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Title: Evidence for interfacial geometric interactions at metal–support interfaces and their influence on the electroactivity and stability of Pt nanoparticles

Abstract

We present evidence for long-range interfacial geometric interactions at metal–support interfaces by a combination of atomic scale and in situ characterizations.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2]; ORCiD logo [2]; ORCiD logo [2];  [3];  [3];  [4]; ORCiD logo [5]; ORCiD logo [3]
  1. Innovation Research Center for Fuel Cells, The University of Electro-Communications, Chofu, Japan
  2. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
  3. Department of Chemical Engineering, University of Waterloo, Waterloo, Canada
  4. Japan Synchrotron Radiation Research Institute, Sayo, Japan
  5. (Feng) [Department of Chemical and Petroleum Engineering, University of Kansas, Lawrence, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1580771
Grant/Contract Number:  
SC0014561
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 3; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zhao, Xiao, Gunji, Takao, Kaneko, Takuma, Takao, Shinobu, Sakata, Tomohiro, Higashi, Kotaro, Yoshida, Yusuke, Ge, Junjie, Liu, Changpeng, Xing, Wei, Zhu, Jianbing, Xiao, Meiling, Uruga, Tomoya, Tao, Franklin, and Chen, Zhongwei. Evidence for interfacial geometric interactions at metal–support interfaces and their influence on the electroactivity and stability of Pt nanoparticles. United Kingdom: N. p., 2020. Web. doi:10.1039/C9TA12456J.
Zhao, Xiao, Gunji, Takao, Kaneko, Takuma, Takao, Shinobu, Sakata, Tomohiro, Higashi, Kotaro, Yoshida, Yusuke, Ge, Junjie, Liu, Changpeng, Xing, Wei, Zhu, Jianbing, Xiao, Meiling, Uruga, Tomoya, Tao, Franklin, & Chen, Zhongwei. Evidence for interfacial geometric interactions at metal–support interfaces and their influence on the electroactivity and stability of Pt nanoparticles. United Kingdom. doi:10.1039/C9TA12456J.
Zhao, Xiao, Gunji, Takao, Kaneko, Takuma, Takao, Shinobu, Sakata, Tomohiro, Higashi, Kotaro, Yoshida, Yusuke, Ge, Junjie, Liu, Changpeng, Xing, Wei, Zhu, Jianbing, Xiao, Meiling, Uruga, Tomoya, Tao, Franklin, and Chen, Zhongwei. Wed . "Evidence for interfacial geometric interactions at metal–support interfaces and their influence on the electroactivity and stability of Pt nanoparticles". United Kingdom. doi:10.1039/C9TA12456J.
@article{osti_1580771,
title = {Evidence for interfacial geometric interactions at metal–support interfaces and their influence on the electroactivity and stability of Pt nanoparticles},
author = {Zhao, Xiao and Gunji, Takao and Kaneko, Takuma and Takao, Shinobu and Sakata, Tomohiro and Higashi, Kotaro and Yoshida, Yusuke and Ge, Junjie and Liu, Changpeng and Xing, Wei and Zhu, Jianbing and Xiao, Meiling and Uruga, Tomoya and Tao, Franklin and Chen, Zhongwei},
abstractNote = {We present evidence for long-range interfacial geometric interactions at metal–support interfaces by a combination of atomic scale and in situ characterizations.},
doi = {10.1039/C9TA12456J},
journal = {Journal of Materials Chemistry. A},
number = 3,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {1}
}

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Works referenced in this record:

Determination of O and OH Adsorption Sites and Coverage in Situ on Pt Electrodes from Pt L 23 X-ray Absorption Spectroscopy
journal, April 2005

  • Teliska, M.; O'Grady, W. E.; Ramaker, D. E.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 16
  • DOI: 10.1021/jp0502003

Insights into Interfacial Synergistic Catalysis over Ni@TiO 2– x Catalyst toward Water–Gas Shift Reaction
journal, July 2018

