Orbital Character Effects in the Photon Energy and Polarization Dependence of Pure C60 Photoemission

Latzke, Drew W.; Ojeda-Aristizabal, Claudia; Denlinger, Jonathan D.; Reno, Ryan; Zettl, Alex; Lanzara, Alessandra

doi:10.1021/acsnano.9b04536

Title: Orbital Character Effects in the Photon Energy and Polarization Dependence of Pure C₆₀ Photoemission

Journal Article · 21 October 2019 · ACS Nano

DOI: https://doi.org/10.1021/acsnano.9b04536 · OSTI ID:1581081

Latzke, Drew W. ^[1];

^[2]; Denlinger, Jonathan D. ^[3]; Reno, Ryan ^[2]; Zettl, Alex ^[4]; Lanzara, Alessandra ^[5]

Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
California State Univ. (CalState), Long Beach, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Kavli Energy NanoSciences Inst.
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)

We report that recent direct experimental observation of multiple highly dispersive C₆₀ valence bands has allowed for a detailed analysis of the unusual photoemission traits of these features through photon energy- and polarization-dependent measurements. Previously obscured dispersions and strong photoemission traits are now revealed by specific light polarizations. The observed intensity effects prove the locking in place of the C₆₀ molecules at low temperatures and the existence of an orientational order imposed by the substrate chosen. Most importantly, photon energy- and polarization-dependent effects are shown to be intimately linked with the orbital character of the C₆₀ band manifolds which allow for a more precise determination of the orbital character within the third highest occupied molecular orbital (HOMO-2). In conclusion, our observations and analysis provide important considerations for the connection between molecular and crystalline C₆₀ electronic structure, past and future band structure studies, and for increasingly popular C₆₀ electronic device applications, especially those making use of heterostructures.

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Research Organization:: California State Univ. (CalState), Long Beach, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-05CH11231; SC0018154

OSTI ID:: 1581081

Journal Information:: ACS Nano, Journal Name: ACS Nano Journal Issue: 11 Vol. 13; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (53)

