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Title: A tailored oxide interface creates dense Pt single-atom catalysts with high catalytic activity

Abstract

Catalytic supremacy of Pt-single atoms achieved by CeO x –TiO 2 interfaces.

Authors:
 [1];  [2]; ORCiD logo [1];  [3];  [4];  [5];  [1];  [1]; ORCiD logo [1]; ORCiD logo [6]; ORCiD logo [5];  [2];  [2];  [2];  [2];  [2]; ORCiD logo [3];  [1]; ORCiD logo [1]
  1. Department of Materials Science and Engineering, Chungnam National University, Daejeon 34134, Republic of Korea
  2. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, USA
  3. Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
  4. KAIST Analysis Center for Research Advancement, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
  5. Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea, Department of Chemistry
  6. Pohang Accelerator Laboratory, Pohang University of Science and Technology, Pohang 37673, Republic of Korea
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1581201
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Yoo, Mi, Yu, Young-Sang, Ha, Hyunwoo, Lee, Siwon, Choi, Jin-Seok, Oh, Sunyoung, Kang, Eunji, Choi, Hyuk, An, Hyesung, Lee, Kug-Seung, Park, Jeong Young, Celestre, Richard, Marcus, Matthew A., Nowrouzi, Kasra, Taube, Doug, Shapiro, David A., Jung, WooChul, Kim, Chunjoong, and Kim, Hyun You. A tailored oxide interface creates dense Pt single-atom catalysts with high catalytic activity. United Kingdom: N. p., 2020. Web. doi:10.1039/C9EE03492G.
Yoo, Mi, Yu, Young-Sang, Ha, Hyunwoo, Lee, Siwon, Choi, Jin-Seok, Oh, Sunyoung, Kang, Eunji, Choi, Hyuk, An, Hyesung, Lee, Kug-Seung, Park, Jeong Young, Celestre, Richard, Marcus, Matthew A., Nowrouzi, Kasra, Taube, Doug, Shapiro, David A., Jung, WooChul, Kim, Chunjoong, & Kim, Hyun You. A tailored oxide interface creates dense Pt single-atom catalysts with high catalytic activity. United Kingdom. doi:10.1039/C9EE03492G.
Yoo, Mi, Yu, Young-Sang, Ha, Hyunwoo, Lee, Siwon, Choi, Jin-Seok, Oh, Sunyoung, Kang, Eunji, Choi, Hyuk, An, Hyesung, Lee, Kug-Seung, Park, Jeong Young, Celestre, Richard, Marcus, Matthew A., Nowrouzi, Kasra, Taube, Doug, Shapiro, David A., Jung, WooChul, Kim, Chunjoong, and Kim, Hyun You. Wed . "A tailored oxide interface creates dense Pt single-atom catalysts with high catalytic activity". United Kingdom. doi:10.1039/C9EE03492G.
@article{osti_1581201,
title = {A tailored oxide interface creates dense Pt single-atom catalysts with high catalytic activity},
author = {Yoo, Mi and Yu, Young-Sang and Ha, Hyunwoo and Lee, Siwon and Choi, Jin-Seok and Oh, Sunyoung and Kang, Eunji and Choi, Hyuk and An, Hyesung and Lee, Kug-Seung and Park, Jeong Young and Celestre, Richard and Marcus, Matthew A. and Nowrouzi, Kasra and Taube, Doug and Shapiro, David A. and Jung, WooChul and Kim, Chunjoong and Kim, Hyun You},
abstractNote = {Catalytic supremacy of Pt-single atoms achieved by CeO x –TiO 2 interfaces.},
doi = {10.1039/C9EE03492G},
journal = {Energy & Environmental Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

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Works referenced in this record:

Toward Rational Design of Oxide-Supported Single-Atom Catalysts: Atomic Dispersion of Gold on Ceria
journal, April 2017

  • Liu, Jin-Cheng; Wang, Yang-Gang; Li, Jun
  • Journal of the American Chemical Society, Vol. 139, Issue 17
  • DOI: 10.1021/jacs.7b01602

Unravelling inherent electrocatalysis of mixed-conducting oxide activated by metal nanoparticle for fuel cell electrodes
journal, February 2019


Catalysis by Gold: Isolated Surface Au3+ Ions are Active Sites for Selective Hydrogenation of 1,3-Butadiene over Au/ZrO2 Catalysts
journal, November 2005

  • Zhang, Xin; Shi, Hui; Xu, Bo-Qing
  • Angewandte Chemie International Edition, Vol. 44, Issue 43
  • DOI: 10.1002/anie.200502101

Direct observation of noble metal nanoparticles transforming to thermally stable single atoms
journal, July 2018


Fuel cells for transportation
journal, January 1990


Controlling activity and selectivity using water in the Au-catalysed preferential oxidation of CO in H2
journal, April 2016

  • Saavedra, Johnny; Whittaker, Todd; Chen, Zhifeng
  • Nature Chemistry, Vol. 8, Issue 6
  • DOI: 10.1038/nchem.2494

Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions
journal, May 2017


Catalysis by Doped Oxides
journal, December 2012

  • McFarland, Eric W.; Metiu, Horia
  • Chemical Reviews, Vol. 113, Issue 6
  • DOI: 10.1021/cr300418s

CO Oxidation as a Prototypical Reaction for Heterogeneous Processes
journal, September 2011

  • Freund, Hans-Joachim; Meijer, Gerard; Scheffler, Matthias
  • Angewandte Chemie International Edition, Vol. 50, Issue 43
  • DOI: 10.1002/anie.201101378

Pt-Based electrocatalysts with high atom utilization efficiency: from nanostructures to single atoms
journal, January 2019

  • Zhang, Lei; Doyle-Davis, Kieran; Sun, Xueliang
  • Energy & Environmental Science, Vol. 12, Issue 2
  • DOI: 10.1039/C8EE02939C

Sintering inhibition mechanism of platinum supported on ceria-based oxide and Pt-oxide–support interaction
journal, August 2006


Catalysis by clusters with precise numbers of atoms
journal, July 2015


Recent Advances in Preferential Oxidation of CO Reaction over Platinum Group Metal Catalysts
journal, April 2012

  • Liu, Kuo; Wang, Aiqin; Zhang, Tao
  • ACS Catalysis, Vol. 2, Issue 6
  • DOI: 10.1021/cs200418w

Non defect-stabilized thermally stable single-atom catalyst
journal, January 2019


Tuning the Structure of Platinum Particles on Ceria In Situ for Enhancing the Catalytic Performance of Exhaust Gas Catalysts
journal, September 2017

  • Gänzler, Andreas M.; Casapu, Maria; Vernoux, Philippe
  • Angewandte Chemie International Edition, Vol. 56, Issue 42
  • DOI: 10.1002/anie.201707842

Controlled Growth of Ceria Nanoarrays on Anatase Titania Powder: A Bottom-up Physical Picture
journal, December 2016


Towards dense single-atom catalysts for future automotive applications
journal, July 2019


Dynamic formation of single-atom catalytic active sites on ceria-supported gold nanoparticles
journal, March 2015

  • Wang, Yang-Gang; Mei, Donghai; Glezakou, Vassiliki-Alexandra
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7511

Heterogeneous single-atom catalysis
journal, May 2018


Catalytic CO Oxidation over Au Nanoparticles Supported on CeO 2 Nanocrystals: Effect of the Au–CeO 2 Interface
journal, October 2018


Tuning the Catalytic Selectivity of Copper Using TiO 2 : Water-Gas Shift versus CO Oxidation
journal, September 2013


Theoretical Approach To Predict the Stability of Supported Single-Atom Catalysts
journal, March 2019


Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013

  • Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300361m

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen
journal, March 2008

  • Alayoglu, Selim; Nilekar, Anand U.; Mavrikakis, Manos
  • Nature Materials, Vol. 7, Issue 4, p. 333-338
  • DOI: 10.1038/nmat2156

Tuning Pt-CeO2 interactions by high-temperature vapor-phase synthesis for improved reducibility of lattice oxygen
journal, March 2019

  • Pereira-Hernández, Xavier Isidro; DeLaRiva, Andrew; Muravev, Valery
  • Nature Communications, Vol. 10, Issue 1
  • DOI: 10.1038/s41467-019-09308-5

Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
journal, August 2003


Atomically dispersed iron hydroxide anchored on Pt for preferential oxidation of CO in H2
journal, January 2019


Determination of Ce4+/Ce3+ in electron-beam-damaged CeO2 by electron energy-loss spectroscopy
journal, December 1999


Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011

  • Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
  • Nature Chemistry, Vol. 3, Issue 8
  • DOI: 10.1038/nchem.1095

Nature of the Mixed-Oxide Interface in Ceria–Titania Catalysts: Clusters, Chains, and Nanoparticles
journal, July 2013

  • Johnston-Peck, Aaron C.; Senanayake, Sanjaya D.; Plata, José J.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 28
  • DOI: 10.1021/jp3125268

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
journal, July 2016


Gold catalysts in environmental remediation and water-gas shift technologies
journal, January 2013

  • Barakat, Tarek; Rooke, Joanna C.; Genty, Eric
  • Energy Environ. Sci., Vol. 6, Issue 2
  • DOI: 10.1039/C2EE22859A

Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
journal, September 2008


Activation of surface lattice oxygen in single-atom Pt/CeO 2 for low-temperature CO oxidation
journal, December 2017


Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts
journal, September 2015


Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane
journal, February 2009

  • Vajda, Stefan; Pellin, Michael J.; Greeley, Jeffrey P.
  • Nature Materials, Vol. 8, Issue 3
  • DOI: 10.1038/nmat2384

Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts
journal, July 2013


Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts
journal, November 2017

  • Shan, Junjun; Li, Mengwei; Allard, Lawrence F.
  • Nature, Vol. 551, Issue 7682
  • DOI: 10.1038/nature24640

Oxidations carried out by means of vanadium oxide catalysts
journal, January 1954


Creating single-atom Pt-ceria catalysts by surface step decoration
journal, February 2016

  • Dvořák, Filip; Farnesi Camellone, Matteo; Tovt, Andrii
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10801