Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations

Evoy, Erin; Maclean, Adrian M.; Rovelli, Grazia; Li, Ying; Tsimpidi, Alexandra P.; Karydis, Vlassis A.; Kamal, Saeid; Lelieveld, Jos; Shiraiwa, Manabu; Reid, Jonathan P.; Bertram, Allan K.

doi:10.5194/acp-19-10073-2019

Title: Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations

Journal Article · 09 August 2019 · Atmospheric Chemistry and Physics (Online)

DOI: https://doi.org/10.5194/acp-19-10073-2019 · OSTI ID:1581748

^[1]; Maclean, Adrian M. ^[1];

^[2]; Li, Ying ^[3]; Tsimpidi, Alexandra P. ^[4]; Karydis, Vlassis A. ^[5]; Kamal, Saeid ^[1];

^[6]; Shiraiwa, Manabu ^[3];

^[7];

^[1]

Univ. of Columbia, Vancouver, BC (Canada)
Univ. of Bristol (United Kingdom); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Irvine, CA (United States)
Max Planck Inst. for Chemistry, Mainz (Germany); National Observatory of Athens, Palea Penteli (Greece)
Max Planck Inst. for Chemistry, Mainz (Germany); Forschungszentrum Jülich (Germany)
Max Planck Inst. for Chemistry, Mainz (Germany); The Cyprus Inst., Nicosia (Cyprus)
Univ. of Bristol (United Kingdom)

Information on the rate of diffusion of organic molecules within secondary organic aerosol (SOA) is needed to accurately predict the effects of SOA on climate and air quality. Diffusion can be important for predicting the growth, evaporation, and reaction rates of SOA under certain atmospheric conditions. Often, researchers have predicted diffusion rates of organic molecules within SOA using measurements of viscosity and the Stokes–Einstein relation ($D∝1/η$, where D is the diffusion coefficient and η is viscosity). However, the accuracy of this relation for predicting diffusion in SOA remains uncertain. Using rectangular area fluorescence recovery after photobleaching (rFRAP), we determined diffusion coefficients of fluorescent organic molecules over 8 orders in magnitude in proxies of SOA including citric acid, sorbitol,and a sucrose–citric acid mixture. These results were combined with literature data to evaluate the Stokes–Einstein relation for predicting the diffusion of organic molecules in SOA. Although almost all the data agree with the Stokes–Einstein relation within a factor of 10, a fractional Stokes–Einstein relation ($D∝1/η^ξ$) with ξ=0.93 is a better model for predicting the diffusion of organic molecules in the SOA proxies studied. In addition, based on the output from a chemical transport model, the Stokes–Einstein relation can overpredict mixing times of organic molecules within SOA by as much as 1 order of magnitude at an altitude of ~3 km compared to the fractional Stokes–Einstein relation with ξ=0.93. These results also have implications for other areas such as in food sciences and the preservation of biomolecules.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1581748

Journal Information:: Atmospheric Chemistry and Physics (Online), Vol. 19, Issue 15; ISSN 1680-7324

Publisher:: European Geosciences UnionCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 30 works

Citation information provided by
Web of Science

References (120)

