Using Heat as a Predictor of CO2 Breakthrough in Highly Heterogeneous Reservoirs

Jayne, Richard S.; Zhang, Yingqi; Pollyea, Ryan M.

doi:10.1029/2019gl083362

Title: Using Heat as a Predictor of CO₂ Breakthrough in Highly Heterogeneous Reservoirs

Abstract

Injecting supercritical CO₂ into the subsurface changes the temperature, pressure, and geochemistry of the storage reservoir. Understanding these perturbations within the reservoir may be used to monitor the CO₂ plume during a carbon capture and sequestration (CCS) project. Here we analyze results from 1-D, 2-D, and 3-D numerical modeling studies to investigate how the thermal signature of the CO₂-water system evolves during CCS. These models show that the thermodynamic processes of the CO₂-water system results in a characteristic thermal profile within a homogeneous storage reservoir during a CO₂ injection. This thermal signature is characterized by warming front of up to 4 °C, which is caused by CO₂ dissolution and migrates contemporaneously with free-phase CO₂ migration. When reservoir properties are highly heterogeneous, this thermal front travels well ahead of free-phase CO₂, thus implying that thermal monitoring may be an effective predictor of CO₂ breakthrough.

Authors:

^[1];

^[2];

^[1]

Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:: 2019-06-07

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1580882

Alternate Identifier(s):: OSTI ID: 1525332

Grant/Contract Number:: AC02-05CH11231; FE0023381

Resource Type:: Accepted Manuscript

Journal Name:: Geophysical Research Letters

Additional Journal Information:: Journal Volume: 46; Journal Issue: 11; Journal ID: ISSN 0094-8276

Publisher:: American Geophysical Union

Country of Publication:: United States

Language:: English

Subject:: 58 GEOSCIENCES

Citation Formats


                    Jayne, Richard S., Zhang, Yingqi, and Pollyea, Ryan M. Using Heat as a Predictor of CO2 Breakthrough in Highly Heterogeneous Reservoirs.  United States: N. p., 2019. 
Web.  doi:10.1029/2019gl083362.

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                    Jayne, Richard S., Zhang, Yingqi, & Pollyea, Ryan M. Using Heat as a Predictor of CO2 Breakthrough in Highly Heterogeneous Reservoirs.  United States.  https://doi.org/10.1029/2019gl083362

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                    Jayne, Richard S., Zhang, Yingqi, and Pollyea, Ryan M. Fri .  
"Using Heat as a Predictor of CO2 Breakthrough in Highly Heterogeneous Reservoirs".  United States.  https://doi.org/10.1029/2019gl083362.  https://www.osti.gov/servlets/purl/1580882.

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@article{osti_1580882,

  title        = {Using Heat as a Predictor of CO2 Breakthrough in Highly Heterogeneous Reservoirs},

  author       = {Jayne, Richard S. and Zhang, Yingqi and Pollyea, Ryan M.},

  abstractNote = {Injecting supercritical CO2 into the subsurface changes the temperature, pressure, and geochemistry of the storage reservoir. Understanding these perturbations within the reservoir may be used to monitor the CO2 plume during a carbon capture and sequestration (CCS) project. Here we analyze results from 1-D, 2-D, and 3-D numerical modeling studies to investigate how the thermal signature of the CO2-water system evolves during CCS. These models show that the thermodynamic processes of the CO2-water system results in a characteristic thermal profile within a homogeneous storage reservoir during a CO2 injection. This thermal signature is characterized by warming front of up to 4 °C, which is caused by CO2 dissolution and migrates contemporaneously with free-phase CO2 migration. When reservoir properties are highly heterogeneous, this thermal front travels well ahead of free-phase CO2, thus implying that thermal monitoring may be an effective predictor of CO2 breakthrough.},

  doi          = {10.1029/2019gl083362},

  journal      = {Geophysical Research Letters},

  number       = 11,

  volume       = 46,

  place        = {United States},

  year         = {2019},

  month        = {6}

}

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Potential of $$\hbox {CO}_{2}$$CO2 based geothermal energy extraction from hot sedimentary and dry rock reservoirs, and enabling carbon geo-sequestration
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Singh, Mrityunjay; Tangirala, Sri Kalyan; Chaudhuri, Abhijit
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Similar Records

Title: Using Heat as a Predictor of CO2 Breakthrough in Highly Heterogeneous Reservoirs

Abstract

Citation Formats

Joule-Thomson cooling due to CO2 injection into natural gas reservoirs journal, June 2007

