Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols

Cook, Andrew W.; Jones, Zachary R.; Wu, Guang; Teat, Simon J.; Scott, Susannah L.; Hayton, Trevor W.

doi:10.1021/acs.inorgchem.9b01140

Title: Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu²⁺ with Thiols

Journal Article · 13 June 2019 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.9b01140 · OSTI ID:1581349

Cook, Andrew W. ^[1]; Jones, Zachary R. ^[1]; Wu, Guang ^[1]; Teat, Simon J. ^[2];

^[1];

^[1]

Univ. of California, Santa Barbara, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Thiolates are a widely used ligand class for the stabilization of M(0)-containing gold and silver nanoclusters. Curiously, though, very few thiolate-stabilized Cu nanoclusters are known. Herein, we report an examination of the reactivity of RSH (R = CH₂CH₂Ph, n-Bu, n-C₁₂H₂₅) with Cu²⁺ under anhydrous conditions. These reactions result in the formation of fluorescent "Atlas-sphere"-type copper thiolate nanoclusters, including [Cu₁₂(SR')₆Cl₁₂][(Cu(R'SH))₆] (2, R' = ⁿBu) and [H(THF)₂]₂[Cu₁₇(SR'')₆Cl₁₃(THF)₂(R''SH)₃] (3, R'' = CH₂CH₂Ph), which were characterized by X-ray crystallography, electrospray ionization mass spectrometry, NMR spectroscopy, as well as X-ray absorption near-edge structure and extended X-ray absorption fine structure (EXAFS) spectroscopies. Consistent with our X-ray crystallographic results, the edge energies of 2 and 3 suggest they are constructed exclusively with Cu(I) ions. Likewise, EXAFS of 2 and 3 reveals long Cu-Cu pathlengths, which is also consistent with their X-ray crystal structures. Given these results, as well as past work on Cu²⁺/thiol reactivity, we suggest that Cu(0) is unlikely to be formed by the reaction of Cu²⁺ with a thiol and that previous reports of Cu(0)-containing nanoclusters synthesized by reaction of Cu²⁺ with thiols are likely erroneous.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)

Grant/Contract Number:: AC02-05CH11231; FG02-03ER15467

OSTI ID:: 1581349

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 13 Vol. 58; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (85)

