Casting Nanoporous Platinum in Metal–Organic Frameworks

Gao, Xiang; Pei, Xiaokun; Gardner, David W.; Diercks, Christian S.; Lee, Seungkyu; Rungtaweevoranit, Bunyarat; Prevot, Mathieu S.; Zhu, Chenhui; Fakra, Sirine; Maboudian, Roya

doi:10.1002/adma.201807553

Title: Casting Nanoporous Platinum in Metal–Organic Frameworks

Journal Article · 27 January 2019 · Advanced Materials

DOI: https://doi.org/10.1002/adma.201807553 · OSTI ID:1581334

^[1]; Pei, Xiaokun ^[1]; Gardner, David W. ^[1]; Diercks, Christian S. ^[1]; Lee, Seungkyu ^[1]; Rungtaweevoranit, Bunyarat ^[1]; Prevot, Mathieu S. ^[1]; Zhu, Chenhui ^[2]; Fakra, Sirine ^[2];

^[1]

Univ. of California, Berkeley CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Nanocasting based on porous templates is a powerful strategy in accessing materials and structures that are difficult to form by bottom-up syntheses in a controlled fashion. A facile synthetic strategy for casting ordered, nanoporous platinum (NP-Pt) networks with a high degree of control by using metal-organic frameworks (MOFs) as templates is reported here. The Pt precursor is first infiltrated into zirconium-based MOFs and subsequently transformed to 3D metallic networks via a chemical reduction process. It is demonstrated that the dimensions and topologies of the cast NP-Pt networks can be accurately controlled by using different MOFs as templates. The Brunauer-Emmett-Teller surface areas of the NP-Pt networks are estimated to be >100 m² g^-1 and they exhibit excellent catalytic activities in the methanol electrooxidation reaction (MEOR). Finally, this new methodology presents an attractive route to prepare well-defined nanoporous materials for diverse applications ranging from energy to sensing and biotechnology.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1581334

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 12 Vol. 31; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
metal-organic frameworks
methanol electrooxidation reaction
nanocasting
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Title: Casting Nanoporous Platinum in Metal–Organic Frameworks

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