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Title: Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex

Abstract

A dicopper complex featuring a symmetrically bridging nitrile ligand and supported by a binucleating naphthyridine-based ligand was treated with phosphaalkynes to yield dicopper complexes that exhibit phosphaalkynes in rare μ-η 2 : η 2 binding modes.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2];  [3]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemistry, University of California, Berkeley, Berkeley, USA, Chemical Sciences Division
  2. Department of Chemistry, University of California, Berkeley, Berkeley, USA
  3. Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg, Germany
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1581662
Grant/Contract Number:  
AC02-05CH11231; DE-AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Nicolay, Amélie, Ziegler, Micah S., Small, David W., Grünbauer, Rebecca, Scheer, Manfred, and Tilley, T. Don. Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex. United Kingdom: N. p., 2020. Web. doi:10.1039/C9SC05835D.
Nicolay, Amélie, Ziegler, Micah S., Small, David W., Grünbauer, Rebecca, Scheer, Manfred, & Tilley, T. Don. Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex. United Kingdom. doi:10.1039/C9SC05835D.
Nicolay, Amélie, Ziegler, Micah S., Small, David W., Grünbauer, Rebecca, Scheer, Manfred, and Tilley, T. Don. Wed . "Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex". United Kingdom. doi:10.1039/C9SC05835D.
@article{osti_1581662,
title = {Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex},
author = {Nicolay, Amélie and Ziegler, Micah S. and Small, David W. and Grünbauer, Rebecca and Scheer, Manfred and Tilley, T. Don},
abstractNote = {A dicopper complex featuring a symmetrically bridging nitrile ligand and supported by a binucleating naphthyridine-based ligand was treated with phosphaalkynes to yield dicopper complexes that exhibit phosphaalkynes in rare μ-η 2 : η 2 binding modes.},
doi = {10.1039/C9SC05835D},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9SC05835D

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