skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on December 18, 2020

Title: Morphology control of metal-modified zirconium phosphate support structures for the oxygen evolution reaction

Abstract

The morphology of ZrP supports affects the loading and coverage of Co and Ni species, explaining their different OER performances.

Authors:
 [1]; ORCiD logo [2];  [1];  [3]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry, University of Puerto Rico at Río Piedras, San Juan, USA, PREM Center for Interfacial Electrochemistry of Energy Materials
  2. Department of Chemical Engineering, Stanford University, Stanford, USA, SUNCAT Center for Interface Science and Catalysis
  3. Department of Chemistry, University of Puerto Rico at Río Piedras, San Juan, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1580766
Grant/Contract Number:  
AC02-76SF00515
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Ramos-Garcés, Mario V., Sanchez, Joel, La Luz-Rivera, Kálery, Del Toro-Pedrosa, Daniel E., Jaramillo, Thomas F., and Colón, Jorge L. Morphology control of metal-modified zirconium phosphate support structures for the oxygen evolution reaction. United Kingdom: N. p., 2020. Web. doi:10.1039/C9DT04135D.
Ramos-Garcés, Mario V., Sanchez, Joel, La Luz-Rivera, Kálery, Del Toro-Pedrosa, Daniel E., Jaramillo, Thomas F., & Colón, Jorge L. Morphology control of metal-modified zirconium phosphate support structures for the oxygen evolution reaction. United Kingdom. doi:10.1039/C9DT04135D.
Ramos-Garcés, Mario V., Sanchez, Joel, La Luz-Rivera, Kálery, Del Toro-Pedrosa, Daniel E., Jaramillo, Thomas F., and Colón, Jorge L. Wed . "Morphology control of metal-modified zirconium phosphate support structures for the oxygen evolution reaction". United Kingdom. doi:10.1039/C9DT04135D.
@article{osti_1580766,
title = {Morphology control of metal-modified zirconium phosphate support structures for the oxygen evolution reaction},
author = {Ramos-Garcés, Mario V. and Sanchez, Joel and La Luz-Rivera, Kálery and Del Toro-Pedrosa, Daniel E. and Jaramillo, Thomas F. and Colón, Jorge L.},
abstractNote = {The morphology of ZrP supports affects the loading and coverage of Co and Ni species, explaining their different OER performances.},
doi = {10.1039/C9DT04135D},
journal = {Dalton Transactions},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on December 18, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices
journal, March 2015

  • McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M.
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/ja510442p

Transition Metal-Modified Zirconium Phosphate Electrocatalysts for the Oxygen Evolution Reaction
journal, May 2017

  • Sanchez, Joel; Ramos-Garcés, Mario V.; Narkeviciute, Ieva
  • Catalysts, Vol. 7, Issue 12
  • DOI: 10.3390/catal7050132

Direct Preparation of θ-Zirconium Phosphate
journal, September 1982

  • Kijima, Tsuyoshi
  • Bulletin of the Chemical Society of Japan, Vol. 55, Issue 9
  • DOI: 10.1246/bcsj.55.3031

Revised Oxygen Evolution Reaction Activity Trends for First-Row Transition-Metal (Oxy)hydroxides in Alkaline Media
journal, August 2015

  • Burke, Michaela S.; Zou, Shihui; Enman, Lisa J.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 18
  • DOI: 10.1021/acs.jpclett.5b01650

Nanoencapsulation of Insulin into Zirconium Phosphate for Oral Delivery Applications
journal, September 2010

  • Díaz, Agustín; David, Amanda; Pérez, Riviam
  • Biomacromolecules, Vol. 11, Issue 9
  • DOI: 10.1021/bm100659p

Room-Temperature Emission from Platinum(II) Complexes Intercalated into Zirconium Phosphate-Layered Materials
journal, October 2007

  • Rivera, Eladio J.; Figueroa, Cristina; Colón, Jorge L.
  • Inorganic Chemistry, Vol. 46, Issue 21
  • DOI: 10.1021/ic7006183

Impact of Nanostructuring on the Photoelectrochemical Performance of Si/Ta 3 N 5 Nanowire Photoanodes
journal, December 2017

  • Narkeviciute, Ieva; Jaramillo, Thomas F.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 49
  • DOI: 10.1021/acs.jpcc.7b08690

Nanostructured Manganese Oxide Supported onto Particulate Glassy Carbon as an Active and Stable Oxygen Reduction Catalyst in Alkaline-Based Fuel Cells
journal, January 2014

  • Ng, Jia Wei Desmond; Gorlin, Yelena; Nordlund, Dennis
  • Journal of The Electrochemical Society, Vol. 161, Issue 7
  • DOI: 10.1149/2.014407jes

Minimalistic Liquid-Assisted Route to Highly Crystalline α-Zirconium Phosphate
journal, July 2017

  • Cheng, Yu; Wang, Xiaodong Tony; Jaenicke, Stephan
  • ChemSusChem, Vol. 10, Issue 16
  • DOI: 10.1002/cssc.201700885