Ether-Soluble Cu ₅₃ Nanoclusters as an Effective Precursor of High-Quality CuI Films for Optoelectronic Applications Yuan, Peng; Chen, Ruihao; Zhang, Xiaomin Angewandte Chemie International Edition, Vol. 58, Issue 3 https://doi.org/10.1002/anie.201812236	journal	December 2018
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure Ankudinov, A. L.; Ravel, B.; Rehr, J. J. Physical Review B, Vol. 58, Issue 12 https://doi.org/10.1103/PhysRevB.58.7565	journal	September 1998
Synthesis and Structures of Cuprous Triptycylthiolate Complexes Ferrara, Skylar J.; Mague, Joel T.; Donahue, James P. Inorganic Chemistry, Vol. 51, Issue 12 https://doi.org/10.1021/ic300124n	journal	April 2012
Synthesis, characterization and crystal structure of copper(I) thiolates: [(C6H5)4P+]2[Cu4(C2H5S−)6]·0.5C2H6O2 and [(C6H5)4P+][Cu7(C2H5S−)8] Baumgartner, Markus; Schmalle, Helmut; Dubler, Erich Polyhedron, Vol. 9, Issue 9 https://doi.org/10.1016/S0277-5387(00)86890-4	journal	January 1990
Self-Assembly Driven Aggregation-Induced Emission of Copper Nanoclusters: A Novel Technology for Lighting Liu, Yi; Yao, Dong; Zhang, Hao ACS Applied Materials & Interfaces, Vol. 10, Issue 15 https://doi.org/10.1021/acsami.7b13940	journal	November 2017
Self-assembly of 1D Coordination Polymers Containing Copper(I) tert-butylthiolato Clusters: Structural Characterization and Properties Li, Zhihua; Li, Xiuling; Lin, Ping Journal of Cluster Science, Vol. 19, Issue 2 https://doi.org/10.1007/s10876-007-0161-6	journal	November 2007
Crystal Structure of the Gold Nanoparticle [N(C ₈ H ₁₇ ) ₄ ][Au ₂₅ (SCH ₂ CH ₂ Ph) ₁₈ ] Heaven, Michael W.; Dass, Amala; White, Peter S. Journal of the American Chemical Society, Vol. 130, Issue 12 https://doi.org/10.1021/ja800561b	journal	March 2008
Self-Assembly of Nanometer-Scale [Cu24I10L12]14+ Cages and Ball-Shaped Keggin Clusters into a (4,12)-Connected 3D Framework with Photoluminescent and Electrochemical Properties Wang, Xin-Long; Qin, Chao; Wang, En-Bo Angewandte Chemie International Edition, Vol. 45, Issue 44 https://doi.org/10.1002/anie.200603250	journal	November 2006
All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures Yang, Huayan; Wang, Yu; Huang, Huaqi Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3422	journal	September 2013
Coordination chemistry of sterically hindered thiolate ligands. Preparation and structural characterization of the oligomeric homoleptic complexes [o-trimethylsilylbenzenethiolato]copper dodecamer and [o-trimethylsilylbenzenethiolato]silver octamer and a comparison to the structure of the cadmium mononuclear species (Et4N)2[Cd(SC6H4-o-SiMe3)4] Block, Eric; Gernon, Michael; Kang, Hyunkyu Inorganic Chemistry, Vol. 28, Issue 7 https://doi.org/10.1021/ic00306a013	journal	April 1989
The formation and crystal and molecular structures of hexa(μ-organothiolato)tetracuprate(I) cage dianions: bis-(tetramethylammonium)hexa-(μ-methanethiolato)tetracuprate(I) and two polymorphs of bis(tetramethylammonium)hexa-(μ-benzenethiolato)-tetracuprate(I) Dance, Ian G.; Bowmaker, Graham A.; Clark, George R. Polyhedron, Vol. 2, Issue 10 https://doi.org/10.1016/S0277-5387(00)81450-3	journal	January 1983
The isomeric effect of mercaptobenzoic acids on the preparation and fluorescence properties of copper nanoclusters Lin, Yi-Jyun; Chen, Po-Cheng; Yuan, Zhiqin Chemical Communications, Vol. 51, Issue 60 https://doi.org/10.1039/C5CC02342D	journal	January 2015