Assessing the Influence of Secondary Organic versus Primary Carbonaceous Aerosols on Long-Range Atmospheric Polycyclic Aromatic Hydrocarbon Transport Friedman, C. L.; Pierce, J. R.; Selin, N. E. Environmental Science & Technology, Vol. 48, Issue 6 https://doi.org/10.1021/es405219r	journal	March 2014
β-Relaxation governs protein stability in sugar-glass matrices Cicerone, Marcus T.; Douglas, Jack F. Soft Matter, Vol. 8, Issue 10 https://doi.org/10.1039/c2sm06979b	journal	January 2012
Cloud condensation nuclei activation of monoterpene and sesquiterpene secondary organic aerosol: BIOGENIC SECONDARY AEROSOL CCN ACTIVITY Huff Hartz, Kara E.; Rosenørn, Thomas; Ferchak, Shaun R. Journal of Geophysical Research: Atmospheres, Vol. 110, Issue D14 https://doi.org/10.1029/2004JD005754	journal	July 2005
Formation of 2-methyl tetrols and 2-methylglyceric acid in secondary organic aerosol from laboratory irradiated isoprene/NOX/SO2/air mixtures and their detection in ambient PM2.5 samples collected in the eastern United States Edney, E. O.; Kleindienst, T. E.; Jaoui, M. Atmospheric Environment, Vol. 39, Issue 29 https://doi.org/10.1016/j.atmosenv.2005.05.031	journal	September 2005
Moisture diffusivity in food materials van der Sman, R. G. M.; Meinders, M. B. J. Food Chemistry, Vol. 138, Issue 2-3 https://doi.org/10.1016/j.foodchem.2012.10.062	journal	June 2013
Organic aerosol components observed in Northern Hemispheric datasets from Aerosol Mass Spectrometry Ng, N. L.; Canagaratna, M. R.; Zhang, Q. Atmospheric Chemistry and Physics, Vol. 10, Issue 10 https://doi.org/10.5194/acp-10-4625-2010	journal	January 2010
The transition from liquid to solid-like behaviour in ultrahigh viscosity aerosol particles Power, R. M.; Simpson, S. H.; Reid, J. P. Chemical Science, Vol. 4, Issue 6 https://doi.org/10.1039/c3sc50682g	journal	January 2013
Fast airborne aerosol size and chemistry measurements above Mexico City and Central Mexico during the MILAGRO campaign DeCarlo, P. F.; Dunlea, E. J.; Kimmel, J. R. Atmospheric Chemistry and Physics, Vol. 8, Issue 14 https://doi.org/10.5194/acp-8-4027-2008	journal	January 2008
ORACLE (v1.0): module to simulate the organic aerosol composition and evolution in the atmosphere Tsimpidi, A. P.; Karydis, V. A.; Pozzer, A. Geoscientific Model Development, Vol. 7, Issue 6 https://doi.org/10.5194/gmd-7-3153-2014	journal	January 2014
Quantifying water diffusion in high-viscosity and glassy aqueous solutions using a Raman isotope tracer method Price, H. C.; Murray, B. J.; Mattsson, J. Atmospheric Chemistry and Physics, Vol. 14, Issue 8 https://doi.org/10.5194/acp-14-3817-2014	journal	January 2014
The effect of hydroxyl functional groups and molar mass on the viscosity of non-crystalline organic and organic–water particles Grayson, James W.; Evoy, Erin; Song, Mijung Atmospheric Chemistry and Physics, Vol. 17, Issue 13 https://doi.org/10.5194/acp-17-8509-2017	journal	January 2017
Estimating the Viscosity Range of SOA Particles Based on Their Coalescence Time Pajunoja, Aki; Malila, Jussi; Hao, Liqing Aerosol Science and Technology, Vol. 48, Issue 2 https://doi.org/10.1080/02786826.2013.870325	journal	December 2013
Validation of the poke-flow technique combined with simulations of fluid flow for determining viscosities in samples with small volumes and high viscosities Grayson, J. W.; Song, M.; Sellier, M. Atmospheric Measurement Techniques, Vol. 8, Issue 6 https://doi.org/10.5194/amt-8-2463-2015	journal	January 2015
A simplified description of the evolution of organic aerosol composition in the atmosphere: VAN KREVELEN DIAGRAM OF ORGANIC AEROSOL Heald, C. L.; Kroll, J. H.; Jimenez, J. L. Geophysical Research Letters, Vol. 37, Issue 8 https://doi.org/10.1029/2010GL042737	journal	April 2010
Highly Viscous States Affect the Browning of Atmospheric Organic Particulate Matter Liu, Pengfei; Li, Yong Jie; Wang, Yan ACS Central Science, Vol. 4, Issue 2 https://doi.org/10.1021/acscentsci.7b00452	journal	January 2018
The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges Nozière, Barbara; Kalberer, Markus; Claeys, Magda Chemical Reviews, Vol. 115, Issue 10 https://doi.org/10.1021/cr5003485	journal	February 2015
Carboxylic acids, sulfates, and organosulfates in processed continental organic aerosol over the southeast Pacific Ocean during VOCALS-REx 2008 Hawkins, L. N.; Russell, L. M.; Covert, D. S. Journal of Geophysical Research, Vol. 115, Issue D13 https://doi.org/10.1029/2009JD013276	journal	January 2010
Nonequilibrium atmospheric secondary organic aerosol formation and growth Perraud, V.; Bruns, E. A.; Ezell, M. J. Proceedings of the National Academy of Sciences, Vol. 109, Issue 8 https://doi.org/10.1073/pnas.1119909109	journal	January 2012
An omnipresent diversity and variability in the chemical composition of atmospheric functionalized organic aerosol Ditto, Jenna C.; Barnes, Emily B.; Khare, Peeyush Communications Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/s42004-018-0074-3	journal	November 2018