Fullerenforschung in der zweiten Generation Kuzmany, Hans Physik in unserer Zeit, Vol. 29, Issue 1 https://doi.org/10.1002/piuz.19980290104	journal	January 1998
Analysis of occupied and empty electronic states of C60 Martins, José Luís; Troullier, N.; Weaver, J. H. Chemical Physics Letters, Vol. 180, Issue 5 https://doi.org/10.1016/0009-2614(91)85149-Q	journal	May 1991
Angle-resolved UPS studies on the cleaved (111) surface of C60 single crystals He, Peimo; Bao, Shining; Yu, Chaowen Surface Science, Vol. 328, Issue 3 https://doi.org/10.1016/0039-6028(95)00036-4	journal	May 1995
Experimental observation of circular dichroism in photoemission Westphal, C.; Bansmann, J.; Getzlaff, M. Vacuum, Vol. 41, Issue 1-3 https://doi.org/10.1016/0042-207X(90)90281-3	journal	January 1990
Structure factor in photoemission from valence band Daimon, H.; Imada, S.; Nishimoto, H. Journal of Electron Spectroscopy and Related Phenomena, Vol. 76 https://doi.org/10.1016/0368-2048(95)02478-6	journal	December 1995
Electronic structure and bonding of C60 to metals Lichtenberger, Dennis L.; Wright, Laura L.; Gruhn, Nadine E. Synthetic Metals, Vol. 59, Issue 3 https://doi.org/10.1016/0379-6779(93)91167-Z	journal	August 1993
Electronic structure of single crystal C60 Wu, J.; Shen, Z. -X.; Dessau, D. S. Physica C: Superconductivity, Vol. 197, Issue 3-4 https://doi.org/10.1016/0921-4534(92)90007-Y	journal	July 1992
High energy oscillations in the valence photoionization partial cross-section of C60 Decleva, P.; Furlan, S.; Fronzoni, G. Chemical Physics Letters, Vol. 348, Issue 5-6 https://doi.org/10.1016/S0009-2614(01)01166-6	journal	November 2001
Diffraction effects in the photoionization of clusters Frank, Olaf; Rost, Jan-Michael Chemical Physics Letters, Vol. 271, Issue 4-6 https://doi.org/10.1016/S0009-2614(97)00471-5	journal	June 1997
Circular dichroism in angular resolved photoemission from pure and Rb-doped C60 and C22H14 layers on platinum and tungsten Fecher, G. H.; Grünewald, Ch.; Merkel, M. Thin Solid Films, Vol. 303, Issue 1-2 https://doi.org/10.1016/S0040-6090(97)00088-6	journal	July 1997
Photoelectron scattering in molecules and fullerenes Becker, Uwe; Gessner, Oliver; Rüdel, Andy Journal of Electron Spectroscopy and Related Phenomena, Vol. 108, Issue 1-3 https://doi.org/10.1016/S0368-2048(00)00128-6	journal	July 2000
Comparison between calculated and measured photoemission spectra of C60 thin films Hasegawa, S.; Miyamae, T.; Yakushi, K. Journal of Electron Spectroscopy and Related Phenomena, Vol. 88-91 https://doi.org/10.1016/S0368-2048(97)00208-9	journal	March 1998
Low energy excitations in graphite: The role of dimensionality and lattice defects Zhou, S. Y.; Gweon, G. -H.; Lanzara, A. Annals of Physics, Vol. 321, Issue 7 https://doi.org/10.1016/j.aop.2006.04.011	journal	July 2006
Computational characterization of the HOMO-2 photoemission intensity oscillations in C60 Toffoli, Daniele; Stener, Mauro; Fronzoni, Giovanna Chemical Physics Letters, Vol. 516, Issue 4-6 https://doi.org/10.1016/j.cplett.2011.10.006	journal	November 2011
Photoemission intensity oscillations in the HOMO-2 band of C60 film Wang, Xiao-Xiong; Xu, Ya-Bo; Li, Hong-Nian Journal of Electron Spectroscopy and Related Phenomena, Vol. 165, Issue 1-3 https://doi.org/10.1016/j.elspec.2008.07.004	journal	September 2008
Structural and Electrical Investigation of C ₆₀ –Graphene Vertical Heterostructures Kim, Kwanpyo; Lee, Tae Hoon; Santos, Elton J. G. ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b00581	journal	May 2015
Molecular Arrangement and Charge Transfer in C ₆₀ /Graphene Heterostructures Ojeda-Aristizabal, Claudia; Santos, Elton J. G.; Onishi, Seita ACS Nano, Vol. 11, Issue 5 https://doi.org/10.1021/acsnano.7b00551	journal	April 2017
Electronic structure, conductivity and superconductivity of alkali metal doped (C60) Haddon, R. C. Accounts of Chemical Research, Vol. 25, Issue 3 https://doi.org/10.1021/ar00015a005	journal	March 1992
Exciton Fission and Charge Generation via Triplet Excitons in Pentacene/C ₆₀ Bilayers Rao, Akshay; Wilson, Mark W. B.; Hodgkiss, Justin M. Journal of the American Chemical Society, Vol. 132, Issue 36 https://doi.org/10.1021/ja1042462	journal	September 2010
