Reversible coordinative binding and separation of sulfur dioxide in a robust metal–organic framework with open copper sites

Smith, Gemma L.; Eyley, Jennifer E.; Han, Xue; Zhang, Xinran; Li, Jiangnan; Jacques, Nicholas M.; Godfrey, Harry G. W.; Argent, Stephen P.; McCormick McPherson, Laura J.; Teat, Simon J.; Cheng, Yongqiang; Frogley, Mark D.; Cinque, Gianfelice; Day, Sarah J.; Tang, Chiu C.; Easun, Timothy L.; Rudić, Svemir; Ramirez-Cuesta, Anibal J.; Yang, Sihai; Schröder, Martin

doi:10.1038/s41563-019-0495-0

Title: Reversible coordinative binding and separation of sulfur dioxide in a robust metal–organic framework with open copper sites

Journal Article · 14 October 2019 · Nature Materials

DOI: https://doi.org/10.1038/s41563-019-0495-0 · OSTI ID:1580420

^[1]; Eyley, Jennifer E. ^[1]; Han, Xue ^[1]; Zhang, Xinran ^[1]; Li, Jiangnan ^[1]; Jacques, Nicholas M. ^[1]; Godfrey, Harry G. W. ^[1]; Argent, Stephen P. ^[2]; McCormick McPherson, Laura J. ^[3];

^[3]; Cheng, Yongqiang ^[4];

^[5]; Cinque, Gianfelice ^[5]; Day, Sarah J. ^[5]; Tang, Chiu C. ^[5];

^[6]; Rudić, Svemir ^[7];

^[4];

^[1];

^[1]

Univ. of Manchester, Manchester (United Kingdom)
Univ. of Nottingham, Nottingham (United Kingdom)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Diamond Light Source, Didcot (United Kingdom)
Cardiff Univ., Cardiff (United Kingdom)
STFC Rutherford Appleton Lab., Chilton (United Kingdom)

Emissions of SO₂ from flue gas and marine transport have detrimental impacts on the environment and human health, but SO₂ is also an important industrial feedstock if it can be recovered, stored and transported efficiently. In this paper, we report the exceptional adsorption and separation of SO₂ in a porous material, [Cu₂(L)] (H₄L = 4',4'''-(pyridine-3,5-diyl)bis([1,1'-biphenyl]-3,5-dicarboxylic acid)), MFM-170. MFM-170 exhibits fully reversible SO₂ uptake of 17.5 mmol g^-1 at 298 K and 1.0 bar, and the SO₂ binding domains for trapped molecules within MFM-170 have been determined. We report the reversible coordination of SO₂ to open Cu(II) sites, which contributes to excellent adsorption thermodynamics and selectivities for SO₂ binding and facile regeneration of MFM-170 after desorption. MFM-170 is stable to water, acid and base and shows great promise for the dynamic separation of SO₂ from simulated flue gas mixtures, as confirmed by breakthrough experiments.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1580420

Journal Information:: Nature Materials, Journal Name: Nature Materials Journal Issue: 12 Vol. 18; ISSN 1476-1122

Publisher:: Springer Nature - Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Reversible coordinative binding and separation of sulfur dioxide in a robust metal–organic framework with open copper sites

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