Correction to: Investigation of Alkali-Ion (Li, Na, and K) Intercalation in KxVPO4 F(x ~ 0) Cathode
Abstract
This work compares the intercalation of K, Na, and Li in KxVPO4F (x~0). The KxVPO4F (x~0) cathode delivers reversible capacities of ≈90-100 mAh g-1 in K, Na, and Li cells, at an average voltage of ≈4.33 V for K, ≈3.98 V for Na, and ≈3.96 V for Li. This is so far the highest average voltage known for a K-intercalation cathode. The lower voltage of Li insertion compared to Na is attributable to undercoordinated Li ions in the KxVPO4F (x~0) framework. While the material shows high rate capability for all the alkali ions, Li migration in KxVPO4F (x~0) is more difficult than with Na and K. Here, this work suggests that a large cavity is not always good for insertion of alkali ions and cathode materials need to be suitably tailored to each intercalating ion species.
- Authors:
-
[1];
[4]
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Kyushu Univ., Kasuga, Fukuoka (Japan)
- Univ. of California, Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); Battery Innovative Contest (BIC)
- OSTI Identifier:
- 1580900
- Grant/Contract Number:
- AC02-05CH11231; 20181787
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 29; Journal Issue: 43; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Potassium; Sodium; Lithium; Batteries; Cathodes
Citation Formats
Kim, Haegyeom, Ishado, Yuji, Tian, Yaosen, and Ceder, Gerbrand. Correction to: Investigation of Alkali-Ion (Li, Na, and K) Intercalation in KxVPO4 F(x ~ 0) Cathode. United States: N. p., 2019.
Web. doi:10.1002/adfm.201906269.
Kim, Haegyeom, Ishado, Yuji, Tian, Yaosen, & Ceder, Gerbrand. Correction to: Investigation of Alkali-Ion (Li, Na, and K) Intercalation in KxVPO4 F(x ~ 0) Cathode. United States. https://doi.org/10.1002/adfm.201906269
Kim, Haegyeom, Ishado, Yuji, Tian, Yaosen, and Ceder, Gerbrand. Tue .
"Correction to: Investigation of Alkali-Ion (Li, Na, and K) Intercalation in KxVPO4 F(x ~ 0) Cathode". United States. https://doi.org/10.1002/adfm.201906269. https://www.osti.gov/servlets/purl/1580900.
@article{osti_1580900,
title = {Correction to: Investigation of Alkali-Ion (Li, Na, and K) Intercalation in KxVPO4 F(x ~ 0) Cathode},
author = {Kim, Haegyeom and Ishado, Yuji and Tian, Yaosen and Ceder, Gerbrand},
abstractNote = {This work compares the intercalation of K, Na, and Li in KxVPO4F (x~0). The KxVPO4F (x~0) cathode delivers reversible capacities of ≈90-100 mAh g-1 in K, Na, and Li cells, at an average voltage of ≈4.33 V for K, ≈3.98 V for Na, and ≈3.96 V for Li. This is so far the highest average voltage known for a K-intercalation cathode. The lower voltage of Li insertion compared to Na is attributable to undercoordinated Li ions in the KxVPO4F (x~0) framework. While the material shows high rate capability for all the alkali ions, Li migration in KxVPO4F (x~0) is more difficult than with Na and K. Here, this work suggests that a large cavity is not always good for insertion of alkali ions and cathode materials need to be suitably tailored to each intercalating ion species.},
doi = {10.1002/adfm.201906269},
journal = {Advanced Functional Materials},
number = 43,
volume = 29,
place = {United States},
year = {2019},
month = {10}
}
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