Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal–organic framework Co(4,4′-bipyrazolate)

Taylor, Mercedes K.; Juhl, Martin; Hadaf, Gul Barg; Hwang, Dasol; Velasquez, Ever; Oktawiec, Julia; Lefton, Jonathan B.; Runčevski, Tomče; Long, Jeffrey R.; Lee, Ji-Woong

doi:10.1039/C9CC08614E

Title: Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal–organic framework Co(4,4′-bipyrazolate)

Journal Article · 27 January 2020 · ChemComm

DOI: https://doi.org/10.1039/C9CC08614E · OSTI ID:1581029

^[1]; Juhl, Martin ^[2]; Hadaf, Gul Barg ^[2]; Hwang, Dasol ^[2]; Velasquez, Ever ^[3]; Oktawiec, Julia ^[4]; Lefton, Jonathan B. ^[5]; Runčevski, Tomče ^[5];

^[6];

^[2]

Center for Integrated Nanotechnologies, Sandia National Laboratories, Albuquerque, USA, Department of Chemistry
Department of Chemistry & Nano-Science Center, University of Copenhagen, Denmark
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Chemical and Biomolecular Engineering
Department of Chemistry, University of California, Berkeley, USA
Department of Chemistry, Southern Methodist University, USA
Department of Chemistry, University of California, Berkeley, USA, Materials Sciences Division

A facile catalytic protocol achieves the homocoupling of pyrazole boronic esters, enabling access to the structurally-flexible metal–organic framework Co(bpz).

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Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; AC02-06CH11357; NA0003525

OSTI ID:: 1581029

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 8 Vol. 56; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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