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Title: Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal–organic framework Co(4,4′-bipyrazolate)

Abstract

A facile catalytic protocol achieves the homocoupling of pyrazole boronic esters, enabling access to the structurally-flexible metal–organic framework Co(bpz).

Authors:
ORCiD logo [1];  [2];  [2];  [2];  [3];  [4];  [5];  [5]; ORCiD logo [6]; ORCiD logo [2]
+ Show Author Affiliations
  1. Center for Integrated Nanotechnologies, Sandia National Laboratories, Albuquerque, USA, Department of Chemistry
  2. Department of Chemistry & Nano-Science Center, University of Copenhagen, Denmark
  3. Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Chemical and Biomolecular Engineering
  4. Department of Chemistry, University of California, Berkeley, USA
  5. Department of Chemistry, Southern Methodist University, USA
  6. Department of Chemistry, University of California, Berkeley, USA, Materials Sciences Division
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1581029
Grant/Contract Number:  
AC02-06CH11357; AC02-05CH11231; NA-0003525
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 56 Journal Issue: 8; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Taylor, Mercedes K., Juhl, Martin, Hadaf, Gul Barg, Hwang, Dasol, Velasquez, Ever, Oktawiec, Julia, Lefton, Jonathan B., Runčevski, Tomče, Long, Jeffrey R., and Lee, Ji-Woong. Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal–organic framework Co(4,4′-bipyrazolate). United Kingdom: N. p., 2020. Web. doi:10.1039/C9CC08614E.
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Taylor, Mercedes K., Juhl, Martin, Hadaf, Gul Barg, Hwang, Dasol, Velasquez, Ever, Oktawiec, Julia, Lefton, Jonathan B., Runčevski, Tomče, Long, Jeffrey R., & Lee, Ji-Woong. Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal–organic framework Co(4,4′-bipyrazolate). United Kingdom. https://doi.org/10.1039/C9CC08614E
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Taylor, Mercedes K., Juhl, Martin, Hadaf, Gul Barg, Hwang, Dasol, Velasquez, Ever, Oktawiec, Julia, Lefton, Jonathan B., Runčevski, Tomče, Long, Jeffrey R., and Lee, Ji-Woong. Tue . "Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal–organic framework Co(4,4′-bipyrazolate)". United Kingdom. https://doi.org/10.1039/C9CC08614E.
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@article{osti_1581029,
title = {Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal–organic framework Co(4,4′-bipyrazolate)},
author = {Taylor, Mercedes K. and Juhl, Martin and Hadaf, Gul Barg and Hwang, Dasol and Velasquez, Ever and Oktawiec, Julia and Lefton, Jonathan B. and Runčevski, Tomče and Long, Jeffrey R. and Lee, Ji-Woong},
abstractNote = {A facile catalytic protocol achieves the homocoupling of pyrazole boronic esters, enabling access to the structurally-flexible metal–organic framework Co(bpz).},
doi = {10.1039/C9CC08614E},
journal = {ChemComm},
number = 8,
volume = 56,
place = {United Kingdom},
year = {2020},
month = {1}
}
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Journal Article:
Free Publicly Available Full Text
Accepted Manuscript (Publisher)
Publisher's Version of Record
https://doi.org/10.1039/C9CC08614E
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