Controlled Heterometallic Composition in Linear Trinuclear [LnCeLn] Lanthanide Molecular Assemblies
Abstract
Here, the combination of two different β-diketone ligands facilitates the size-controlled assembly of pure heterometallic [LnLn'Ln] linear compounds thanks to two different coordination sites present in the molecular scaffold. [HoCeHo], [ErCeEr], and [YbCeYb] analogues are presented here and are characterized both in the solid state and in solution, demonstrating the selectivity of this unique method to produce heterometallic 4f molecular entities.
- Authors:
-
[2];
[1];
[1]
- University of Barcelona (Spain)
- Univ. de Zaragoza (Spain)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1581608
- Alternate Identifier(s):
- OSTI ID: 1571306
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Volume: 25; Journal Issue: 67; Journal ID: ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; coordination chemistry; heterometallic complexes; lanthanides; ligand design; quantum computing
Citation Formats
Velasco, Verónica, Barrios, Leoní A., Schütze, Mike, Roubeau, Olivier, Luis, Fernando, Teat, Simon J., Aguilà, David, and Aromí, Guillem. Controlled Heterometallic Composition in Linear Trinuclear [LnCeLn] Lanthanide Molecular Assemblies. United States: N. p., 2019.
Web. doi:10.1002/chem.201903829.
Velasco, Verónica, Barrios, Leoní A., Schütze, Mike, Roubeau, Olivier, Luis, Fernando, Teat, Simon J., Aguilà, David, & Aromí, Guillem. Controlled Heterometallic Composition in Linear Trinuclear [LnCeLn] Lanthanide Molecular Assemblies. United States. https://doi.org/10.1002/chem.201903829
Velasco, Verónica, Barrios, Leoní A., Schütze, Mike, Roubeau, Olivier, Luis, Fernando, Teat, Simon J., Aguilà, David, and Aromí, Guillem. Tue .
"Controlled Heterometallic Composition in Linear Trinuclear [LnCeLn] Lanthanide Molecular Assemblies". United States. https://doi.org/10.1002/chem.201903829. https://www.osti.gov/servlets/purl/1581608.
@article{osti_1581608,
title = {Controlled Heterometallic Composition in Linear Trinuclear [LnCeLn] Lanthanide Molecular Assemblies},
author = {Velasco, Verónica and Barrios, Leoní A. and Schütze, Mike and Roubeau, Olivier and Luis, Fernando and Teat, Simon J. and Aguilà, David and Aromí, Guillem},
abstractNote = {Here, the combination of two different β-diketone ligands facilitates the size-controlled assembly of pure heterometallic [LnLn'Ln] linear compounds thanks to two different coordination sites present in the molecular scaffold. [HoCeHo], [ErCeEr], and [YbCeYb] analogues are presented here and are characterized both in the solid state and in solution, demonstrating the selectivity of this unique method to produce heterometallic 4f molecular entities.},
doi = {10.1002/chem.201903829},
journal = {Chemistry - A European Journal},
number = 67,
volume = 25,
place = {United States},
year = {2019},
month = {9}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 1 work
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Synthesis and characterization of dinuclear heterometallic lanthanide complexes exhibiting MRI and luminescence response
journal, January 2010
- Mamedov, Ilgar; Parac-Vogt, Tatjana N.; Logothetis, Nikos K.
- Dalton Transactions, Vol. 39, Issue 24
Selective Lanthanide Distribution within a Comprehensive Series of Heterometallic [LnPr] Complexes
journal, June 2018
- Aguilà, David; Velasco, Verónica; Barrios, Leoní A.
- Inorganic Chemistry, Vol. 57, Issue 14
A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit
journal, July 2017
- Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong
- Angewandte Chemie International Edition, Vol. 56, Issue 38
Purely Heterometallic Lanthanide(III) Macrocycles through Controlled Assembly of Disulfide Bonds for Dual Color Emission
journal, February 2011
- Lewis, David J.; Glover, Peter B.; Solomons, Melissa C.
- Journal of the American Chemical Society, Vol. 133, Issue 4
Electron-Donating Alkoxy-Group-Driven Synthesis of Heteroleptic Tris(phthalocyaninato) Lanthanide(III) Triple-Deckers with Symmetrical Molecular Structure
journal, February 2005
- Zhu, Peihua; Pan, Na; Li, Renjie
- Chemistry - A European Journal, Vol. 11, Issue 5
Molecular magnetic hysteresis at 60 kelvin in dysprosocenium
journal, August 2017
- Goodwin, Conrad A. P.; Ortu, Fabrizio; Reta, Daniel
- Nature, Vol. 548, Issue 7668
Self-assembly between dicarboxylate ions and a binuclear europium complex: formation of stable adducts and heterometallic lanthanide complexes
journal, January 2011
- Tilney, James A.; Sørensen, Thomas Just; Burton-Pye, Benjamin P.
- Dalton Transactions, Vol. 40, Issue 45
Using lanthanide ions in molecular bioimaging
journal, January 2015
- Amoroso, Angelo J.; Pope, Simon J. A.
