Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Review—Electrolytic Metal Atoms Enabled Manufacturing of Nanostructured Sensor Electrodes

Abstract

Sensing materials play a key role in the successful implementation of electrochemical sensors, and nanotechnology has emerged as an important and rapidly growing field for stimulating the innovation of high-performance sensors. The fabrication, characterization, and evaluation of the nanostructured electrodes are therefore a focus of this field. Compared to a variety of dry and wet technologies which have been extensively developed for this purpose, electrochemical methods are typically convenient, highly effective, and potentially low-cost for the production of different nanostructures. This minireview is designed to introduce a unique electrochemical method - electrolytic metal-atom enabled manufacturing (EM 2 ) and its application in electrochemical sensors. The EM 2 technique employs electrolytic metal atoms generated from their corresponding salt precursor as a tool to nanostructure a wide range of substrate electrodes used in electrochemical sensors, based on a one-pot electrochemical deposition and dissolution of the metal atoms in the same electrolyte bath. Briefly, the metal atoms are electrodeposited on a substrate electrode during the cathode reduction, and they are selectively removed from the substrate during the subsequent anode oxidation. Because of the interactions between the electrolytic metal atoms and the substrate atoms, the repetitive electrodeposition and dissolution of the former on themore » substrate enable the nanostructuration of the substrate, particularly within its surface layers. The nanostructured electrodes have demonstrated very attractive performance for the determination of numerous analytes, such as high sensitivity and selectivity, high interference tolerance, and low detection limits. However, the EM 2 technique and the application of the resulting nanostructured electrodes in electrochemical sensors and beyond have still been very limitedly investigated. In order to bring the community from academic, industries, agencies, and customers together to develop the EM 2 technique and advance electrochemical sensor systems, this minireview will introduce the thermodynamic and kinetic fundamentals of this technique, the characterization of resulting nanostructures, the analysis of their electrochemical behavior, and the implementation of this technique for the development of advanced sensor electrodes. Finally, an outlook with a focus on further research areas is provided.« less

Authors:
ORCiD logo;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1580776
Resource Type:
Published Article
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Name: Journal of the Electrochemical Society Journal Volume: 167 Journal Issue: 3; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English

Citation Formats

Jiang, Junhua, and Wang, Congjian. Review—Electrolytic Metal Atoms Enabled Manufacturing of Nanostructured Sensor Electrodes. United States: N. p., 2019. Web. doi:10.1149/2.0212003JES.
Copy to clipboard
Jiang, Junhua, & Wang, Congjian. Review—Electrolytic Metal Atoms Enabled Manufacturing of Nanostructured Sensor Electrodes. United States. https://doi.org/10.1149/2.0212003JES
Copy to clipboard
Jiang, Junhua, and Wang, Congjian. Fri . "Review—Electrolytic Metal Atoms Enabled Manufacturing of Nanostructured Sensor Electrodes". United States. https://doi.org/10.1149/2.0212003JES.
Copy to clipboard
@article{osti_1580776,
title = {Review—Electrolytic Metal Atoms Enabled Manufacturing of Nanostructured Sensor Electrodes},
author = {Jiang, Junhua and Wang, Congjian},
abstractNote = {Sensing materials play a key role in the successful implementation of electrochemical sensors, and nanotechnology has emerged as an important and rapidly growing field for stimulating the innovation of high-performance sensors. The fabrication, characterization, and evaluation of the nanostructured electrodes are therefore a focus of this field. Compared to a variety of dry and wet technologies which have been extensively developed for this purpose, electrochemical methods are typically convenient, highly effective, and potentially low-cost for the production of different nanostructures. This minireview is designed to introduce a unique electrochemical method - electrolytic metal-atom enabled manufacturing (EM 2 ) and its application in electrochemical sensors. The EM 2 technique employs electrolytic metal atoms generated from their corresponding salt precursor as a tool to nanostructure a wide range of substrate electrodes used in electrochemical sensors, based on a one-pot electrochemical deposition and dissolution of the metal atoms in the same electrolyte bath. Briefly, the metal atoms are electrodeposited on a substrate electrode during the cathode reduction, and they are selectively removed from the substrate during the subsequent anode oxidation. Because of the interactions between the electrolytic metal atoms and the substrate atoms, the repetitive electrodeposition and dissolution of the former on the substrate enable the nanostructuration of the substrate, particularly within its surface layers. The nanostructured electrodes have demonstrated very attractive performance for the determination of numerous analytes, such as high sensitivity and selectivity, high interference tolerance, and low detection limits. However, the EM 2 technique and the application of the resulting nanostructured electrodes in electrochemical sensors and beyond have still been very limitedly investigated. In order to bring the community from academic, industries, agencies, and customers together to develop the EM 2 technique and advance electrochemical sensor systems, this minireview will introduce the thermodynamic and kinetic fundamentals of this technique, the characterization of resulting nanostructures, the analysis of their electrochemical behavior, and the implementation of this technique for the development of advanced sensor electrodes. Finally, an outlook with a focus on further research areas is provided.},
doi = {10.1149/2.0212003JES},
journal = {Journal of the Electrochemical Society},
number = 3,
volume = 167,
place = {United States},
year = {2019},
month = {12}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1149/2.0212003JES
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Molecular transport in nanopores: a theoretical perspective
journal, January 2011

  • Bhatia, Suresh K.; Bonilla, Mauricio Rincon; Nicholson, David
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 34
  • DOI: 10.1039/c1cp21166h

Facile Synthesis of Hollow and Porous Palladium Nanospheres on Reduced Graphene Oxide Nanosheets and Their Application for Electrochemical Sensing
journal, January 2016

  • Yang, Ziyin; Zheng, Xiaohui; Zheng, Jianbin
  • Journal of The Electrochemical Society, Vol. 163, Issue 8
  • DOI: 10.1149/2.1351608jes

Insights into Electrochemical Behavior, Phase Evolution and Stability of Sn upon K-alloying/de-alloying via In Situ Studies
journal, January 2017

