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Title: Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex

Journal Article · · Chemical Science
DOI: https://doi.org/10.1039/C9SC05835D · OSTI ID:1581662
ORCiD logo [1]; ORCiD logo [1];  [2];  [3]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemistry, University of California, Berkeley, Berkeley, USA, Chemical Sciences Division
  2. Department of Chemistry, University of California, Berkeley, Berkeley, USA
  3. Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg, Germany
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A dicopper complex featuring a symmetrically bridging nitrile ligand and supported by a binucleating naphthyridine-based ligand was treated with phosphaalkynes to yield dicopper complexes that exhibit phosphaalkynes in rare μ-η 2 : η 2 binding modes.

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
Grant/Contract Number:
AC02-05CH11231; AC02-05CH11231
OSTI ID:
1581662
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 6 Vol. 11; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United Kingdom
Language:
English

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