The formation, properties and impact of secondary organic aerosol: current and emerging issues Hallquist, M.; Wenger, J. C.; Baltensperger, U. Atmospheric Chemistry and Physics, Vol. 9, Issue 14 https://doi.org/10.5194/acp-9-5155-2009	journal	January 2009
Translational Diffusion in Sucrose Solutions in the Vicinity of Their Glass Transition Temperature Champion, D.; Hervet, H.; Blond, G. The Journal of Physical Chemistry B, Vol. 101, Issue 50 https://doi.org/10.1021/jp971899i	journal	December 1997
Global long-range transport and lung cancer risk from polycyclic aromatic hydrocarbons shielded by coatings of organic aerosol Shrivastava, Manish; Lou, Silja; Zelenyuk, Alla Proceedings of the National Academy of Sciences, Vol. 114, Issue 6 https://doi.org/10.1073/pnas.1618475114	journal	January 2017
Raman Spectroscopy of Isotopic Water Diffusion in Ultraviscous, Glassy, and Gel States in Aerosol by Use of Optical Tweezers Davies, James F.; Wilson, Kevin R. Analytical Chemistry, Vol. 88, Issue 4 https://doi.org/10.1021/acs.analchem.5b04315	journal	January 2016
Atomic test of the Stokes-Einstein law: Diffusion and solubility of Xe Pollack, Gerald L. Physical Review A, Vol. 23, Issue 5 https://doi.org/10.1103/PhysRevA.23.2660	journal	May 1981
An amorphous solid state of biogenic secondary organic aerosol particles Virtanen, Annele; Joutsensaari, Jorma; Koop, Thomas Nature, Vol. 467, Issue 7317 https://doi.org/10.1038/nature09455	journal	October 2010
Effect of the Aerosol-Phase State on Secondary Organic Aerosol Formation from the Reactive Uptake of Isoprene-Derived Epoxydiols (IEPOX) Zhang, Yue; Chen, Yuzhi; Lambe, Andrew T. Environmental Science & Technology Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acs.estlett.8b00044	journal	February 2018
Recent advances in understanding secondary organic aerosol: Implications for global climate forcing: Advances in Secondary Organic Aerosol Shrivastava, Manish; Cappa, Christopher D.; Fan, Jiwen Reviews of Geophysics, Vol. 55, Issue 2 https://doi.org/10.1002/2016RG000540	journal	June 2017
Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene Surratt, Jason D.; Murphy, Shane M.; Kroll, Jesse H. The Journal of Physical Chemistry A, Vol. 110, Issue 31 https://doi.org/10.1021/jp061734m	journal	August 2006
The atmospheric chemistry general circulation model ECHAM5/MESSy1: consistent simulation of ozone from the surface to the mesosphere Jöckel, P.; Tost, H.; Pozzer, A. Atmospheric Chemistry and Physics, Vol. 6, Issue 12 https://doi.org/10.5194/acp-6-5067-2006	journal	January 2006
Viscosity of Aqueous Carbohydrate Solutions at Different Temperatures and Concentrations Telis, V. R. N.; Telis-Romero, J.; Mazzotti, H. B. International Journal of Food Properties, Vol. 10, Issue 1 https://doi.org/10.1080/10942910600673636	journal	January 2007
Multi-generation gas-phase oxidation, equilibrium partitioning, and the formation and evolution of secondary organic aerosol Cappa, C. D.; Wilson, K. R. Atmospheric Chemistry and Physics, Vol. 12, Issue 20 https://doi.org/10.5194/acp-12-9505-2012	journal	January 2012
Temperature effect on phase state and reactivity controls atmospheric multiphase chemistry and transport of PAHs Mu, Qing; Shiraiwa, Manabu; Octaviani, Mega Science Advances, Vol. 4, Issue 3 https://doi.org/10.1126/sciadv.aap7314	journal	March 2018
Multiphase reactivity of polycyclic aromatic hydrocarbons is driven by phase separation and diffusion limitations Zhou, Shouming; Hwang, Brian C. H.; Lakey, Pascale S. J. Proceedings of the National Academy of Sciences https://doi.org/10.1073/pnas.1902517116	journal	May 2019
Sucrose diffusion in aqueous solution Price, Hannah C.; Mattsson, Johan; Murray, Benjamin J. Physical Chemistry Chemical Physics, Vol. 18, Issue 28 https://doi.org/10.1039/C6CP03238A	journal	January 2016
Rheology of supersaturated sucrose solutions Quintas, M.; Brandão, T. R. S.; Silva, C. L. M. Journal of Food Engineering, Vol. 77, Issue 4 https://doi.org/10.1016/j.jfoodeng.2005.08.011	journal	December 2006
Straightforward FRAP for quantitative diffusion measurements with a laser scanning microscope Deschout, Hendrik; Hagman, Joel; Fransson, Sophia Optics Express, Vol. 18, Issue 22 https://doi.org/10.1364/OE.18.022886	journal	January 2010
Measurements and Predictions of Binary Component Aerosol Particle Viscosity Song, Young Chul; Haddrell, Allen E.; Bzdek, Bryan R. The Journal of Physical Chemistry A, Vol. 120, Issue 41 https://doi.org/10.1021/acs.jpca.6b07835	journal	October 2016
Rainforest Aerosols as Biogenic Nuclei of Clouds and Precipitation in the Amazon Poschl, U.; Martin, S. T.; Sinha, B. Science, Vol. 329, Issue 5998 https://doi.org/10.1126/science.1191056	journal	September 2010
Crystallization of Aqueous Ammonium Sulfate Particles Internally Mixed with Soot and Kaolinite: Crystallization Relative Humidities and Nucleation Rates Pant, Atul; Parsons, Matthew T.; Bertram, Allan K. The Journal of Physical Chemistry A, Vol. 110, Issue 28 https://doi.org/10.1021/jp060985s	journal	July 2006
