Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

Yu, Liang; Wang, Hao; Liu, Wei; Teat, Simon J.; Li, Jing

doi:10.1021/acs.cgd.9b01284

Title: Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

Journal Article · 28 October 2019 · Crystal Growth and Design

DOI: https://doi.org/10.1021/acs.cgd.9b01284 · OSTI ID:1581611

Yu, Liang ^[1];

^[1]; Liu, Wei ^[1]; Teat, Simon J. ^[2];

^[1]

Shenzhen Polytechnic (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Here, we demonstrate that two new zirconium-based metal-organic frameworks can be constructed from organic chromophore ligands. Both compounds show intense yellow emission when excited by blue light, with a notable fluorescence red shift and quantum yield enhancement compared to the organic chromophore.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1581611

Journal Information:: Crystal Growth and Design, Journal Name: Crystal Growth and Design Journal Issue: 12 Vol. 19; ISSN 1528-7483

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

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