skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Activation of Gold on Metal Carbides: Novel Catalysts for C1 Chemistry

Authors:
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1581650
Resource Type:
Published Article
Journal Name:
Frontiers in Chemistry
Additional Journal Information:
Journal Name: Frontiers in Chemistry Journal Volume: 7; Journal ID: ISSN 2296-2646
Publisher:
Frontiers Media SA
Country of Publication:
Switzerland
Language:
English

Citation Formats

Rodriguez, José A. Activation of Gold on Metal Carbides: Novel Catalysts for C1 Chemistry. Switzerland: N. p., 2020. Web. doi:10.3389/fchem.2019.00875.
Rodriguez, José A. Activation of Gold on Metal Carbides: Novel Catalysts for C1 Chemistry. Switzerland. doi:10.3389/fchem.2019.00875.
Rodriguez, José A. Wed . "Activation of Gold on Metal Carbides: Novel Catalysts for C1 Chemistry". Switzerland. doi:10.3389/fchem.2019.00875.
@article{osti_1581650,
title = {Activation of Gold on Metal Carbides: Novel Catalysts for C1 Chemistry},
author = {Rodriguez, José A.},
abstractNote = {},
doi = {10.3389/fchem.2019.00875},
journal = {Frontiers in Chemistry},
number = ,
volume = 7,
place = {Switzerland},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.3389/fchem.2019.00875

Save / Share:

Works referenced in this record:

Activation of noble metals on metal-carbide surfaces: novel catalysts for CO oxidation, desulfurization and hydrogenation reactions
journal, January 2012

  • Rodriguez, José A.; Illas, Francesc
  • Phys. Chem. Chem. Phys., Vol. 14, Issue 2
  • DOI: 10.1039/C1CP22738F

Surface chemistry of carbon dioxide revisited
journal, December 2016


Elucidating the role of oxygen coverage in CO 2 reduction on Mo 2 C
journal, January 2017

  • Dixit, Mudit; Peng, Xi; Porosoff, Marc D.
  • Catalysis Science & Technology, Vol. 7, Issue 23
  • DOI: 10.1039/C7CY01810J

Role of Au−C Interactions on the Catalytic Activity of Au Nanoparticles Supported on TiC(001) toward Molecular Oxygen Dissociation
journal, March 2010

  • Rodríguez, José A.; Feria, Leticia; Jirsak, Tomas
  • Journal of the American Chemical Society, Vol. 132, Issue 9
  • DOI: 10.1021/ja910146g

On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper
journal, January 2008

  • Gokhale, Amit A.; Dumesic, James A.; Mavrikakis, Manos
  • Journal of the American Chemical Society, Vol. 130, Issue 4
  • DOI: 10.1021/ja0768237

Catalysis by Gold: Isolated Surface Au3+ Ions are Active Sites for Selective Hydrogenation of 1,3-Butadiene over Au/ZrO2 Catalysts
journal, November 2005

  • Zhang, Xin; Shi, Hui; Xu, Bo-Qing
  • Angewandte Chemie International Edition, Vol. 44, Issue 43
  • DOI: 10.1002/anie.200502101

Highly Active Au/δ-MoC and Cu/δ-MoC Catalysts for the Conversion of CO 2 : The Metal/C Ratio as a Key Factor Defining Activity, Selectivity, and Stability
journal, June 2016

  • Posada-Pérez, Sergio; Ramírez, Pedro J.; Evans, Jaime
  • Journal of the American Chemical Society, Vol. 138, Issue 26
  • DOI: 10.1021/jacs.6b04529

PHYSICS: The Active Site in Nanoparticle Gold Catalysis
journal, October 2004


Charge Polarization at a Au-TiC Interface and the Generation of Highly Active and Selective Catalysts for the Low-Temperature Water-Gas Shift Reaction
journal, September 2014

  • Rodriguez, José A.; Ramírez, Pedro J.; Asara, Gian Giacomo
  • Angewandte Chemie International Edition, Vol. 53, Issue 42
  • DOI: 10.1002/anie.201407208

Why gold is the noblest of all the metals
journal, July 1995


CO2 hydrogenation on Au/TiC, Cu/TiC, and Ni/TiC catalysts: Production of CO, methanol, and methane
journal, November 2013


Effect of Ceria on Gold–Titania Catalysts for the Water–Gas Shift Reaction: Fundamental Studies for Au/CeO x /TiO 2 (110) and Au/CeO x /TiO 2 Powders
journal, October 2012

  • Si, Rui; Tao, Jing; Evans, Jaime
  • The Journal of Physical Chemistry C, Vol. 116, Issue 44
  • DOI: 10.1021/jp3089325

Size- and support-dependency in the catalysis of gold
journal, April 1997


CO 2 Activation and Methanol Synthesis on Novel Au/TiC and Cu/TiC Catalysts
journal, August 2012