Viscosity of -pinene secondary organic material and implications for particle growth and reactivity Renbaum-Wolff, L.; Grayson, J. W.; Bateman, A. P. Proceedings of the National Academy of Sciences, Vol. 110, Issue 20 https://doi.org/10.1073/pnas.1219548110	journal	April 2013
Evaporation kinetics and phase of laboratory and ambient secondary organic aerosol Vaden, T. D.; Imre, D.; Beranek, J. Proceedings of the National Academy of Sciences, Vol. 108, Issue 6 https://doi.org/10.1073/pnas.1013391108	journal	January 2011
Mass spectral characterization of submicron biogenic organic particles in the Amazon Basin Chen, Q.; Farmer, D. K.; Schneider, J. Geophysical Research Letters, Vol. 36, Issue 20 https://doi.org/10.1029/2009GL039880	journal	January 2009
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations Riipinen, I.; Pierce, J. R.; Yli-Juuti, T. Atmospheric Chemistry and Physics, Vol. 11, Issue 8 https://doi.org/10.5194/acp-11-3865-2011	journal	January 2011
Relative humidity-dependent viscosity of secondary organic material from toluene photo-oxidation and possible implications for organic particulate matter over megacities Song, Mijung; Liu, Pengfei F.; Hanna, Sarah J. Atmospheric Chemistry and Physics, Vol. 16, Issue 14 https://doi.org/10.5194/acp-16-8817-2016	journal	January 2016
Organic functional groups in aerosol particles from burning and non-burning forest emissions at a high-elevation mountain site Takahama, S.; Schwartz, R. E.; Russell, L. M. Atmospheric Chemistry and Physics, Vol. 11, Issue 13 https://doi.org/10.5194/acp-11-6367-2011	journal	January 2011
The viscosity of atmospherically relevant organic particles Reid, Jonathan P.; Bertram, Allan K.; Topping, David O. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03027-z	journal	March 2018
Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies Ervens, B.; Turpin, B. J.; Weber, R. J. Atmospheric Chemistry and Physics, Vol. 11, Issue 21 https://doi.org/10.5194/acp-11-11069-2011	journal	January 2011
Mass Spectrometry Analysis in Atmospheric Chemistry Laskin, Julia; Laskin, Alexander; Nizkorodov, Sergey A. Analytical Chemistry, Vol. 90, Issue 1 https://doi.org/10.1021/acs.analchem.7b04249	journal	November 2017
Experimental determination of chemical diffusion within secondary organic aerosol particles Abramson, Evan; Imre, Dan; Beránek, Josef Physical Chemistry Chemical Physics, Vol. 15, Issue 8 https://doi.org/10.1039/c2cp44013j	journal	January 2013
Modeling kinetic partitioning of secondary organic aerosol and size distribution dynamics: representing effects of volatility, phase state, and particle-phase reaction Zaveri, R. A.; Easter, R. C.; Shilling, J. E. Atmospheric Chemistry and Physics, Vol. 14, Issue 10 https://doi.org/10.5194/acp-14-5153-2014	journal	January 2014
Mixing of secondary organic aerosols versus relative humidity Ye, Qing; Robinson, Ellis Shipley; Ding, Xiang Proceedings of the National Academy of Sciences, Vol. 113, Issue 45 https://doi.org/10.1073/pnas.1604536113	journal	October 2016
Identification of Organic Acids in Secondary Organic Aerosol and the Corresponding Gas Phase from Chamber Experiments Fisseha, R.; Dommen, J.; Sax, M. Analytical Chemistry, Vol. 76, Issue 22 https://doi.org/10.1021/ac048975f	journal	November 2004
Chemical Reactivity and Liquid/Nonliquid States of Secondary Organic Material Li, Yong Jie; Liu, Pengfei; Gong, Zhaoheng Environmental Science & Technology, Vol. 49, Issue 22 https://doi.org/10.1021/acs.est.5b03392	journal	October 2015
Secondary organic aerosol from α-pinene ozonolysis in dynamic chamber system Chen, X.; Hopke, P. K. Indoor Air, Vol. 19, Issue 4 https://doi.org/10.1111/j.1600-0668.2009.00596.x	journal	August 2009
Fluorescent lifetime imaging of atmospheric aerosols: a direct probe of aerosol viscosity Hosny, Neveen A.; Fitzgerald, Clare; Tong, Changlun Faraday Discussions, Vol. 165 https://doi.org/10.1039/c3fd00041a	journal	January 2013
Gas uptake and chemical aging of semisolid organic aerosol particles Shiraiwa, M.; Ammann, M.; Koop, T. Proceedings of the National Academy of Sciences, Vol. 108, Issue 27 https://doi.org/10.1073/pnas.1103045108	journal	June 2011
O/C and OM/OC Ratios of Primary, Secondary, and Ambient Organic Aerosols with High-Resolution Time-of-Flight Aerosol Mass Spectrometry Aiken, Allison C.; DeCarlo, Peter F.; Kroll, Jesse H. Environmental Science & Technology, Vol. 42, Issue 12 https://doi.org/10.1021/es703009q	journal	June 2008
Kinetic limitations in gas-particle reactions arising from slow diffusion in secondary organic aerosol Zhou, Shouming; Shiraiwa, Manabu; McWhinney, Robert D. Faraday Discuss., Vol. 165 https://doi.org/10.1039/C3FD00030C	journal	January 2013
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere Koop, Thomas; Bookhold, Johannes; Shiraiwa, Manabu Physical Chemistry Chemical Physics, Vol. 13, Issue 43 https://doi.org/10.1039/c1cp22617g	journal	January 2011
Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation Ullmann, Dagny A.; Hinks, Mallory L.; Maclean, Adrian M. Atmospheric Chemistry and Physics, Vol. 19, Issue 3 https://doi.org/10.5194/acp-19-1491-2019	journal	January 2019
Reactive intermediates revealed in secondary organic aerosol formation from isoprene Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C. Proceedings of the National Academy of Sciences, Vol. 107, Issue 15 https://doi.org/10.1073/pnas.0911114107	journal	December 2009
Inhibition of efflorescence in mixed organic–inorganic particles at temperatures less than 250 K Bodsworth, A.; Zobrist, B.; Bertram, A. K. Physical Chemistry Chemical Physics, Vol. 12, Issue 38 https://doi.org/10.1039/c0cp00572j	journal	January 2010
Evolution of Organic Aerosols in the Atmosphere Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M. Science, Vol. 326, Issue 5959 https://doi.org/10.1126/science.1180353	journal	December 2009
Relative humidity-dependent viscosities of isoprene-derived secondary organic material and atmospheric implications for isoprene-dominant forests Song, M.; Liu, P. F.; Hanna, S. J. Atmospheric Chemistry and Physics, Vol. 15, Issue 9 https://doi.org/10.5194/acp-15-5145-2015	journal	January 2015
Diffusion coefficients of organic molecules in sucrose–water solutions and comparison with Stokes–Einstein predictions Chenyakin, Yuri; Ullmann, Dagny A.; Evoy, Erin Atmospheric Chemistry and Physics, Vol. 17, Issue 3 https://doi.org/10.5194/acp-17-2423-2017	journal	January 2017
Mixing times of organic molecules within secondary organic aerosol particles: a global planetary boundary layer perspective Maclean, Adrian M.; Butenhoff, Christopher L.; Grayson, James W. Atmospheric Chemistry and Physics, Vol. 17, Issue 21 https://doi.org/10.5194/acp-17-13037-2017	journal	January 2017
Global distribution of particle phase state in atmospheric secondary organic aerosols Shiraiwa, Manabu; Li, Ying; Tsimpidi, Alexandra P. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15002	journal	April 2017
The effect of viscosity and diffusion on the HO ₂ uptake by sucrose and secondary organic aerosol particles Lakey, Pascale S. J.; Berkemeier, Thomas; Krapf, Manuel Atmospheric Chemistry and Physics, Vol. 16, Issue 20 https://doi.org/10.5194/acp-16-13035-2016	journal	January 2016
Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene Claeys, M. Science, Vol. 303, Issue 5661 https://doi.org/10.1126/science.1092805	journal	February 2004
Biopreservation. Putting proteins under glass Fox, K. Science, Vol. 267, Issue 5206 https://doi.org/10.1126/science.7701317	journal	March 1995
Viscosity of Multicomponent Solutions of Simple and Complex Sugars in Water Migliori, Massimo; Gabriele, Domenico; Di Sanzo, Rosa Journal of Chemical & Engineering Data, Vol. 52, Issue 4 https://doi.org/10.1021/je700062x	journal	July 2007
Diffusivity measurements of volatile organics in levitated viscous aerosol particles Bastelberger, Sandra; Krieger, Ulrich K.; Luo, Beiping Atmospheric Chemistry and Physics, Vol. 17, Issue 13 https://doi.org/10.5194/acp-17-8453-2017	journal	January 2017
Deposition nucleation on mineral dust particles: a case against classical nucleation theory with the assumption of a single contact angle Wheeler, M. J.; Bertram, A. K. Atmospheric Chemistry and Physics, Vol. 12, Issue 2 https://doi.org/10.5194/acp-12-1189-2012	journal	January 2012
Carboxylic Acids in Secondary Aerosols from Oxidation of Cyclic Monoterpenes by Ozone Glasius, Marianne; Lahaniati, Maria; Calogirou, Aggelos Environmental Science & Technology, Vol. 34, Issue 6 https://doi.org/10.1021/es990445r	journal	March 2000
Supercooled liquids and the glass transition Debenedetti, Pablo G.; Stillinger, Frank H. Nature, Vol. 410, Issue 6825 https://doi.org/10.1038/35065704	journal	March 2001
Ozone-driven daytime formation of secondary organic aerosol containing carboxylic acid groups and alkane groups Liu, S.; Day, D. A.; Shields, J. E. Atmospheric Chemistry and Physics, Vol. 11, Issue 16 https://doi.org/10.5194/acp-11-8321-2011	journal	January 2011
Temperature dependence of yields of secondary organic aerosols from the ozonolysis of α -pinene and limonene Saathoff, H.; Naumann, K. -H.; Möhler, O. Atmospheric Chemistry and Physics, Vol. 9, Issue 5 https://doi.org/10.5194/acp-9-1551-2009	journal	January 2009
Hydroxydicarboxylic Acids: Markers for Secondary Organic Aerosol from the Photooxidation of α-Pinene Claeys, Magda; Szmigielski, Rafal; Kourtchev, Ivan Environmental Science & Technology, Vol. 41, Issue 5 https://doi.org/10.1021/es0620181	journal	March 2007
Nanoscale interfacial gradients formed by the reactive uptake of OH radicals onto viscous aerosol surfaces Davies, James F.; Wilson, Kevin R. Chemical Science, Vol. 6, Issue 12 https://doi.org/10.1039/C5SC02326B	journal	January 2015
Connecting Bulk Viscosity Measurements to Kinetic Limitations on Attaining Equilibrium for a Model Aerosol Composition Booth, A. Murray; Murphy, Ben; Riipinen, Ilona Environmental Science & Technology, Vol. 48, Issue 16 https://doi.org/10.1021/es501705c	journal	August 2014