  • Ramireddy, Thrinathreddy; Kali, Ravi; Jangid, Manoj K.
  • Journal of The Electrochemical Society, Vol. 164, Issue 12
  • DOI: 10.1149/2.0481712jes

Performance of SiO 2 , ZrO 2 , TiO 2 , Al 2 O 3 or Fe 2 O 3 Coatings on Ti Electrodes for Arsenic (V) Detection Utilizing Electrochemical Impedance Spectroscopy
journal, January 2018

  • Wouters, Jesse J.; Tejedor-Tejedor, M. Isabel; Anderson, Marc A.
  • Journal of The Electrochemical Society, Vol. 165, Issue 2
  • DOI: 10.1149/2.0611802jes

Simultaneous determination of the diffusion coefficient of the depolarizer and the number of electrons involved in processes at hemispherical platinum electrodes
journal, February 1970

  • Biondi, C.; Bellugi, L.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 24, Issue 2-3
  • DOI: 10.1016/S0022-0728(70)80150-4

Voltammetric Determination of Glucose at Bismuth-Modified Mesoporous Platinum Microelectrodes
journal, May 2010

  • Daniele, Salvatore; Battistel, Dario; Bergamin, Simone
  • Electroanalysis, Vol. 22, Issue 13
  • DOI: 10.1002/elan.200970014

Theory of ultramicroelectrodes
journal, September 1993

Manipulating Molecular Transport through Nanoporous Membranes by Control of Electrokinetic Flow:  Effect of Surface Charge Density and Debye Length
journal, October 2001

  • Kuo, Tzu-Chi; Sloan, Lisa A.; Sweedler, Jonathan V.
  • Langmuir, Vol. 17, Issue 20
  • DOI: 10.1021/la010429j

Advanced electroanalytical chemistry at nanoelectrodes
journal, January 2017

  • Ying, Yi-Lun; Ding, Zhifeng; Zhan, Dongping
  • Chemical Science, Vol. 8, Issue 5
  • DOI: 10.1039/C7SC00433H

Nanoporous Metals Fabricated through Electrochemical Dealloying of Ag-Au-Pt with Systematic Variation of Au:Pt Ratio
journal, October 2013

  • Vega, Adrián A.; Newman, Roger C.
  • Journal of The Electrochemical Society, Vol. 161, Issue 1
  • DOI: 10.1149/2.003401jes

Nanostructuring a Gold Microelectrode through Electrochemical Alloying-Dealloying for Nitrite Detection
journal, January 2012

Diffusion-related behaviour of gold in thin film systems
journal, June 1979

A Sensitive Electrochemical H 2 O 2 Sensor Based on PdAg-Decorated Reduced Graphene Oxide Nanocomposites
journal, January 2016

  • Uzunoglu, Aytekin; Song, Siyi; Stanciu, Lia A.
  • Journal of The Electrochemical Society, Vol. 163, Issue 7
  • DOI: 10.1149/2.1201607jes

Oxygen Reduction Studies of Templated Mesoporous Platinum Catalysts
journal, January 1999

  • Jiang, Junhua
  • Electrochemical and Solid-State Letters, Vol. 3, Issue 12
  • DOI: 10.1149/1.1391208

Size Effects in the Electrochemical Alloying and Cycling of Electrodeposited Aluminum with Lithium
journal, January 2012

  • Hudak, Nicholas S.; Huber, Dale L.
  • Journal of The Electrochemical Society, Vol. 159, Issue 5
  • DOI: 10.1149/2.023206jes

Electrochemical Sensors and Biosensors Based on Nanomaterials and Nanostructures
journal, December 2014

  • Zhu, Chengzhou; Yang, Guohai; Li, He
  • Analytical Chemistry, Vol. 87, Issue 1
  • DOI: 10.1021/ac5039863

Microfluidics, MEMS/NEMS, Sensors and Devices
journal, January 2014

  • Khosla, Ajit; Hesketh, Peter J.
  • Journal of The Electrochemical Society, Vol. 161, Issue 2
  • DOI: 10.1149/2.025402jes

Electrochemical Determination of Nitrite Using Catalyst Free Mesoporous Carbon Nanoparticles from Bio Renewable Areca nut Seeds
journal, January 2018

  • Yallappa, S.; Shivakumar, M.; Nagashree, K. L.
  • Journal of The Electrochemical Society, Vol. 165, Issue 10
  • DOI: 10.1149/2.0561810jes

Fabrication of Nanoporous Pt by Electrochemical Alloying and Dealloying with Li
journal, January 2013

  • Nishio, K.; Yoshida, M.; Masuda, H.
  • ECS Electrochemistry Letters, Vol. 2, Issue 11
  • DOI: 10.1149/2.007311eel

Primary and Secondary Dealloying of Au(Pt)-Ag: Structural and Compositional Evolutions, and Volume Shrinkage
journal, January 2014

  • Ye, Xing-Long; Lu, Ning; Li, Xiao-Ju
  • Journal of The Electrochemical Society, Vol. 161, Issue 12
  • DOI: 10.1149/2.0131412jes

Electrochemical Preparation of Porous Copper Surfaces in Zinc Chloride-1-ethyl-3-methyl Imidazolium Chloride Ionic Liquid
journal, January 2007

  • Lin, Yi-Wen; Tai, Chia-Cheng; Sun, I-Wen
  • Journal of The Electrochemical Society, Vol. 154, Issue 6
  • DOI: 10.1149/1.2724154

Engineering of Au/Ag Nanostructures for Enhanced Electrochemical Performance
journal, January 2018

  • Navarreto-Lugo, Monica; Lim, Jae Hee; Samia, Anna Cristina S.
  • Journal of The Electrochemical Society, Vol. 165, Issue 3
  • DOI: 10.1149/2.0361803jes

Mechano-Electrochemical Interaction Gives Rise to Strain Relaxation in Sn Electrodes
journal, January 2016

  • Barai, Pallab; Huang, Bo; Dillon, Shen J.
  • Journal of The Electrochemical Society, Vol. 163, Issue 14
  • DOI: 10.1149/2.0801614jes