  • Xu, Ming; Yao, Siyu; Rao, Deming
  • Journal of the American Chemical Society, Vol. 140, Issue 36
  • DOI: 10.1021/jacs.8b03117

Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure
journal, April 2006

  • Stamenkovic, Vojislav; Mun, Bongjin Simon; Mayrhofer, Karl J. J.
  • Angewandte Chemie International Edition, Vol. 45, Issue 18
  • DOI: 10.1002/anie.200504386

Direct and continuous strain control of catalysts with tunable battery electrode materials
journal, November 2016


Size-dependent dynamic structures of supported gold nanoparticles in CO oxidation reaction condition
journal, July 2018

  • He, Yang; Liu, Jin-Cheng; Luo, Langli
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 30
  • DOI: 10.1073/pnas.1800262115

The role of Copper–Ceria interactions in catalysis science: Recent theoretical and experimental advances
journal, December 2016


Metal and Metal Oxide Interactions and Their Catalytic Consequences for Oxygen Reduction Reaction
journal, June 2017

  • Jia, Qingying; Ghoshal, Shraboni; Li, Jingkun
  • Journal of the American Chemical Society, Vol. 139, Issue 23
  • DOI: 10.1021/jacs.7b02378

Interfacial Effects of CeO 2 -Supported Pd Nanorod in Catalytic CO Oxidation: A Theoretical Study
journal, May 2015


Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
journal, February 2014


Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs
journal, March 2005

  • Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar
  • Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35
  • DOI: 10.1016/j.apcatb.2004.06.021

Lattice Strain Mapping of Platinum Nanoparticles on Carbon and SnO2 Supports
journal, August 2015

  • Daio, Takeshi; Staykov, Aleksandar; Guo, Limin
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep13126

A Theory/Experience Description of Support Effects in Carbon-Supported Catalysts
journal, October 2019


Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts
journal, September 2016

  • Matsubu, John C.; Zhang, Shuyi; DeRita, Leo
  • Nature Chemistry, Vol. 9, Issue 2
  • DOI: 10.1038/nchem.2607

Coordination-dependent surface atomic contraction in nanocrystals revealed by coherent diffraction
journal, March 2008

  • Huang, W. J.; Sun, R.; Tao, J.
  • Nature Materials, Vol. 7, Issue 4
  • DOI: 10.1038/nmat2132

Strain-controlled electrocatalysis on multimetallic nanomaterials
journal, September 2017


An Integrated Single-Electrode Method Reveals the Template Roles of Atomic Steps: Disturb Interfacial Water Networks and Thus Affect the Reactivity of Electrocatalysts
journal, May 2019

  • Zhao, Xiao; Gunji, Takao; Kaneko, Takuma
  • Journal of the American Chemical Society, Vol. 141, Issue 21
  • DOI: 10.1021/jacs.9b02049

Surface-Regulated Nano-SnO 2 /Pt 3 Co/C Cathode Catalysts for Polymer Electrolyte Fuel Cells Fabricated by a Selective Electrochemical Sn Deposition Method
journal, September 2015

  • Nagasawa, Kensaku; Takao, Shinobu; Nagamatsu, Shin-ichi
  • Journal of the American Chemical Society, Vol. 137, Issue 40
  • DOI: 10.1021/jacs.5b04256

Charge Transfer in Metal Catalysts Supported on Doped TiO2: A Theoretical Approach Based on Metal–Semiconductor Contact Theory
journal, July 1996

  • Ioannides, Theophilos; Verykios, Xenophon E.
  • Journal of Catalysis, Vol. 161, Issue 2
  • DOI: 10.1006/jcat.1996.0218

High Stability, High Activity Pt/ITO Oxygen Reduction Electrocatalysts
journal, December 2012

  • Liu, Ying; Mustain, William E.
  • Journal of the American Chemical Society, Vol. 135, Issue 2
  • DOI: 10.1021/ja307635r

Platinum-Based Nanostructured Materials: Synthesis, Properties, and Applications
journal, June 2010