  • Vidal, Alba B.; Feria, Leticia; Evans, Jaime
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 16
  • DOI: 10.1021/jz300989e

In situ gas-phase catalytic properties of TiC-supported size-selected gold nanoparticles synthesized by diblock copolymer encapsulation
journal, December 2006


On the bonding and reactivity of CO2 on metal surfaces
journal, June 1986


Effects of carbon on the stability and chemical performance of transition metal carbides: A density functional study
journal, March 2004

  • Liu, Ping; Rodriguez, José A.
  • The Journal of Chemical Physics, Vol. 120, Issue 11
  • DOI: 10.1063/1.1647050

Local investigation of the electronic properties of size-selected Au nanoparticles by scanning tunneling spectroscopy
journal, July 2006

  • Naitabdi, A.; Ono, L. K.; Roldan Cuenya, B.
  • Applied Physics Letters, Vol. 89, Issue 4
  • DOI: 10.1063/1.2233601

Highly active Au/δ-MoC and Au/β-Mo 2 C catalysts for the low-temperature water gas shift reaction: effects of the carbide metal/carbon ratio on the catalyst performance
journal, January 2017

  • Posada-Pérez, Sergio; Gutiérrez, Ramón A.; Zuo, Zhijun
  • Catalysis Science & Technology, Vol. 7, Issue 22
  • DOI: 10.1039/C7CY00639J

Synthesis of α-MoC1-x and β-MoCy Catalysts for CO2 Hydrogenation by Thermal Carburization of Mo-oxide in Hydrocarbon and Hydrogen Mixtures
journal, June 2014


The bending machine: CO 2 activation and hydrogenation on δ-MoC(001) and β-Mo 2 C(001) surfaces
journal, January 2014

  • Posada-Pérez, Sergio; Viñes, Francesc; Ramirez, Pedro J.
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 28
  • DOI: 10.1039/C4CP01943A

Density functional theory study into the adsorption of CO2, H and CHx (x=0–3) as well as C2H4 on α-Mo2C(0001)
journal, June 2006


Surface Chemistry of Transition Metal Carbides
journal, January 2005

  • Hwu, Henry H.; Chen, Jingguang G.
  • Chemical Reviews, Vol. 105, Issue 1
  • DOI: 10.1021/cr0204606

Surface chemistry of carbon dioxide
journal, January 1996


Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013

  • Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300361m

Effect of the Support on the Electronic Structure of Au Nanoparticles Supported on Transition Metal Carbides: Choice of the Best Substrate for Au Activation
journal, October 2009

  • Florez, Elizabeth; Feria, Leticia; Viñes, Francesc
  • The Journal of Physical Chemistry C, Vol. 113, Issue 46
  • DOI: 10.1021/jp907043g

Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
journal, August 2003


Supported Single Pt 1 /Au 1 Atoms for Methanol Steam Reforming
journal, October 2014

  • Gu, Xiang-Kui; Qiao, Botao; Huang, Chuan-Qi
  • ACS Catalysis, Vol. 4, Issue 11
  • DOI: 10.1021/cs500740u

Transition metal carbides as novel materials for CO 2 capture, storage, and activation
journal, January 2016

  • Kunkel, Christian; Viñes, Francesc; Illas, Francesc
  • Energy & Environmental Science, Vol. 9, Issue 1
  • DOI: 10.1039/C5EE03649F

CO, CO 2 , and H 2 Interactions with (0001) and (001) Tungsten Carbide Surfaces: Importance of Carbon and Metal Sites
journal, March 2019

  • Koverga, Andrey A.; Flórez, Elizabeth; Dorkis, Ludovic
  • The Journal of Physical Chemistry C, Vol. 123, Issue 14
  • DOI: 10.1021/acs.jpcc.8b11840

Adsorption of gold on TiC(001): Au–C interactions and charge polarization
journal, December 2007

  • Rodriguez, J. A.; Viñes, F.; Illas, F.
  • The Journal of Chemical Physics, Vol. 127, Issue 21
  • DOI: 10.1063/1.2814246

Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction
journal, June 2017


CO2 Hydrogenation over Carbide Catalysts.
journal, January 1992

  • Dubois, Jean-Luc; Sayama, Kazuhiro; Arakawa, Hironori
  • Chemistry Letters, Issue 1
  • DOI: 10.1246/cl.1992.5

Kinetics and mechanism of the water-gas shift reaction catalysed by the clean and Cs-promoted Cu(110) surface: a comparison with Cu(111)
journal, January 1990

  • Nakamura, Junji; Campbell, Joseph M.; Campbell, Charles T.
  • Journal of the Chemical Society, Faraday Transactions, Vol. 86, Issue 15
  • DOI: 10.1039/ft9908602725

Classification of chemical bonds based on topological analysis of electron localization functions
journal, October 1994