Layer-by-layer assembled nanorough iridium-oxide/platinum-black for low-voltage microscale electrode neurostimulation
journal, January 2015

  • Yamagiwa, Shota; Fujishiro, Akifumi; Sawahata, Hirohito
  • Sensors and Actuators B: Chemical, Vol. 206
  • DOI: 10.1016/j.snb.2014.09.048

Application of ionic liquids to the electrodeposition of metals
journal, January 2006

  • Abbott, Andrew P.; McKenzie, Katy J.
  • Physical Chemistry Chemical Physics, Vol. 8, Issue 37
  • DOI: 10.1039/b607329h

Nanopatterning Palladium Surface Layers through Electrochemical Deposition and Dissolution of Zinc in Ionic Liquid
journal, November 2013

  • Jiang, Junhua; Zhang, Lei; Wang, Xinying
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 23
  • DOI: 10.1021/am4040703

Detection of Glucose Based on Bimetallic PtCu Nanochains Modified Electrodes
journal, May 2013

  • Cao, Xia; Wang, Ning; Jia, Shu
  • Analytical Chemistry, Vol. 85, Issue 10
  • DOI: 10.1021/ac400292n

Electrochemical oxidation of hydrogen peroxide at nanoporous platinum electrodes and the application to glutamate microsensor
journal, December 2006

Diffusion and reactions in gold films: A review of fundamental aspects
journal, March 1981

Kinetics of Crystal Etching Limited by Terrace Dissolution
journal, January 2010

  • Snyder, J.; Erlebacher, J.
  • Journal of The Electrochemical Society, Vol. 157, Issue 3
  • DOI: 10.1149/1.3280299

Highly Sensitive and Selective Glucose Sensor Realized by Conducting Polymer Modified Nanoporous PtZn Alloy Electrode
journal, March 2013

  • Jo, Hyejin; Piao, Hushan; Son, Yongkeun
  • Journal of Electrochemical Science and Technology, Vol. 4, Issue 1
  • DOI: 10.33961/JECST.2013.4.1.41

Communication—Electrochemical Atomic Layer Etching of Copper
journal, January 2018

  • Gong, Yukun; Venkatraman, Kailash; Akolkar, Rohan
  • Journal of The Electrochemical Society, Vol. 165, Issue 7
  • DOI: 10.1149/2.0901807jes

An Atomistic Description of Dealloying
journal, January 2004

  • Erlebacher, Jonah
  • Journal of The Electrochemical Society, Vol. 151, Issue 10
  • DOI: 10.1149/1.1784820

Electrically Conducting PDMS Nanocomposite Using In Situ Reduction of Gold Nanostructures and Mechanical Stimulation of Carbon Nanotubes and Silver Nanoparticles
journal, January 2015

  • Ozhikandathil, Jayan; Khosla, Ajit; Packirisamy, Muthukumaran
  • ECS Journal of Solid State Science and Technology, Vol. 4, Issue 10
  • DOI: 10.1149/2.0091510jss

The Realm of the Nanopore
journal, January 2008

A Glucose Biosensor Based on a 3D Nanostructured Gold Electrode
journal, November 2012

  • Tsai, Chung-Che; Wang, Gou-Jen
  • Journal of The Electrochemical Society, Vol. 160, Issue 1
  • DOI: 10.1149/2.035301jes

Fabrication and Characterization of Nanoporous Gold Electrodes for Sensor Applications
journal, December 2018

  • Francis, Nicholas J.; Knospe, Carl R.
  • Advanced Engineering Materials, Vol. 21, Issue 3
  • DOI: 10.1002/adem.201800857

Micro and nanostructure based electrochemical sensor platform for glutamate detection
journal, January 2018

  • Jamal, Mamun; Chakrabarty, Sumon; Yousuf, Mohammad A.
  • Microsystem Technologies, Vol. 24, Issue 10
  • DOI: 10.1007/s00542-018-3710-z

Electrochemical AFM “Dip-Pen” Nanolithography
journal, March 2001

  • Li, Yan; Maynor, Benjamin W.; Liu, Jie
  • Journal of the American Chemical Society, Vol. 123, Issue 9, p. 2105-2106
  • DOI: 10.1021/ja005654m

Preface—JES Focus Issue on Biosensors and Micro-Nano Fabricated Electromechanical Systems
journal, January 2017

  • Mukundan, Rangachary; Khosla, Ajit; Hesketh, Peter
  • Journal of The Electrochemical Society, Vol. 164, Issue 5
  • DOI: 10.1149/2.0201705jes

Electrochemical fabrication of nanoporous gold electrodes in a deep eutectic solvent for electrochemical detections
journal, January 2018

  • Rong, Kai; Huang, Liang; Zhang, Hui
  • Chemical Communications, Vol. 54, Issue 64
  • DOI: 10.1039/C8CC04454F

Enhancement of the Enzymatic Biosensor Response through Targeted Electrode Surface Roughness
journal, January 2018

  • Perry, Samuel C.; Gateman, Samantha M.; Sifakis, Joseph
  • Journal of The Electrochemical Society, Vol. 165, Issue 12
  • DOI: 10.1149/2.0121812jes

Probing the Dealloying Critical Potential
journal, January 2005

  • Dursun, Aziz; Pugh, Dylan V.; Corcoran, Sean G.
  • Journal of The Electrochemical Society, Vol. 152, Issue 2
  • DOI: 10.1149/1.1848351

Nano-Roughening a Pt Disk Microelectrode via Electrochemical Alloying-Dealloying in Ionic Liquid Electrolyte
journal, July 2013

Volume Change during the Formation of Nanoporous Gold by Dealloying
journal, July 2006

Bionanoelectronics Platform with DNA Molecular Wires Attached to High Aspect-Ratio 3D Metal Microelectrodes
journal, December 2013

  • Vahidi, Nasim W.; Hirabayashi, Mieko; Mehta, Beejal
  • ECS Journal of Solid State Science and Technology, Vol. 3, Issue 3
  • DOI: 10.1149/2.001403jss