  • Chen, Aicheng; Holt-Hindle, Peter
  • Chemical Reviews, Vol. 110, Issue 6
  • DOI: 10.1021/cr9003902

Interaction of nanometer-sized gold nanocrystals with rutile (110) surface steps revealed at atomic resolution
journal, July 2014


Acid-Promoter-Free Ethylene Methoxycarbonylation over Ru-Clusters/Ceria: The Catalysis of Interfacial Lewis Acid–Base Pair
journal, February 2018

  • An, Jinghua; Wang, Yehong; Lu, Jianmin
  • Journal of the American Chemical Society, Vol. 140, Issue 11
  • DOI: 10.1021/jacs.8b01742

Tuning the Electronic Properties of Single-Atom Pt Catalysts by Functionalization of the Carbon Support Material
journal, September 2017

  • Mahmoodinia, Mehdi; Åstrand, Per-Olof; Chen, De
  • The Journal of Physical Chemistry C, Vol. 121, Issue 38
  • DOI: 10.1021/acs.jpcc.7b05894

Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction
journal, November 2016


Electrocatalyst approaches and challenges for automotive fuel cells
journal, June 2012


Highly corrosion resistant platinum–niobium oxide–carbon nanotube electrodes for the oxygen reduction in PEM fuel cells
journal, January 2012

  • Zhang, Li; Wang, Liya; Holt, Chris M. B.
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee02689a

Oxygen Reduction Reaction Activity and Electrochemical Stability of Thin-Film Bilayer Systems of Platinum on Niobium Oxide
journal, September 2010

  • Zhang, Li; Wang, Liya; Holt, Chris M. B.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 39
  • DOI: 10.1021/jp104306j

Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts
journal, April 2010

  • Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli
  • Nature Chemistry, Vol. 2, Issue 6
  • DOI: 10.1038/nchem.623

Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability
journal, January 2007

  • Stamenkovic, V. R.; Fowler, B.; Mun, B. S.
  • Science, Vol. 315, Issue 5811, p. 493-497
  • DOI: 10.1126/science.1135941

Surface and interface stress effects in thin films
journal, May 1994


Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
journal, February 2016


Batteries and fuel cells for emerging electric vehicle markets
journal, April 2018


Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015

  • Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
  • Angewandte Chemie International Edition, Vol. 54, Issue 15
  • DOI: 10.1002/anie.201411581

Influence of Carbon Support on Electronic Structure and Catalytic Activity of Pt Catalysts: Binding to the CO Molecule
journal, June 2016

  • Mahmoodinia, Mehdi; Åstrand, Per-Olof; Chen, De
  • The Journal of Physical Chemistry C, Vol. 120, Issue 23
  • DOI: 10.1021/acs.jpcc.6b02001

Structural and electronic properties of the Pt n –PAH complex (n = 1, 2) from density functional calculations
journal, January 2014

  • Mahmoodinia, Mehdi; Ebadi, Mahsa; Åstrand, Per-Olof
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 34
  • DOI: 10.1039/C4CP02488E

Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells
journal, November 2019


Combining In-Situ Transmission Electron Microscopy and Infrared Spectroscopy for Understanding Dynamic and Atomic-Scale Features of Supported Metal Catalysts
journal, June 2018

  • Resasco, Joaquin; Dai, Sheng; Graham, George
  • The Journal of Physical Chemistry C, Vol. 122, Issue 44
  • DOI: 10.1021/acs.jpcc.8b03959

Understanding Catalytic Activity Trends in the Oxygen Reduction Reaction
journal, December 2017


Decoupling the electronic, geometric and interfacial contributions to support effects in heterogeneous catalysis
journal, June 2014


Oriented Catalytic Platinum Nanoparticles on High Surface Area Strontium Titanate Nanocuboids
journal, March 2011

  • Enterkin, James A.; Poeppelmeier, Kenneth R.; Marks, Laurence D.
  • Nano Letters, Vol. 11, Issue 3
  • DOI: 10.1021/nl104263j