Preparation, Spectroscopic Characterization, and Molecular Structure of Copper(I) Aliphatic Thiolate Complexes Fujisawa, Kiyoshi; Imai, Sadako; Kitajima, Nobumasa Inorganic Chemistry, Vol. 37, Issue 2 https://doi.org/10.1021/ic971317b	journal	January 1998
Luminescence in Phosphine-Stabilized Copper Chalcogenide Cluster Molecules—A Comparative Study Eichhöfer, Andreas; Buth, Gernot; Lebedkin, Sergei Inorganic Chemistry, Vol. 54, Issue 19 https://doi.org/10.1021/acs.inorgchem.5b01146	journal	August 2015
Assembly-Induced Enhancement of Cu Nanoclusters Luminescence with Mechanochromic Property Wu, Zhennan; Liu, Jiale; Gao, Yang Journal of the American Chemical Society, Vol. 137, Issue 40 https://doi.org/10.1021/jacs.5b06550	journal	September 2015
Luminescent Thermochromism of 2D Coordination Polymers Based on Copper(I) Halides with 4-Hydroxythiophenol Troyano, Javier; Perles, Josefina; Amo-Ochoa, Pilar Chemistry - A European Journal, Vol. 22, Issue 50 https://doi.org/10.1002/chem.201603675	journal	November 2016
Emergence of hierarchical structural complexities in nanoparticles and their assembly Zeng, Chenjie; Chen, Yuxiang; Kirschbaum, Kristin Science, Vol. 354, Issue 6319 https://doi.org/10.1126/science.aak9750	journal	December 2016
Molecular Structure of the Solvated Proton in Isolated Salts. Short, Strong, Low Barrier (SSLB) H-bonds Stasko, Daniel; Hoffmann, Stephan P.; Kim, Kee-Chan Journal of the American Chemical Society, Vol. 124, Issue 46 https://doi.org/10.1021/ja012671i	journal	November 2002
An Organometallic Cu ₂₀ Nanocluster: Synthesis, Characterization, Immobilization on Silica, and “Click” Chemistry Cook, Andrew W.; Jones, Zachary R.; Wu, Guang Journal of the American Chemical Society, Vol. 140, Issue 1 https://doi.org/10.1021/jacs.7b10960	journal	December 2017
Luminescence of copper(I) arenethiolates and its relation to copper(I) luminescence in other complexes Knotter, D. Martin; Blasse, George; Van Vliet, Jacques P. M. Inorganic Chemistry, Vol. 31, Issue 11 https://doi.org/10.1021/ic00037a038	journal	May 1992
Crystal Structure of Faradaurate-279: Au ₂₇₉ (SPh- t Bu) ₈₄ Plasmonic Nanocrystal Molecules Sakthivel, Naga Arjun; Theivendran, Shevanuja; Ganeshraj, Vigneshraja Journal of the American Chemical Society, Vol. 139, Issue 43 https://doi.org/10.1021/jacs.7b08651	journal	October 2017
The hepta(µ ₂ -benzenethiolato)pentacuprate( I ) dianion; X-ray crystal and molecular structure Dance, Ian G. J. Chem. Soc., Chem. Commun., Issue 3 https://doi.org/10.1039/C3976000103B	journal	January 1976
Ambient Synthesis of Au ₁₄₄ (SR) ₆₀ Nanoclusters in Methanol Qian, Huifeng; Jin, Rongchao Chemistry of Materials, Vol. 23, Issue 8 https://doi.org/10.1021/cm200143s	journal	April 2011
Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U–I bond Schnaars, David D.; Wu, Guang; Hayton, Trevor W. Dalton Transactions, Issue 19 https://doi.org/10.1039/b823002a	journal	January 2009
Synthesis and Characterization of a Cu ₁₄ Hydride Cluster Supported by Neutral Donor Ligands Nguyen, Thuy-Ai D.; Goldsmith, Bryan R.; Zaman, Homaira T. Chemistry - A European Journal, Vol. 21, Issue 14 https://doi.org/10.1002/chem.201500422	journal	February 2015