Dealloying of Cu 3 Pd Single Crystal Surfaces
journal, January 2013

  • Ankah, Genesis N.; Meimandi, S.; Renner, Frank U.
  • Journal of The Electrochemical Society, Vol. 160, Issue 8
  • DOI: 10.1149/2.079308jes

Development of Nanoscale Interdigitated Array Electrode as Electrochemical Sensor Platform for Highly Sensitive Detection of Biomolecules
journal, January 2008

  • Hayashi, Katsuyoshi; Takahashi, Jun-ichi; Horiuchi, Tsutomu
  • Journal of The Electrochemical Society, Vol. 155, Issue 9
  • DOI: 10.1149/1.2952668

Electrochemical and Morphological Characterization of Pt–Cu Dealloying
journal, January 2005

  • Pugh, Dylan V.; Dursun, Aziz; Corcoran, Sean G.
  • Journal of The Electrochemical Society, Vol. 152, Issue 11, p. B455-B459
  • DOI: 10.1149/1.2048140

Development of Tungsten Oxide Nanoparticle Modified Carbon Fibre Cloth as Flexible pH Sensor
journal, March 2019

Review—Recent Developments on Graphene-Based Electrochemical Sensors toward Nitrite
journal, January 2019

  • Li, Guangli; Xia, Yonghui; Tian, Yaling
  • Journal of The Electrochemical Society, Vol. 166, Issue 12
  • DOI: 10.1149/2.0171912jes

Review on Micro- and Nanolithography Techniques and their Applications
journal, January 2012

Electrochemical Formation of Porous Nickel in Zinc Chloride-Alkali Chloride Melts
journal, January 2006

  • Fukumizu, T.; Kotani, F.; Yoshida, A.
  • Journal of The Electrochemical Society, Vol. 153, Issue 9
  • DOI: 10.1149/1.2216401

Highly-Sensitive Non-Enzymatic Glucose Sensor via Nano Platinum Crystals Fabricated by Phase-Controlled Electrochemical Deposition
journal, January 2018

  • Wei, Yu-Hsuan; Hsieh, Chien-Kuo; Tseng, Fan-Gang
  • Journal of The Electrochemical Society, Vol. 165, Issue 2
  • DOI: 10.1149/2.1141802jes

Air and water stable ionic liquids in physical chemistry
journal, January 2006

  • Endres, Frank; Zein El Abedin, Sherif
  • Physical Chemistry Chemical Physics, Vol. 8, Issue 18
  • DOI: 10.1039/b600519p

Nanostructured platinum as an electrocatalyst for the electrooxidation of formic acid
journal, February 2002

Nonenzymatic Electrochemical Glucose Sensor Based on Nanoporous PtPb Networks
journal, February 2008

  • Wang, Jingpeng; Thomas, Dan F.; Chen, Aicheng
  • Analytical Chemistry, Vol. 80, Issue 4
  • DOI: 10.1021/ac701790z

Synthesis of Nanoporous Gold Structures via Dealloying of Electroplated Au-Ni Alloy Films
journal, April 2007

  • Rouya, Eric; Reed, Michael L.; Kelly, Robert G.
  • ECS Transactions, Vol. 6, Issue 11
  • DOI: 10.1149/1.2790413

Non-Enzymatic Amperometric Sensing of Hydrogen Peroxide Based on Vanadium Pentoxide Nanostructures
journal, January 2019

  • Ghanei-Motlagh, Masoud; Taher, Mohammad Ali; Fayazi, Maryam
  • Journal of The Electrochemical Society, Vol. 166, Issue 6
  • DOI: 10.1149/2.0521906jes

3D printing technologies for electrochemical energy storage
journal, October 2017

Mechanisms and Morphology Evolution in Dealloying
journal, January 2013

  • Chen, Qing; Sieradzki, Karl
  • Journal of The Electrochemical Society, Vol. 160, Issue 6
  • DOI: 10.1149/2.064306jes

Emerging applications of nanotechnology for diagnosis and therapy of disease: a review
journal, July 2017

  • Bayford, Richard; Rademacher, Tom; Roitt, Ivan
  • Physiological Measurement, Vol. 38, Issue 8
  • DOI: 10.1088/1361-6579/aa7182

Chemically-modified nanopores for sensing
journal, July 2008

Nanoporous Gold by Alloy Corrosion: Method-Structure-Property Relationships
journal, January 2017

  • Graf, M.; Roschning, B.; Weissmüller, J.
  • Journal of The Electrochemical Society, Vol. 164, Issue 4
  • DOI: 10.1149/2.1681704jes

Combinatorial Discovery of Alloy Electrocatalysts for Amperometric Glucose Sensors
journal, April 2001

  • Sun, Yipeng; Buck, Harvey; Mallouk, Thomas E.
  • Analytical Chemistry, Vol. 73, Issue 7
  • DOI: 10.1021/ac0015117

Potassium-Ion Battery Anode Materials Operating through the Alloying-Dealloying Reaction Mechanism
journal, December 2017

  • Sultana, Irin; Rahman, Md Mokhlesur; Chen, Ying
  • Advanced Functional Materials, Vol. 28, Issue 5
  • DOI: 10.1002/adfm.201703857

Electrochemical Defect-Mediated Thin-Film Growth
journal, April 1999

Spring-block model for a single-lane highway traffic
journal, January 2011

Evaluation of the Electroextractions of Ce and Nd from LiCl-KCl Molten Salt Using Liquid Ga Electrode
journal, January 2017

  • Liu, Kui; Liu, Ya-Lan; Chai, Zhi-Fang
  • Journal of The Electrochemical Society, Vol. 164, Issue 4
  • DOI: 10.1149/2.0511704jes

A Gold Micro-Reference Electrode for Impedance and Potential Measurements in Lithium Ion Batteries
journal, January 2016

  • Solchenbach, Sophie; Pritzl, Daniel; Kong, Edmund Jia Yi
  • Journal of The Electrochemical Society, Vol. 163, Issue 10
  • DOI: 10.1149/2.0581610jes