Effects of temperature on salt precipitation due to formation dry-out during CO 2 injection in saline aquifers : Modeling and Analysis: Effects of temperature on salt precipitation due to formation dry-out during CO journal, February 2017

Thermal Signature of Free-Phase CO2 in Porous Rocks: Detectability of CO2 by Temperature Logging conference, April 2013

Factors controlling riffle-scale hyporheic exchange flows and their seasonal changes in a gaining stream: A three-dimensional groundwater flow model: FACTORS CONTROLLING EXCHANGE FLOWS journal, February 2003

Analysis of heat transfer processes and geothermal pattern in the Alberta Basin, Canada journal, January 1988

PETSc Users Manual Revision 3.8 report, September 2017

Relating permeability to the structural setting of a fault-controlled hydrothermal system in southeast Oregon, USA journal, January 2008

On relative permeability data uncertainty and CO2 injectivity estimation for brine aquifers journal, January 2013

Numerical Simulations of the Thermal Impact of Supercritical CO2 Injection on Chemical Reactivity in a Carbonate Saline Reservoir journal, September 2009

Numerical studies of fluid leakage from a geologic disposal reservoir for CO 2 show self-limiting feedback between fluid flow and heat transfer : LEAKAGE FROM A CO journal, July 2005

Field Validation of Supercritical CO 2 Reactivity with Basalts journal, November 2016

The Joule-Thomson Effect in Carbon Dioxide journal, February 1942

Delineating and Quantifying Ground Water Discharge Zones Using Streambed Temperatures journal, March 2004

Evaluation of potential nonisothermal processes and heat transport during CO 2 sequestration journal, January 2010

Implications of spatial reservoir uncertainty for CO2 sequestration in the east Snake River Plain, Idaho (USA) journal, April 2012

On the temperature of water flowing through fractures journal, April 1969

Estimating CO2 residual trapping from a single-well test: Experimental design calculations journal, January 2011

Using surface characteristics to infer the permeability structure of an active fault zone journal, February 2006

Influence of relative permeability on injection pressure and plume configuration during CO2 injections in a mafic reservoir journal, March 2016

Investigation of uncertainty in CO2 reservoir models: A sensitivity analysis of relative permeability parameter values journal, June 2016

Geologic CO2 sequestration and permeability uncertainty in a highly heterogeneous reservoir journal, April 2019

Method for locating sediment anomalies in lakebeds that can be caused by groundwater flow journal, July 1985

Permeability correlation structure of the Columbia River Plateau and implications for fluid system architecture in continental large igneous provinces journal, July 2018

Using distributed temperature sensing to detect CO2 leakage along the injection well casing journal, July 2018

Joule–Thomson Effects on the Flow of Liquid Water journal, August 2014

Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions journal, June 2016

Enthalpy and solubility data of CO2 in water and NaCl(aq) at conditions of interest for geological sequestration journal, September 2006

Using Springs to Study Groundwater Flow and Active Geologic Processes journal, May 2001

Use of tracers and temperature to estimate fracture surface area for EGS reservoirs journal, May 2017

TOUGH2 User's Guide Version 2 report, November 1999

TOUGH3: A new efficient version of the TOUGH suite of multiphase flow and transport simulators journal, November 2017

A Closed-form Equation for Predicting the Hydraulic Conductivity of Unsaturated Soils1 journal, January 1980

Monitoring above-zone temperature variations associated with CO2 and brine leakage from a storage aquifer journal, February 2014

Solubility of water in compressed carbon dioxide, nitrous oxide, and ethane. Evidence for hydration of carbon dioxide and nitrous oxide in the gas phase journal, April 1971

Modeling of Spatiotemporal Thermal Response to CO2 Injection in Saline Formations: Interpretation for Monitoring journal, February 2012

A parametric analysis of capillary pressure effects during geologic carbon sequestration in a sandstone reservoir: Modeling and Analysis: A parametric analysis of capillary pressure effects during geologic carbon sequestration journal, September 2018

The Solubility of Carbon Dioxide in Water at Low Pressure journal, November 1991

Monitoring above-zone temperature variations associated with CO2 and brine leakage from a storage aquifer text, January 2014

A probabilistic assessment of geomechanical reservoir integrity during CO 2 sequestration in flood basalt formations journal, August 2019

Potential of $$\hbox {CO}_{2}$$CO2 based geothermal energy extraction from hot sedimentary and dry rock reservoirs, and enabling carbon geo-sequestration journal, January 2020

Title: Using Heat as a Predictor of CO₂ Breakthrough in Highly Heterogeneous Reservoirs

Joule-Thomson cooling due to CO2 injection into natural gas reservoirs
journal, June 2007