Crystallization and structure of bis(tetramethylammonium) octakis(benzenethiolato)hexaargentate(I), extending the series of cages [M4(SPh)6]2-, [M5(SPh)7]2-, [M6(SPh)8]2-, and [M12(SPh)16]4- Dance, Ian G. Inorganic Chemistry, Vol. 20, Issue 5 https://doi.org/10.1021/ic50219a031	journal	May 1981
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes Brookhart, M.; Grant, B.; Volpe, A. F. Organometallics, Vol. 11, Issue 11 https://doi.org/10.1021/om00059a071	journal	November 1992
Red-luminescent biphosphine stabilized ‘Cu ₁₂ S ₆ ’ cluster molecules Yang, Xiao-Xun; Issac, Ibrahim; Lebedkin, Sergej Chemical Communications, Vol. 50, Issue 75 https://doi.org/10.1039/C4CC04702H	journal	January 2014
Twelve-Connected Net with Face-Centered Cubic Topology: A Coordination Polymer Based on [Cu12(μ4-SCH3)6]6+ Clusters and CN− Linkers Li, Dan; Wu, Tao; Zhou, Xiao-Ping Angewandte Chemie International Edition, Vol. 44, Issue 27 https://doi.org/10.1002/anie.200500290	journal	July 2005
Self-assembling copper(I) clusters involving electron-deficient, quadruply bridging thiolate ligands Prichard, Robin G.; Parish, R. V.; Salehi, Zahra Journal of the Chemical Society, Dalton Transactions, Issue 2 https://doi.org/10.1039/a808125e	journal	January 1999
A Cu ₂₅ Nanocluster with Partial Cu(0) Character Nguyen, Thuy-Ai D.; Jones, Zachary R.; Goldsmith, Bryan R. Journal of the American Chemical Society, Vol. 137, Issue 41 https://doi.org/10.1021/jacs.5b07574	journal	October 2015
Synthese und Struktur von Thiolatokomplexen des einwertigen Kupfers: Tetrameres und Octameres [CuSC ₆ H ₂ (i-Pr) ₃ ] / Synthesis and Structure of Thiolato Complexes of Monovalent Copper: Tetrameric and Octameric [CuSC ₆ H ₂ (i-Pr) ₃ ] Schröter-Schmid, Ingrid; Strähle, Joachim Zeitschrift für Naturforschung B, Vol. 45, Issue 11 https://doi.org/10.1515/znb-1990-1113	journal	November 1990
A Mixed (Arenethiolato)copper(I)/Copper Bromide Aggregate: X-ray Structure of Octanuclear [Cu ₈ {SC ₆ H ₃ (CH ₂ NMe ₂ ) ₂ -2,6} ₃ Br ₅ ] Janssen, Maurits D.; Spek, Anthony L.; Grove, David M. Inorganic Chemistry, Vol. 35, Issue 13 https://doi.org/10.1021/ic9515315	journal	January 1996
Flexible CuI–Thiolate Clusters with Relevance to Metallothioneins Maiti, Biplab K.; Pal, Kuntal; Sarkar, Sabyasachi European Journal of Inorganic Chemistry, Vol. 2007, Issue 35 https://doi.org/10.1002/ejic.200700784	journal	December 2007
The Hepta(μ-benzenethiolato)pentametallate(I) dianions of copper and silver: Formation and crystal structures Dance, Ig Australian Journal of Chemistry, Vol. 31, Issue 10 https://doi.org/10.1071/CH9782195	journal	January 1978
Standard Electrode Potentials and Temperature Coefficients in Water at 298.15 K Bratsch, Steven G. Journal of Physical and Chemical Reference Data, Vol. 18, Issue 1 https://doi.org/10.1063/1.555839	journal	January 1989
Steric control of aggregation in neutral silver(I) thiolates, [AgSR]n. Crystal and molecular structures of [AgSCH(SiMe3)2]8, a discrete molecular biscycle of weakly interacting [AgSCH(SiMe3)2]4 units, and of [AgSC(SiPhMe2)3]3 and [AgSC(SiMe3)3]4, discrete molecular monocycles containing linearly coordinated silver(I) and doubly bridging mercapto sulfur donors from novel sterically hindered thiolate ligands. A comparison with the nonmolecular structure of [Ag4{SCH2(SiMe3)}3]n1 Tang, Kaluo; Aslam, Mohammad; Block, Eric Inorganic Chemistry, Vol. 26, Issue 10 https://doi.org/10.1021/ic00257a007	journal	May 1987
