Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

doi:10.1021/acs.cgd.9b01284

This content will become publicly available on October 28, 2020

Title: Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

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Abstract

Here, we demonstrate that two new zirconium-based metal-organic frameworks can be constructed from organic chromophore ligands. Both compounds show intense yellow emission when excited by blue light, with a notable fluorescence red shift and quantum yield enhancement compared to the organic chromophore.

Authors:

Yu, Liang ^[1];

^[1]; Liu, Wei ^[1]; Teat, Simon J. ^[2];

^[1]

Shenzhen Polytechnic (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Publication Date:: 2019-10-28

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1581611

Grant/Contract Number:: [AC02-05CH11231]

Resource Type:: Accepted Manuscript

Journal Name:: Crystal Growth and Design

Additional Journal Information:: [ Journal Volume: 19; Journal Issue: 12]; Journal ID: ISSN 1528-7483

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; phosphors; ligands; metal organic frameworks; chromophores energy

Citation Formats


                    Yu, Liang, Wang, Hao, Liu, Wei, Teat, Simon J., and Li, Jing. Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores.  United States: N. p., 2019. 
        Web.  doi:10.1021/acs.cgd.9b01284.

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                    Yu, Liang, Wang, Hao, Liu, Wei, Teat, Simon J., & Li, Jing. Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores.  United States.  doi:10.1021/acs.cgd.9b01284.

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                    Yu, Liang, Wang, Hao, Liu, Wei, Teat, Simon J., and Li, Jing. Mon .  
        "Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores".  United States.  doi:10.1021/acs.cgd.9b01284.

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@article{osti_1581611,

  title        = {Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores},

  author       = {Yu, Liang and Wang, Hao and Liu, Wei and Teat, Simon J. and Li, Jing},

  abstractNote = {Here, we demonstrate that two new zirconium-based metal-organic frameworks can be constructed from organic chromophore ligands. Both compounds show intense yellow emission when excited by blue light, with a notable fluorescence red shift and quantum yield enhancement compared to the organic chromophore.},

  doi          = {10.1021/acs.cgd.9b01284},

  journal      = {Crystal Growth and Design},

  number       = [12],

  volume       = [19],

  place        = {United States},

  year         = {2019},

  month        = {10}

}

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