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Title: Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates

Journal Article · · Crystals
 [1]; ORCiD logo [1];  [1];  [2];  [3]
  1. Univ. of Valencia (Spain)
  2. Univ. of Cantabria, Santander (Spain)
  3. Diamond Light Source, Oxon (United Kingdom)
+ Show Author Affiliations

The laser-heating diamond-anvil cell technique enables direct investigations of materials under high pressures and temperatures, usually confining the samples with high yield strength W and Re gaskets. This work presents experimental data that evidences the chemical reactivity between these refractory metals and CO2 or carbonates at temperatures above 1300 °C and pressures above 6 GPa. Metal oxides and diamond are identified as reaction products. Recommendations to minimize non-desired chemical reactions in high-pressure high-temperature experiments are given.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
Spanish Ministerio de Ciencia, Innovación y Universidades (MICINN); Generalitat Valenciana Grant; MINECO
OSTI ID:
1581815
Journal Information:
Crystals, Journal Name: Crystals Journal Issue: 12 Vol. 9; ISSN CRYSBC; ISSN 2073-4352
Publisher:
MDPICopyright Statement
Country of Publication:
United States
Language:
ENGLISH

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Related Subjects

36 MATERIALS SCIENCE
carbon dioxide
carbonates
high-pressure high-temperature experiments
reactivity
rhenium
tungsten