Ultrastable silver nanoparticles Desireddy, Anil; Conn, Brian E.; Guo, Jingshu Nature, Vol. 501, Issue 7467 https://doi.org/10.1038/nature12523	journal	September 2013
Metal-mercaptide chemistry. The synthesis and structural characterization of the [Cu(SC6H5)3]2- anion. A rational synthesis and the structure of the [Cu4(SC6H5)6]2- cluster Coucouvanis, D.; Murphy, C. N.; Kanodia, S. K. Inorganic Chemistry, Vol. 19, Issue 10 https://doi.org/10.1021/ic50212a030	journal	October 1980
Engineering a red emission of copper nanocluster self-assembly architectures by employing aromatic thiols as capping ligands Ai, Lin; Jiang, Wanrun; Liu, Zhaoyu Nanoscale, Vol. 9, Issue 34 https://doi.org/10.1039/C7NR03985A	journal	January 2017
Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag ₆ H ₄ (dppm) ₄ (OAc) ₂ ] and [Cu ₃ H(dppm) ₃ (OAc) ₂ ] Cook, Andrew W.; Nguyen, Thuy-Ai D.; Buratto, William R. Inorganic Chemistry, Vol. 55, Issue 23 https://doi.org/10.1021/acs.inorgchem.6b02385	journal	November 2016
Solvates of Manganese Trichloride Revisited - Synthesis, Isolation, and Crystal Structure of MnCl ₃ (THF) ₃: Solvates of Manganese Trichloride Revisited Nachtigall, Olaf; Pataki, Astrid; Molski, Matthias Zeitschrift für anorganische und allgemeine Chemie, Vol. 641, Issue 6 https://doi.org/10.1002/zaac.201500106	journal	March 2015
[Cu ₁₃ {S ₂ CN ⁿ Bu ₂ } ₆ (acetylide) ₄ ] ⁺ : A Two-Electron Superatom Chakrahari, Kiran Kumarvarma; Liao, Jian-Hong; Kahlal, Samia Angewandte Chemie International Edition, Vol. 55, Issue 47 https://doi.org/10.1002/anie.201608609	journal	October 2016
Synthesis, optical properties and applications of light-emitting copper nanoclusters Wang, Zhenguang; Chen, Bingkun; Rogach, Andrey L. Nanoscale Horizons, Vol. 2, Issue 3 https://doi.org/10.1039/C7NH00013H	journal	January 2017
Preparation, Structure and Reactivity of Polynuclear Gold(I) Phosphanyl Alkanethiolates Battisti, Antonella; Bellina, Oliver; Diversi, Pietro European Journal of Inorganic Chemistry, Vol. 2007, Issue 6 https://doi.org/10.1002/ejic.200600939	journal	February 2007
Luminescence in Functionalized Copper Thiolate Clusters - Synthesis and Structural Effects Langer, Robert; Yadav, Munendra; Weinert, Bastian European Journal of Inorganic Chemistry, Vol. 2013, Issue 21 https://doi.org/10.1002/ejic.201300155	journal	June 2013
The formation and structural chemistry of the hexa(μ-t-butylthiolato) pentacuprate(I) cage anion with triethylammonium and tetraethylammonium cations Bowmaker, Graham A.; Clark, George R.; Seadon, Jeffrey K. Polyhedron, Vol. 3, Issue 5 https://doi.org/10.1016/S0277-5387(00)88084-5	journal	January 1984
Contribution of Metal Defects in the Assembly Induced Emission of Cu Nanoclusters Wu, Zhennan; Liu, Huiwen; Li, Tingting Journal of the American Chemical Society, Vol. 139, Issue 12 https://doi.org/10.1021/jacs.7b00773	journal	March 2017
One-Pot Synthesis, Photoluminescence, and Electrocatalytic Properties of Subnanometer-Sized Copper Clusters Wei, Wentao; Lu, Yizhong; Chen, Wei Journal of the American Chemical Society, Vol. 133, Issue 7 https://doi.org/10.1021/ja109303z	journal	February 2011