- Chemical Society Reviews, Vol. 44, Issue 14
Synthesis and Properties of a Family of Unsymmetric Dinuclear Complexes of Ln III (Ln = Eu, Gd, Tb)
journal, August 2010
- Aguilà, David; Barrios, Leoní A.; Luis, Fernando
- Inorganic Chemistry, Vol. 49, Issue 15
Synthesis and Spectroscopic Studies on Azo-Dye Derivatives of Polymetallic Lanthanide Complexes: Using Diazotization to Link Metal Complexes Together
journal, July 2009
- Placidi, Matteo P.; Villaraza, Aaron Joseph L.; Natrajan, Louise S.
- Journal of the American Chemical Society, Vol. 131, Issue 29
A Metal-Organic Framework as Attractive Cryogenic Magnetorefrigerant
journal, August 2012
- Sibille, Romain; Mazet, Thomas; Malaman, Bernard
- Chemistry - A European Journal, Vol. 18, Issue 41
Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal–organic frameworks
journal, January 2012
- Lorusso, Giulia; Palacios, Maria A.; Nichol, Gary S.
- Chemical Communications, Vol. 48, Issue 61
Unequivocal Synthetic Pathway to Heterodinuclear (4f,4f′) Complexes: Magnetic Study of Relevant (LnIII, GdIII) and (GdIII, LnIII) Complexes
journal, August 2002
- Costes, Jean-Pierre; Nicodème, Franck
- Chemistry - A European Journal, Vol. 8, Issue 15
A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit
journal, July 2017
- Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong
- Angewandte Chemie, Vol. 129, Issue 38
Molecular spin qubits based on lanthanide ions encapsulated in cubic polyoxopalladates: design criteria to enhance quantum coherence
journal, January 2015
- Baldoví, José J.; Rosaleny, Lorena E.; Ramachandran, Vasanth
- Inorganic Chemistry Frontiers, Vol. 2, Issue 10
Supramolecular Recognition of Heteropairs of Lanthanide Ions: A Step toward Self-Assembled Bifunctional Probes
journal, January 2004
- André, Nicolas; Jensen, Thomas B.; Scopelliti, Rosario
- Inorganic Chemistry, Vol. 43, Issue 2
Coherent Manipulation of a Molecular Ln-Based Nuclear Qudit Coupled to an Electron Qubit
journal, July 2018
- Hussain, Riaz; Allodi, Giuseppe; Chiesa, Alessandro
- Journal of the American Chemical Society, Vol. 140, Issue 31
Indium-Catalyzed Retro-Claisen Condensation
journal, October 2007
- Kawata, Atsushi; Takata, Kazumi; Kuninobu, Yoichiro
- Angewandte Chemie International Edition, Vol. 46, Issue 41
Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level
journal, July 2003
- Ishikawa, Naoto; Sugita, Miki; Ishikawa, Tadahiko
- Journal of the American Chemical Society, Vol. 125, Issue 29
A Long Journey in Lanthanide Chemistry: From Fundamental Crystallogenesis Studies to Commercial Anticounterfeiting Taggants
journal, April 2016
- Guillou, Olivier; Daiguebonne, Carole; Calvez, Guillaume
- Accounts of Chemical Research, Vol. 49, Issue 5
Structure-Based Description of a Step-by-Step Synthesis of Homo- and Heterodinuclear (4f, 4f ‘) Lanthanide Complexes
journal, October 2003
- Costes, Jean-Pierre; Dahan, Françoise; Nicodème, Franck
- Inorganic Chemistry, Vol. 42, Issue 20
Molecular Prototypes for Spin-Based CNOT and SWAP Quantum Gates
journal, September 2011
- Luis, F.; Repollés, A.; Martínez-Pérez, M. J.
- Physical Review Letters, Vol. 107, Issue 11
Toward Molecular 4f Single-Ion Magnet Qubits
journal, April 2016
- Pedersen, Kasper S.; Ariciu, Ana-Maria; McAdams, Simon
- Journal of the American Chemical Society, Vol. 138, Issue 18
Thermodynamic Stability of Heterodimetallic [LnLn′] Complexes: Synthesis and DFT Studies
journal, March 2017
- Gónzalez-Fabra, Joan; Bandeira, Nuno A. G.; Velasco, Verónica
- Chemistry - A European Journal, Vol. 23, Issue 21
Shape maps and polyhedral interconversion paths in transition metal chemistry
journal, September 2005
- Alvarez, S.; Alemany, P.; Casanova, D.