Comparison of Approaches for Measuring and Predicting the Viscosity of Ternary Component Aerosol Particles Rovelli, Grazia; Song, Young-Chul; Maclean, Adrian M. Analytical Chemistry, Vol. 91, Issue 8 https://doi.org/10.1021/acs.analchem.8b05353	journal	February 2019
ORACLE 2-D (v2.0): an efficient module to compute the volatility and oxygen content of organic aerosol with a global chemistry–climate model Tsimpidi, Alexandra P.; Karydis, Vlassis A.; Pozzer, Andrea Geoscientific Model Development, Vol. 11, Issue 8 https://doi.org/10.5194/gmd-11-3369-2018	journal	January 2018
Lability of secondary organic particulate matter Liu, Pengfei; Li, Yong Jie; Wang, Yan Proceedings of the National Academy of Sciences, Vol. 113, Issue 45 https://doi.org/10.1073/pnas.1603138113	journal	October 2016
Diffusion and reactivity in ultraviscous aerosol and the correlation with particle viscosity Marshall, Frances H.; Miles, Rachael E. H.; Song, Young-Chul Chemical Science, Vol. 7, Issue 2 https://doi.org/10.1039/C5SC03223G	journal	January 2016
An overview of the Amazonian Aerosol Characterization Experiment 2008 (AMAZE-08) Martin, S. T.; Andreae, M. O.; Althausen, D. Atmospheric Chemistry and Physics, Vol. 10, Issue 23 https://doi.org/10.5194/acp-10-11415-2010	journal	January 2010
On the pressure dependence of the viscosity of aqueous sugar solutions Först, Petra; Werner, Franz; Delgado, Antonio Rheologica Acta, Vol. 41, Issue 4 https://doi.org/10.1007/s00397-002-0238-y	journal	January 2002
Synergy between Secondary Organic Aerosols and Long-Range Transport of Polycyclic Aromatic Hydrocarbons Zelenyuk, Alla; Imre, Dan; Beránek, Josef Environmental Science & Technology, Vol. 46, Issue 22 https://doi.org/10.1021/es302743z	journal	November 2012
Formation of Glasses from Liquids and Biopolymers Angell, C. A. Science, Vol. 267, Issue 5206 https://doi.org/10.1126/science.267.5206.1924	journal	March 1995
S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS Ediger, M. D. Annual Review of Physical Chemistry, Vol. 51, Issue 1 https://doi.org/10.1146/annurev.physchem.51.1.99	journal	October 2000
Multi-generation gas-phase oxidation, equilibrium partitioning, and the formation and evolution of secondary organic aerosol Cappa, C. D.; Wilson, K. R. Atmospheric Chemistry and Physics Discussions, Vol. 12, Issue 1 https://doi.org/10.5194/acpd-12-3295-2012	journal	January 2012
Validation of the poke-flow technique combined with simulations of fluid flow for determining viscosities in samples with small volumes and high viscosities Grayson, J. W.; Song, M.; Sellier, M. Atmospheric Measurement Techniques Discussions, Vol. 8, Issue 1 https://doi.org/10.5194/amtd-8-877-2015	journal	January 2015
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations Riipinen, I.; Pierce, J. R.; Yli-Juuti, T. Carnegie Mellon University https://doi.org/10.1184/r1/6467339	text	January 2011
Inhibition of efflorescence in mixed organic-inorganic particles at temperatures less than 250 K. Bodsworth, A.; Zobrist, B.; Bertram, Allan K. Royal Society of Chemistry https://doi.org/10.14288/1.0041874	text	January 2010
Reactive intermediates revealed in secondary organic aerosol formation from isoprene C., Flagan, Richard; C., Eddingsaas, Nathan; L., Loza, Christine The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/sz9v-nb58	text	January 2009
Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies Ervens, B.; Turpin, B. J.; Weber, R. J. Atmospheric Chemistry and Physics Discussions, Vol. 11, Issue 8 https://doi.org/10.5194/acpd-11-22301-2011	journal	January 2011
The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges Decesari, Stefano; Allan, James; Claeys, Magda American Chemical Society https://doi.org/10.7892/boris.69473	text	January 2015
The formation, properties and impact of secondary organic aerosol: current and emerging issues Y., Rudich,; M., Jang,; A. S. H., Prevot, Copernicus Publications https://doi.org/10.17615/k22s-ek71	text	January 2009
Effect of the Aerosol-Phase State on Secondary Organic Aerosol Formation from the Reactive Uptake of Isoprene-Derived Epoxydiols (IEPOX) Z., Zhang,; A. T., Lambe,; J. A., Thornton, American Chemical Society https://doi.org/10.17615/db2e-hs88	text	January 2018
Diffusivity measurements of volatile organics in levitated viscous aerosol particles Bastelberger, Sandra; Krieger, Ulrich K.; Luo, Beiping ETH Zurich https://doi.org/10.3929/ethz-b-000190334	text	January 2017
Comparison of Approaches for Measuring and Predicting the Viscosity of Ternary Component Aerosol Particles Reid, Jonathan; Haddrell, Allen; Bzdek, Bryan University of Bristol https://doi.org/10.5523/bris.1kqew0q12nk5q2km5pqwgwmzbq	dataset	January 2019