The crystal and molecular structure of a tetranuclear copper thiolate cluster, [Cu{SC6H3-2,6-(SiMe3)2}]4 Block, Eric; Kang, Hyunkyu; Ofori-Okai, Gabriel Inorganica Chimica Acta, Vol. 167, Issue 2 https://doi.org/10.1016/S0020-1693(00)80489-2	journal	January 1990
Subnanometer-Sized Copper Clusters: A Critical Re-evaluation of the Synthesis and Characterization of Cu ₈ (MPP) ₄ (HMPP = 2-Mercapto-5- n -propylpyrimidine) Nguyen, Thuy-Ai D.; Cook, Andrew W.; Wu, Guang Inorganic Chemistry, Vol. 56, Issue 14 https://doi.org/10.1021/acs.inorgchem.7b01062	journal	June 2017
[Ag ₂₅ (SR) ₁₈ ] ⁻ : The “Golden” Silver Nanoparticle Joshi, Chakra P.; Bootharaju, Megalamane S.; Alhilaly, Mohammad J. Journal of the American Chemical Society, Vol. 137, Issue 36 https://doi.org/10.1021/jacs.5b07088	journal	September 2015
Chlorotripyridinecopper(I) Scholz, Stefan; Lerner, Hans-Wolfram; Bolte, Michael Acta Crystallographica Section E Structure Reports Online, Vol. 58, Issue 2 https://doi.org/10.1107/S1600536802001630	journal	January 2002
A polymeric cationic copper(I) complex involving a quadruply bridging, zwitterionic thiolate ligand: {[Cu8Cl6(SCH2CH2NH3)6]Cl2}n Salehi, Zahra; Parish, R. V.; Pritchard, Robin G. Journal of the Chemical Society, Dalton Transactions, Issue 22 https://doi.org/10.1039/a705217k	journal	January 1997
Model studies on the coordination of copper in enzymes. IV. Structure and stability of cuprous complexes with sulfur-containing ligands Vortisch, V.; Kroneck, P.; Hemmerich, P. Journal of the American Chemical Society, Vol. 98, Issue 10 https://doi.org/10.1021/ja00426a025	journal	May 1976
The photoluminescence properties of the copper(I) clusters Cu4I4A4 (A = aromatic amine) in solution Kyle, Kevin R.; Palke, William E.; Ford, Peter C. Coordination Chemistry Reviews, Vol. 97 https://doi.org/10.1016/0010-8545(90)80078-8	journal	January 1990
Mössbauer and nuclear magnetic resonance spectroscopic studies on ‘Myocrisin’, ‘Solganol’, ‘Auranofin’, and related gold( I ) thiolates Al-Sa'ady, Ali K. H.; Moss, Karen; McAuliffe, Charles A. J. Chem. Soc., Dalton Trans., Issue 8 https://doi.org/10.1039/DT9840001609	journal	January 1984
Correlating the Crystal Structure of A Thiol-Protected Au₂₅ Cluster and Optical Properties Zhu, Manzhou; Aikens, Christine M.; Hollander, Frederick J. Journal of the American Chemical Society, Vol. 130, Issue 18, p. 5883-5885 https://doi.org/10.1021/ja801173r	journal	May 2008
Photochemical and photophysical properties of tetranuclear and hexanuclear clusters of metals with d10 and s2 electronic configurations Ford, Peter C.; Vogler, Arnd Accounts of Chemical Research, Vol. 26, Issue 4 https://doi.org/10.1021/ar00028a013	journal	April 1993
Thiolato-complexes of the transition metals Blower, P. J.; Dilworth, J. R. Coordination Chemistry Reviews, Vol. 76 https://doi.org/10.1016/0010-8545(87)85003-8	journal	February 1987
Synthesis and X-ray crystal structure of [Cu(SC6H2Pri 3)]8 Yang, Qingchuan; Tang, Kaluo; Liao, Hua Journal of the Chemical Society, Chemical Communications, Issue 14 https://doi.org/10.1039/c39870001076	journal	January 1987
Photoluminescence Properties of Multinuclear Copper(I) Compounds Ford, Peter C.; Cariati, Elena; Bourassa, James Chemical Reviews, Vol. 99, Issue 12 https://doi.org/10.1021/cr960109i	journal	December 1999