Vapochromic and vapoluminescent response of materials based on platinum(ii) complexes intercalated into layered zirconium phosphate
journal, January 2011

  • Rivera, Eladio J.; Barbosa, Cindy; Torres, Rafael
  • Journal of Materials Chemistry, Vol. 21, Issue 40
  • DOI: 10.1039/C1JM12053K

Mechanism of ion exchange in zirconium phosphates. 20. Refinement of the crystal structure of .alpha.-zirconium phosphate
journal, December 1977


Benchmarking nanoparticulate metal oxide electrocatalysts for the alkaline water oxidation reaction
journal, January 2016

  • Jung, Suho; McCrory, Charles C. L.; Ferrer, Ivonne M.
  • Journal of Materials Chemistry A, Vol. 4, Issue 8
  • DOI: 10.1039/C5TA07586F

The synthesis and applications of α-zirconium phosphate
journal, April 2019


Zirconium phosphate (ZrP)-based functional materials: Synthesis, properties and applications
journal, October 2018


Direct intercalation of cisplatin into zirconium phosphate nanoplatelets for potential cancer nanotherapy
journal, January 2013

  • Díaz, Agustín; González, Millie L.; Pérez, Riviam J.
  • Nanoscale, Vol. 5, Issue 23
  • DOI: 10.1039/c3nr02206d

The preparation of crystalline zirconium phosphate and some observations on its ion exchange behaviour
journal, January 1964


Do the Evaluation Parameters Reflect Intrinsic Activity of Electrocatalysts in Electrochemical Water Splitting?
journal, May 2019


Materials for solar fuels and chemicals
journal, December 2016

  • Montoya, Joseph H.; Seitz, Linsey C.; Chakthranont, Pongkarn
  • Nature Materials, Vol. 16, Issue 1
  • DOI: 10.1038/nmat4778

The infrared and Raman spectra of α-zirconium phosphate
journal, February 1974

  • Horsley, S. E.; Nowell, D. V.; Stewart, D. T.
  • Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 30, Issue 2
  • DOI: 10.1016/0584-8539(74)80093-0

Poly(ethylene glycol)-modified zirconium phosphate nanoplatelets for improved doxorubicin delivery
journal, November 2017

  • González-Villegas, Julissa; Kan, Yuwei; Bakhmutov, Vladimir I.
  • Inorganica Chimica Acta, Vol. 468
  • DOI: 10.1016/j.ica.2017.05.057

X-ray powder diffraction data for a new compound (NH 4 )H 2 Co 2 O(OH)(MoO 4 ) 1.6 (WO 4 ) 0.4 •H 2 O type ϕ y
journal, September 2018


NADH Electrooxidation Using Bis(1,10-phenanthroline-5,6-dione)(2,2′-bipyridine)ruthenium(II)-Exchanged Zirconium Phosphate Modified Carbon Paste Electrodes
journal, March 2006

  • Santiago, Mitk'El B.; Vélez, Meredith M.; Borrero, Solmarie
  • Electroanalysis, Vol. 18, Issue 6
  • DOI: 10.1002/elan.200503432

Layered Metal(IV) Phosphonates with Rigid Pendant Groups: New Synthetic Approaches to Nanosized Zirconium Phosphate Phenylphosphonates
journal, December 2013

  • Pica, Monica; Donnadio, Anna; D’Amato, Roberto
  • Inorganic Chemistry, Vol. 53, Issue 4
  • DOI: 10.1021/ic402884g

Synthesis of spherical mesostructured zirconium phosphate with acidic properties
journal, October 2006


Inorganic Ion Exchangers with Layered Structures
journal, August 1984


Direct Ion Exchange of Tris(2,2‘-bipyridine)ruthenium(II) into an α-Zirconium Phosphate Framework
journal, May 2003

  • Martí, Angel A.; Colón, Jorge L.
  • Inorganic Chemistry, Vol. 42, Issue 9
  • DOI: 10.1021/ic025548g

Nanostructuring Strategies To Increase the Photoelectrochemical Water Splitting Activity of Silicon Photocathodes
journal, January 2019

  • Hellstern, Thomas R.; Nielander, Adam C.; Chakthranont, Pongkarn
  • ACS Applied Nano Materials, Vol. 2, Issue 1
  • DOI: 10.1021/acsanm.8b01966

Layered Inorganic Materials as Redox Agents:  Ferrocenium-Intercalated Zirconium Phosphate
journal, July 2007

  • Santiago, Mitk'El B.; Declet-Flores, Chasterie; Díaz, Agustín
  • Langmuir, Vol. 23, Issue 14
  • DOI: 10.1021/la7005309

Luminescence Rigidochromism and Redox Chemistry of Pyrazolate-Bridged Binuclear Platinum(II) Diimine Complex Intercalated into Zirconium Phosphate Layers
journal, February 2012

  • Rivera, Eladio J.; Barbosa, Cindy; Torres, Rafael
  • Inorganic Chemistry, Vol. 51, Issue 5
  • DOI: 10.1021/ic201423q

