantum efficiency
journal, May 2000
- Shi, Y.; Liu, J.; Yang, Y.
- Journal of Applied Physics, Vol. 87, Issue 9
Self-assembly of semiconductor/insulator interfaces in one-step spin-coating: a versatile approach for organic field-effect transistors
journal, January 2013
- Liu, Chuan; Li, Yun; Lee, Michael V.
- Physical Chemistry Chemical Physics, Vol. 15, Issue 21
Spin coating of thin and ultrathin polymer films
journal, December 1998
- Hall, David B.; Underhill, Patrick; Torkelson, John M.
- Polymer Engineering & Science, Vol. 38, Issue 12
Scanning tunneling microscopy and atomic force microscopy characterization of polystyrene spin-coated onto silicon surfaces
journal, March 1992
- Stange, T. G.; Mathew, Roy; Evans, D. Fennell
- Langmuir, Vol. 8, Issue 3
The importance of solvent quality on the modification of conjugated polymer conformation and thermodynamics with illumination
journal, January 2017
- Morgan, Brian; Dadmun, Mark D.
- Soft Matter, Vol. 13, Issue 15
Use of poly(3-hexylthiophene)/poly(methyl methacrylate) (P3HT/PMMA) blends to improve the performance of water-gated organic field-effect transistors
journal, July 2011
- Kergoat, Loig; Battaglini, Nicolas; Miozzo, Luciano
- Organic Electronics, Vol. 12, Issue 7
Characteristics of resist films produced by spinning
journal, July 1978
- Meyerhofer, Dietrich
- Journal of Applied Physics, Vol. 49, Issue 7
Dependence of Regioregular Poly(3-hexylthiophene) Film Morphology and Field-Effect Mobility on Molecular Weight
journal, April 2005
- Kline, R. Joseph; McGehee, Michael D.; Kadnikova, Ekaterina N.
- Macromolecules, Vol. 38, Issue 8, p. 3312-3319
Bulk heterojunction solar cells with internal quantum efficiency approaching 100%
journal, April 2009
- Park, Sung Heum; Roy, Anshuman; Beaupré, Serge
- Nature Photonics, Vol. 3, Issue 5, p. 297-302
Dynamic Surface Enrichment in Drying Thin-Film Binary Polymer Solutions
journal, July 2017
- Schaefer, C.; Michels, J. J.; van der Schoot, P.
- Macromolecules, Vol. 50, Issue 15
An investigation of spin coating of electron resists
journal, November 1979
- Lai, Juey H.
- Polymer Engineering and Science, Vol. 19, Issue 15
Conjugated-Polymer Blends for Organic Photovoltaics: Rational Control of Vertical Stratification for High Performance
journal, February 2017
- Yan, Yu; Liu, Xuan; Wang, Tao
- Advanced Materials, Vol. 29, Issue 20
Elucidating the Kinetic and Thermodynamic Driving Forces in Polymer Blend Film Self-Stratification
journal, September 2018
- Rinehart, Samantha J.; Yuan, Guangcui; Dadmun, Mark D.
- Macromolecules, Vol. 51, Issue 19
Polyelectrolyte Spin-Assembly
journal, January 2002
- Chiarelli, Peter A.; Johal, Malkiat S.; Holmes, Daniel J.
- Langmuir, Vol. 18, Issue 1
Poly(3-hexylthiophene)/polystyrene (P3HT/PS) blends based organic field-effect transistor ammonia gas sensor
journal, March 2016
- Han, Shijiao; Zhuang, Xinming; Shi, Wei
- Sensors and Actuators B: Chemical, Vol. 225
A solution concentration dependent transition from self-stratification to lateral phase separation in spin-cast PS:d-PMMA thin films
journal, April 2010
- Dunbar, A. D. F.; Mokarian-Tabari, P.; Parnell, A. J.
- The European Physical Journal E, Vol. 31, Issue 4
Illumination of Conjugated Polymer in Solution Alters Its Conformation and Thermodynamics
journal, April 2016
- Morgan, Brian; Dadmun, Mark D.
- Macromolecules, Vol. 49, Issue 9
How do evaporating thin films evolve? Unravelling phase-separation mechanisms during solvent-based fabrication of polymer blends
journal, October 2014
- Wodo, Olga; Ganapathysubramanian, Baskar
- Applied Physics Letters, Vol. 105, Issue 15
Illumination alters the structure of gels formed from the model optoelectronic material P3HT
journal, January 2017
- Morgan, Brian; Dadmun, Mark D.
- Polymer, Vol. 108
Self-stratifying coatings: A review
journal, September 2017
- Beaugendre, A.; Degoutin, S.; Bellayer, S.
- Progress in Organic Coatings, Vol. 110
Multilayer formation in spin-coated thin films of low-bandgap polyfluorene:PCBM blends
journal, December 2005
- Björström, Cecilia M.; Bernasik, Andrzej; Rysz, Jakub
- Journal of Physics: Condensed Matter, Vol. 17, Issue 50
Vertical stratification and its impact on device performance in a polycarbazole based copolymer solar cells
journal, January 2015
- Wang, Tao; Scarratt, Nicholas W.; Yi, Hunan
- Journal of Materials Chemistry C, Vol. 3, Issue 16
The effect of illumination on the depth profile of thermally annealed MEH-PPV/dPS blends
journal, June 2017
- Morgan, Brian; Dadmun, Mark D.
- Journal of Polymer Science Part B: Polymer Physics, Vol. 55, Issue 15
Highly oriented crystals at the buried interface in polythiophene thin-film transistors
journal, February 2006
- Joseph Kline, R.; McGehee, Michael D.; Toney, Michael F.
- Nature Materials, Vol. 5, Issue 3