This content will become publicly available on December 10, 2020
How coverage influences thermodynamic and kinetic isotope effects for H 2 /D 2 dissociative adsorption on transition metals
Abstract
Hydrogen isotope effects are influenced by adsorbate coverage: at high coverages, isotope effects are lower than at low coverages. This helps to rationalize observed isotope effects, allowing more precise elucidation of reaction mechanisms.
- Authors:
-
[1];
[1]
- Department of Chemical and Biological Engineering, University of Wisconsin – Madison, Madison, USA
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- OSTI Identifier:
- 1581022
- Grant/Contract Number:
- FG02-05ER15731
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Catalysis Science and Technology
- Additional Journal Information:
- Journal Name: Catalysis Science and Technology; Journal ID: ISSN 2044-4753
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Chen, Benjamin W. J., and Mavrikakis, Manos. How coverage influences thermodynamic and kinetic isotope effects for H 2 /D 2 dissociative adsorption on transition metals. United Kingdom: N. p., 2020.
Web. doi:10.1039/C9CY02338K.
Chen, Benjamin W. J., & Mavrikakis, Manos. How coverage influences thermodynamic and kinetic isotope effects for H 2 /D 2 dissociative adsorption on transition metals. United Kingdom. doi:10.1039/C9CY02338K.
Chen, Benjamin W. J., and Mavrikakis, Manos. Wed .
"How coverage influences thermodynamic and kinetic isotope effects for H 2 /D 2 dissociative adsorption on transition metals". United Kingdom. doi:10.1039/C9CY02338K.
@article{osti_1581022,
title = {How coverage influences thermodynamic and kinetic isotope effects for H 2 /D 2 dissociative adsorption on transition metals},
author = {Chen, Benjamin W. J. and Mavrikakis, Manos},
abstractNote = {Hydrogen isotope effects are influenced by adsorbate coverage: at high coverages, isotope effects are lower than at low coverages. This helps to rationalize observed isotope effects, allowing more precise elucidation of reaction mechanisms.},
doi = {10.1039/C9CY02338K},
journal = {Catalysis Science and Technology},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}
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DOI: 10.1039/C9CY02338K
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