Analysis of Lithium Insertion/Deinsertion in a Silicon Electrode Particle at Room Temperature
journal, January 2010

  • Chandrasekaran, Rajeswari; Magasinski, Alexandre; Yushin, Gleb
  • Journal of The Electrochemical Society, Vol. 157, Issue 10
  • DOI: 10.1149/1.3474225

Factors Controlling the Less Noble Metal Retention in Nanoporous Structures Processed by Electrochemical Dealloying
journal, January 2010

  • Liu, Y.; Bliznakov, S.; Dimitrov, N.
  • Journal of The Electrochemical Society, Vol. 157, Issue 8
  • DOI: 10.1149/1.3454753

A New Low-Temperature Electrochemical Hydrocarbon and NOx Sensor
journal, November 2017

  • Sekhar, Praveen; Moore, Zachary; Aravamudhan, Shyam
  • Sensors, Vol. 17, Issue 12
  • DOI: 10.3390/s17122759

Carbon fiber doped thermosetting elastomer for flexible sensors: physical properties and microfabrication
journal, August 2018

Electrochemical nucleation and growth of nano- and microparticles: some theoretical and experimental aspects
journal, September 2003

Manufacturing of high aspect-ratio 3-dimensional PolyFerroCNT nanocomposite polymer electrodes
journal, July 2014

Electrochemical oxidation of nitrite: Kinetic, mechanistic and analytical study by square wave voltammetry
journal, April 2012

Electrochemistry of Nanopore Electrodes in Low Ionic Strength Solutions
journal, February 2006

  • Zhang, Yanhui; Zhang, Bo; White, Henry S.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 4
  • DOI: 10.1021/jp054704c

Efficient Nanostructuring of Silicon by Electrochemical Alloying/Dealloying in Molten Salts for Improved Lithium Storage
journal, October 2018

  • Yuan, Yating; Xiao, Wei; Wang, Zhiyong
  • Angewandte Chemie International Edition, Vol. 57, Issue 48
  • DOI: 10.1002/anie.201809646

Electrocatalysis on Platinum Nanoparticles: Particle Size Effect on Oxygen Reduction Reaction Activity
journal, September 2011

  • Shao, Minhua; Peles, Amra; Shoemaker, Krista
  • Nano Letters, Vol. 11, Issue 9
  • DOI: 10.1021/nl2017459

Additive Manufacturing of Microreservoir Devices for Oral Drug Delivery Using an Acculas BA-30 Micro-Stereolithography Instrument: A Feasibility Study
journal, January 2019

  • Vaut, Lukas; Jensen, Kristian E.; Tosello, Guido
  • Journal of The Electrochemical Society, Vol. 166, Issue 9
  • DOI: 10.1149/2.0421909jes

Glucose electrooxidation over PdxRh/C electrocatalysts in alkaline medium
journal, April 2014

Design and Testing of an Impedance-Based Sensor for Monitoring Drug Delivery
journal, January 2005

  • Johnson, Audrey M.; Sadoway, Donald R.; Cima, Michael J.
  • Journal of The Electrochemical Society, Vol. 152, Issue 1
  • DOI: 10.1149/1.1824045

Preparation of a High Surface Area Nickel Electrode by Alloying and Dealloying in a ZnCl[sub 2]-NaCl Melt
journal, January 2003

  • Katagiri, A.; Nakata, M.
  • Journal of The Electrochemical Society, Vol. 150, Issue 9
  • DOI: 10.1149/1.1595662

Combining Structural and Electrochemical Analysis of Electrodes Using Micro-Computed Tomography and a Microfluidic Fuel Cell
journal, January 2012

  • Jhong, Huei-Ru (Molly); Brushett, Fikile R.; Yin, Leilei
  • Journal of The Electrochemical Society, Vol. 159, Issue 3
  • DOI: 10.1149/2.033203jes

Modeling of impedance mechanisms in electropolishing
journal, March 1995

Formation of Porous Silver by Electrochemical Alloying/Dealloying in a Water-Insensitive Zinc Chloride-1-ethyl-3-methyl Imidazolium Chloride Ionic Liquid
journal, March 2006

  • Yeh, Fu-Hwa; Tai, Chia-Cheng; Huang, Jing-Fang
  • The Journal of Physical Chemistry B, Vol. 110, Issue 11
  • DOI: 10.1021/jp0552527

Investigation of Printing Properties on Paper Substrate
journal, January 2018

  • Saha, Tonmoy Kumar; Knaus, Tyler Nathan; Khosla, Ajit
  • Journal of The Electrochemical Society, Vol. 165, Issue 8
  • DOI: 10.1149/2.0211808jes

Nanoparticle-doped Electrically-conducting Polymers for Flexible Nano-Micro Systems
journal, January 2012

Mechanistic Analysis of Mechano-Electrochemical Interaction in Silicon Electrodes with Surface Film
journal, January 2017

  • Verma, Ankit; Mukherjee, Partha P.
  • Journal of The Electrochemical Society, Vol. 164, Issue 14
  • DOI: 10.1149/2.0391714jes

Effective Surface Area of Electrochemical Sensors
journal, January 2014

  • Krejci, Jan; Sajdlova, Zuzana; Nedela, Vilem
  • Journal of The Electrochemical Society, Vol. 161, Issue 6
  • DOI: 10.1149/2.091406jes

In Situ Electrochemical Fabrication of Three Dimensional Hierarchical Nanoporous Copper Films and Their Electrocatalytic Performance
journal, January 2016

  • Yang, C.; Zhang, Q. B.; Gao, M. Y.
  • Journal of The Electrochemical Society, Vol. 163, Issue 9
  • DOI: 10.1149/2.0461609jes

Development of High Performance Electrochemical and Physical Biosensors Based on Chemically Modified Graphene Nanostructured Electrodes
journal, January 2017

  • Hossain, M. F.; Das, P. S.; Park, J. Y.
  • Journal of The Electrochemical Society, Vol. 164, Issue 9
  • DOI: 10.1149/2.0301709jes

All Electrochemical Fabrication of a Platinized Nanoporous Au Thin-Film Catalyst
journal, October 2011