Formation of 2-methyl tetrols and 2-methylglyceric acid in secondary organic aerosol from laboratory irradiated isoprene/NOX/SO2/air mixtures and their detection in ambient PM2.5 samples collected in the eastern United States Edney, E. O.; Kleindienst, T. E.; Jaoui, M. Atmospheric Environment, Vol. 39, Issue 29 https://doi.org/10.1016/j.atmosenv.2005.05.031	journal	September 2005
c,T-Dependence of the viscosity and the self-diffusion coefficients in some aqueous carbohydrate solutions Rampp, Martin; Buttersack, Christoph; Lüdemann, Hans-Dietrich Carbohydrate Research, Vol. 328, Issue 4 https://doi.org/10.1016/s0008-6215(00)00141-5	journal	October 2000
Identification of Organic Acids in Secondary Organic Aerosol and the Corresponding Gas Phase from Chamber Experiments Fisseha, R.; Dommen, J.; Sax, M. Analytical Chemistry, Vol. 76, Issue 22 https://doi.org/10.1021/ac048975f	journal	November 2004
Synergy between Secondary Organic Aerosols and Long-Range Transport of Polycyclic Aromatic Hydrocarbons Zelenyuk, Alla; Imre, Dan; Beránek, Josef Environmental Science & Technology, Vol. 46, Issue 22 https://doi.org/10.1021/es302743z	journal	November 2012
Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene Surratt, Jason D.; Murphy, Shane M.; Kroll, Jesse H. The Journal of Physical Chemistry A, Vol. 110, Issue 31 https://doi.org/10.1021/jp061734m	journal	August 2006
Translational Diffusion in Sucrose Solutions in the Vicinity of Their Glass Transition Temperature Champion, D.; Hervet, H.; Blond, G. The Journal of Physical Chemistry B, Vol. 101, Issue 50 https://doi.org/10.1021/jp971899i	journal	December 1997
An amorphous solid state of biogenic secondary organic aerosol particles Virtanen, Annele; Joutsensaari, Jorma; Koop, Thomas Nature, Vol. 467, Issue 7317 https://doi.org/10.1038/nature09455	journal	October 2010
An omnipresent diversity and variability in the chemical composition of atmospheric functionalized organic aerosol Ditto, Jenna C.; Barnes, Emily B.; Khare, Peeyush Communications Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/s42004-018-0074-3	journal	November 2018
Reactive intermediates revealed in secondary organic aerosol formation from isoprene Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C. Proceedings of the National Academy of Sciences, Vol. 107, Issue 15 https://doi.org/10.1073/pnas.0911114107	journal	December 2009
Evaporation kinetics and phase of laboratory and ambient secondary organic aerosol Vaden, T. D.; Imre, D.; Beranek, J. Proceedings of the National Academy of Sciences, Vol. 108, Issue 6 https://doi.org/10.1073/pnas.1013391108	journal	January 2011
Gas uptake and chemical aging of semisolid organic aerosol particles Shiraiwa, M.; Ammann, M.; Koop, T. Proceedings of the National Academy of Sciences, Vol. 108, Issue 27 https://doi.org/10.1073/pnas.1103045108	journal	June 2011
Nonequilibrium atmospheric secondary organic aerosol formation and growth Perraud, V.; Bruns, E. A.; Ezell, M. J. Proceedings of the National Academy of Sciences, Vol. 109, Issue 8 https://doi.org/10.1073/pnas.1119909109	journal	January 2012
Viscosity of -pinene secondary organic material and implications for particle growth and reactivity Renbaum-Wolff, L.; Grayson, J. W.; Bateman, A. P. Proceedings of the National Academy of Sciences, Vol. 110, Issue 20 https://doi.org/10.1073/pnas.1219548110	journal	April 2013
Lability of secondary organic particulate matter Liu, Pengfei; Li, Yong Jie; Wang, Yan Proceedings of the National Academy of Sciences, Vol. 113, Issue 45 https://doi.org/10.1073/pnas.1603138113	journal	October 2016
Multiphase reactivity of polycyclic aromatic hydrocarbons is driven by phase separation and diffusion limitations Zhou, Shouming; Hwang, Brian C. H.; Lakey, Pascale S. J. Proceedings of the National Academy of Sciences https://doi.org/10.1073/pnas.1902517116	journal	May 2019
Secondary organic aerosol from α-pinene ozonolysis in dynamic chamber system Chen, X.; Hopke, P. K. Indoor Air, Vol. 19, Issue 4 https://doi.org/10.1111/j.1600-0668.2009.00596.x	journal	August 2009
Quantifying water diffusion in high-viscosity and glassy aqueous solutions using a Raman isotope tracer method Price, H. C.; Murray, B. J.; Mattsson, J. Atmospheric Chemistry and Physics, Vol. 14, Issue 8 https://doi.org/10.5194/acp-14-3817-2014	journal	January 2014
Modeling kinetic partitioning of secondary organic aerosol and size distribution dynamics: representing effects of volatility, phase state, and particle-phase reaction Zaveri, R. A.; Easter, R. C.; Shilling, J. E. Atmospheric Chemistry and Physics, Vol. 14, Issue 10 https://doi.org/10.5194/acp-14-5153-2014	journal	January 2014
Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation Ullmann, Dagny A.; Hinks, Mallory L.; Maclean, Adrian M. Atmospheric Chemistry and Physics, Vol. 19, Issue 3 https://doi.org/10.5194/acp-19-1491-2019	journal	January 2019
Fast airborne aerosol size and chemistry measurements above Mexico City and Central Mexico during the MILAGRO campaign DeCarlo, P. F.; Dunlea, E. J.; Kimmel, J. R. Atmospheric Chemistry and Physics, Vol. 8, Issue 14 https://doi.org/10.5194/acp-8-4027-2008	journal	January 2008