Effects of temperature on salt precipitation due to formation dry-out during CO ₂ injection in saline aquifers : Modeling and Analysis: Effects of temperature on salt precipitation due to formation dry-out during CO
journal, February 2017

Thermal Signature of Free-Phase CO2 in Porous Rocks: Detectability of CO2 by Temperature Logging
conference, April 2013

Factors controlling riffle-scale hyporheic exchange flows and their seasonal changes in a gaining stream: A three-dimensional groundwater flow model: FACTORS CONTROLLING EXCHANGE FLOWS
journal, February 2003

Analysis of heat transfer processes and geothermal pattern in the Alberta Basin, Canada
journal, January 1988

PETSc Users Manual Revision 3.8
report, September 2017

Relating permeability to the structural setting of a fault-controlled hydrothermal system in southeast Oregon, USA
journal, January 2008

On relative permeability data uncertainty and CO2 injectivity estimation for brine aquifers
journal, January 2013

Numerical Simulations of the Thermal Impact of Supercritical CO2 Injection on Chemical Reactivity in a Carbonate Saline Reservoir
journal, September 2009

Numerical studies of fluid leakage from a geologic disposal reservoir for CO ₂ show self-limiting feedback between fluid flow and heat transfer : LEAKAGE FROM A CO
journal, July 2005

Field Validation of Supercritical CO ₂ Reactivity with Basalts
journal, November 2016

The Joule-Thomson Effect in Carbon Dioxide
journal, February 1942

Delineating and Quantifying Ground Water Discharge Zones Using Streambed Temperatures
journal, March 2004

Evaluation of potential nonisothermal processes and heat transport during CO ₂ sequestration
journal, January 2010

Implications of spatial reservoir uncertainty for CO2 sequestration in the east Snake River Plain, Idaho (USA)
journal, April 2012

On the temperature of water flowing through fractures
journal, April 1969

Estimating CO2 residual trapping from a single-well test: Experimental design calculations
journal, January 2011

Using surface characteristics to infer the permeability structure of an active fault zone
journal, February 2006

Influence of relative permeability on injection pressure and plume configuration during CO2 injections in a mafic reservoir
journal, March 2016

Investigation of uncertainty in CO2 reservoir models: A sensitivity analysis of relative permeability parameter values
journal, June 2016

Geologic CO2 sequestration and permeability uncertainty in a highly heterogeneous reservoir
journal, April 2019

Method for locating sediment anomalies in lakebeds that can be caused by groundwater flow
journal, July 1985

Permeability correlation structure of the Columbia River Plateau and implications for fluid system architecture in continental large igneous provinces
journal, July 2018

Using distributed temperature sensing to detect CO2 leakage along the injection well casing
journal, July 2018

Joule–Thomson Effects on the Flow of Liquid Water
journal, August 2014

Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions
journal, June 2016

Enthalpy and solubility data of CO2 in water and NaCl(aq) at conditions of interest for geological sequestration
journal, September 2006

Using Springs to Study Groundwater Flow and Active Geologic Processes
journal, May 2001

Use of tracers and temperature to estimate fracture surface area for EGS reservoirs
journal, May 2017

TOUGH2 User's Guide Version 2
report, November 1999

TOUGH3: A new efficient version of the TOUGH suite of multiphase flow and transport simulators
journal, November 2017

A Closed-form Equation for Predicting the Hydraulic Conductivity of Unsaturated Soils1
journal, January 1980

Monitoring above-zone temperature variations associated with CO2 and brine leakage from a storage aquifer
journal, February 2014

Solubility of water in compressed carbon dioxide, nitrous oxide, and ethane. Evidence for hydration of carbon dioxide and nitrous oxide in the gas phase
journal, April 1971

Modeling of Spatiotemporal Thermal Response to CO2 Injection in Saline Formations: Interpretation for Monitoring
journal, February 2012

A parametric analysis of capillary pressure effects during geologic carbon sequestration in a sandstone reservoir: Modeling and Analysis: A parametric analysis of capillary pressure effects during geologic carbon sequestration
journal, September 2018

The Solubility of Carbon Dioxide in Water at Low Pressure
journal, November 1991

Monitoring above-zone temperature variations associated with CO2 and brine leakage from a storage aquifer
text, January 2014

A probabilistic assessment of geomechanical reservoir integrity during CO ₂ sequestration in flood basalt formations
journal, August 2019

Potential of $$\hbox {CO}_{2}$$CO2 based geothermal energy extraction from hot sedimentary and dry rock reservoirs, and enabling carbon geo-sequestration
journal, January 2020