  • McCurry, Daniel A.; Kamundi, Martha; Fayette, Matthew
  • ACS Applied Materials & Interfaces, Vol. 3, Issue 11
  • DOI: 10.1021/am2011433

Review—Organic-Inorganic Hybrid Functional Materials: An Integrated Platform for Applied Technologies
journal, January 2018

  • Mir, Sajjad Husain; Nagahara, Larry Akio; Thundat, Thomas
  • Journal of The Electrochemical Society, Vol. 165, Issue 8
  • DOI: 10.1149/2.0191808jes

Advanced Micro- and Nano-Gas Sensor Technology: A Review
journal, March 2019

  • Nazemi, Haleh; Joseph, Aashish; Park, Jaewoo
  • Sensors, Vol. 19, Issue 6
  • DOI: 10.3390/s19061285

Effects of adsorption and confinement on nanoporous electrochemistry
journal, January 2013

  • Bae, Je Hyun; Han, Ji-Hyung; Han, Donghyeop
  • Faraday Discussions, Vol. 164
  • DOI: 10.1039/c3fd00014a

Facile fabrication of nanoporous platinum by alloying–dealloying process and its application in glucose sensing
journal, October 2012

Fabrication of Highly Porous Platinum by Cyclic Electrodeposition of PtCu Alloys: How do Process Parameters Affect Morphology?
journal, January 2013

  • Kloke, Arne; Köhler, Christian; Dryzga, Anna
  • Journal of The Electrochemical Society, Vol. 160, Issue 3
  • DOI: 10.1149/2.001304jes

Nanoporous metal as a platform for electrochemical and optical sensing
journal, January 2014

  • Qiu, H. -J.; Li, Xiao; Xu, Hai-Tao
  • J. Mater. Chem. C, Vol. 2, Issue 46
  • DOI: 10.1039/C4TC01913J

Preparation of a porous nanostructured germanium from GeO 2 via a “reduction–alloying–dealloying” approach
journal, January 2015

  • Yin, Huayi; Xiao, Wei; Mao, Xuhui
  • Journal of Materials Chemistry A, Vol. 3, Issue 4
  • DOI: 10.1039/C4TA05244G

Electrochemical micro/nano-machining: principles and practices
journal, January 2017

  • Zhan, Dongping; Han, Lianhuan; Zhang, Jie
  • Chemical Society Reviews, Vol. 46, Issue 5
  • DOI: 10.1039/C6CS00735J

Nanofabrication of Robust Nanoelectrodes for Electrochemical Applications
journal, April 2010

  • Dawson, Karen; Strutwolf, Jorg; Herzog, Gregorie
  • ECS Transactions, Vol. 28, Issue 34
  • DOI: 10.1149/1.3514074

Nanotechnology impact on sensors
journal, October 2009

Crack Pattern Formation in Thin Film Lithium-Ion Battery Electrodes
journal, January 2011

  • Li, Juchuan; Dozier, Alan K.; Li, Yunchao
  • Journal of The Electrochemical Society, Vol. 158, Issue 6
  • DOI: 10.1149/1.3574027

Tailoring nanostructures in micrometer size germanium particles to improve their performance as an anode for lithium ion batteries
journal, January 2014

  • Ke, Fu-Sheng; Mishra, Kuber; Jamison, Lauryn
  • Chemical Communications, Vol. 50, Issue 28
  • DOI: 10.1039/c4cc00051j

Introduction to Mechano-Electro-Chemical Coupling in Energy Related Materials and Devices
journal, January 2014

  • Nicholas, Jason D.; Qi, Yue; Bishop, Sean R.
  • Journal of The Electrochemical Society, Vol. 161, Issue 11
  • DOI: 10.1149/2.0231411jes

Editors' Choice—Interface Engineering Strategy Utilizing Electrochemical ALD of Cu-Zn for Enabling Metallization of Sub-10 nm Semiconductor Device Nodes
journal, January 2019

  • Joi, Aniruddha; Venkatraman, Kailash; Tso, Kuang-Chih
  • ECS Journal of Solid State Science and Technology, Vol. 8, Issue 9
  • DOI: 10.1149/2.0181909jss

Nanoporous Gold Leaf for Amperometric Determination of Nitrite
journal, November 2010

Fracture in microsphere monolayers studied by experiment and computer simulation
journal, September 1988

  • Skjeltorp, A. T.; Meakin, Paul
  • Nature, Vol. 335, Issue 6189
  • DOI: 10.1038/335424a0

Efficient Electrocatalytic System Comprising of Aqueous Polyoxometalates and Nanoporous Gold for CO Electrooxidation
journal, January 2012

Strain development in nanoporous metallic foils formed by dealloying
journal, January 2008

  • Schofield, Eleanor J.; Ingham, Bridget; Turnbull, Alan
  • Applied Physics Letters, Vol. 92, Issue 4
  • DOI: 10.1063/1.2838351

Miniature Nitro and Peroxide Vapor Sensors Using Nanoporous Thin Films
journal, December 2016

Diffusion mechanism in the gold-copper system
journal, April 2012

  • Ravi, R.; Paul, A.
  • Journal of Materials Science: Materials in Electronics, Vol. 23, Issue 12
  • DOI: 10.1007/s10854-012-0729-2

Electrochemical and Thermodynamic Properties of Pr on the Liquid Bi Electrode in LiCl-KCl Eutectic Melt
journal, January 2018

  • Yin, Taiqi; Liu, Kui; Liu, Yalan
  • Journal of The Electrochemical Society, Vol. 165, Issue 10
  • DOI: 10.1149/2.0781810jes

Nanostructured Materials Used for Pattern Recognition of Bisphenols in Waste Water Samples
journal, January 2019

  • Stefan-van Staden, Raluca-Ioana; Moscalu-Lungu, Alexandrina; van Staden, Jacobus Frederick
  • Journal of The Electrochemical Society, Vol. 166, Issue 12
  • DOI: 10.1149/2.0521912jes

