Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates
Abstract
The laser-heating diamond-anvil cell technique enables direct investigations of materials under high pressures and temperatures, usually confining the samples with high yield strength W and Re gaskets. This work presents experimental data that evidences the chemical reactivity between these refractory metals and CO2 or carbonates at temperatures above 1300 °C and pressures above 6 GPa. Metal oxides and diamond are identified as reaction products. Recommendations to minimize non-desired chemical reactions in high-pressure high-temperature experiments are given.
- Authors:
-
[1];
- Univ. of Valencia (Spain)
- Univ. of Cantabria, Santander (Spain)
- Diamond Light Source, Oxon (United Kingdom)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- Spanish Ministerio de Ciencia, Innovación y Universidades (MICINN); Generalitat Valenciana Grant; Ministry of Economic Affairs and Digital Transformation of Spain (MINECO)
- OSTI Identifier:
- 1581815
- Grant/Contract Number:
- PGC 2018-097520-A-I00; RED2018-102612-T; PROMETEO/2018/123; RyC-2014-15643
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Crystals
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN 2073-4352
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 36 MATERIALS SCIENCE; reactivity; tungsten; rhenium; carbon dioxide; carbonates; high-pressure high-temperature experiments
Citation Formats
Chuliá-Jordán, Raquel, Santamaría-Pérez, David, Marqueño, Tomás, Ruiz-Fuertes, Javier, and Daisenberger, Dominik. Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates. United States: N. p., 2019.
Web. doi:10.3390/cryst9120676.
Chuliá-Jordán, Raquel, Santamaría-Pérez, David, Marqueño, Tomás, Ruiz-Fuertes, Javier, & Daisenberger, Dominik. Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates. United States. https://doi.org/10.3390/cryst9120676
Chuliá-Jordán, Raquel, Santamaría-Pérez, David, Marqueño, Tomás, Ruiz-Fuertes, Javier, and Daisenberger, Dominik. Tue .
"Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates". United States. https://doi.org/10.3390/cryst9120676. https://www.osti.gov/servlets/purl/1581815.
@article{osti_1581815,
title = {Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates},
author = {Chuliá-Jordán, Raquel and Santamaría-Pérez, David and Marqueño, Tomás and Ruiz-Fuertes, Javier and Daisenberger, Dominik},
abstractNote = {The laser-heating diamond-anvil cell technique enables direct investigations of materials under high pressures and temperatures, usually confining the samples with high yield strength W and Re gaskets. This work presents experimental data that evidences the chemical reactivity between these refractory metals and CO2 or carbonates at temperatures above 1300 °C and pressures above 6 GPa. Metal oxides and diamond are identified as reaction products. Recommendations to minimize non-desired chemical reactions in high-pressure high-temperature experiments are given.},
doi = {10.3390/cryst9120676},
journal = {Crystals},
number = 12,
volume = 9,
place = {United States},
year = {2019},
month = {12}
}
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