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Title: Optimizing the monomer structure of polyhedral oligomeric silsesquioxane for ion transport in hybrid organic–inorganic block copolymers

Authors:
ORCiD logo [1];  [2];  [1];  [3];  [4];  [5];  [1]
  1. Department of Chemical and Biomolecular EngineeringUniversity of California Berkeley California 94720, Materials Sciences DivisionLawrence Berkeley National Laboratory Berkeley California 94720, Joint Center for Energy Storage Research (JCESR)Lawrence Berkeley National Laboratory Berkeley California 94720
  2. Materials Sciences DivisionLawrence Berkeley National Laboratory Berkeley California 94720
  3. Materials Sciences DivisionLawrence Berkeley National Laboratory Berkeley California 94720, Department of Materials Science and EngineeringUniversity of California Berkeley California 94720
  4. Department of Chemical and Biomolecular EngineeringUniversity of California Berkeley California 94720, Materials Sciences DivisionLawrence Berkeley National Laboratory Berkeley California 94720
  5. Department of Chemical and Biomolecular EngineeringUniversity of California Berkeley California 94720
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1581659
Grant/Contract Number:  
DE‐AC02‐76SF00515; DE‐AC02‐06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Polymer Science
Additional Journal Information:
Journal Name: Journal of Polymer Science; Journal ID: ISSN 2642-4150
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Country unknown/Code not available
Language:
English

Citation Formats

Gao, Kevin W., Jiang, Xi, Hoffman, Zach J., Sethi, Gurmukh K., Chakraborty, Saheli, Villaluenga, Irune, and Balsara, Nitash P. Optimizing the monomer structure of polyhedral oligomeric silsesquioxane for ion transport in hybrid organic–inorganic block copolymers. Country unknown/Code not available: N. p., 2020. Web. doi:10.1002/pol.20190073.
Gao, Kevin W., Jiang, Xi, Hoffman, Zach J., Sethi, Gurmukh K., Chakraborty, Saheli, Villaluenga, Irune, & Balsara, Nitash P. Optimizing the monomer structure of polyhedral oligomeric silsesquioxane for ion transport in hybrid organic–inorganic block copolymers. Country unknown/Code not available. doi:10.1002/pol.20190073.
Gao, Kevin W., Jiang, Xi, Hoffman, Zach J., Sethi, Gurmukh K., Chakraborty, Saheli, Villaluenga, Irune, and Balsara, Nitash P. Wed . "Optimizing the monomer structure of polyhedral oligomeric silsesquioxane for ion transport in hybrid organic–inorganic block copolymers". Country unknown/Code not available. doi:10.1002/pol.20190073.
@article{osti_1581659,
title = {Optimizing the monomer structure of polyhedral oligomeric silsesquioxane for ion transport in hybrid organic–inorganic block copolymers},
author = {Gao, Kevin W. and Jiang, Xi and Hoffman, Zach J. and Sethi, Gurmukh K. and Chakraborty, Saheli and Villaluenga, Irune and Balsara, Nitash P.},
abstractNote = {},
doi = {10.1002/pol.20190073},
journal = {Journal of Polymer Science},
number = ,
volume = ,
place = {Country unknown/Code not available},
year = {2020},
month = {1}
}

Journal Article:
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Works referenced in this record:

Effect of Molecular Weight on the Mechanical and Electrical Properties of Block Copolymer Electrolytes
journal, June 2007

  • Singh, Mohit; Odusanya, Omolola; Wilmes, Gregg M.
  • Macromolecules, Vol. 40, Issue 13
  • DOI: 10.1021/ma0629541

Polymer solid electrolytes - an overview
journal, December 1983


Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

Salt Doping in PEO-Containing Block Copolymers: Counterion and Concentration Effects
journal, April 2009

  • Young, Wen-Shiue; Epps, Thomas H.
  • Macromolecules, Vol. 42, Issue 7
  • DOI: 10.1021/ma802799p

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Block Copolymer Electrolytes Synthesized by Atom Transfer Radical Polymerization for Solid-State, Thin-Film Lithium Batteries
journal, January 2002

  • Trapa, Patrick E.; Huang, Biying; Won, You-Yeon
  • Electrochemical and Solid-State Letters, Vol. 5, Issue 5
  • DOI: 10.1149/1.1461996