Electrodeposition and Dissolution of Zn on PdAg Foil in a Chlorozincate Ionic Liquid to Fabricate Micro-Nanostructured PdAgZn Alloy Films for Electrocatalysis
journal, January 2017

  • Hsieh, Li-Ying; Wang, Po-Kai; Chang, Che-Chen
  • Journal of The Electrochemical Society, Vol. 164, Issue 12
  • DOI: 10.1149/2.1511712jes

Particle Size and Support Effects in Electrocatalysis
journal, April 2013

  • Hayden, Brian E.
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar400001n

Electrochemistry for a cleaner environment
journal, January 1997

Nickel Hydroxide Nanoflowers for a Nonenzymatic Electrochemical Glucose Sensor
journal, January 2014

  • Yang, Haipeng; Gao, Guangwei; Teng, Fei
  • Journal of The Electrochemical Society, Vol. 161, Issue 10
  • DOI: 10.1149/2.0521410jes

Improving Electrochemical Sensitivity of Silver Electrodes for Nitrate Detection in Neutral and Base Media through Surface Nanostructuration
journal, November 2013

  • Jiang, Junhua; Zhang, Lei; Shanbhag, Vinay
  • Journal of The Electrochemical Society, Vol. 161, Issue 2
  • DOI: 10.1149/2.004402jes

Voltage hysteresis of lithium ion batteries caused by mechanical stress
journal, January 2016

  • Lu, Bo; Song, Yicheng; Zhang, Qinglin
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 6
  • DOI: 10.1039/C5CP06179B

Electrocatalytic Interface Based on Novel Carbon Nanomaterials for Advanced Electrochemical Sensors
journal, July 2015

Gold etching for microfabrication
journal, May 2014

Oxidation of Nitrite on Solid Electrodes
journal, January 2002

  • Piela, Barbara; Piela, Piotr; Wrona, Piotr K.
  • Journal of The Electrochemical Society, Vol. 149, Issue 10
  • DOI: 10.1149/1.1502691

Electrochemical Determination of the Thermodynamic Properties of Lithium-Antimony Alloys
journal, December 2014

  • Kane, Margaret M.; Newhouse, Jocelyn M.; Sadoway, Donald R.
  • Journal of The Electrochemical Society, Vol. 162, Issue 3
  • DOI: 10.1149/2.0671503jes

Oxidation of Nitrites on Solid Electrodes
journal, January 2002

  • Piela, Barbara; Wrona, Piotr K.
  • Journal of The Electrochemical Society, Vol. 149, Issue 2
  • DOI: 10.1149/1.1433751

Nanoporous Gold Thin Film: Fabrication, Structure Evolution, and Electrocatalytic Activity
journal, December 2008

  • Dong, Hua; Cao, Xiaodong
  • The Journal of Physical Chemistry C, Vol. 113, Issue 2
  • DOI: 10.1021/jp8086607

Simple Electrochemical Detection Method Employing a Hydrogel Soft Matrix: Application in Tap Water
journal, January 2018

  • Martinez, María V.; Rodriguez, Rusbel Coneo; Bruno, Mariano M.
  • Journal of The Electrochemical Society, Vol. 165, Issue 16
  • DOI: 10.1149/2.0031816jes

Microelectrodes: new dimensions in electrochemistry
journal, January 1994

Iridium Oxide–Electrodeposited Nanoporous Gold Multielectrode Array with Enhanced Stimulus Efficacy
journal, October 2016

Nanoporous Metal (Cu, Ag, Au) Films with High Surface Area:  General Fabrication and Preliminary Electrochemical Performance
journal, June 2007

  • Jia, Falong; Yu, Chuanfang; Deng, Kejian
  • The Journal of Physical Chemistry C, Vol. 111, Issue 24
  • DOI: 10.1021/jp071815y

Surface Alloying/Dealloying in Pb/Au(111) System
journal, April 2010

  • Nutariya, Jeerapat; Velleuer, Jonathan; Schwarzacher, Walther
  • ECS Transactions, Vol. 28, Issue 25
  • DOI: 10.1149/1.3492097

Nanostructured Platinum-iridium Alloy Microelectrode for Ammonia Determination
journal, June 2017

Fabrication of Nanoporous Gold Film Electrodes with Ultrahigh Surface Area and Electrochemical Activity
journal, July 2007

  • Jia, Falong; Yu, Chuanfang; Ai, Zhihui
  • Chemistry of Materials, Vol. 19, Issue 15
  • DOI: 10.1021/cm070425l

Nanostructured gold microelectrodes for extracellular recording from electrogenic cells
journal, May 2011

Review—The Development of Gas Sensor Based on Carbon Nanotubes
journal, January 2016

  • Septiani, Ni Luh Wulan; Yuliarto, Brian
  • Journal of The Electrochemical Society, Vol. 163, Issue 3
  • DOI: 10.1149/2.0591603jes

Steady-State Voltammetric Response of the Nanopore Electrode
journal, January 2006

  • Zhang, Bo; Zhang, Yanhui; White, Henry S.
  • Analytical Chemistry, Vol. 78, Issue 2
  • DOI: 10.1021/ac051330a

Evolution of nanoporosity in dealloying
journal, March 2001

  • Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain
  • Nature, Vol. 410, Issue 6827, p. 450-453
  • DOI: 10.1038/35068529

Nanotechnology: from In Vivo Imaging System to Controlled Drug Delivery
journal, August 2017

The electrochemical behaviour of the Pr(III)/Pr redox system at Bi and Cd liquid electrodes in molten eutectic LiCl–KCl
journal, June 2005

Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations
journal, January 2018

  • Jeevanandam, Jaison; Barhoum, Ahmed; Chan, Yen S.
  • Beilstein Journal of Nanotechnology, Vol. 9
  • DOI: 10.3762/bjnano.9.98

Impedance Analysis of a Model Mechanism for Acceptor-Limited Electropolishing
journal, January 1994

  • Matlosz, M.
  • Journal of The Electrochemical Society, Vol. 141, Issue 2
  • DOI: 10.1149/1.2054741