Cited By (4)

Effect of Bulk Composition on the Heterogeneous Oxidation of Semi-Solid Atmospheric Aerosols Fan, Hanyu; Goulay, Fabien Atmosphere, Vol. 10, Issue 12 https://doi.org/10.3390/atmos10120791	journal	December 2019
Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors Song, Mijung; Maclean, Adrian M.; Huang, Yuanzhou Atmospheric Chemistry and Physics, Vol. 19, Issue 19 https://doi.org/10.5194/acp-19-12515-2019	journal	January 2019
Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors Song, Mijung; Maclean, Adrian M.; Huang, Yuanzhou Atmospheric Chemistry and Physics, Vol. 19, Issue 19 https://doi.org/10.5194/acp-19-12515-2019	journal	January 2019
Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model Schmedding, Ryan; Rasool, Quazi Z.; Zhang, Yue Atmospheric Chemistry and Physics, Vol. 20, Issue 13 https://doi.org/10.5194/acp-20-8201-2020	journal	January 2020

Similar Records

Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation

Journal Article · 2019 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1612637

Ullmann, Dagny A.; Hinks, Mallory L.; Maclean, Adrian M.; +7 more

Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors

Journal Article · 2019 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1571302

Song, Mijung; Maclean, Adrian M.; Huang, Yuanzhou; +9 more

High temperature breakdown of the Stokes-Einstein relation in a computer simulated Cu-Zr melt

Journal Article · 2016 · Journal of Chemical Physics · OSTI ID:22657865

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations

Citation Formats

References (120)

Cited By (4)

Similar Records

Related Subjects