Laboratory confirmation of C60+ as the carrier of two diffuse interstellar bands Campbell, E. K.; Holz, M.; Gerlich, D. Nature, Vol. 523, Issue 7560 https://doi.org/10.1038/nature14566	journal	July 2015
Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells Liu, Yuhang; Zhao, Jingbo; Li, Zhengke Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6293	journal	November 2014
Single Junction Inverted Polymer Solar Cell Reaching Power Conversion Efficiency 10.31% by Employing Dual-Doped Zinc Oxide Nano-Film as Cathode Interlayer Liao, Sih-Hao; Jhuo, Hong-Jyun; Yeh, Po-Nan Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06813	journal	October 2014
Theoretical study of the valence and core photoemission spectra of C60 Colavita, P.; De Alti, G.; Fronzoni, G. Physical Chemistry Chemical Physics, Vol. 3, Issue 20 https://doi.org/10.1039/b104761m	journal	September 2001
Angular Distribution of Photoelectrons Cooper, J.; Zare, R. N. The Journal of Chemical Physics, Vol. 48, Issue 2 https://doi.org/10.1063/1.1668742	journal	January 1968
A precise method for visualizing dispersive features in image plots Zhang, P.; Richard, P.; Qian, T. Review of Scientific Instruments, Vol. 82, Issue 4 https://doi.org/10.1063/1.3585113	journal	April 2011
Photoionization of C60 by large scale one-center density functional explicit continuum wave-function Venuti, M.; Stener, M.; De Alti, G. The Journal of Chemical Physics, Vol. 111, Issue 10 https://doi.org/10.1063/1.479220	journal	September 1999
Circular Dichroism and Spin Polarization in Photoemission from Adsorbates and Non-Magnetic Solids Schönhense, Gerd Physica Scripta, Vol. T31 https://doi.org/10.1088/0031-8949/1990/T31/035	journal	January 1990
Angle-dependent oscillations in valence-band photoemission intensity of C ₆₀ He, S.; Arita, M.; Namatame, H. Journal of Physics: Condensed Matter, Vol. 19, Issue 2 https://doi.org/10.1088/0953-8984/19/2/026202	journal	December 2006
Fine structure of C ₆₀ photoionization cross-section oscillations Li, Hong-Nian; Ni, Jin-Fu; Ying, Li-Jian Journal of Physics: Condensed Matter, Vol. 19, Issue 43 https://doi.org/10.1088/0953-8984/19/43/436223	journal	October 2007
C ₆₀ IN REFLECTION NEBULAE Sellgren, Kris; Werner, Michael W.; Ingalls, James G. The Astrophysical Journal, Vol. 722, Issue 1 https://doi.org/10.1088/2041-8205/722/1/L54	journal	September 2010
Photo-Ionization in the Soft X-Ray Range: Angular Distributions of Photoelectrons and Interpretation in Terms of Subshell Structure Cooper, John W.; Manson, Steven T. Physical Review, Vol. 177, Issue 1 https://doi.org/10.1103/PhysRev.177.157	journal	January 1969
Angle-resolved photoelectron spectroscopy of C 60 Liebsch, T.; Plotzke, O.; Heiser, F. Physical Review A, Vol. 52, Issue 1 https://doi.org/10.1103/PhysRevA.52.457	journal	July 1995
Circular dichroism in photoelectron angular distributions from adsorbed atoms Dubs, Richard L.; Dixit, S. N.; McKoy, V. Physical Review B, Vol. 32, Issue 12 https://doi.org/10.1103/PhysRevB.32.8389	journal	December 1985
Electronic states of solid C 60 : Symmetries and photoionization cross sections Benning, P. J.; Poirier, D. M.; Troullier, N. Physical Review B, Vol. 44, Issue 4 https://doi.org/10.1103/PhysRevB.44.1962	journal	July 1991
Structural and electronic properties of C 60 Troullier, N.; Martins, José Luís Physical Review B, Vol. 46, Issue 3 https://doi.org/10.1103/PhysRevB.46.1754	journal	July 1992
Conduction-band structure of alkali-metal-doped C 60 Satpathy, S.; Antropov, V. P.; Andersen, O. K. Physical Review B, Vol. 46, Issue 3 https://doi.org/10.1103/PhysRevB.46.1773	journal	July 1992
Brillouin-zone-selection effects in graphite photoelectron angular distributions Shirley, Eric L.; Terminello, L. J.; Santoni, A. Physical Review B, Vol. 51, Issue 19 https://doi.org/10.1103/PhysRevB.51.13614	journal	May 1995
Electron-momentum spectroscopy of fullerene Vos, M.; Canney, S. A.; McCarthy, I. E. Physical Review B, Vol. 56, Issue 3 https://doi.org/10.1103/PhysRevB.56.1309	journal	July 1997
Origin of the photoemission intensity oscillation of C 60 Hasegawa, Shinji; Miyamae, Takayuki; Yakushi, Kyuya Physical Review B, Vol. 58, Issue 8 https://doi.org/10.1103/PhysRevB.58.4927	journal	August 1998