Modeling the delamination of amorphous-silicon thin film anode for lithium-ion battery
journal, January 2014

Hierarchical nanoporous gold film electrode with extra high surface area and electrochemical activity
journal, October 2009

Electrochemical hydrogen sensor for safety monitoring
journal, November 2004

Dealloying of Ag-Au Alloys in Halide-Containing Electrolytes
journal, January 2003

  • Dursun, A.; Pugh, D. V.; Corcoran, S. G.
  • Journal of The Electrochemical Society, Vol. 150, Issue 7
  • DOI: 10.1149/1.1580824

Enhancement of Redox Cycling Currents at Interdigitated Electrodes with Elevated Fingers
journal, January 2014

  • Morita, Masao; Hayashi, Katsuyoshi; Horiuchi, Tsutomu
  • Journal of The Electrochemical Society, Vol. 161, Issue 4
  • DOI: 10.1149/2.101403jes

Flexible fiber-shaped supercapacitors based on hierarchically nanostructured composite electrodes
journal, November 2014

Nanopore-enabled electrode arrays and ensembles
journal, December 2015

Powder microelectrodes
journal, April 1994

Fabrication of Nanoporous Gold Film by Electrochemical Alloying and Dealloying with Li at Room Temperature
journal, November 2012

  • Nishio, K.; Yuda, K.; Masuda, H.
  • ECS Electrochemistry Letters, Vol. 2, Issue 1
  • DOI: 10.1149/2.009301eel

Mesoporous Microspheres Composed of PtRu Alloy
journal, April 2004

  • Jiang, Junhua; Kucernak, Anthony
  • Chemistry of Materials, Vol. 16, Issue 7
  • DOI: 10.1021/cm035237j

Ni nanotube array-based electrodes by electrochemical alloying and de-alloying for efficient water splitting
journal, January 2018

  • Teng, Xue; Wang, Jianying; Ji, Lvlv
  • Nanoscale, Vol. 10, Issue 19
  • DOI: 10.1039/C8NR02238K

Formation of Nanoporous Nickel by Selective Anodic Etching of the Nobler Copper Component from Electrodeposited Nickel−Copper Alloys
journal, February 2008

  • Chang, Jeng-Kuei; Hsu, Shih-Hsun; Sun, I-Wen
  • The Journal of Physical Chemistry C, Vol. 112, Issue 5
  • DOI: 10.1021/jp0772474

Electrochemical behaviors of silicon based anode material
journal, February 2006

Electrochemical analysis based on nanoporous structures
journal, January 2012

  • Park, Sangyun; Kim, Hee Chan; Chung, Taek Dong
  • The Analyst, Vol. 137, Issue 17
  • DOI: 10.1039/c2an35294j

In vitro comparison of sputtered iridium oxide and platinum-coated neural implantable microelectrode arrays
journal, February 2010

Porous Gold Films—A Short Review on Recent Progress
journal, May 2014

Fabrication of high-surface nanoporous gold microelectrode
journal, July 2012

Nanoporous gold microelectrode prepared from potential modulated electrochemical alloying–dealloying in ionic liquid
journal, November 2013

Electrochemical fabrication of nanoporous copper films in choline chloride–urea deep eutectic solvent
journal, January 2015

  • Zhang, Q. B.; Abbott, Andrew P.; Yang, C.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 22
  • DOI: 10.1039/C5CP01276G

Group IVA Element (Si, Ge, Sn)-Based Alloying/Dealloying Anodes as Negative Electrodes for Full-Cell Lithium-Ion Batteries
journal, October 2017

Nitrite reduction at powder microelectrodes
journal, July 1999

Nonenzymatic Glucose Detection Using Mesoporous Platinum
journal, July 2003

  • Park, Sejin; Chung, Taek Dong; Kim, Hee Chan
  • Analytical Chemistry, Vol. 75, Issue 13
  • DOI: 10.1021/ac0263465

Miniaturized Amperometric Glucose Sensors Based on Polymer/ Enzyme Modified Carbon Electrodes in the Sub-Micrometer Scale
journal, January 2018

  • Marquitan, Miriam; Bobrowski, Tim; Ernst, Andrzej
  • Journal of The Electrochemical Society, Vol. 165, Issue 12
  • DOI: 10.1149/2.0021812jes

Nanoporous gold supported cobalt oxide microelectrodes as high-performance electrochemical biosensors
journal, July 2013

  • Lang, Xing-You; Fu, Hong-Ying; Hou, Chao
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3169

A Non-Enzymatic Glucose Sensor based on Copper Oxide Nanowires-Single Wall Carbon Nanotubes
journal, December 2014

  • Bao, Jing; Hou, Changjun; Zhang, Yuchan
  • Journal of The Electrochemical Society, Vol. 162, Issue 3
  • DOI: 10.1149/2.1111501jes

Sensors, Chemical Sensors, Electrochemical Sensors, and ECS
journal, January 2003

  • Stetter, Joseph R.; Penrose, William R.; Yao, Sheng
  • Journal of The Electrochemical Society, Vol. 150, Issue 2
  • DOI: 10.1149/1.1539051

Electrochemistry at nanoporous interfaces: new opportunity for electrocatalysis
journal, January 2012

  • Bae, Je Hyun; Han, Ji-Hyung; Chung, Taek Dong
  • Phys. Chem. Chem. Phys., Vol. 14, Issue 2
  • DOI: 10.1039/C1CP22927C

Improved Anodic Stripping Voltammetric Detection of Arsenic (III) Using Nanoporous Gold Microelectrode
journal, January 2015

  • Jiang, Junhua; Holm, Nancy; O'Brien, Kevin
  • ECS Journal of Solid State Science and Technology, Vol. 4, Issue 10
  • DOI: 10.1149/2.0061510jss

Nanoporous Pt Microelectrode for Neural Stimulation and Recording: In Vitro Characterization
journal, April 2010

  • Park, Sejin; Song, Youn Joo; Boo, Hankil
  • The Journal of Physical Chemistry C, Vol. 114, Issue 19
  • DOI: 10.1021/jp911256h
    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: