Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates

Chuliá-Jordán, Raquel; Santamaría-Pérez, David; Marqueño, Tomás; Ruiz-Fuertes, Javier; Daisenberger, Dominik

doi:10.3390/cryst9120676

Title: Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates

Journal Article · 17 December 2019 · Crystals

DOI: https://doi.org/10.3390/cryst9120676 · OSTI ID:1581815

Chuliá-Jordán, Raquel ^[1];

^[1]; Marqueño, Tomás ^[1]; Ruiz-Fuertes, Javier ^[2]; Daisenberger, Dominik ^[3]

Univ. of Valencia (Spain)
Univ. of Cantabria, Santander (Spain)
Diamond Light Source, Oxon (United Kingdom)

The laser-heating diamond-anvil cell technique enables direct investigations of materials under high pressures and temperatures, usually confining the samples with high yield strength W and Re gaskets. This work presents experimental data that evidences the chemical reactivity between these refractory metals and CO₂ or carbonates at temperatures above 1300 °C and pressures above 6 GPa. Metal oxides and diamond are identified as reaction products. Recommendations to minimize non-desired chemical reactions in high-pressure high-temperature experiments are given.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Spanish Ministerio de Ciencia, Innovación y Universidades (MICINN); Generalitat Valenciana Grant; Ministry of Economic Affairs and Digital Transformation of Spain (MINECO)

Grant/Contract Number:: PGC 2018-097520-A-I00; RED2018-102612-T; PROMETEO/2018/123; RyC-2014-15643

OSTI ID:: 1581815

Journal Information:: Crystals, Vol. 9, Issue 12; ISSN 2073-4352

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: ENGLISH

Citation Metrics:

Cited by: 7 works

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36 MATERIALS SCIENCE
reactivity
tungsten
rhenium
carbon dioxide
carbonates
high-pressure high-temperature experiments

Title: Oxidation of High Yield Strength Metals Tungsten and Rhenium in High-Pressure High-Temperature Experiments of Carbon Dioxide and Carbonates

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