Molybdocene dichloride intercalation into zirconium phosphate nanoparticles
journal, August 2015


Layered and pillared metal(IV) phosphates and phosphonates
journal, April 1996

  • Alberti, Giulio; Casciola, Mario; Costantino, Umberto
  • Advanced Materials, Vol. 8, Issue 4
  • DOI: 10.1002/adma.19960080405

Immobilization of ionic liquids in θ-zirconium phosphate for catalyzing the coupling of CO2 and epoxides
journal, January 2012

  • Hu, Hang; Martin, Jarett C.; Zhang, Meng
  • RSC Advances, Vol. 2, Issue 9
  • DOI: 10.1039/c2ra00015f

Surface Engineering of 3D Gas Diffusion Electrodes for High‐Performance H 2 Production with Nonprecious Metal Catalysts
journal, September 2019

  • Sanchez, Joel; Hellstern, Thomas R.; King, Laurie A.
  • Advanced Energy Materials, Vol. 9, Issue 40
  • DOI: 10.1002/aenm.201901824

Preparation of α-zirconium phosphate nanoplatelets with wide variations in aspect ratios
journal, January 2007

  • Sun, Luyi; Boo, Woong J.; Sue, Hung-Jue
  • New J. Chem., Vol. 31, Issue 1
  • DOI: 10.1039/B604054C

Cobalt-Bridged Ionic Liquid Polymer on a Carbon Nanotube for Enhanced Oxygen Evolution Reaction Activity
journal, February 2018

  • Ding, Yuxiao; Klyushin, Alexander; Huang, Xing
  • Angewandte Chemie International Edition, Vol. 57, Issue 13
  • DOI: 10.1002/anie.201711688

Small is Beautiful: The Unusual Transformation of Nanocrystalline Layered α-Zirconium Phosphate into a New 3D Structure
journal, August 2015


Cobalt oxide nanosheets anchored onto nitrogen-doped carbon nanotubes as dual purpose electrodes for lithium-ion batteries and oxygen evolution reaction
journal, September 2017

  • Wu, Jian; Liu, Yongqiang; Geng, Dongsheng
  • International Journal of Energy Research, Vol. 42, Issue 2
  • DOI: 10.1002/er.3862

Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
journal, January 2015

  • Jiao, Yan; Zheng, Yao; Jaroniec, Mietek
  • Chemical Society Reviews, Vol. 44, Issue 8
  • DOI: 10.1039/C4CS00470A

Synthesis and characterization of self-assembling (NH4)0.5V2O5 nanowires
journal, January 2004

  • Wu, Xingcai; Tao, Yourong; Dong, Lin
  • Journal of Materials Chemistry, Vol. 14, Issue 5
  • DOI: 10.1039/B314775D

Nanostructured catalysts for electrochemical water splitting: current state and prospects
journal, January 2016

  • Li, Xiumin; Hao, Xiaogang; Abudula, Abuliti
  • Journal of Materials Chemistry A, Vol. 4, Issue 31
  • DOI: 10.1039/C6TA02334G

Sulfonic Acid-Functionalized α-Zirconium Phosphate Single-Layer Nanosheets as a Strong Solid Acid for Heterogeneous Catalysis Applications
journal, April 2014

  • Zhou, Yingjie; Huang, Rongcai; Ding, Fuchuan
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 10
  • DOI: 10.1021/am5008408

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013

  • McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja407115p

Highly durable and active Co3O4 nanocrystals supported on carbon nanotubes as bifunctional electrocatalysts in alkaline media
journal, April 2017


Core–Shell Au@Metal-Oxide Nanoparticle Electrocatalysts for Enhanced Oxygen Evolution
journal, September 2017

  • Strickler, Alaina L.; Escudero-Escribano, Marı́a; Jaramillo, Thomas F.
  • Nano Letters, Vol. 17, Issue 10
  • DOI: 10.1021/acs.nanolett.7b02357

Zirconium Phosphate: The Pathway from Turbostratic Disorder to Crystallinity
journal, October 2019


Transition Metal-Modified Exfoliated Zirconium Phosphate as an Electrocatalyst for the Oxygen Evolution Reaction
journal, April 2019

  • Ramos-Garcés, Mario V.; Sanchez, Joel; Del Toro-Pedrosa, Daniel E.
  • ACS Applied Energy Materials, Vol. 2, Issue 5
  • DOI: 10.1021/acsaem.9b00299

Zirconium and titanium phosphates as catalysts: a review
journal, January 1986


Effect of Enzyme and Cofactor Immobilization on the Response of Ethanol Oxidation in Zirconium Phosphate Modified Biosensors
journal, March 2010

  • Santiago, Mitk'El B.; Daniel, Gabriel A.; David, Amanda
  • Electroanalysis, Vol. 22, Issue 10
  • DOI: 10.1002/elan.200900329

Combining theory and experiment in electrocatalysis: Insights into materials design
journal, January 2017