- Coordination Chemistry Reviews, Vol. 249, Issue 17-18
Revised Ionic Radii of Lanthanoid(III) Ions in Aqueous Solution
journal, May 2011
- D’Angelo, Paola; Zitolo, Andrea; Migliorati, Valentina
- Inorganic Chemistry, Vol. 50, Issue 10
A two-qubit molecular architecture for electron-mediated nuclear quantum simulation
journal, January 2018
- Atzori, Matteo; Chiesa, Alessandro; Morra, Elena
- Chemical Science, Vol. 9, Issue 29
A near-infrared organic light-emitting diode based on an Yb( iii ) complex synthesized by vacuum co-deposition
journal, January 2017
- Jinnai, Kazuya; Kabe, Ryota; Adachi, Chihaya
- Chemical Communications, Vol. 53, Issue 39
Magnetic interplay between two different lanthanides in a tris-phthalocyaninato complex: a viable synthetic route and detailed investigation in the bulk and on the surface
journal, January 2015
- Lan, Yanhua; Klyatskaya, Svetlana; Ruben, Mario
- Journal of Materials Chemistry C, Vol. 3, Issue 38
Indium-Catalyzed Retro-Claisen Condensation
journal, October 2007
- Kawata, Atsushi; Takata, Kazumi; Kuninobu, Yoichiro
- Angewandte Chemie, Vol. 119, Issue 41
Design of magnetic coordination complexes for quantum computing
journal, January 2012
- Aromí, Guillem; Aguilà, David; Gamez, Patrick
- Chem. Soc. Rev., Vol. 41, Issue 2
Upconversion Luminescent Materials: Advances and Applications
journal, November 2014
- Zhou, Jing; Liu, Qian; Feng, Wei
- Chemical Reviews, Vol. 115, Issue 1
Heterodinuclear Lanthanoid-Containing Polyoxometalates: Stepwise Synthesis and Single-Molecule Magnet Behavior
journal, September 2013
- Sato, Rinta; Suzuki, Kosuke; Sugawa, Midori
- Chemistry - A European Journal, Vol. 19, Issue 39
Programming Heteropolymetallic Lanthanide Helicates: Thermodynamic Recognition of Different Metal Ions Along the Strands
journal, March 2004
- Floquet, Sébastien; Borkovec, Michal; Bernardinelli, Gérald
- Chemistry - A European Journal, Vol. 10, Issue 5
Unusual Crystal Packing in a Family of [Fe{2,6-bis(pyrazol-3-yl)pyridine} 2 ] 2+ Compounds and the Effect on the Occurrence of Spin Crossover and Its Cooperative Character : Crystal Packing in [Fe{2,6-bis(pyrazol-3-yl)pyridine}
journal, November 2014
- Barrios, Leoní A.; Peyrecave-Lleixà, Eugènia; Craig, Gavin A.
- European Journal of Inorganic Chemistry, Vol. 2014, Issue 35
Cryogenic Magnetocaloric Effect in a Ferromagnetic Molecular Dimer
journal, June 2011
- Evangelisti, Marco; Roubeau, Olivier; Palacios, Elias
- Angewandte Chemie, Vol. 123, Issue 29
Cryogenic Magnetocaloric Effect in a Ferromagnetic Molecular Dimer
journal, June 2011
- Evangelisti, Marco; Roubeau, Olivier; Palacios, Elias
- Angewandte Chemie International Edition, Vol. 50, Issue 29
Lanthanide Contraction within a Series of Asymmetric Dinuclear [Ln 2 ] Complexes
journal, March 2013
- Aguilà, David; Barrios, Leoní A.; Velasco, Verónica
- Chemistry - A European Journal, Vol. 19, Issue 19
Heterodimetallic [LnLn′] Lanthanide Complexes: Toward a Chemical Design of Two-Qubit Molecular Spin Quantum Gates
journal, August 2014
- Aguilà, David; Barrios, Leoní A.; Velasco, Verónica
- Journal of the American Chemical Society, Vol. 136, Issue 40
An Efficient Iron-Catalyzed Carbon-Carbon Single-Bond Cleavage via Retro-Claisen Condensation: A Mild and Convenient Approach to Synthesize a Variety of Esters or Ketones
journal, April 2010
- Biswas, Srijit; Maiti, Sukhendu; Jana, Umasish
- European Journal of Organic Chemistry, Vol. 2010, Issue 15
Controlled preparation of a heterometallic lanthanide complex containing different lanthanides in symmetrical binding pockets
journal, January 2009
- Natrajan, Louise S.; Villaraza, Aaron Joseph L.; Kenwright, Alan M.
- Chemical Communications, Issue 40
Lanthanide-Sensitized Lanthanide Luminescence: Terbium-Sensitized Ytterbium Luminescence in a Trinuclear Complex
journal, September 2003
- Faulkner, Stephen; Pope, Simon J. A.
- Journal of the American Chemical Society, Vol. 125, Issue 35
Discriminating between lanthanide ions: self-assembly of heterodimetallic triple-stranded helicates
journal, January 2002
- André, Nicolas; Scopelliti, Rosario; Hopfgartner, Gérard
- Chemical Communications, Issue 3
Lanthanide Single-Molecule Magnets
journal, March 2013
- Woodruff, Daniel N.; Winpenny, Richard E. P.; Layfield, Richard A.
- Chemical Reviews, Vol. 113, Issue 7
Magnetic interplay between two different lanthanides in a tris-phthalocyaninato complex: a viable synthetic route and detailed investigation in the bulk and on the surface
text, January 2015
- Lan, Y.; Klyatskaya, S.; Ruben, M.
- Karlsruhe