Synthesis, Characterization, and Crystal Structure of Three Homoleptic Copper(I) Thiolates: (Cu(CH3S-))∞, [(C6H5)4P+]2[Cu5(CH3S-)7] · C2H6O2, and [(C3H7)4N+]2[Cu4(CH3S-)6 · CH4O Baumgartner, Markus; Schmalle, Helmut; Baerlocher, Christian Journal of Solid State Chemistry, Vol. 107, Issue 1 https://doi.org/10.1006/jssc.1993.1324	journal	November 1993
Formation and X-ray structure of the hexa(t-butylthiolato)pentacuprate(I) monoanion Dance, Ian G. Journal of the Chemical Society, Chemical Communications, Issue 2 https://doi.org/10.1039/c39760000068	journal	January 1976
Ligand-Exchange-Induced Growth of an Atomically Precise Cu ₂₉ Nanocluster from a Smaller Cluster Nguyen, Thuy-Ai D.; Jones, Zachary R.; Leto, Domenick F. Chemistry of Materials, Vol. 28, Issue 22 https://doi.org/10.1021/acs.chemmater.6b03879	journal	November 2016
Perfluorinated Alkoxyaluminate Salts of Cationic Brønsted Acids: Synthesis, Structure, and Characterization of [H(OEt2)2][Al{OC(CF3)3}4] and[H(THF)2][Al{OC(CF3)3}4] Krossing, Ingo; Reisinger, Andreas European Journal of Inorganic Chemistry, Vol. 2005, Issue 10 https://doi.org/10.1002/ejic.200400436	journal	May 2005
Luminescent Copper Nanoclusters as a Specific Cell-Imaging Probe and a Selective Metal Ion Sensor Das, Nirmal Kumar; Ghosh, Subhadip; Priya, Amulya The Journal of Physical Chemistry C, Vol. 119, Issue 43 https://doi.org/10.1021/acs.jpcc.5b08123	journal	October 2015
Atomically precise gold nanocrystal molecules with surface plasmon resonance Qian, H.; Zhu, Y.; Jin, R. Proceedings of the National Academy of Sciences, Vol. 109, Issue 3 https://doi.org/10.1073/pnas.1115307109	journal	January 2012
[Cu12S6(PnPr3)8] and [Cu20S10(PnBu1Bu2)8]: Two sulfur bridged copper clusters with Cu-s cluster cores of known compositions but new structures Dehnen, Stefanie; Fenske, Dieter; Deveson, Anne C. Journal of Cluster Science, Vol. 7, Issue 3 https://doi.org/10.1007/BF01171188	journal	September 1996
Synthesis and X-ray Characterization of Mono- and Polynuclear Thiolatocopper(I) Complexes: The Effect of Steric Bulk on Coordination Number and Nuclearity Zeevi, Shiri; Tshuva, Edit Y. European Journal of Inorganic Chemistry, Vol. 2007, Issue 34 https://doi.org/10.1002/ejic.200700710	journal	December 2007
Preparation and X-ray characterization of two-coordinate Cu(I) complex of aliphatic thiolato ligand: Effect of steric bulk on coordination features Kohner-Kerten, Amir; Tshuva, Edit Y. Journal of Organometallic Chemistry, Vol. 693, Issue 11 https://doi.org/10.1016/j.jorganchem.2008.03.002	journal	May 2008
M–S vibrational study in three-coordinate thiolato compounds (NEt4)2[M(SC6H4-p-X)3] and (NEt4)2[M4(μ-SC6H4-p-Cl)6]: M=Cu(I) and Ag(I), X=Cl and Br Fujisawa, Kiyoshi; Imai, Sadako; Suzuki, Syusuke Journal of Inorganic Biochemistry, Vol. 82, Issue 1-4 https://doi.org/10.1016/S0162-0134(00)00148-3	journal	November 2000
Layered structure of crystalline compounds silver thiolates (AgSR) Dance, Ian G.; Fisher, Keith J.; Banda, R. M. Herath. Inorganic Chemistry, Vol. 30, Issue 2 https://doi.org/10.1021/ic00002a008	journal	January 1991
Synthesis, Crystal Structure, and Application of the Oxonium Acid [H(OEt ₂ ) ₂ ] ⁺ [B(C ₆ F ₅ ) ₄ ] ^- Jutzi, Peter; Müller, Christian; Stammler, Anja Organometallics, Vol. 19, Issue 7 https://doi.org/10.1021/om990612w	journal	April 2000
