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Title: Designed asymmetric coordination helicates with bis-β-diketonate ligands

Journal Article · · Dalton Transactions
DOI: https://doi.org/10.1039/c9dt03398j · OSTI ID:1581609
 [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]; ORCiD logo [1]
  1. Univ. de Barcelona (Spain)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  3. Univ. de Zaragoza (Spain)
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A new bis-(β-diketone) ligand featuring built-up structural asymmetry yields non-symmetric Fe(III) and Ga(III) dinuclear, triple-stranded helicates by design. Their structural properties have been studied, both in solid state and in solution, and compared with their corresponding symmetric analogues. Finally, the robustness observed shows the potential of this synthetic strategy to develop non-symmetric helicoidal motifs with specific functional groups.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1581609
Alternate ID(s):
OSTI ID: 1573076
Journal Information:
Dalton Transactions, Vol. 48, Issue 45; ISSN 1477-9226
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

References (24)

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Linked Research (4)

Figures / Tables (5)

Figure 1(p. 2)figure Figure 1
Scheme 1(p. 2)figure Scheme 1
Table 1(p. 3)table Table 1
Scheme 2(p. 4)figure Scheme 2
Figure 2(p. 5)figure Figure 2

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