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Title: Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates

Abstract

The laser-heating diamond-anvil cell technique enables direct investigations of materials under high pressures and temperatures, usually confining the samples with high yield strength W and Re gaskets. This work presents experimental data that evidences the chemical reactivity between these refractory metals and CO2 or carbonates at temperatures above 1300 °C and pressures above 6 GPa. Metal oxides and diamond are identified as reaction products. Recommendations to minimize non-desired chemical reactions in high-pressure high-temperature experiments are given.

Authors:
 [1]; ORCiD logo [1];  [1];  [2];  [3]
  1. Univ. of Valencia (Spain)
  2. Univ. of Cantabria, Santander (Spain)
  3. Diamond Light Source, Oxon (United Kingdom)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
Spanish Ministerio de Ciencia, Innovación y Universidades (MICINN); Generalitat Valenciana Grant; MINECO
OSTI Identifier:
1581815
Grant/Contract Number:  
PGC 2018-097520-A-I00; RED2018-102612-T; PROMETEO/2018/123; RyC-2014-15643
Resource Type:
Accepted Manuscript
Journal Name:
Crystals
Additional Journal Information:
Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN 2073-4352
Publisher:
MDPI
Country of Publication:
United States
Language:
ENGLISH
Subject:
36 MATERIALS SCIENCE; reactivity; tungsten; rhenium; carbon dioxide; carbonates; high-pressure high-temperature experiments

Citation Formats

Chuliá-Jordán, Raquel, Santamaría-Pérez, David, Marqueño, Tomás, Ruiz-Fuertes, Javier, and Daisenberger, Dominik. Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates. United States: N. p., 2019. Web. https://doi.org/10.3390/cryst9120676.
Chuliá-Jordán, Raquel, Santamaría-Pérez, David, Marqueño, Tomás, Ruiz-Fuertes, Javier, & Daisenberger, Dominik. Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates. United States. https://doi.org/10.3390/cryst9120676
Chuliá-Jordán, Raquel, Santamaría-Pérez, David, Marqueño, Tomás, Ruiz-Fuertes, Javier, and Daisenberger, Dominik. Tue . "Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates". United States. https://doi.org/10.3390/cryst9120676. https://www.osti.gov/servlets/purl/1581815.
@article{osti_1581815,
title = {Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates},
author = {Chuliá-Jordán, Raquel and Santamaría-Pérez, David and Marqueño, Tomás and Ruiz-Fuertes, Javier and Daisenberger, Dominik},
abstractNote = {The laser-heating diamond-anvil cell technique enables direct investigations of materials under high pressures and temperatures, usually confining the samples with high yield strength W and Re gaskets. This work presents experimental data that evidences the chemical reactivity between these refractory metals and CO2 or carbonates at temperatures above 1300 °C and pressures above 6 GPa. Metal oxides and diamond are identified as reaction products. Recommendations to minimize non-desired chemical reactions in high-pressure high-temperature experiments are given.},
doi = {10.3390/cryst9120676},
journal = {Crystals},
number = 12,
volume = 9,
place = {United States},
year = {2019},
month = {12}
}

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Free Publicly Available Full Text
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