Equilibrium constants for thiol-disulfide interchange reactions: a coherent, corrected set Lees, Watson J.; Whitesides, George M. The Journal of Organic Chemistry, Vol. 58, Issue 3 https://doi.org/10.1021/jo00055a016	journal	January 1993
The crystal and molecular structure of the hexa-(μ2-benzenethiolato)tetracuprate(I) dianion Dance, I. G.; Calabrese, J. C. Inorganica Chimica Acta, Vol. 19 https://doi.org/10.1016/S0020-1693(00)91127-7	journal	January 1976
New Copper Chalcogenide Clusters with a Selenide Core and a Sulfide Shell Fuhr, Olaf; Fernandez-Recio, Lucia; Fenske, Dieter European Journal of Inorganic Chemistry, Vol. 2005, Issue 12 https://doi.org/10.1002/ejic.200400758	journal	June 2005
Advanced analysis of copper X-ray photoelectron spectra: Advanced analysis of copper X-ray photoelectron spectra Biesinger, Mark C. Surface and Interface Analysis, Vol. 49, Issue 13 https://doi.org/10.1002/sia.6239	journal	May 2017
[HL ₂ ][P(1,2-O ₂ C ₆ Cl ₄ ) ₃ ] (L = THF, DMF): Brønsted acid initiators for the polymerization of n-butyl vinyl ether and p-methoxystyrene Hazin, Khatera; Serin, Spencer C.; Patrick, Brian O. Dalton Transactions, Vol. 46, Issue 18 https://doi.org/10.1039/C6DT04820J	journal	January 2017
The Fate of Sulfur-Bound Hydrogen on Formation of Self-Assembled Thiol Monolayers on Gold: ¹ H NMR Spectroscopic Evidence from Solutions of Gold Clusters Hasan, Masihul; Bethell, Donald; Brust, Mathias Journal of the American Chemical Society, Vol. 124, Issue 7 https://doi.org/10.1021/ja0120577	journal	February 2002
The Mackay-Type Cluster [Cu ₄₃ Al ₁₂ ](Cp*) ₁₂ : Open-Shell 67-Electron Superatom with Emerging Metal-Like Electronic Structure Weßing, Jana; Ganesamoorthy, Chelladurai; Kahlal, Samia Angewandte Chemie International Edition, Vol. 57, Issue 44 https://doi.org/10.1002/anie.201806039	journal	July 2018
Halogenation of tellurium by SO2Cl2. Formation and crystal structures of (H3O)[Te3Cl13]·1/2SO2, [(C4H8O)2H][TeCl5]·(C4H8O), [(Me2SO)2H]2[TeCl6], and [Ni(NCCH3)6][Te2Cl10] Pietikäinen, Jarkko; Maaninen, Arto; Laitinen, Risto S. Polyhedron, Vol. 21, Issue 11 https://doi.org/10.1016/S0277-5387(02)00909-9	journal	May 2002
Total Structure Determination of Thiolate-Protected Au ₃₈ Nanoparticles Qian, Huifeng; Eckenhoff, William T.; Zhu, Yan Journal of the American Chemical Society, Vol. 132, Issue 24 https://doi.org/10.1021/ja103592z	journal	June 2010
Five-Coordinate Sulfur in a Polymeric Copper(I) Thiolate Complex Parish, Richard V.; Salehi, Zahra; Pritchard, Robin G. Angewandte Chemie International Edition in English, Vol. 36, Issue 3 https://doi.org/10.1002/anie.199702511	journal	February 1997
Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities Jin, Rongchao; Zeng, Chenjie; Zhou, Meng Chemical Reviews, Vol. 116, Issue 18 https://doi.org/10.1021/acs.chemrev.5b00703	journal	September 2016

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
thiols
ligands
extended x-ray absorption fine structure
nanoclusters materials

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Title: Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu2+ with Thiols

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Title: Synthesis and Characterization of “Atlas-Sphere” Copper Nanoclusters: New Insights into the Reaction of Cu²⁺ with Thiols