Salt Diffusion Coefficients in Block Copolymer Electrolytes
journal, January 2011

  • Mullin, Scott A.; Stone, Gregory M.; Panday, Ashoutosh
  • Journal of The Electrochemical Society, Vol. 158, Issue 6
  • DOI: 10.1149/1.3563802

Relationship between Steady-State Current in Symmetric Cells and Transference Number of Electrolytes Comprising Univalent and Multivalent Ions
journal, January 2015

  • Balsara, Nitash P.; Newman, John
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0651514jes

Modeling of transport of small molecules in polymer blends: Application of effective medium theory
journal, February 1983


A Giant Surfactant of Polystyrene−(Carboxylic Acid-Functionalized Polyhedral Oligomeric Silsesquioxane) Amphiphile with Highly Stretched Polystyrene Tails in Micellar Assemblies
journal, December 2010

  • Yu, Xinfei; Zhong, Sheng; Li, Xiaopeng
  • Journal of the American Chemical Society, Vol. 132, Issue 47
  • DOI: 10.1021/ja1078305

Theory of Microphase Separation in Block Copolymers
journal, November 1980


Comparing the Energy Content of Batteries, Fuels, and Materials
journal, March 2013

  • Balsara, Nitash P.; Newman, John
  • Journal of Chemical Education, Vol. 90, Issue 4
  • DOI: 10.1021/ed3004066

Polymer Electrolytes: Ionic Transport Mechanisms and Relaxation Coupling
journal, March 2000

  • Ratner, Mark A.; Johansson, Patrik; Shriver, Duward F.
  • MRS Bulletin, Vol. 25, Issue 3
  • DOI: 10.1557/mrs2000.16

Ion Conduction in Microphase-Separated Block Copolymer Electrolytes
journal, January 2017

  • Kambe, Yu; Arges, Christopher G.; Patel, Shrayesh
  • The Electrochemical Society Interface, Vol. 26, Issue 1
  • DOI: 10.1149/2.F07171if

A SAXS/WAXS/GISAXS Beamline with Multilayer Monochromator
journal, October 2010


Rubbery Block Copolymer Electrolytes for Solid-State Rechargeable Lithium Batteries
journal, January 1999

  • Soo, Philip P.
  • Journal of The Electrochemical Society, Vol. 146, Issue 1
  • DOI: 10.1149/1.1391560

Polypropylene-POSS Nanocomposites: Morphology and Crystallization Behaviour
journal, February 2006

  • Pracella, Mariano; Chionna, Donatella; Fina, Alberto
  • Macromolecular Symposia, Vol. 234, Issue 1
  • DOI: 10.1002/masy.200650209

The influence of alkyl substituents of POSS in polyethylene nanocomposites
journal, April 2013


Properties and self-assembled packing morphology of long alkyl-chained substituted polyhedral oligomeric silsesquioxanes (POSS) cages
journal, January 2013

  • Heeley, Ellen L.; Hughes, Darren J.; El Aziz, Youssef
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 15
  • DOI: 10.1039/c3cp44356f

Complexes of alkali metal ions with poly(ethylene oxide)
journal, November 1973


Functional groups on POSS nanoparticles influence the self-assembled structures of diblock copolymer composites
journal, January 2014


The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces
journal, January 2005

  • Monroe, Charles; Newman, John
  • Journal of The Electrochemical Society, Vol. 152, Issue 2
  • DOI: 10.1149/1.1850854

Study of thermal properties of polyethylene and polypropylene nanocomposites with long alkyl chain-substituted POSS fillers
journal, May 2016

  • Niemczyk, Arkadiusz; Dziubek, Katarzyna; Sacher-Majewska, Beata
  • Journal of Thermal Analysis and Calorimetry, Vol. 125, Issue 3
  • DOI: 10.1007/s10973-016-5497-4

Effect of Molecular Weight and Salt Concentration on Conductivity of Block Copolymer Electrolytes
journal, July 2009

  • Panday, Ashoutosh; Mullin, Scott; Gomez, Enrique D.
  • Macromolecules, Vol. 42, Issue 13
  • DOI: 10.1021/ma900451e

Negative Stefan-Maxwell Diffusion Coefficients and Complete Electrochemical Transport Characterization of Homopolymer and Block Copolymer Electrolytes
journal, January 2018

  • Villaluenga, Irune; Pesko, Danielle M.; Timachova, Ksenia
  • Journal of The Electrochemical Society, Vol. 165, Issue 11
  • DOI: 10.1149/2.0641811jes

Epoxy Networks Reinforced with Polyhedral Oligomeric Silsesquioxanes (POSS). Structure and Morphology
journal, December 2004

  • Matějka, Libor; Strachota, Adam; Pleštil, Josef
  • Macromolecules, Vol. 37, Issue 25
  • DOI: 10.1021/ma0484577

Polypropylene–polyhedral oligomeric silsesquioxanes (POSS) nanocomposites
journal, September 2005


Ohm’s law for ion conduction in lithium and beyond-lithium battery electrolytes
journal, July 2019

  • Galluzzo, Michael D.; Maslyn, Jacqueline A.; Shah, Deep B.
  • The Journal of Chemical Physics, Vol. 151, Issue 2
  • DOI: 10.1063/1.5109684

Effect of molecular weight on conductivity of polymer electrolytes
journal, November 2011

  • Teran, Alexander A.; Tang, Maureen H.; Mullin, Scott A.
  • Solid State Ionics, Vol. 203, Issue 1
  • DOI: 10.1016/j.ssi.2011.09.021

Reentrant phase behavior and coexistence in asymmetric block copolymer electrolytes
journal, January 2018

  • Loo, Whitney S.; Jiang, Xi; Maslyn, Jacqueline A.
  • Soft Matter, Vol. 14, Issue 15
  • DOI: 10.1039/C8SM00175H

Nika : software for two-dimensional data reduction
journal, March 2012


Synthesis of POSS Derivatives Having Dual Types of Alkyl Substituents and Their Application as a Molecular Filler for Low-Refractive and Highly Durable Materials
journal, February 2017

  • Ueda, Kazunari; Tanaka, Kazuo; Chujo, Yoshiki
  • Bulletin of the Chemical Society of Japan, Vol. 90, Issue 2
  • DOI: 10.1246/bcsj.20160338

Thermodynamic and Structural Changes in Ion-Containing Symmetric Diblock Copolymers: A Small-Angle X-ray Scattering Study
journal, December 2011

  • Gunkel, Ilja; Thurn-Albrecht, Thomas
  • Macromolecules, Vol. 45, Issue 1
  • DOI: 10.1021/ma201334h

Anomalous Self-Assembly and Ion Transport in Nanostructured Organic–Inorganic Solid Electrolytes
journal, August 2018


Phase Behavior of a Block Copolymer/Salt Mixture through the Order-to-Disorder Transition
journal, April 2014

  • Thelen, Jacob L.; Teran, Alexander A.; Wang, Xin
  • Macromolecules, Vol. 47, Issue 8
  • DOI: 10.1021/ma500292n

Restricted diffusion in binary solutions
journal, March 1973


Selective assemblies of giant tetrahedra via precisely controlled positional interactions
journal, April 2015


Structure–Conductivity Relationships in Ordered and Disordered Salt-Doped Diblock Copolymer/Homopolymer Blends
journal, September 2016


Lithium Dendrite Growth in Glassy and Rubbery Nanostructured Block Copolymer Electrolytes
journal, December 2014

  • Schauser, Nicole S.; Harry, Katherine J.; Parkinson, Dilworth Y.
  • Journal of The Electrochemical Society, Vol. 162, Issue 3
  • DOI: 10.1149/2.0511503jes

Superlattice by charged block copolymer self-assembly
journal, May 2019


Nanoparticle-Driven Assembly of Highly Conducting Hybrid Block Copolymer Electrolytes
journal, January 2015

  • Villaluenga, Irune; Chen, Xi Chelsea; Devaux, Didier
  • Macromolecules, Vol. 48, Issue 2
  • DOI: 10.1021/ma502234y

Thermodynamics of Block Copolymers with and without Salt
journal, December 2013

  • Teran, Alexander A.; Balsara, Nitash P.
  • The Journal of Physical Chemistry B, Vol. 118, Issue 1
  • DOI: 10.1021/jp408079z