High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction
journal, June 2015


Effect of chemical environment on magnitude of x‐ray absorption resonance at L I I I edges. Studies on metallic elements, compounds, and catalysts
journal, June 1979

  • Lytle, F. W.; Wei, P. S. P.; Greegor, R. B.
  • The Journal of Chemical Physics, Vol. 70, Issue 11
  • DOI: 10.1063/1.437376

Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges
journal, April 2012

  • Rabis, Annett; Rodriguez, Paramaconi; Schmidt, Thomas J.
  • ACS Catalysis, Vol. 2, Issue 5
  • DOI: 10.1021/cs3000864

Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
journal, January 1978

  • Tauster, S. J.; Fung, S. C.; Garten, R. L.
  • Journal of the American Chemical Society, Vol. 100, Issue 1
  • DOI: 10.1021/ja00469a029

Understanding the electrocatalysis of oxygen reduction on platinum and its alloys
journal, January 2012

  • Stephens, Ifan E. L.; Bondarenko, Alexander S.; Grønbjerg, Ulrik
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee03590a

Coexistence of interfacial stress and charge transfer in graphene oxide-based magnetic nanocomposites
journal, April 2017

  • Mishra, Amodini; Singh, Vikash Kumar; Mohanty, Tanuja
  • Journal of Materials Science, Vol. 52, Issue 13
  • DOI: 10.1007/s10853-017-1062-1

Enhanced activity of Pt nano-crystals supported on a novel TiO2@N-doped C nano-composite for methanol oxidation reaction
journal, January 2012

  • Zhao, Xiao; Zhu, Jianbing; Liang, Liang
  • Journal of Materials Chemistry, Vol. 22, Issue 37
  • DOI: 10.1039/c2jm33926a

A molecular orbital study of strong metal-support interaction between platinum and titanium dioxide
journal, May 1979

  • Horsley, J. A.
  • Journal of the American Chemical Society, Vol. 101, Issue 11
  • DOI: 10.1021/ja00505a011

Effect of carbon nanofiber-induced microstrain on the catalytic activity of Ni crystals
journal, April 2004


Icosahedral Platinum Alloy Nanocrystals with Enhanced Electrocatalytic Activities
journal, July 2012

  • Wu, Jianbo; Qi, Liang; You, Hongjun
  • Journal of the American Chemical Society, Vol. 134, Issue 29
  • DOI: 10.1021/ja303950v

Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
journal, November 2004

  • Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 46
  • DOI: 10.1021/jp047349j

Universality in Oxygen Reduction Electrocatalysis on Metal Surfaces
journal, July 2012

  • Viswanathan, Venkatasubramanian; Hansen, Heine Anton; Rossmeisl, Jan
  • ACS Catalysis, Vol. 2, Issue 8
  • DOI: 10.1021/cs300227s

Combining theory and experiment in electrocatalysis: Insights into materials design
journal, January 2017


Role of Structural and Electronic Properties of Pt and Pt Alloys on Electrocatalysis of Oxygen Reduction
journal, January 1995

  • Mukerjee, Sanjeev; Srinivasan, Supramaniam; Soriaga, Manuel P.
  • Journal of The Electrochemical Society, Vol. 142, Issue 5, p. 1409-1422
  • DOI: 10.1149/1.2048590

First-principles study of metal adatom adsorption on graphene
journal, June 2008


Geometrical flexibility of platinum nanoclusters: impacts on catalytic decomposition of ethylene glycol
journal, January 2017

  • Mahmoodinia, Mehdi; Trinh, Thuat T.; Åstrand, Per-Olof
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 42
  • DOI: 10.1039/C7CP04485B

Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
journal, September 2009

  • Greeley, J.; Stephens, I. E. L.; Bondarenko, A. S.
  • Nature Chemistry, Vol. 1, Issue 7, p. 552-556
  • DOI: 10.1038/nchem.367

Strong metal-support interactions
journal, November 1987