Modulations of valence-band photoemission spectrum from C 60 monolayers on Ag(111) Ton-That, C.; Shard, A. G.; Egger, S. Physical Review B, Vol. 67, Issue 15 https://doi.org/10.1103/PhysRevB.67.155415	journal	April 2003
Polarization-dependent angular photoelectron distribution of solid C 60 Schiessling, J.; Kjeldgaard, L.; Balasubramanian, T. Physical Review B, Vol. 68, Issue 20 https://doi.org/10.1103/PhysRevB.68.205405	journal	November 2003
Orbital character variation of the Fermi surface and doping dependent changes of the dimensionality in BaFe 2 − x Co x As 2 from angle-resolved photoemission spectroscopy Thirupathaiah, S.; de Jong, S.; Ovsyannikov, R. Physical Review B, Vol. 81, Issue 10 https://doi.org/10.1103/PhysRevB.81.104512	journal	March 2010
Orbital characters determined from Fermi surface intensity patterns using angle-resolved photoemission spectroscopy Wang, X. -P.; Richard, P.; Huang, Y. -B. Physical Review B, Vol. 85, Issue 21 https://doi.org/10.1103/PhysRevB.85.214518	journal	June 2012
Monolayer MoS 2 : Trigonal warping, the Γ valley, and spin-orbit coupling effects Kormányos, Andor; Zólyomi, Viktor; Drummond, Neil D. Physical Review B, Vol. 88, Issue 4 https://doi.org/10.1103/PhysRevB.88.045416	journal	July 2013
Effective lattice Hamiltonian for monolayer MoS 2 : Tailoring electronic structure with perpendicular electric and magnetic fields Rostami, Habib; Moghaddam, Ali G.; Asgari, Reza Physical Review B, Vol. 88, Issue 8 https://doi.org/10.1103/PhysRevB.88.085440	journal	August 2013
Oscillatory surface dichroism of the insulating topological insulator Bi 2 Te 2 Se Neupane, M.; Basak, S.; Alidoust, N. Physical Review B, Vol. 88, Issue 16 https://doi.org/10.1103/PhysRevB.88.165129	journal	October 2013
Photon energy dependent circular dichroism in angle-resolved photoemission from Au(111) surface states Ryu, Hanyoung; Song, Inkyung; Kim, Beomyoung Physical Review B, Vol. 95, Issue 11 https://doi.org/10.1103/PhysRevB.95.115144	journal	March 2017
Observation of highly dispersive bands in pure thin film C 60 Latzke, Drew W.; Ojeda-Aristizabal, Claudia; Griffin, Sinéad M. Physical Review B, Vol. 99, Issue 4 https://doi.org/10.1103/PhysRevB.99.045425	journal	January 2019
Reversal of the Circular Dichroism in Angle-Resolved Photoemission from Bi 2 Te 3 Scholz, M. R.; Sánchez-Barriga, J.; Braun, J. Physical Review Letters, Vol. 110, Issue 21 https://doi.org/10.1103/PhysRevLett.110.216801	journal	May 2013
Oscillations in the Photoionization Cross Section of C 60 Xu, Y. B.; Tan, M. Q.; Becker, U. Physical Review Letters, Vol. 76, Issue 19 https://doi.org/10.1103/PhysRevLett.76.3538	journal	May 1996
Imaging Delocalized Electron Clouds: Photoionization of C 60 in Fourier Reciprocal Space Rüdel, Andy; Hentges, Rainer; Becker, Uwe Physical Review Letters, Vol. 89, Issue 12 https://doi.org/10.1103/PhysRevLett.89.125503	journal	August 2002
Detection of C60 and C70 in a Young Planetary Nebula Cami, J.; Bernard-Salas, J.; Peeters, E. Science, Vol. 329, Issue 5996 https://doi.org/10.1126/science.1192035	journal	July 2010
Circular Dichroism in Photoemission from Nonmagnetic, Low- Z Solids: A Conspicuous Effect of the Photon Spin Schönhense, G.; Westphal, C.; Bansmann, J. Europhysics Letters (EPL), Vol. 17, Issue 8 https://doi.org/10.1209/0295-5075/17/8/011	journal	February 1992

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C60
C60
angle resolved photoemission spectroscopy
polarization-dependent photoemission
molecular solid
orbital character
angle resolved photoemission spectroscopy
energy
light
molecular solid
orbital character
oscillation
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polarization
polarization-dependent photoemission

Title: Orbital Character Effects in the Photon Energy and Polarization Dependence of Pure C60 Photoemission

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References (53)

Cited By (1)

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Title: Orbital Character Effects in the Photon Energy and Polarization Dependence of Pure C₆₀ Photoemission