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Title: Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

Abstract

Here, we demonstrate that two new zirconium-based metal-organic frameworks can be constructed from organic chromophore ligands. Both compounds show intense yellow emission when excited by blue light, with a notable fluorescence red shift and quantum yield enhancement compared to the organic chromophore.

Authors:
 [1]; ORCiD logo [1];  [1];  [2]; ORCiD logo [1]
  1. Shenzhen Polytechnic (China)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1581611
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Crystal Growth and Design
Additional Journal Information:
Journal Volume: 19; Journal Issue: 12; Journal ID: ISSN 1528-7483
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; phosphors; ligands; metal organic frameworks; chromophores energy

Citation Formats

Yu, Liang, Wang, Hao, Liu, Wei, Teat, Simon J., and Li, Jing. Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores. United States: N. p., 2019. Web. doi:10.1021/acs.cgd.9b01284.
Yu, Liang, Wang, Hao, Liu, Wei, Teat, Simon J., & Li, Jing. Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores. United States. https://doi.org/10.1021/acs.cgd.9b01284
Yu, Liang, Wang, Hao, Liu, Wei, Teat, Simon J., and Li, Jing. Mon . "Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores". United States. https://doi.org/10.1021/acs.cgd.9b01284. https://www.osti.gov/servlets/purl/1581611.
@article{osti_1581611,
title = {Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores},
author = {Yu, Liang and Wang, Hao and Liu, Wei and Teat, Simon J. and Li, Jing},
abstractNote = {Here, we demonstrate that two new zirconium-based metal-organic frameworks can be constructed from organic chromophore ligands. Both compounds show intense yellow emission when excited by blue light, with a notable fluorescence red shift and quantum yield enhancement compared to the organic chromophore.},
doi = {10.1021/acs.cgd.9b01284},
journal = {Crystal Growth and Design},
number = 12,
volume = 19,
place = {United States},
year = {2019},
month = {10}
}

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